CN112592522A - High-performance flame-retardant self-cleaning daylighting panel material easy to melt and free of dripping and production process thereof - Google Patents

High-performance flame-retardant self-cleaning daylighting panel material easy to melt and free of dripping and production process thereof Download PDF

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CN112592522A
CN112592522A CN202011473518.9A CN202011473518A CN112592522A CN 112592522 A CN112592522 A CN 112592522A CN 202011473518 A CN202011473518 A CN 202011473518A CN 112592522 A CN112592522 A CN 112592522A
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retardant
flame
melt
daylighting
daylighting panel
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CN112592522B (en
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赵泽永
王玉忠
邓聪
王子晟
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Sichuan University
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Abstract

The invention discloses a high-performance flame-retardant self-cleaning daylighting panel material which is easy to melt and does not drip and a production process thereof, wherein the production process comprises the following steps: drying and mixing polyolefin resin, low-melting-point resin, a flame retardant, a compatilizer, an antioxidant and a lubricant to obtain a mixture; adding the mixture from the main feeding port of the screw extruder, adding continuous fibers by adopting a melt impregnation method or adding discontinuous fibers through the side feeding port of the extruder, extruding and granulating to obtain the glass fiber reinforced polyolefin flame-retardant composite material, and carrying out extrusion forming by a multi-roll calender to obtain the easily-fusible and non-dripping high-performance flame-retardant daylighting panel. The daylighting panel has the characteristic of easy meltdown, can automatically break the hole within the temperature range of 100-. Meanwhile, the addition of the reinforcing fiber enables the material to have higher melt strength and not to melt and drip in the melting temperature range.

Description

High-performance flame-retardant self-cleaning daylighting panel material easy to melt and free of dripping and production process thereof
Technical Field
The invention belongs to the technical field of easily-fusible daylighting panels, and particularly relates to an easily-fusible non-dripping high-performance flame-retardant daylighting panel and a production process thereof.
Background
The daylighting panel is a light-transmitting sheet material used for replacing a light-transmitting material for a building ceiling, and is widely applied to house buildings such as industrial production workshops, storage warehouses, commercial buildings, airports, stadiums, village and town biological base buildings and the like. At present, most of daylighting panels are prepared from polycarbonate, glass fiber reinforced epoxy resin and other materials, and have the characteristics of light weight, light transmission, easiness in installation, attractiveness and the like. However, the prior daylighting plate material still has a plurality of defects: firstly, due to the characteristics of flammability and the like of the high polymer material, passive fire is likely to form under the condition of an external fire source, for example, the fire risks are caused when fireworks, cigarette ends fall off, electrical short circuit and the like occur; secondly, after a fire disaster happens, the daylighting panel does not have the fusible performance, so a large amount of toxic smog cannot be emitted in time, and a large amount of casualties are easy to cause. In order to solve the problems, the fusible daylighting panel is produced, for example, the utility model patent application with the application number of 201921223127.4 discloses a preparation method of a fusible fixed daylighting window, which is characterized in that a plurality of heat insulation blocks are arranged between an upper layer and a lower layer of fusible daylighting panel, and the upper layer and the lower layer of fusible daylighting panel and the heat insulation blocks are fixed on a circular arch steel skeleton through a plurality of self-tapping screws. However, the fusible daylighting panel technology is mainly monopolized by foreign enterprises, and is usually prepared from modified polyester materials, so that the material cost is high, and the fusible performance is not ideal (the fusible performance needs to be about 150 ℃ to start fusing). If the common low-melting-point polymer is used as a base material of the easily-fusible daylighting panel, the mechanical property of the daylighting panel is too low, the daylighting panel is easy to drip, and the like, so that the use requirement cannot be met. Meanwhile, the lighting board is usually located at a position which is difficult to be manually cleaned, such as the top of a building, and the like, and the lighting board is often polluted by water stain, dust and the like after being used for a certain time, so that the lighting performance, the attractiveness and the like are influenced. Therefore, a need exists in the market for a novel daylighting plate material which is easily melted and does not drip, and has certain self-cleaning performance and flame retardant performance.
Disclosure of Invention
The invention aims to overcome the defects of the existing daylighting panel, provides a high-performance flame-retardant self-cleaning daylighting panel material which is easy to melt and does not drip, and a production process thereof, and greatly improves the fire safety performance of the daylighting panel on the premise of meeting other performance requirements.
An object of the present invention is to solve at least the above problems and/or disadvantages and to provide at least the advantages described hereinafter.
To achieve these objects and other advantages in accordance with the present invention, there is provided a high-performance fire retardant daylighting panel material which is easily fusible and does not drip, comprising the following components in percentage by mass:
30-75% of polyolefin resin; 5-25% of low-melting-point resin; 20-30% of flame retardant; 15-40% of reinforcing fiber; 1-10% of a compatilizer; 0.5 to 1.5 percent of antioxidant; 0.5 to 1.5 percent of lubricant.
Preferably, a transparent super-amphiphobic coating with the thickness of 0.5-50 mu m is coated on the surface of the prepared daylighting plate material, so that the high-performance flame-retardant self-cleaning daylighting plate material which is easy to melt and does not drip is obtained.
Preferably, the polyolefin resin is one or a combination of more of LDPE, LLDPE, HDPE, PP, EVA, POE, EPDM and PVC; the low-melting-point resin is one or a combination of more of chlorinated paraffin, chlorinated polyethylene, polyethylene wax and EVA; the flame retardant is one or a combination of more of intumescent flame retardant, phosphorus-nitrogen flame retardant, halogen flame retardant and phosphorus flame retardant; the compatilizer is one or a combination of more of maleic anhydride grafted polyethylene and maleic anhydride grafted polypropylene; the antioxidant is one or a combination of more of antioxidant 1618 and antioxidant 1010; the lubricant is one or a combination of more of silicone powder, silicone oil, polyethylene wax and mineral oil; the reinforced fiber is one or more of glass fiber, carbon fiber, basalt fiber, aramid fiber, ceramic fiber, ramie fiber, jute fiber, bamboo fiber, mineral wool fiber or rock wool fiber.
Preferably, the method further comprises the following steps: 0.5 to 1.5 percent of color master batch; 0.5 to 1.5 percent of release agent; 0.5 to 1.5 percent of heat stabilizer; 0.5 to 1.5 percent of uvioresistant agent; 0.5-1.5% of hydrolysis resistant agent.
Preferably, the release agent is one or a combination of more of silicone powder, silicone oil, polyethylene wax, paraffin and mineral oil; the heat stabilizer is an organic tin stabilizer; the ultraviolet resistant agent is UV-531; the hydrolysis resistant agent is a diimine hydrolysis resistant agent.
Preferably, the glass fiber is replaced by a modified glass fiber, and the preparation method of the modified glass fiber comprises the following steps: adding 10-15 parts by weight of glass fiber and 50-120 parts by weight of absolute ethyl alcohol into a supercritical device, soaking for 60-75 min in a supercritical ethanol system with the temperature of 240-320 ℃ and the pressure of 6-10 MPa, taking out and naturally drying; adding naturally air-dried glass fibers into a heating pipe which is horizontally placed, heating the heating pipe, simultaneously introducing ultrasonic atomized liquid into two ends of the heating pipe through carrier gas, and arranging an exhaust hole in the middle of the heating pipe; the ultrasonic atomization liquid is formed by adding the modified liquid into an ultrasonic atomization device and performing ultrasonic atomization; carrying out ultraviolet irradiation treatment on the glass fiber treated by the ultrasonic atomized liquid for 15-25 min; the preparation method of the modified liquid comprises the following steps: according to the weight parts, 1-3 parts of polyvinyl alcohol, 3-5 parts of tea polyphenol and 0.5-1.5 parts of boron nitride are added into 200-300 parts of water in a nanometer mode, stirring is carried out for 15-30 min at the speed of 500-800 r/min, and then pressure ultrasonic dispersion is carried out for 60-90 min; the pressure of the pressurized ultrasonic dispersion is 0.8-1.5 MPa, and the frequency is 50-65 KHz; the mass volume ratio of the glass fiber to the modification liquid is 1g: 10-30 mL; heating the heating pipe at 120-150 ℃; the technological parameters of the ultrasonic atomization are as follows: the frequency of ultrasonic atomization is 1.5-3.5 MHz, the carrier gas is nitrogen, and the flow rate of the carrier gas is 10-15 mL/min; the ultraviolet wavelength of the ultraviolet radiation is 200-400 nm, and the radiation intensity is 150-250 mW/cm2And the irradiation distance is 5-10 cm.
The invention also provides a production process of the easily-fusible and non-dripping high-performance flame-retardant lighting board material, which is characterized by comprising the following steps of:
step one, taking polyolefin resin, low-melting-point resin, a flame retardant, a compatilizer, an antioxidant and a lubricant, drying, and mixing by a high-speed mixer to obtain a mixture;
step two, adding the mixture from the main feeding port of the screw extruder, adding continuous reinforcing fibers by adopting a melt impregnation method or adding the reinforcing fibers through the side feeding port of the extruder, and extruding and granulating under the process conditions that the extrusion temperature is 180-;
and step three, carrying out extrusion forming on the fiber reinforced polyolefin flame-retardant composite material by a multi-roll calender or preparing the fiber reinforced polyolefin flame-retardant composite material into a sheet by an injection molding machine and a plate pressing machine forming device to obtain the high-performance flame-retardant daylighting panel which is easy to melt and does not drip.
Preferably, the method further comprises the following steps: step four, coating the transparent super-amphiphobic coating solution on the surface of the daylighting plate in a dip-coating or spraying mode, and drying in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.5-50 mu m on the surface of the daylighting plate, so that the high-performance flame-retardant self-cleaning daylighting plate which is easy to melt and does not drip is obtained; or before spraying the transparent super-amphiphobic coating solution, spraying/coating a layer of adhesive on the surface of the base material, then coating the transparent super-amphiphobic coating solution on the surface of the daylighting panel, and drying in a baking oven at normal temperature or 45 ℃ to obtain the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip; the adhesive is any one of polydimethylsiloxane, epoxy resin, commercial double-sided adhesive or 3M 77 spray adhesive;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 0.5-20 parts by mass of nano particles into a mixed solution of 200 parts by volume of water and anhydrous ethanol, then adding 0.5-3 parts by volume of positively charged silane coupling agent, stirring at normal temperature for 6 hours, then adding 0.5-20 parts by mass of micron particles with negatively charged surfaces, stirring for 2 hours, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 200-500 volume parts of ethanol solution, adding 0.5-3 volume parts of fluorosilane, stirring, mixing and reacting to obtain transparent super-amphiphobic coating solution; one or more of the nano-particle silicon dioxide, titanium dioxide or zinc oxide; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane or perfluorodecyl triethoxy silane. .
The invention also provides a production process of the easily-fusible and non-dripping high-performance flame-retardant lighting board material, which comprises the following steps:
step I, drying polyolefin resin, low-melting-point resin, a flame retardant, a compatilizer, an antioxidant, a lubricant, color master batches, a release agent, a heat stabilizer, an anti-ultraviolet agent and a hydrolysis resistance agent, and mixing by a high-speed mixer to obtain a mixture;
step II, adding the mixture from the main feeding port of the screw extruder, adding continuous reinforcing fibers by adopting a melt impregnation method or adding the reinforcing fibers through the side feeding port of the extruder, and extruding and granulating under the process conditions that the extrusion temperature is 180-;
and step III, carrying out extrusion molding on the fiber reinforced polyolefin flame-retardant composite material by a three-roll calendar or preparing the fiber reinforced polyolefin flame-retardant composite material into a sheet by an injection molding machine and a plate pressing machine molding device to obtain the high-performance flame-retardant daylighting panel which is easy to melt and does not drip.
Preferably, the method further comprises the following steps: step IV, coating the transparent super-amphiphobic coating solution on the surface of the daylighting panel in a dip-coating or spraying mode, and drying in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.5-50 mu m on the surface of the daylighting panel; obtaining the easily-fusible and non-dripping high-performance flame-retardant self-cleaning daylighting panel; or before spraying the transparent super-amphiphobic coating solution, spraying/coating a layer of adhesive on the surface of the base material, then coating the transparent super-amphiphobic coating solution on the surface of the daylighting panel, and drying in a baking oven at normal temperature or 45 ℃ to obtain the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip; the adhesive is any one of polydimethylsiloxane, epoxy resin, commercial double-sided adhesive or 3M 77 spray adhesive;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 0.5-20 parts by mass of nano particles into a mixed solution of 200 parts by volume of water and anhydrous ethanol, then adding 0.5-3 parts by volume of positively charged silane coupling agent, stirring at normal temperature for 6 hours, then adding 0.5-20 parts by mass of micron particles with negatively charged surfaces, stirring for 2 hours, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 200-500 volume parts of ethanol solution, adding 0.5-3 volume parts of fluorosilane, stirring, mixing and reacting to obtain transparent super-amphiphobic coating solution; one or more of the nano-particle silicon dioxide, titanium dioxide or zinc oxide; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane or perfluorodecyl triethoxy silane. .
The invention at least comprises the following beneficial effects:
(1) in the invention, the prepared daylighting panel has the characteristic of easy meltdown by a specific formula and a production process, and can automatically break a hole within the temperature range of 100-150 ℃ (which can be regulated and controlled according to specific requirements), so that toxic smoke can escape, and the purpose of reducing casualties is realized. Meanwhile, the addition of the reinforcing fiber enables the material to have higher melt strength and not to melt and drip in the melting temperature range.
(2) In the invention, the reinforced fiber is added into the raw materials of the daylighting panel, so that the tensile strength, hardness, thermal stability and heat insulation of the daylighting panel can be obviously improved. Therefore, the daylighting panel can simultaneously realize lower fusing temperature and better mechanical property, particularly tensile strength, the tensile strength can reach 20-50MPa, and the thermal expansion coefficient is small.
(3) According to the invention, the fire retardant is added into the raw materials of the daylighting panel, so that the daylighting panel has the characteristics of flame retardance, greatly improved limit oxygen index and self-extinguishing after leaving fire. The potential safety hazard that the passive fire hazard occurs to the lighting panel can be eliminated, and the requirements of related laws and regulations can be met.
(4) In the invention, the surface of the daylighting panel is sprayed with the transparent super-amphiphobic coating, so that the daylighting panel has hydrophobic and oleophobic self-cleaning performance. This will greatly increase the stain resistance and aesthetics of the daylighting panel during use.
(4) In the production process of the daylighting panel, the flame retardant and the polyolefin resin are blended by a double screw, then the fiber is added and granulated, so that the flame retardant is dispersed and distributed in the matrix resin more uniformly, and the fiber is added for reinforcement, so that the mechanical property of the daylighting panel is better, and the thermal stability is also obviously improved.
(5) In the invention, the production processes including raw material mixing granulation and sheet preparation are continuous production, no toxic and harmful gas or substance is generated in the production process, and the selected material has lower price, so that the requirement of large-scale industrial production is fully met, and the method is suitable for popularization and use.
Additional advantages, objects, and features of the invention will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from practice of the invention.
Description of the drawings:
FIG. 1 is a water contact angle test chart of a high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip, prepared in example 1 of the invention;
FIG. 2 is an oil antenna test chart of a high-performance flame-retardant self-cleaning daylighting panel prepared in example 1 of the present invention;
FIG. 3 is a water contact angle test chart of the high-performance fire-retardant daylighting panel prepared in example 1 of the invention, which is easy to be broken and does not drip;
FIG. 4 is a graph showing the oil contact angle test of a high-performance fire-retardant daylighting panel prepared in example 1 of the present invention;
the specific implementation mode is as follows:
the present invention is further described in detail below with reference to examples so that those skilled in the art can practice the invention with reference to the description.
It will be understood that terms such as "having," "including," and "comprising," as used herein, do not preclude the presence or addition of one or more other elements or groups thereof.
Example 1:
the self-cleaning flame-retardant daylighting panel which is easy to melt and does not drip comprises the following components in percentage by mass:
30% of low-density polyolefin, 20% of polypropylene, 5% of ethylene wax, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 20% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder, wherein the surface of the daylighting panel prepared from the components is coated with a 0.8 mu m transparent super-amphiphobic coating,
the production process comprises the following steps:
step one, weighing all components according to the formula of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip, and drying for later use;
mixing the low-density polyolefin, the polypropylene, the ethylene wax, the intumescent flame retardant, the maleic anhydride grafted polyethylene, the antioxidant 1618, the antioxidant 1010 and the silicone powder by a high-speed mixer to obtain a mixture;
step three, adding the mixture from a feed inlet of a double-screw extruder, wherein the processing temperature of the double screws is 150 ℃, 175 ℃, 195 ℃, 200 ℃, 185 ℃ in sequence from a feed section to a mouth die, and the rotating speed of the screws is 380 rpm;
step four, the mixture is melted and blended by a double screw and then enters a glass fiber impregnation opening die, the impregnation and mixing of continuous glass fiber and melt are realized in the opening die, and continuous glass fiber reinforced granules are obtained after the mixture is cut off by a granulator;
adding the glass fiber reinforced aggregate into a three-roller calendaring extrusion device, wherein the temperature of a compression roller is 60 ℃, and obtaining the high-performance flame-retardant daylighting panel which is easy to melt and does not drip after molding;
step six, coating the super-amphiphobic coating solution on the surface of the daylighting panel in a dip-coating or spraying mode, drying the modified surface in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.8 mu m on the surface of the daylighting panel, and thus obtaining the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 0.5g of nano particles into 500mL of mixed solution of water and absolute ethyl alcohol, then adding 1mL of positively charged silane coupling agent, stirring at normal temperature for 6h, then adding 0.5g of micron particles with negatively charged surfaces, stirring for 2h, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 500mL of ethanol solution, adding 5mL of fluorosilane, stirring, mixing and reacting to obtain transparent super-amphiphobic coating solution; the nanoparticulate silica; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane.
Example 2:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-vinyl acetate copolymer, 5% of ethylene wax, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 20% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder, wherein the surface of the daylighting panel prepared from the components is coated with a 0.8 mu m transparent super-amphiphobic coating;
the production process was the same as in example 1.
Example 3:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
25% of low-density polyolefin, 15% of polypropylene, 5% of ethylene wax, 22% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 28% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder, wherein the surface of the daylighting panel prepared from the components is coated with a 0.8-micron transparent super-amphiphobic coating;
the production process was the same as in example 1.
Example 4:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
30% of low-density polyolefin, 20% of polypropylene, 5% of chlorinated polyethylene, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 20% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder, wherein the surface of the daylighting panel prepared from the components is coated with a 0.8 mu m transparent super-amphiphobic coating;
the production process was the same as in example 1.
Example 5:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-octene copolymer, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 21% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant, 1% of silicone powder, 0.5% of color master batch, 0.5% of silicone oil, 1% of organic tin stabilizer, UV-5311% and 1% of diimine hydrolysis resistant agent, wherein the surface of the plane skylight prepared from the components is coated with a 0.8 mu m transparent super-amphiphobic coating;
the production process comprises the following steps:
step one, weighing all components according to the formula of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip, and drying for later use;
mixing low-density polyolefin, polypropylene, ethylene wax, an intumescent flame retardant, maleic anhydride grafted polyethylene, an antioxidant 1618, an antioxidant 1010, silicone powder, color master batches, silicone oil, an organic tin stabilizer, UV-531 and a diimine hydrolysis resisting agent by a high-speed mixer to obtain a mixture;
step three, adding the mixture from a feed inlet of a double-screw extruder, wherein the processing temperature of the double screws is 150 ℃, 175 ℃, 195 ℃, 200 ℃, 185 ℃ in sequence from a feed section to a mouth die, and the rotating speed of the screws is 380 rpm;
step four, the mixture is melted and blended by a double screw and then enters a glass fiber impregnation opening die, the impregnation and mixing of continuous glass fiber and melt are realized in the opening die, and continuous glass fiber reinforced granules are obtained after the mixture is cut off by a granulator;
adding the glass fiber reinforced aggregate into a three-roller calendaring extrusion device, wherein the temperature of a compression roller is 60 ℃, and obtaining the high-performance flame-retardant daylighting panel which is easy to melt and does not drip after molding;
step six, coating the super-amphiphobic coating solution on the surface of the daylighting panel in a dip-coating or spraying mode, drying the modified surface in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.8 mu m on the surface of the daylighting panel, and thus obtaining the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 2g of nano particles into 300mL of mixed solution of water and absolute ethyl alcohol, then adding 1mL of positively charged silane coupling agent, stirring at normal temperature for 6 hours, then adding 2g of micron particles with negatively charged surfaces, stirring for 2 hours, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 300mL of ethanol solution, adding 1mL of fluorosilane, stirring, mixing and reacting to obtain a transparent super-amphiphobic coating solution; the nanoparticulate silica; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane.
Example 6:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-vinyl acetate copolymer, 5% of ethylene wax, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 20% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder; wherein the surface of the plane skylight prepared from the components is coated with a 0.8-micron transparent super-amphiphobic coating;
the production process comprises the following steps:
step one, weighing all components according to the formula of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip, and drying for later use;
mixing the low-density polyolefin, the polypropylene, the ethylene wax, the intumescent flame retardant, the maleic anhydride grafted polyethylene, the antioxidant 1618, the antioxidant 1010 and the silicone powder by a high-speed mixer to obtain a mixture;
adding the mixture from a feed inlet of a double-screw extruder, and adding the glass fiber into the double-screw extruder from a lateral feed inlet; the processing temperature of the double screw is 150 ℃, 175 ℃, 195 ℃, 200 ℃ and 185 ℃ from the feeding section to the neck mold in sequence, and the rotating speed of the screw is 380 rpm; obtaining glass fiber reinforced granules after bracing and dicing;
adding the glass fiber reinforced granules into a three-roller calendaring extrusion device, wherein the temperature of a compression roller is 60 ℃, and obtaining the high-performance flame-retardant daylighting panel which is easy to melt and does not drip after molding;
step five, coating the super-amphiphobic coating solution on the surface of the daylighting panel in a dip-coating or spraying mode, drying the modified surface in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.8 mu m on the surface of the daylighting panel, and thus obtaining the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 1g of nano particles into 100mL of mixed solution of water and absolute ethyl alcohol, then adding 5mL of positively charged silane coupling agent, stirring at normal temperature for 6h, then adding 5g of micron particles with negatively charged surfaces, stirring for 2h, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 200mL of ethanol solution, adding 2mL of fluorosilane, stirring, mixing and reacting to obtain a transparent super-amphiphobic coating solution; the nanoparticulate silica; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane.
Example 7:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-octene copolymer, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 21% of glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant, 1% of silicone powder, 0.5% of color master batch, 0.5% of silicone oil, 1% of organic tin stabilizer, UV-5311% and 1% of diimine hydrolysis resistant agent;
the production process comprises the following steps:
step one, weighing all components according to the formula of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip, and drying for later use;
mixing low-density polyolefin, polypropylene, ethylene wax, an intumescent flame retardant, maleic anhydride grafted polyethylene, an antioxidant 1618, an antioxidant 1010, silicone powder, color master batches, silicone oil, an organic tin stabilizer, UV-531 and a diimine hydrolysis resisting agent by a high-speed mixer to obtain a mixture;
adding the mixture from a feed inlet of a double-screw extruder, and adding the glass fiber into the double-screw extruder from a lateral feed inlet; the processing temperature of the double screw is 150 ℃, 175 ℃, 195 ℃, 200 ℃ and 185 ℃ from the feeding section to the neck mold in sequence, and the rotating speed of the screw is 380 rpm; obtaining glass fiber reinforced granules after bracing and dicing;
adding the glass fiber reinforced granules into a three-roller calendaring extrusion device, wherein the temperature of a compression roller is 60 ℃, and obtaining the high-performance flame-retardant daylighting panel which is easy to melt and does not drip after molding;
step five, coating the super-amphiphobic coating solution on the surface of the daylighting panel in a dip-coating or spraying mode, drying the modified surface in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.8 mu m on the surface of the daylighting panel, and thus obtaining the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 2g of nano particles into 300mL of mixed solution of water and absolute ethyl alcohol, then adding 1mL of positively charged silane coupling agent, stirring at normal temperature for 6 hours, then adding 2g of micron particles with negatively charged surfaces, stirring for 2 hours, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 300mL of ethanol solution, adding 1mL of fluorosilane, stirring, mixing and reacting to obtain a transparent super-amphiphobic coating solution; the nanoparticulate silica; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane.
Example 8:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-vinyl acetate copolymer, 5% of ethylene wax, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 20% of modified glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder, wherein the surface of the daylighting panel prepared from the components is coated with a 0.8 mu m transparent super-amphiphobic coating;
the preparation method of the modified glass fiber comprises the following steps: adding 15g of glass fiber and 100g of absolute ethyl alcohol into a supercritical device, soaking for 60min in a supercritical ethanol system with the temperature of 260 ℃ and the pressure of 8MPa, taking out and naturally drying; adding naturally air-dried glass fibers into a heating pipe which is horizontally placed, heating the heating pipe, simultaneously introducing ultrasonic atomized liquid into two ends of the heating pipe through carrier gas, and arranging an exhaust hole in the middle of the heating pipe; the ultrasonic atomization liquid is formed by adding the modified liquid into an ultrasonic atomization device and performing ultrasonic atomization; carrying out ultraviolet irradiation treatment on the glass fiber treated by the ultrasonic atomized liquid for 20 min; the preparation method of the modified liquid comprises the following steps: adding 1g polyvinyl alcohol, 3g tea polyphenol and 1g boron nitride nanometer into 200g water, stirring at 500r/min for 30min, and then pressurizing and ultrasonically dispersing for 90 min; the pressure of the pressurized ultrasonic dispersion is 1MPa, and the frequency is 55 KHz; the mass volume ratio of the glass fiber to the modification liquid is 1g:15 mL; the heating temperature of the heating pipe is 125 ℃; the technological parameters of the ultrasonic atomization are as follows: the frequency of the ultrasonic atomization is 2MHz, the carrier gas is nitrogen, and the flow rate of the carrier gas is 10 mL/min; the ultraviolet wavelength of the ultraviolet radiation is 200nm, and the radiation intensity is 150mW/cm2The irradiation distance is 5 cm; the method of the invention is adopted to modify the glass fiber, which can well improve the activity degree and the surface free energy of the surface of the glass fiber, and the active groups generated by modification form firm chemical bonding with polyolefin resin, low-melting resin and the like, thereby greatly enhancing the bonding capability of the interface and the cohesiveness of the material, and further improving the performance of the daylighting panel.
The production process of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip is the same as that of the embodiment 1;
example 9:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-vinyl acetate copolymer, 5% of ethylene wax, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 20% of modified glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant and 1% of silicone powder; wherein the surface of the plane skylight prepared from the components is coated with a 0.8-micron transparent super-amphiphobic coating;
the preparation method of the modified glass fiber comprises the following steps: adding 12g of glass fiber and 120g of absolute ethyl alcohol into a supercritical device, soaking for 75min in a supercritical ethanol system with the temperature of 250 ℃ and the pressure of 9MPa, taking out and naturally drying; adding naturally air-dried glass fibers into a heating pipe which is horizontally placed, heating the heating pipe, simultaneously introducing ultrasonic atomized liquid into two ends of the heating pipe through carrier gas, and arranging an exhaust hole in the middle of the heating pipe; the ultrasonic atomization liquid is formed by adding the modified liquid into an ultrasonic atomization device and performing ultrasonic atomization; carrying out ultraviolet irradiation treatment on the glass fiber treated by the ultrasonic atomized liquid for 20 min; the preparation method of the modified liquid comprises the following steps: adding 2g of polyvinyl alcohol, 4g of tea polyphenol and 1.2g of boron nitride into 220g of water, stirring for 30min at the speed of 800r/min, and then pressurizing and ultrasonically dispersing for 80 min; the pressure of the pressurized ultrasonic dispersion is 1.2MPa, and the frequency is 55 KHz; the mass volume ratio of the glass fiber to the modification liquid is 1g:20 mL; the heating temperature of the heating pipe is 130 ℃; the technological parameters of the ultrasonic atomization are as follows: the frequency of the ultrasonic atomization is 2MHz, the carrier gas is nitrogen, and the flow rate of the carrier gas is 12 mL/min; the ultraviolet wavelength of the ultraviolet radiation is 365nm, and the radiation intensity is 200mW/cm2The irradiation distance is 10 cm;
the production process of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip is the same as that of example 6.
Example 10:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene-octene copolymer, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 21% of modified glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant, 1% of silicone powder, 0.5% of color master batch, 0.5% of silicone oil, 1% of organic tin stabilizer, UV-5311% and 1% of diimine hydrolysis resistant agent, wherein the surface of the plane skylight prepared from the components is coated with a 0.8 mu m transparent super-amphiphobic coating;
the preparation method of the modified glass fiber comprises the following steps: adding 15g of glass fiber and 100g of absolute ethyl alcohol into a supercritical device, soaking for 60min in a supercritical ethanol system with the temperature of 260 ℃ and the pressure of 8MPa, taking out and naturally drying; adding naturally air-dried glass fibers into a heating pipe which is horizontally placed, heating the heating pipe, simultaneously introducing ultrasonic atomized liquid into two ends of the heating pipe through carrier gas, and arranging an exhaust hole in the middle of the heating pipe; the ultrasonic atomization liquid is formed by adding the modified liquid into an ultrasonic atomization device and performing ultrasonic atomization; carrying out ultraviolet irradiation treatment on the glass fiber treated by the ultrasonic atomized liquid for 20 min; the preparation method of the modified liquid comprises the following steps: adding 1g polyvinyl alcohol, 3g tea polyphenol and 1g boron nitride nanometer into 200g water, stirring at 500r/min for 30min, and then pressurizing and ultrasonically dispersing for 90 min; the pressure of the pressurized ultrasonic dispersion is 1MPa, and the frequency is 55 KHz; the mass volume ratio of the glass fiber to the modification liquid is 1g:15 mL; the heating temperature of the heating pipe is 125 ℃; the technological parameters of the ultrasonic atomization are as follows: the frequency of the ultrasonic atomization is 2MHz, the carrier gas is nitrogen, and the flow rate of the carrier gas is 10 mL/min; the ultraviolet wavelength of the ultraviolet radiation is 200nm, and the radiation intensity is 150mW/cm2The irradiation distance is 5 cm;
the production process of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip is the same as that of the embodiment 5;
example 11:
the high-performance flame-retardant daylighting panel easy to melt and free of dripping comprises the following components in percentage by mass:
20% of low-density polyolefin, 20% of polypropylene, 10% of ethylene octene copolymer, 20% of intumescent flame retardant (ammonium polyphosphate and triazine charring agent with the mass ratio of 1: 1), 21% of modified glass fiber, 3% of maleic anhydride grafted polyethylene, 16180.5% of antioxidant, 10100.5% of antioxidant, 1% of silicone powder, 0.5% of silicone oil, 1% of organic tin stabilizer, 1% of UV-5311% and 1% of diimine hydrolysis resistant agent; wherein the surface of the plane skylight prepared from the components is coated with a 0.8-micron transparent super-amphiphobic coating;
the preparation method of the modified glass fiber comprises the following steps: adding 15g of glass fiber and 100g of absolute ethyl alcohol into a supercritical device, soaking for 60min in a supercritical ethanol system with the temperature of 260 ℃ and the pressure of 8MPa, taking out and naturally drying; adding naturally air-dried glass fibers into a heating pipe which is horizontally placed, heating the heating pipe, simultaneously introducing ultrasonic atomized liquid into two ends of the heating pipe through carrier gas, and arranging an exhaust hole in the middle of the heating pipe; the ultrasonic atomization liquid is formed by adding the modified liquid into an ultrasonic atomization device and performing ultrasonic atomization; carrying out ultraviolet irradiation treatment on the glass fiber treated by the ultrasonic atomized liquid for 20 min; the preparation method of the modified liquid comprises the following steps: adding 1g polyvinyl alcohol, 3g tea polyphenol and 1g boron nitride nanometer into 200g water, stirring at 500r/min for 30min, and then pressurizing and ultrasonically dispersing for 90 min; the pressure of the pressurized ultrasonic dispersion is 1MPa, and the frequency is 55 KHz; the mass volume ratio of the glass fiber to the modification liquid is 1g:15 mL; the heating temperature of the heating pipe is 125 ℃; the technological parameters of the ultrasonic atomization are as follows: the frequency of the ultrasonic atomization is 2MHz, the carrier gas is nitrogen, and the flow rate of the carrier gas is 10 mL/min; the ultraviolet wavelength of the ultraviolet radiation is 200nm, and the radiation intensity is 150mW/cm2The irradiation distance is 5 cm;
the production process of the high-performance flame-retardant daylighting panel which is easy to melt and does not drip is the same as that of example 7.
The materials prepared in examples 1-11 were tested for their relevant properties, wherein,
1. tensile strength: testing the tensile strength of the sample according to the method specified in GB/T1447-2005, tensile property test method for fiber reinforced plastics;
2. bending strength: testing the bending strength of the sample according to the method specified in GB/T1449-2005, method for testing the bending performance of the fiber reinforced plastics;
3. light transmittance: the light transmittance of the sample was measured according to the method specified in GB/T4206-2008 "measurement of light transmittance and haze of transparent plastics";
4. limiting oxygen index: testing the limiting oxygen index of the sample according to the method specified in GB2406-93 (plastics) test method for plastics combustion performance;
5. vertical burning test: the vertical burning grade of the sample is tested according to the method specified in GB 4609-1984 vertical burning method for testing the burning performance of the plastic;
6. heat distortion temperature: testing the heat distortion temperature of the sample according to the method specified in GB/T1634-2004 'measurement of Plastic load distortion temperature';
7. contact angle test: the surface contact angle of the sample was measured according to the method specified in GB/T30447-2013 'method for measuring contact angle of Nano thin film'.
TABLE 1
Figure BDA0002836782120000141
Figure BDA0002836782120000151
While embodiments of the invention have been described above, it is not limited to the applications set forth in the description and the embodiments, which are fully applicable to various fields of endeavor for which the invention may be embodied with additional modifications as would be readily apparent to those skilled in the art, and the invention is therefore not limited to the details given herein and to the examples shown and described without departing from the generic concept as defined by the claims and their equivalents.

Claims (10)

1. The high-performance flame-retardant lighting board material which is easy to melt and does not drip is characterized by comprising the following components in percentage by mass:
30-75% of polyolefin resin; 5-25% of low-melting-point resin; 20-30% of flame retardant; 15-40% of reinforcing fiber; 1-10% of a compatilizer; 0.5 to 1.5 percent of antioxidant; 0.5 to 1.5 percent of lubricant.
2. The fusible non-dripping high-performance flame-retardant daylighting plate material as claimed in claim 1, wherein the transparent super-amphiphobic coating with the thickness of 0.5-50 μm is coated on the surface of the prepared daylighting plate material to obtain the fusible non-dripping high-performance flame-retardant self-cleaning daylighting plate material.
3. The fusible non-dripping high-performance flame-retardant lighting board material according to claim 1, wherein the polyolefin resin is one or a combination of LDPE, LLDPE, HDPE, PP, EVA, POE, EPDM and PVC; the low-melting-point resin is one or a combination of more of chlorinated paraffin, chlorinated polyethylene, polyethylene wax and EVA; the flame retardant is one or a combination of more of intumescent flame retardant, phosphorus-nitrogen flame retardant, halogen flame retardant and phosphorus flame retardant; the compatilizer is one or a combination of more of maleic anhydride grafted polyethylene and maleic anhydride grafted polypropylene; the antioxidant is one or a combination of more of antioxidant 1618 and antioxidant 1010; the lubricant is one or a combination of more of silicone powder, ethylene wax, silicone oil and mineral oil; the reinforced fiber is one or more of glass fiber, carbon fiber, basalt fiber, aramid fiber, ceramic fiber, ramie fiber, jute fiber, bamboo fiber, mineral wool fiber or rock wool fiber.
4. A fusible non-drip high performance fire retardant daylighting sheet material according to claim 1, further comprising: 0.5 to 1.5 percent of color master batch; 0.5 to 1.5 percent of release agent; 0.5 to 1.5 percent of heat stabilizer; 0.5 to 1.5 percent of uvioresistant agent; 0.5-1.5% of hydrolysis resistant agent.
5. The fusible non-dripping high-performance flame-retardant lighting board material as claimed in claim 1, wherein the release agent is one or more of silicone powder, ethylene wax, silicone oil and mineral oil; the heat stabilizer is an organic tin stabilizer; the ultraviolet resistant agent is UV-531; the hydrolysis resistant agent is a diimine hydrolysis resistant agent.
6. The fusible non-dripping high-performance flame-retardant daylighting plate material according to claim 3, wherein the glass fiber is replaced by modified glass fiber, and the preparation method of the modified glass fiber comprises the following steps: adding 10-15 parts by weight of glass fiber and 50-120 parts by weight of absolute ethyl alcohol into a supercritical device, soaking for 60-75 min in a supercritical ethanol system with the temperature of 240-320 ℃ and the pressure of 6-10 MPa, taking out and naturally drying; adding naturally air-dried glass fibers into a heating pipe which is horizontally placed, heating the heating pipe, simultaneously introducing ultrasonic atomized liquid into two ends of the heating pipe through carrier gas, and arranging an exhaust hole in the middle of the heating pipe; the ultrasonic atomization liquid is formed by adding the modified liquid into an ultrasonic atomization device and performing ultrasonic atomization; carrying out ultraviolet irradiation treatment on the glass fiber treated by the ultrasonic atomized liquid for 15-25 min; the preparation method of the modified liquid comprises the following steps: according to the weight parts, 1-3 parts of polyvinyl alcohol, 3-5 parts of tea polyphenol and 0.5-1.5 parts of boron nitride are added into 200-300 parts of water in a nanometer mode, stirring is carried out for 15-30 min at the speed of 500-800 r/min, and then pressure ultrasonic dispersion is carried out for 60-90 min; the pressure of the pressurized ultrasonic dispersion is 0.8-1.5 MPa, and the frequency is 50-65 KHz; the mass volume ratio of the glass fiber to the modification liquid is 1g: 10-30 mL; heating the heating pipe at 120-150 ℃; the technological parameters of the ultrasonic atomization are as follows: the frequency of ultrasonic atomization is 1.5-3.5 MHz, the carrier gas is nitrogen, and the flow rate of the carrier gas is 10-15 mL/min; the ultraviolet wavelength of the ultraviolet radiation is 200-400 nm, and the radiation intensity is 150-250 mW/cm2And the irradiation distance is 5-10 cm.
7. A process for producing a fusible non-dripping high-performance flame-retardant daylighting sheet material according to claim 1, which comprises the following steps:
step one, taking polyolefin resin, low-melting-point resin, a flame retardant, a compatilizer, an antioxidant and a lubricant, drying, and mixing by a high-speed mixer to obtain a mixture;
step two, adding the mixture from the main feeding port of the screw extruder, adding continuous reinforcing fibers by adopting a melt impregnation method or adding the reinforcing fibers through the side feeding port of the extruder, and extruding and granulating under the process conditions that the extrusion temperature is 180-;
and step three, carrying out extrusion forming on the fiber reinforced polyolefin flame-retardant composite material by a multi-roll calender or preparing the fiber reinforced polyolefin flame-retardant composite material into a sheet by an injection molding machine and a plate pressing machine forming device to obtain the high-performance flame-retardant daylighting panel which is easy to melt and does not drip.
8. The process for producing a fusible non-dripping high-performance flame-retardant lighting board material according to claim 7, further comprising: step four, coating the transparent super-amphiphobic coating solution on the surface of the daylighting plate in a dip-coating or spraying mode, and drying in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.5-50 mu m on the surface of the daylighting plate, so that the high-performance flame-retardant self-cleaning daylighting plate which is easy to melt and does not drip is obtained; or before spraying the transparent super-amphiphobic coating solution, spraying/coating a layer of adhesive on the surface of the base material, then coating the transparent super-amphiphobic coating solution on the surface of the daylighting panel, and drying in a baking oven at normal temperature or 45 ℃ to obtain the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip; the adhesive is any one of polydimethylsiloxane, epoxy resin, commercial double-sided adhesive or 3M 77 spray adhesive;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 0.5-20 parts by mass of nano particles into a mixed solution of 200 parts by volume of water and anhydrous ethanol, then adding 1-5 parts by volume of positively charged silane coupling agent, stirring at normal temperature for 6 hours, then adding 0.5-20 parts by mass of micron particles with negatively charged surfaces, stirring for 2 hours, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 200-500 volume parts of ethanol solution, adding 0.5-3 volume parts of fluorosilane, stirring, mixing and reacting to obtain transparent super-amphiphobic coating solution; one or more of the nano-particle silicon dioxide, titanium dioxide or zinc oxide; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane or perfluorodecyl triethoxy silane.
9. A production process of the fusible non-dripping high-performance flame-retardant daylighting plate material according to claim 4, characterized by comprising the following steps:
step I, drying polyolefin resin, low-melting-point resin, a flame retardant, a compatilizer, an antioxidant, a lubricant, color master batches, a release agent, a heat stabilizer, an anti-ultraviolet agent and a hydrolysis resistance agent, and mixing by a high-speed mixer to obtain a mixture;
step II, adding the mixture from the main feeding port of the screw extruder, adding continuous reinforcing fibers by adopting a melt impregnation method or adding the reinforcing fibers through the side feeding port of the extruder, and extruding and granulating under the process conditions that the extrusion temperature is 180-;
and step III, carrying out extrusion forming on the fiber reinforced polyolefin flame-retardant composite material by a multi-roll calender or preparing the fiber reinforced polyolefin flame-retardant composite material into a sheet by an injection molding machine and a plate pressing machine forming device to obtain the high-performance flame-retardant daylighting panel which is easy to melt and does not drip.
10. A fusible non-drip high performance fire retardant daylighting sheet material according to claim 9, further comprising: step IV, coating the transparent super-amphiphobic coating solution on the surface of the daylighting panel in a dip-coating or spraying mode, and drying in a baking oven at normal temperature or 45 ℃ to coat the transparent super-amphiphobic coating with the thickness of 0.5-50 mu m on the surface of the daylighting panel; obtaining the easily-fusible and non-dripping high-performance flame-retardant self-cleaning daylighting panel; or before spraying the transparent super-amphiphobic coating solution, spraying/coating a layer of adhesive on the surface of the base material, then coating the transparent super-amphiphobic coating solution on the surface of the daylighting panel, and drying in a baking oven at normal temperature or 45 ℃ to obtain the high-performance flame-retardant self-cleaning daylighting panel which is easy to melt and does not drip; the adhesive is any one of polydimethylsiloxane, epoxy resin, commercial double-sided adhesive or 3M 77 spray adhesive;
the preparation method of the transparent super-amphiphobic coating solution comprises the following steps: ultrasonically dispersing 0.5-20 parts by mass of nano particles into a mixed solution of 200 parts by volume of water and anhydrous ethanol, then adding 0.5-3 parts by volume of positively charged silane coupling agent, stirring at normal temperature for 6 hours, then adding 0.5-20 parts by mass of micron particles with negatively charged surfaces, stirring for 2 hours, and separating and washing to obtain a micro-nano aggregate; dispersing the micro-nano aggregate into 200-500 volume parts of ethanol solution, adding 0.5-3 volume parts of fluorosilane, stirring, mixing and reacting to obtain transparent super-amphiphobic coating solution; one or more of the nano-particle silicon dioxide, titanium dioxide or zinc oxide; the positively charged silane coupling agent is dimethyl octadecyl [3- (trimethoxysilyl) propyl ] ammonium chloride; the electronegative microparticles are ammonium polyphosphate microparticles; the fluorosilane is perfluorodecyl trimethoxy silane or perfluorodecyl triethoxy silane.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115477811A (en) * 2022-10-08 2022-12-16 北京天罡助剂有限责任公司 Polypropylene composition for high-weather-resistance high-flame-retardant injection molding material and polypropylene injection molding material
WO2024099922A1 (en) * 2022-11-07 2024-05-16 Sabic Global Technologies B.V. Glass fiber reinforced thermoplastic composition with improved impact resistance

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002240205A (en) * 2001-02-16 2002-08-28 Hiraoka & Co Ltd Acid rain resistant flame retardant polyolefin resin sheet and its manufacturing method
CN102532693A (en) * 2010-12-28 2012-07-04 辽宁杰事杰新材料有限公司 High-performance low-smoke halogen-free flame-retardant polypropylene composite material and preparation method thereof
CN106674741A (en) * 2016-12-26 2017-05-17 重庆普利特新材料有限公司 High heat-resistant, halogen-free and flame-retardant type jute fiber-reinforced polypropylene composite material and preparation method thereof
CN109749243A (en) * 2018-12-29 2019-05-14 江苏和伟美科技发展有限公司 A kind of high glaze, it is resistance to be precipitated, low warpage enhancing halogen-free polypropylene flame redardant and preparation method thereof
CN110746695A (en) * 2019-11-06 2020-02-04 广州市聚赛龙工程塑料股份有限公司 Flame-retardant plant fiber reinforced modified polypropylene composite material and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002240205A (en) * 2001-02-16 2002-08-28 Hiraoka & Co Ltd Acid rain resistant flame retardant polyolefin resin sheet and its manufacturing method
CN102532693A (en) * 2010-12-28 2012-07-04 辽宁杰事杰新材料有限公司 High-performance low-smoke halogen-free flame-retardant polypropylene composite material and preparation method thereof
CN106674741A (en) * 2016-12-26 2017-05-17 重庆普利特新材料有限公司 High heat-resistant, halogen-free and flame-retardant type jute fiber-reinforced polypropylene composite material and preparation method thereof
CN109749243A (en) * 2018-12-29 2019-05-14 江苏和伟美科技发展有限公司 A kind of high glaze, it is resistance to be precipitated, low warpage enhancing halogen-free polypropylene flame redardant and preparation method thereof
CN110746695A (en) * 2019-11-06 2020-02-04 广州市聚赛龙工程塑料股份有限公司 Flame-retardant plant fiber reinforced modified polypropylene composite material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈茜: "《沉淀法二氧化硅的超疏水化原位改性及其在紫外光固化涂料中的应用》", 《硕士毕业论文》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115477811A (en) * 2022-10-08 2022-12-16 北京天罡助剂有限责任公司 Polypropylene composition for high-weather-resistance high-flame-retardant injection molding material and polypropylene injection molding material
WO2024099922A1 (en) * 2022-11-07 2024-05-16 Sabic Global Technologies B.V. Glass fiber reinforced thermoplastic composition with improved impact resistance

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