CN112606503A - High-performance plastic shell and preparation method thereof - Google Patents

High-performance plastic shell and preparation method thereof Download PDF

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Publication number
CN112606503A
CN112606503A CN202011553280.0A CN202011553280A CN112606503A CN 112606503 A CN112606503 A CN 112606503A CN 202011553280 A CN202011553280 A CN 202011553280A CN 112606503 A CN112606503 A CN 112606503A
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China
Prior art keywords
mold
synthetic resin
plastic
mold cavity
plastic shell
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Pending
Application number
CN202011553280.0A
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Chinese (zh)
Inventor
卢敏雁
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Shenzhen Xinguan Precision Technology Co ltd
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Shenzhen Xinguan Precision Technology Co ltd
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Priority to CN202011553280.0A priority Critical patent/CN112606503A/en
Publication of CN112606503A publication Critical patent/CN112606503A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/712Weather resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a high-performance plastic shell and a preparation method thereof, wherein the high-performance plastic shell comprises a base layer, an inner protection layer and an outer protection layer, the inner protection layer is arranged on the outer side of the base layer, the outer protection layer is arranged on one side, away from the base layer, of the inner protection layer, and the base layer comprises the following components in percentage by weight: synthetic resin: 90-95%, 1-3% of filling agent, 1-2% of coloring agent, 1-2% of lubricant, 1-3% of plasticizer and 2-4% of stabilizing agent, the invention adds the transparent polymer formed by PET film layer and polyethylene glycol terephthalate when manufacturing the plastic shell by injection molding, thereby greatly improving the performance of the plastic shell and enabling the manufactured plastic shell to have good weather resistance, wear resistance and optical performance.

Description

High-performance plastic shell and preparation method thereof
Technical Field
The invention belongs to the field of plastic shells, and particularly relates to a high-performance plastic shell and a preparation method thereof.
Background
In the existing life, the plastic is widely applied and is an indispensable component in household appliances, automobiles, mobile phones, PCs, medical instruments and lighting appliances. With the continuous and stable growth of economy in China, industries such as household appliances, automobiles, mobile phones, PCs, medical appliances and the like benefit from good external environments and realize rapid development, the development of downstream industries further draws requirements on plastics, and the shell is often made of plastics.
However, most of the existing plastic shells have single function during manufacturing, and lack weather resistance, wear resistance and optical performance.
The invention content is as follows:
the present invention is directed to a high performance plastic housing and a method for manufacturing the same, which solves the above problems.
In order to solve the above problems, the present invention provides a technical solution:
the utility model provides a high performance plastic casing, includes the basic unit, interior sheath and outer jacket, the outside of basic unit is provided with interior sheath, one side that the basic unit was kept away from to interior sheath is provided with the outer jacket, the basic unit includes by weight percent that: synthetic resin: 90-95%, filler 1-3%, colorant 1-2%, lubricant 1-2%, plasticizer 1-3% and stabilizer 2-4%.
Preferably, the inner sheath layer is a transparent polymer made of polyethylene terephthalate.
Preferably, the outer protective layer is a PET film layer.
Preferably, the filler is a calcium carbonate filler, the lubricant is zinc stearate, and the plasticizer is dibutyl phthalate.
A preparation method of a high-performance plastic shell comprises the following steps:
s1, preparation: firstly, preheating and drying a particle raw material, and simultaneously fully cleaning a charging barrel;
s2, weighing the following raw materials: weighing synthetic resin, filler, colorant, lubricant, plasticizer and stabilizer with corresponding components according to weight percentage;
s3, heating the injected material: then, quantitatively injecting the granular synthetic resin into the cleaned charging barrel for multiple times, and heating the charging barrel to heat the granular synthetic resin in the charging barrel to reach a molten state;
s4, laying an inner protection layer and an outer protection layer: placing a transparent polymer formed by a PET film layer and polyethylene glycol terephthalate in a mold cavity of an injection mold;
s5, injecting the molten plastic into the mold cavity through the screw rod of the injection molding machine, keeping the pressure of the molten plastic for a certain time after the mold filling is finished, and keeping the molten plastic in the mold cavity for cooling for a certain time;
s6, opening the mold and removing the product.
Preferably, in step S4, an adhesive layer is coated on the surface of the transparent polymer composed of the PET film layer and the polyethylene terephthalate.
Preferably, in step S5, after performing the injection molding operation 5S, the mold cavity needs to be heated to 165-175 ℃, and then the low-speed injection molding is performed until the raw material fills the mold cavity.
Preferably, after the mold filling in the step S5 is finished, the pressure is increased to 8.2 to 9.3MPa, the pressure is maintained for 10min, and then the cooling is performed for 30 min.
Preferably, after the product is taken out in step S6, the corner impurity removing operation is performed on the casing base layer.
The invention has the beneficial effects that: according to the invention, the transparent polymer formed by the PET film layer and the polyethylene glycol terephthalate is added when the plastic shell is manufactured by injection molding, so that the performance of the plastic shell is greatly improved, and the manufactured plastic shell has good weather resistance, wear resistance and optical performance.
The specific implementation mode is as follows:
the specific implementation mode adopts the following technical scheme:
example (b):
the utility model provides a high performance plastic casing, includes the basic unit, interior sheath and outer jacket, the outside of basic unit is provided with interior sheath, one side that the basic unit was kept away from to interior sheath is provided with the outer jacket, the basic unit includes by weight percent that: synthetic resin: 90-95%, filler 1-3%, colorant 1-2%, lubricant 1-2%, plasticizer 1-3% and stabilizer 2-4%.
Wherein, the inner sheath layer is transparent polymer formed by polyethylene terephthalate.
Wherein, the outer jacket is the PET thin layer.
Wherein the filler is calcium carbonate filler, the lubricant is zinc stearate, and the plasticizer is dibutyl phthalate.
A preparation method of a high-performance plastic shell comprises the following steps:
s1, preparation: firstly, preheating and drying a particle raw material, and simultaneously fully cleaning a charging barrel;
s2, weighing the following raw materials: weighing synthetic resin, filler, colorant, lubricant, plasticizer and stabilizer with corresponding components according to weight percentage;
s3, heating the injected material: then, quantitatively injecting the granular synthetic resin into the cleaned charging barrel for multiple times, and heating the charging barrel to heat the granular synthetic resin in the charging barrel to reach a molten state;
s4, laying an inner protection layer and an outer protection layer: placing a transparent polymer formed by a PET film layer and polyethylene glycol terephthalate in a mold cavity of an injection mold;
s5, injecting the molten plastic into the mold cavity through the screw rod of the injection molding machine, keeping the pressure of the molten plastic for a certain time after the mold filling is finished, and keeping the molten plastic in the mold cavity for cooling for a certain time;
s6, opening the mold and removing the product.
In step S4, an adhesive layer is coated on the surface of the transparent polymer made of the PET film layer and the polyethylene terephthalate.
After the injection molding operation 5S in step S5, the mold cavity needs to be heated to 165-175 ℃, and then low-speed injection molding is performed until the mold cavity is filled with the raw material.
After the mold filling in the step S5 is finished, increasing the pressure to 8.2-9.3MPa, keeping the pressure for 10min, and then cooling for 30 min.
After the product is taken out in step S6, the corner impurity removing operation is required to be performed on the base layer of the casing.
The embodiment I, a high performance plastic casing, including basic unit, interior sheath and outer jacket, the outside of basic unit is provided with interior sheath, the one side that the basic unit was kept away from to interior sheath is provided with the outer jacket, the basic unit includes by weight percent to constitute by following component: synthetic resin: 92%, filler 1%, colorant 1%, lubricant 1.5%, plasticizer 1.5% and stabilizer 3%.
Material Synthetic resin Filler Coloring agent Lubricant agent Plasticizer Stabilizer
Percentage of 92% 1% 1% 1.5% 1.5% 3%
A preparation method of a high-performance plastic shell comprises the following steps:
s1, preparation: firstly, preheating and drying a particle raw material, and simultaneously fully cleaning a charging barrel;
s2, weighing the following raw materials: weighing synthetic resin, filler, colorant, lubricant, plasticizer and stabilizer with corresponding components according to weight percentage;
s3, heating the injected material: then, quantitatively injecting the granular synthetic resin into the cleaned charging barrel for multiple times, and heating the charging barrel to heat the granular synthetic resin in the charging barrel to reach a molten state;
s4, laying an inner protection layer and an outer protection layer: placing a transparent polymer formed by a PET film layer and polyethylene glycol terephthalate in a mold cavity of an injection mold;
s5, injecting the molten plastic into the mold cavity through the screw rod of the injection molding machine, keeping the pressure of the molten plastic for a certain time after the mold filling is finished, and keeping the molten plastic in the mold cavity for cooling for a certain time;
s6, opening the mold and removing the product.
The second embodiment, a high performance plastic casing, including basic unit, interior sheath and outer jacket, the outside of basic unit is provided with interior sheath, the one side that the basic unit was kept away from to interior sheath is provided with the outer jacket, the basic unit includes by weight percent that: synthetic resin: 91%, filler 1.5%, colorant 1.5%, lubricant 1%, plasticizer 2% and stabilizer 3%.
Material Synthetic resin Filler Coloring agent Lubricant agent Plasticizer Stabilizer
Percentage of 91% 1.5% 1.5% 1% 2% 3%
A preparation method of a high-performance plastic shell comprises the following steps:
s1, preparation: firstly, preheating and drying a particle raw material, and simultaneously fully cleaning a charging barrel;
s2, weighing the following raw materials: weighing synthetic resin, filler, colorant, lubricant, plasticizer and stabilizer with corresponding components according to weight percentage;
s3, heating the injected material: then, quantitatively injecting the granular synthetic resin into the cleaned charging barrel for multiple times, and heating the charging barrel to heat the granular synthetic resin in the charging barrel to reach a molten state;
s4, laying an inner protection layer and an outer protection layer: placing a transparent polymer formed by a PET film layer and polyethylene glycol terephthalate in a mold cavity of an injection mold;
s5, injecting the molten plastic into the mold cavity through the screw rod of the injection molding machine, keeping the pressure of the molten plastic for a certain time after the mold filling is finished, and keeping the molten plastic in the mold cavity for cooling for a certain time;
s6, opening the mold and removing the product.
While there have been shown and described what are at present considered to be the fundamental principles of the invention and its essential features and advantages, it will be understood by those skilled in the art that the invention is not limited by the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents.

Claims (9)

1. The utility model provides a high performance plastic casing, its characterized in that, includes the basic unit, protects layer and outer jacket in, the outside of basic unit is provided with interior sheath, the one side of keeping away from the basic unit in the interior sheath is provided with the outer jacket, the basic unit includes by weight percent to constitute: synthetic resin: 90-95%, filler 1-3%, colorant 1-2%, lubricant 1-2%, plasticizer 1-3% and stabilizer 2-4%.
2. The plastic housing as claimed in claim 1, wherein the inner sheath is a transparent polymer of polyethylene terephthalate.
3. The plastic housing as claimed in claim 1, wherein the outer sheath is a PET film.
4. The plastic housing as claimed in claim 1, wherein the filler is calcium carbonate filler, the lubricant is zinc stearate, and the plasticizer is dibutyl phthalate.
5. The preparation method of the high-performance plastic shell is characterized by comprising the following steps of:
s1, preparation: firstly, preheating and drying a particle raw material, and simultaneously fully cleaning a charging barrel;
s2, weighing the following raw materials: weighing synthetic resin, filler, colorant, lubricant, plasticizer and stabilizer with corresponding components according to weight percentage;
s3, heating the injected material: then, quantitatively injecting the granular synthetic resin into the cleaned charging barrel for multiple times, and heating the charging barrel to heat the granular synthetic resin in the charging barrel to reach a molten state;
s4, laying an inner protection layer and an outer protection layer: placing a transparent polymer formed by a PET film layer and polyethylene glycol terephthalate in a mold cavity of an injection mold;
s5, injecting the molten plastic into the mold cavity through the screw rod of the injection molding machine, keeping the pressure of the molten plastic for a certain time after the mold filling is finished, and keeping the molten plastic in the mold cavity for cooling for a certain time;
s6, opening the mold and removing the product.
6. The method as claimed in claim 5, wherein step S4 comprises coating an adhesive on the surface of the transparent polymer of PET film layer and PET.
7. The method as claimed in claim 5, wherein the step S5, after the injection operation for 5S, is to heat the mold cavity to 165-175 ℃, and then to perform low-speed injection until the mold cavity is filled with the raw material.
8. The method as claimed in claim 5, wherein after the step S5 of filling the mold, the pressure is increased to 8.2-9.3MPa and kept for 10min, and then cooled for 30 min.
9. The method as claimed in claim 5, wherein the removing of the corner impurities from the substrate of the plastic casing is required after the product is taken out in step S6.
CN202011553280.0A 2020-12-24 2020-12-24 High-performance plastic shell and preparation method thereof Pending CN112606503A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011553280.0A CN112606503A (en) 2020-12-24 2020-12-24 High-performance plastic shell and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011553280.0A CN112606503A (en) 2020-12-24 2020-12-24 High-performance plastic shell and preparation method thereof

Publications (1)

Publication Number Publication Date
CN112606503A true CN112606503A (en) 2021-04-06

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Country Status (1)

Country Link
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101600313A (en) * 2008-06-06 2009-12-09 深圳富泰宏精密工业有限公司 Shell and preparation method thereof
CN103665917A (en) * 2013-11-29 2014-03-26 南宁市日建塑料包装有限责任公司 Novel plastic formula
US20170267416A1 (en) * 2014-12-02 2017-09-21 Danapak Flexibles A/S A lid sheet, a method for manufacture, and a package

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101600313A (en) * 2008-06-06 2009-12-09 深圳富泰宏精密工业有限公司 Shell and preparation method thereof
CN103665917A (en) * 2013-11-29 2014-03-26 南宁市日建塑料包装有限责任公司 Novel plastic formula
US20170267416A1 (en) * 2014-12-02 2017-09-21 Danapak Flexibles A/S A lid sheet, a method for manufacture, and a package

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Application publication date: 20210406