CN112608688A - UV adhesive and application thereof - Google Patents

UV adhesive and application thereof Download PDF

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Publication number
CN112608688A
CN112608688A CN202011515921.3A CN202011515921A CN112608688A CN 112608688 A CN112608688 A CN 112608688A CN 202011515921 A CN202011515921 A CN 202011515921A CN 112608688 A CN112608688 A CN 112608688A
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CN
China
Prior art keywords
acrylate
methyl
parts
monomer
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011515921.3A
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Chinese (zh)
Inventor
赵宇斌
刘海鹏
黄欣怡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Saimeisi Polymer Technology Co ltd
Original Assignee
Suzhou Saimeisi Polymer Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Saimeisi Polymer Technology Co ltd filed Critical Suzhou Saimeisi Polymer Technology Co ltd
Priority to CN202011515921.3A priority Critical patent/CN112608688A/en
Publication of CN112608688A publication Critical patent/CN112608688A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21KNON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K9/00Light sources using semiconductor devices as light-generating elements, e.g. using light-emitting diodes [LED] or lasers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21YINDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
    • F21Y2115/00Light-generating elements of semiconductor light sources
    • F21Y2115/10Light-emitting diodes [LED]

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Engineering & Computer Science (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a UV adhesive which comprises the following components in parts by weight: 20-80 parts of UV oligomer, 10-60 parts of UV functional monomer, 1-5 parts of photoinitiator, 0.1-5 parts of auxiliary agent and 1-10 parts of functional filler. The UV oligomer comprises one or a combination of polyurethane (methyl) acrylate, polyester (methyl) acrylate, polyether (methyl) acrylate, epoxy (methyl) acrylate, polyolefin modified (methyl) acrylate, silane modified (methyl) acrylate and pure acrylate. The UV functional monomer is an active monomer which can be initiated to polymerize by a photoinitiator, and comprises one or a combination of (methyl) acrylic acid monomer, olefin monomer, vinyl ether monomer and allyl monomer. The UV adhesive disclosed by the invention has the characteristics of high light transmittance, high curing speed, tough adhesive layer, vibration resistance, good stability, good weather resistance, good insulativity, high temperature resistance, water resistance, high hardness and the like, and is particularly suitable for packaging LED lamp beads.

Description

UV adhesive and application thereof
Technical Field
The invention relates to the field of LED lamps, in particular to a UV adhesive and application thereof.
Background
The TOP type LED packaging glue is mostly formed by mixing A, B two kinds of glue, stirring is needed before use, and baking is needed for 1-2 hours after glue dispensing is completed. For example, the existing packaging adhesive for TOP LEDs has the following disadvantages in the production process: the glue is generally formed by mixing A, B two kinds of glue, needs to be proportioned according to the actual glue condition according to the ratio, needs to be stirred at the same time, is relatively complex to operate, is relatively strict in ratio error, has relatively high requirement on the uniformity of glue stirring, and increases the use difficulty; after dispensing, baking is needed for curing, the curing condition is 1-2h, the productivity is easily limited, and the production cost is high.
In addition, the common problems of LED packaging adhesives in the packaging process are:
firstly, the LED is yellow, and the main reasons are:
1. the drying temperature is too high or the drying time is too long;
2. the glue preparation proportion is not correct, and the glue A is easy to yellow.
Secondly, the LED bubble problem mainly includes:
1. air bubbles in the bowl: the bracket is poor in glue dipping;
2. bracket bubble: the curing temperature is too high, and the epoxy curing is too violent;
3. cracking glue and bursting top: the curing time is short and the epoxy resin is not cured completely or uniformly. The AB glue exceeds the usable time.
Thirdly, the LED support climbs and glues, and its leading reason has:
1. the surface of the bracket is uneven, so that a capillary phenomenon is generated;
and the AB glue contains volatile materials.
Fourth, the LED encapsulation short bakes off-mold back field bake and discolours, and its reason has:
1. the stacking in the oven is too dense, and the ventilation is poor;
2. the local temperature of the oven is too high;
3. other colored contaminants are present in the oven.
In summary, there is a need to research a UV adhesive and its application in LED lamp bead packaging.
Disclosure of Invention
The UV adhesive has the characteristics of high light transmittance, high curing speed, tough adhesive layer, vibration resistance, good stability, good weather resistance, good insulativity, high temperature resistance, water resistance, high hardness and the like, and is particularly suitable for packaging LED lamps; and the LED lamp can emit light in 360 degrees in all directions when being electrified so as to increase the light emitting area and the light effect, and the LED lamp is more energy-saving and environment-friendly.
In order to achieve the technical purpose and achieve the technical effect, the invention is realized by the following technical scheme:
the UV adhesive comprises the following components in parts by weight: 20-80 parts of UV oligomer, 10-60 parts of UV functional monomer, 1-5 parts of photoinitiator, 0.1-5 parts of auxiliary agent and 1-10 parts of functional filler.
Preferably, the UV oligomer comprises one or a combination of polyurethane (meth) acrylate, polyester (meth) acrylate, polyether (meth) acrylate, epoxy (meth) acrylate, polyolefin (meth) acrylate, silane-modified (meth) acrylate and pure acrylate.
Preferably, the UV functional monomer is a reactive monomer capable of being initiated by a photoinitiator, and includes one or more of (meth) acrylic acid monomer, olefin monomer, vinyl ether monomer, and allyl monomer.
Preferably, the photoinitiator comprises one or a combination of a free radical initiator and a cationic initiator.
Preferably, the auxiliary agent comprises an adhesion promoter, a thixotropic agent, a coupling agent, a defoaming agent, a dispersing agent and a heat stabilizer; wherein the coupling agent is silane coupling agent KH550, KH560, KH570, titanate coupling agent; the thixotropic agent is one or two of fumed silica and polyamide wax.
The invention also relates to an application of the UV adhesive in LED lamp bead packaging.
The invention has the beneficial effects that:
the UV adhesive has the characteristics of high light transmittance, high curing speed, tough adhesive layer, vibration resistance, good stability, good weather resistance, good insulativity, high temperature resistance, water resistance, high hardness and the like, and is particularly suitable for packaging LED lamps; and the LED lamp can emit light in 360 degrees in all directions when being electrified so as to increase the light emitting area and the light effect, and the LED lamp is more energy-saving and environment-friendly.
The foregoing is a summary of the present invention, and in order to provide a clear understanding of the technical means of the present invention and to be implemented in accordance with the present specification, preferred embodiments of the present invention are described below in detail. Specific embodiments of the present invention are given in detail by the following examples.
Detailed Description
The invention is further described below:
the UV adhesive comprises the following components in parts by weight: 20-80 parts of UV oligomer, 10-60 parts of UV functional monomer, 1-5 parts of photoinitiator, 0.1-5 parts of auxiliary agent and 1-10 parts of functional filler.
Preferably, the UV oligomer comprises one or a combination of polyurethane (meth) acrylate, polyester (meth) acrylate, polyether (meth) acrylate, epoxy (meth) acrylate, polyolefin (meth) acrylate, silane-modified (meth) acrylate and pure acrylate.
Preferably, the UV functional monomer is a reactive monomer capable of being initiated by a photoinitiator, and includes one or more of (meth) acrylic acid monomer, olefin monomer, vinyl ether monomer, and allyl monomer.
Preferably, the photoinitiator comprises one or a combination of a free radical initiator and a cationic initiator.
Preferably, the auxiliary agent comprises an adhesion promoter, a thixotropic agent, a coupling agent, a defoaming agent, a dispersing agent and a heat stabilizer; wherein the coupling agent is silane coupling agent KH550, KH560, KH570, titanate coupling agent; the thixotropic agent is one or two of fumed silica and polyamide wax.
The invention also relates to an application of the UV adhesive in LED lamp bead packaging.
DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION
During actual packaging, the light-emitting wafer is placed in the wafer groove, the metal wires are welded on the electrodes of the light-emitting wafer and the metal wiring terminals to form a circuit, then UV packaging glue is poured on the light-emitting wafer and the UV base in a dispensing mode, and UVLED ultraviolet light is used for irradiating, so that the UV packaging glue is solidified on the light-emitting wafer and the UV base. The UV packaging adhesive is mainly prepared by mixing the following materials in proportion in the embodiment:
example 1:
30% of special acrylic resin A, 36% of isobornyl methacrylate, 8% of tris (2-hydroxyethyl) isocyanurate triacrylate, 12% of hexamethylenediol diacrylate, 5% of hydrophobic functional material, 1.5% of initiator TPO and 1843%; fumed silica 4%; 0.5 percent of heat stabilizer.
Firstly, 1.5kg of TPO and 3kg of 184, 36kg of isobornyl methacrylate, 8kg of tris (2-hydroxyethyl) isocyanurate triacrylate and 12kg of hexamethylenediol diacrylate as initiators are added into a stirring kettle and stirred until the solid is completely dissolved;
secondly, adding 4kg of fumed silica into the stirring kettle, dispersing at high speed until the fumed silica is uniformly dispersed,
and step three, adding 30kg of UV special acrylic resin A into a stirring kettle, mechanically stirring uniformly, adding 0.5kg of heat stabilizer and 5kg of hydrophobic functional material, dispersing uniformly, filtering and packaging.
Example 2
The special acrylic resin B41%, the dicyclopentanyl methacrylate 30%, the tris (2-hydroxyethyl) isocyanuric acid triacrylate 5%, the tricyclodecane dimethanol dimethacrylate 10%, the hydrophobic functional material 5%, the initiator TPO 1.5%, the initiator 1843%, the fumed silica 4% and the heat stabilizer 0.5%.
Firstly, 1.5kg of TPO, 3kg of 184, 30kg of dicyclopentanyl methacrylate, 5kg of tris (2-hydroxyethyl) isocyanurate triacrylate and 10kg of tricyclodecane dimethanol dimethacrylate as initiators are added into a stirring kettle and stirred until all solids are dissolved;
secondly, adding 4kg of fumed silica into the stirring kettle, dispersing at high speed until the fumed silica is uniformly dispersed,
and step three, adding 41kg of UV special acrylic resin B into a stirring kettle, mechanically stirring uniformly, adding 0.5kg of heat stabilizer and 5kg of hydrophobic functional material, dispersing uniformly, filtering and packaging.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (7)

1. The UV adhesive is characterized in that: the paint comprises the following components in parts by weight: 20-80 parts of UV oligomer, 10-60 parts of UV functional monomer, 1-5 parts of photoinitiator, 0.1-5 parts of auxiliary agent and 1-10 parts of functional filler.
2. The UV adhesive according to claim 1, wherein: the UV oligomer comprises one or a combination of polyurethane (methyl) acrylate, polyester (methyl) acrylate, polyether (methyl) acrylate, epoxy (methyl) acrylate, polyolefin (methyl) acrylate, silane modified (methyl) acrylate and pure acrylate.
3. The UV adhesive according to claim 1, wherein: the UV functional monomer is an active monomer which can be initiated to polymerize by a photoinitiator, and comprises one or a combination of a plurality of monofunctional (methyl) acrylic monomer, olefin monomer, vinyl ether monomer and allyl monomer.
4. The UV adhesive according to claim 1, wherein: the photoinitiator comprises free radical initiators 184, 651, TPO-L, 819, 1173, BP, EDB, ITX.
5. The UV adhesive according to claim 1, wherein: the auxiliary agent comprises at least one of an adhesion promoter, a thixotropic agent, a coupling agent, a defoaming agent, a dispersing agent and a heat stabilizer.
6. The UV adhesive according to claim 1, wherein: the coupling agent is silane coupling agent and titanate coupling agent; the thixotropic agent is one or more of fumed silica and polyamide wax.
7. The use of the UV adhesive according to any one of claims 1-6 in LED bead packaging.
CN202011515921.3A 2020-12-21 2020-12-21 UV adhesive and application thereof Pending CN112608688A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011515921.3A CN112608688A (en) 2020-12-21 2020-12-21 UV adhesive and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011515921.3A CN112608688A (en) 2020-12-21 2020-12-21 UV adhesive and application thereof

Publications (1)

Publication Number Publication Date
CN112608688A true CN112608688A (en) 2021-04-06

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CN202011515921.3A Pending CN112608688A (en) 2020-12-21 2020-12-21 UV adhesive and application thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521870A (en) * 2020-12-21 2021-03-19 苏州赛美思高分子科技有限公司 Ultraviolet light curing adhesive composition and application thereof
CN115254562A (en) * 2022-06-20 2022-11-01 东莞理工学院 Buffer layer applied to bending and attaching of flexible OLED screen and curing method thereof
CN116445097A (en) * 2023-04-28 2023-07-18 太仓斯迪克新材料科技有限公司 Adhesive film for direct display Mini LED packaging protection and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031592A (en) * 2014-06-30 2014-09-10 江苏华程光电科技有限公司 Sealant with low shrinkage rate for encapsulating LED (light-emitting diode)
CN106634789A (en) * 2016-11-09 2017-05-10 东莞市贝特利新材料有限公司 Ultraviolet light cured type adhesive and preparation method thereof
CN112521870A (en) * 2020-12-21 2021-03-19 苏州赛美思高分子科技有限公司 Ultraviolet light curing adhesive composition and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031592A (en) * 2014-06-30 2014-09-10 江苏华程光电科技有限公司 Sealant with low shrinkage rate for encapsulating LED (light-emitting diode)
CN106634789A (en) * 2016-11-09 2017-05-10 东莞市贝特利新材料有限公司 Ultraviolet light cured type adhesive and preparation method thereof
CN112521870A (en) * 2020-12-21 2021-03-19 苏州赛美思高分子科技有限公司 Ultraviolet light curing adhesive composition and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521870A (en) * 2020-12-21 2021-03-19 苏州赛美思高分子科技有限公司 Ultraviolet light curing adhesive composition and application thereof
CN115254562A (en) * 2022-06-20 2022-11-01 东莞理工学院 Buffer layer applied to bending and attaching of flexible OLED screen and curing method thereof
CN115254562B (en) * 2022-06-20 2023-10-03 东莞理工学院 Buffer layer applied to flexible OLED screen bending and bonding and curing method thereof
CN116445097A (en) * 2023-04-28 2023-07-18 太仓斯迪克新材料科技有限公司 Adhesive film for direct display Mini LED packaging protection and preparation method thereof

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Application publication date: 20210406