CN112604226A - Method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerase - Google Patents
Method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerase Download PDFInfo
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- CN112604226A CN112604226A CN202110062423.6A CN202110062423A CN112604226A CN 112604226 A CN112604226 A CN 112604226A CN 202110062423 A CN202110062423 A CN 202110062423A CN 112604226 A CN112604226 A CN 112604226A
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/02—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by biological methods, i.e. processes using enzymes or microorganisms
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/08—Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/22—Organic substances containing halogen
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/28—Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen
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Abstract
The invention belongs to the field of environment-friendly treatment of hazardous waste substances, and particularly relates to a method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohols with manganese RNA (ribonucleic acid) and polymerase, which comprises the following steps: (1) placing polyhydric alcohol fluid containing dioxaanthracene, dioxin and hybrid formaldehyde into a heating container, adding rubber particles, and heating to obtain solution A; (2) adding manganese RNA (ribonucleic acid) auxiliary polymerase into the chemically pure methanol solution, and uniformly stirring to obtain a solution B; (3) mixing the solution A obtained in the step (1) and the solution B obtained in the step (2), pouring the mixture into a flask, carrying out conventional distillation, and reserving carbon crystals in the flask after crude alcohol liquid is collected from a condenser interface. The invention has simple process route and ideal treatment effect on dioxaanthracene and analogues thereof.
Description
Technical Field
The invention belongs to the field of environment-friendly treatment of hazardous waste substances, and particularly relates to a method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohols with manganese RNA (ribonucleic acid) and polymerase.
Background
Dioxining is a colorless and odorless fat-soluble substance, which comprises 210 compounds and has great toxicity, and is called as century toxicity. It has been classified as human primary carcinogen by the international center for cancer research. "Dioxining" often exists in the atmosphere, soil and water as tiny particles, and the main pollution sources are industries such as chemical metallurgy industry, waste incineration, paper making and pesticide production. There are two main sources of dioxin occurrence, namely, in the production of chemical substances including pesticides; the second is from the incineration of the waste. Garbage compounds mainly containing chlorine such as dioxaanthracene and dioxazine are extremely harmful to natural organisms. At present, no effective harmless treatment method is found for polyol fluid containing dioxaanthracene, dioxin and hybrid formaldehyde.
Disclosure of Invention
The invention aims to provide a method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyol by manganese RNA (ribonucleic acid) polymerase and an ideal treatment effect.
In order to solve the technical problem, the invention is realized as follows:
the method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerization is implemented according to the following steps:
(1) placing polyhydric alcohol fluid containing dioxaanthracene, dioxin and hybrid formaldehyde into a heating container, adding rubber particles, and heating to obtain solution A;
(2) adding manganese RNA (ribonucleic acid) auxiliary polymerase into the chemically pure methanol solution, and uniformly stirring to obtain a solution B;
(3) mixing the solution A obtained in the step (1) and the solution B obtained in the step (2), pouring the mixture into a flask, carrying out conventional distillation, and reserving carbon crystals in the flask after crude alcohol liquid is collected from a condenser interface.
In a preferred embodiment, in the present invention, in the step (1), the polyol fluid content of dioxetane, and hybrid formaldehyde is 80% by weight; the rubber particle content is 3%; in the step (2), the content of the chemically pure methanol liquid is 15%; the content of manganese RNA-assisted polymerase is 2%.
Further, in the step (1) of the present invention, the temperature is raised to 26 ℃ to obtain the solution A.
The invention has simple process route and ideal treatment effect on dioxaanthracene and analogues thereof. The manganese RNA-assisted polymerase system can strongly catalyze the multienzyme with organic molecular structures of dioxaanthracene and dioxazine under the normal pressure condition, the speed of cutting and cracking a substrate is hundreds of thousands of times higher than the speed of physical and chemical reactions and hundreds of millions of times higher than the speed of cutting and cracking the substrate, the manganese RNA-assisted polymerase system has the function of strongly driving catalytic reactions on a main enzyme element body, the selectivity of the substrate is extremely accurate, and the purity of the cut organic molecules almost reaches 99.999%.
Detailed Description
The method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerization is implemented according to the following steps:
(1) placing polyhydric alcohol fluid containing dioxaanthracene, dioxin and hybrid formaldehyde into a heating container, adding rubber particles, and heating to 26 ℃ to obtain solution A;
(2) adding manganese RNA (ribonucleic acid) auxiliary polymerase into the chemically pure methanol solution, and uniformly stirring to obtain a solution B;
(3) mixing the solution A obtained in the step (1) and the solution B obtained in the step (2), pouring the mixture into a flask, carrying out conventional distillation, and reserving carbon crystals in the flask after crude alcohol liquid is collected from a condenser interface.
In the invention, in the step (1), the content of the polyol fluid of the dioxaanthracene, the dioxin and the hybrid formaldehyde is 80 percent by weight; the rubber particle content is 3%; in the step (2), the content of the chemically pure methanol liquid is 15%; the content of manganese RNA-assisted polymerase is 2%.
Example (b):
(1) placing 80 wt% (based on the total amount of raw materials, the same below) of polyol fluid containing dioxaanthracene, dioxazine and hybrid formaldehyde into a heating container made of glass and ceramic (non-metal products), adding 3% of rubber particles, and heating to 26 ℃ to obtain solution A;
2. preparing chemical pure methanol solution with the mass percentage of 15 percent, adding manganese RNA (ribonucleic acid) auxiliary polymerase with the mass percentage of 2 percent (producing area: Shenyang Oneng environmental protection science and technology Co., Ltd.), and stirring uniformly to prepare solution B;
3. mixing the solution B and the solution A, pouring the mixture into a flask, carrying out conventional distillation, and collecting crude alcohol liquid from a condenser interface to be used as a hydrophilic organic colloid solution raw material;
distilling the mixed liquid of the liquid A and the liquid B to a dry point, extracting a liquid phase flow state (after crude alcohol), burning and remaining carbon crystals in the mixed liquid, and completely decomposing harmful substances such as dioxin, hybrid formaldehyde and the like contained in the original polyol fluid.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (3)
1. The method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyol with manganese RNA (ribonucleic acid) polymerase, is characterized by comprising the following steps of:
(1) placing polyhydric alcohol fluid containing dioxaanthracene, dioxin and hybrid formaldehyde into a heating container, adding rubber particles, and heating to obtain solution A;
(2) adding manganese RNA (ribonucleic acid) auxiliary polymerase into the chemically pure methanol solution, and uniformly stirring to obtain a solution B;
(3) mixing the solution A obtained in the step (1) and the solution B obtained in the step (2), pouring the mixture into a flask, carrying out conventional distillation, and reserving carbon crystals in the flask after crude alcohol liquid is collected from a condenser interface.
2. The method for removing aldehyde and dissociating dioxaanthracene and analogues thereof from hazardous waste polyol by manganese RNA (ribonucleic acid) polymerase treatment according to claim 1, wherein the method comprises the following steps: in the step (1), the polyol fluid liquid content of dioxin, dioxin and hybrid formaldehyde is 80 percent in percentage by weight; the rubber particle content is 3%; in the step (2), the content of the chemically pure methanol liquid is 15%; the content of manganese RNA-assisted polymerase is 2%.
3. The method for removing aldehyde and dissociating dioxaanthracene and analogues thereof from hazardous waste polyol by manganese RNA (ribonucleic acid) polymerase treatment according to claim 2, wherein the method comprises the following steps: in the step (1), the temperature is raised to 26 ℃ to prepare the solution A.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202110062423.6A CN112604226A (en) | 2021-01-18 | 2021-01-18 | Method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerase |
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| CN202110062423.6A CN112604226A (en) | 2021-01-18 | 2021-01-18 | Method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerase |
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| CN112604226A true CN112604226A (en) | 2021-04-06 |
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| CN202110062423.6A Pending CN112604226A (en) | 2021-01-18 | 2021-01-18 | Method for removing aldehyde and dissociating dioxaanthracene and analogues thereof by treating hazardous waste polyhydric alcohol through manganese RNA (ribonucleic acid) enzyme-assisted polymerase |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001245652A (en) * | 2000-03-03 | 2001-09-11 | Mercian Corp | Method for decomposing dioxin with manganese peroxidase and agent for decomposition treatment |
| CN102039021A (en) * | 2009-10-14 | 2011-05-04 | 中国科学院生态环境研究中心 | Method for treating fly ash by using manganese dioxide |
| CN105195173A (en) * | 2015-10-01 | 2015-12-30 | 常州市奥普泰科光电有限公司 | Preparation method of catalyst for removing dioxins from fume gas |
| CN105344223A (en) * | 2015-11-11 | 2016-02-24 | 华能国际电力股份有限公司 | Multi-pollutant integrated removal multi-effect compound liquid and preparation method thereof |
| CN111393045A (en) * | 2020-03-27 | 2020-07-10 | 朱继杰 | Method for preparing cementing material from waste incineration fly ash |
-
2021
- 2021-01-18 CN CN202110062423.6A patent/CN112604226A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001245652A (en) * | 2000-03-03 | 2001-09-11 | Mercian Corp | Method for decomposing dioxin with manganese peroxidase and agent for decomposition treatment |
| CN102039021A (en) * | 2009-10-14 | 2011-05-04 | 中国科学院生态环境研究中心 | Method for treating fly ash by using manganese dioxide |
| CN105195173A (en) * | 2015-10-01 | 2015-12-30 | 常州市奥普泰科光电有限公司 | Preparation method of catalyst for removing dioxins from fume gas |
| CN105344223A (en) * | 2015-11-11 | 2016-02-24 | 华能国际电力股份有限公司 | Multi-pollutant integrated removal multi-effect compound liquid and preparation method thereof |
| CN111393045A (en) * | 2020-03-27 | 2020-07-10 | 朱继杰 | Method for preparing cementing material from waste incineration fly ash |
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Application publication date: 20210406 |