CN112580289A - Hybrid capacitor power state online estimation method and system - Google Patents

Hybrid capacitor power state online estimation method and system Download PDF

Info

Publication number
CN112580289A
CN112580289A CN202011411591.3A CN202011411591A CN112580289A CN 112580289 A CN112580289 A CN 112580289A CN 202011411591 A CN202011411591 A CN 202011411591A CN 112580289 A CN112580289 A CN 112580289A
Authority
CN
China
Prior art keywords
hybrid capacitor
time
current
peak
voltage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202011411591.3A
Other languages
Chinese (zh)
Other versions
CN112580289B (en
Inventor
王康丽
陈文欣
蒋凯
徐成
陈曼琳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huazhong University of Science and Technology
Original Assignee
Huazhong University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huazhong University of Science and Technology filed Critical Huazhong University of Science and Technology
Priority to CN202011411591.3A priority Critical patent/CN112580289B/en
Publication of CN112580289A publication Critical patent/CN112580289A/en
Application granted granted Critical
Publication of CN112580289B publication Critical patent/CN112580289B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F30/00Computer-aided design [CAD]
    • G06F30/30Circuit design
    • G06F30/36Circuit design at the analogue level
    • G06F30/367Design verification, e.g. using simulation, simulation program with integrated circuit emphasis [SPICE], direct methods or relaxation methods
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F30/00Computer-aided design [CAD]
    • G06F30/30Circuit design
    • G06F30/36Circuit design at the analogue level
    • G06F30/373Design optimisation
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2119/00Details relating to the type or aim of the analysis or the optimisation
    • G06F2119/10Noise analysis or noise optimisation

Landscapes

  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Evolutionary Computation (AREA)
  • Geometry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Measurement Of Resistance Or Impedance (AREA)

Abstract

The invention discloses a hybrid capacitor power state online estimation method and system, and belongs to the technical field of hybrid capacitor application. The method comprises the steps of obtaining a state space equation according to a hybrid capacitor equivalent circuit model, and discretizing the state space equation; the method comprises the steps of carrying out working condition testing on a hybrid capacitor, collecting a voltage value and a current value of the hybrid capacitor, and identifying parameters of a discretized state space equation on line by using a recursive augmented least square method with forgetting factors; the instantaneous peak power estimate and the sustained peak power estimate of the hybrid capacitor are estimated using the parameters obtained in real time. Compared with an offline power state estimation method, the online estimation method for the power state of the hybrid capacitor provided by the invention can realize online update of model parameters and improve the accuracy of the power state estimation of the hybrid capacitor.

Description

Hybrid capacitor power state online estimation method and system
Technical Field
The invention belongs to the technical field of hybrid capacitor application, and particularly relates to a hybrid capacitor power state online estimation method and system.
Background
Cheap and efficient electrochemical energy storage is a key technology for efficiently utilizing renewable energy and developing a smart grid. The hybrid capacitor is an advanced energy storage device developed recently, and has a wide application prospect in the fields of smart power grids, electric automobiles and the like. One pole of the hybrid capacitor stores and converts energy through electrochemical reaction of conventional battery electrodes, and the other pole stores energy through an absorption/desorption mechanism of an electric double layer. The energy density of the hybrid capacitor is 5-10 times higher than that of a double-electric-layer capacitor, and the power density and the cycle life of the hybrid capacitor are higher than those of a battery.
The power state may be used to characterize the peak power of the charge and discharge of the hybrid capacitor over a predetermined time interval. The real-time estimation of the peak power has important theoretical significance and practical value for reasonably using the hybrid capacitor, avoiding the over-charge and discharge phenomenon and prolonging the cycle life of the hybrid capacitor. Therefore, it is crucial to achieve an accurate estimation of the hybrid capacitor power state. Currently, a commonly used power state estimation method is an HPPC method based on a Rint model proposed by the national engineering and environmental laboratory of adadalton. The method neglects the dynamic characteristic of the hybrid capacitor, the calculated peak discharge current is too high, the peak charging current is too conservative, and the real-time characteristic of the hybrid capacitor is difficult to objectively reflect. Furthermore, the method is only directed to instantaneous peak power estimation, while in practical applications, continuous peak power estimation is more important.
Patent CN111060820A discloses a lithium battery SOC and SOP estimation method based on a second-order RC model. The method improves the original battery model which takes current as input and voltage as output into a model which takes voltage as input and current as output. For power state estimation, a model of the known current computation voltage can simplify the computation steps and reduce the computation amount. Patent CN111537894A discloses a method for lithium batteries SOC and SOP. The method fits the relationship between the temperature and the battery discharge capacity, and corrects the available capacity of the battery, thereby improving the accuracy of the estimation result. However, the above method only involves instantaneous peak power estimation, and the off-line parameter identification method is adopted, so that the circuit model parameters cannot be updated in real time, and the estimation effect in practical application is not ideal. Furthermore, the above methods are all based on lithium battery design and do not involve hybrid capacitors with significant differences in mechanism and performance.
In view of the above-mentioned deficiencies and inadequacies, further improvements and modifications are needed in the art. Aiming at the defects of the hybrid capacitor power state estimation method and the problem that the estimation effect of the existing method in practical application is not ideal, the effective hybrid capacitor power state on-line estimation method is designed, the requirements of practical application are met, and the reliability of the estimation result is improved.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide an effective hybrid capacitor power state online estimation method and system aiming at the defects that the existing power state estimation method has unsatisfactory practical application effect and is not suitable for a hybrid capacitor, so that the method and system are suitable for the requirements of practical application, the reliability of an estimation result is improved, and an important theoretical basis is provided for optimal matching of the power performance of the hybrid capacitor and optimization of a control strategy.
In order to achieve the above object, an aspect of the present invention provides an online estimation method for a power state of a hybrid capacitor, which collects voltage and current during operation of the hybrid capacitor based on an equivalent circuit model of the hybrid capacitor, updates model parameters in real time, and estimates instantaneous peak power and continuous peak power of the hybrid capacitor using the model parameters updated in real time. The specific method is realized according to the following steps:
s1, acquiring a state space equation according to a hybrid capacitor equivalent circuit model, and discretizing the state space equation;
preferably, the present invention employs a multi-model fused equivalent circuit model to characterize the external characteristics of the hybrid capacitor. The model includes a variable capacitance, an ohmic internal resistance, and a plurality of series connected RC circuits. Wherein, the variable capacitance C0Characterizing a hybrid capacitor dual electrochemical energy storage mechanism; ohmic internal resistance R0Characterization electrode material, electrolysisLiquid, diaphragm resistance and contact resistance of each part; the RC circuit is a circuit structure formed by connecting a resistor and a capacitor in parallel and represents the polarization characteristic of the hybrid capacitor.
According to kirchhoff's law, establishing a state space equation of a multi-model fusion equivalent circuit model:
Figure BDA0002818327310000031
wherein, C0Is a variable capacitance, R0Is ohmic internal resistance, RiIs the resistance of an RC circuit, CiI denotes the ith RC circuit, I is 1,2,3, …, n, I is the load current, U is the capacitance of the RC circuittIs terminal voltage, UC0And URCiAre respectively a variable capacitance C0And the voltage of the ith RC circuit,
Figure BDA0002818327310000032
representing its differential over time.
Discretizing the state equation to obtain:
Figure BDA0002818327310000033
in the formula, Δ t is a system sampling period. I iskLoad current at time k, Ut,kIs the terminal voltage of the hybrid capacitor at time k. U shapeC0,kIs a variable capacitance C at time k0Voltage of URCi,kIs the voltage of the ith RC circuit at time k.
S2, carrying out working condition testing on the hybrid capacitor, collecting the voltage value and the current value of the hybrid capacitor at the moment k, and utilizing a recursive augmented least square method with forgetting factors to identify parameters of the model on line according to the collected voltage value and current value of the hybrid capacitor;
under the zero initial condition, Z transformation and Z inverse transformation are carried out on the formula (2), and colored noise e in the model is consideredk
Preferably, in the present invention,colored noise ekBy calculating white noise wkIs obtained, the difference equation can be written as:
Figure BDA0002818327310000034
wherein, thetajIs a variable for the model parameter, j ═ 1,2,3, …,2n + 3. e.g. of the typekColored noise of the system at time k, wkWhite noise at time k, r is the order of the white noise moving average model, clIs the coefficient of the model, l ═ 1,2,3, …, r.
Further, equation (3) can be written as:
yk=Hkθk+wk (4)
in the formula, ykIs the mixed capacitor terminal voltage at time k, HkAnd thetakThe measured data matrix and the model parameter matrix of the hybrid capacitor at time k are respectively, namely:
Figure BDA0002818327310000041
preferably, the online parameter identification is carried out by adopting a recursive augmented least square method with a forgetting factor lambda. And the precision of the model in the whole life cycle is ensured through real-time parameter correction and updating. The algorithm recursion process is as follows:
Figure BDA0002818327310000042
in the formula, λ is forgetting factor, KkAs a gain matrix, PkIs an error covariance matrix of the parameter estimation values, and I is an identity matrix.
Further, related circuit parameters in the hybrid capacitor multi-model fusion equivalent circuit model can be calculated in real time.
S3, estimating instantaneous peak power and continuous peak power of the hybrid capacitor by using the parameters obtained in real time;
1) instantaneous peak power estimation
The output voltage equation for the hybrid capacitor equivalent circuit model can be written as:
Figure BDA0002818327310000043
then the current of the hybrid capacitor at time k is:
Figure BDA0002818327310000051
considering the voltage limiting conditions: u shapet,min≤Ut≤Ut,maxWherein U ist,minIs discharge cut-off voltage, Ut,maxIs the charge cut-off voltage. The instantaneous peak current of charging and discharging is:
Figure BDA0002818327310000052
in the formula,
Figure BDA0002818327310000053
and
Figure BDA0002818327310000054
respectively, the instantaneous peak discharge current and the instantaneous peak charge current at time k based on the voltage limit.
In order to ensure the safe and stable operation of the hybrid capacitor, the instantaneous charge-discharge current should satisfy:
Figure BDA0002818327310000055
wherein
Figure BDA0002818327310000056
Is the minimum pulse charging current that is to be charged,
Figure BDA0002818327310000057
is the maximum pulsed discharge current.
Further, the multi-constraint instantaneous peak current is:
Figure BDA0002818327310000058
in the formula,
Figure BDA0002818327310000059
and
Figure BDA00028183273100000510
the instantaneous peak charge current and the instantaneous peak discharge current, respectively, at time k, meet the voltage and current limits.
Further, the instantaneous peak power is calculated:
Figure BDA00028183273100000511
in the formula,
Figure BDA00028183273100000512
and
Figure BDA00028183273100000513
respectively, the instantaneous peak charging power and the instantaneous peak discharging power at time k.
2) Continuous peak power estimation
Preferably, formula (1) is rewritable:
xk+1=Akxk+Bkuk (12)
in the formula, xkIs the state vector of the model at time k, ukIs the control vector of the model at time k, AkIs the state matrix of the model at time k, BkIs the input matrix for the model at time k. The method comprises the following specific steps:
Figure BDA0002818327310000061
preferably, the model parameters within the time T x Δ T are assumed to be approximately constant, since the model parameters change slowly.
Further, assume that the inputs to the system are approximately equal over time T Δ T, i.e., uk+T=uk+T-1=…=ukThen, then
Figure BDA0002818327310000062
Substituting equation (14) into the output equation, the voltage at this time can be found to be:
Figure BDA0002818327310000063
then an approximation of the operating current during time T x Δ T may be calculated as:
Figure BDA0002818327310000064
further, the peak current based on the voltage limit over the duration of T × Δ T can be found:
Figure BDA0002818327310000071
in the formula,
Figure BDA0002818327310000072
and
Figure BDA0002818327310000073
respectively, a sustained peak charging current and a sustained peak discharging current at time k based on the voltage limit.
Preferably, T is 1, and equation (17) is the same as equation (9), i.e., equation (17) is a general equation for the calculation of the instantaneous peak current and the continuous peak current based on the voltage limitation.
In order to ensure the safe and stable operation of the hybrid capacitor, the continuous charge and discharge current should meet the following requirements:
Figure BDA0002818327310000074
wherein
Figure BDA0002818327310000075
Is the minimum continuous charging current that is to be charged,
Figure BDA0002818327310000076
is the maximum sustain discharge current.
Further, a multi-constraint sustained peak current can be obtained as:
Figure BDA0002818327310000077
in the formula,
Figure BDA0002818327310000078
and
Figure BDA0002818327310000079
respectively, a sustained peak charging current and a sustained peak discharging current that satisfy the voltage and current limits at time k.
Further, the sustained peak power is calculated:
Figure BDA00028183273100000710
in the formula,
Figure BDA00028183273100000711
and
Figure BDA00028183273100000712
respectively, the sustained peak charging power and the sustained peak discharging power at time k.
And S4, repeating the steps from S2 to S3 at the next sampling interval.
In another aspect, the present invention provides an online estimation system for power state of a hybrid capacitor, including: a computer-readable storage medium and a processor;
the computer-readable storage medium is used for storing executable instructions;
the processor is used for reading the executable instructions stored in the computer readable storage medium and executing the hybrid capacitor power state online estimation method.
Through the technical scheme, compared with the prior art, the invention has the following beneficial effects:
1. the hybrid capacitor power state online estimation method provided by the invention adopts a recursive augmented least square method with forgetting factors, and can realize real-time online update of the model parameters of the hybrid capacitor multi-model fusion equivalent circuit. Compared with an offline parameter identification method, the method can effectively track the parameter change of the model under different charging and discharging multiplying powers and aging states, and improve the precision of the hybrid capacitor model in the whole life cycle, thereby laying a foundation for accurate and reliable peak power.
2. Compared with an offline power state estimation method, the online estimation method for the power state of the hybrid capacitor provided by the invention can realize online update of model parameters and improve the accuracy of the power state estimation of the hybrid capacitor. In practical application, the method can ensure high precision of power state estimation under various working conditions thanks to real-time updating of model parameters.
3. The hybrid capacitor power state online estimation method provided by the invention is suitable for instantaneous peak power estimation and continuous peak power estimation, fills the blank of power state estimation in the field of hybrid capacitors, and provides an important application basis for optimal matching of hybrid capacitor power performance and optimization of a control strategy.
Drawings
FIG. 1 is a schematic diagram of a hybrid capacitor first-order multi-model fusion equivalent circuit model provided by the present invention;
FIG. 2 is a flow chart of a hybrid capacitor power state online estimation method provided by the present invention;
FIG. 3(a) is a graph of a current curve for a hybrid capacitor according to the present invention;
FIG. 3(b) is a voltage-voltage diagram of the hybrid capacitor according to the present invention;
FIG. 4(a) shows the variable capacitance C of the hybrid capacitor provided by the present invention under a working condition0A real-time recognition result diagram;
FIG. 4(b) shows the polarization capacitance C of the hybrid capacitor provided by the present invention under a working condition1A real-time recognition result diagram;
FIG. 4(c) is the ohmic internal resistance R of the hybrid capacitor provided by the present invention under the working condition0A real-time recognition result diagram;
FIG. 4(d) is the polarization internal resistance R of the hybrid capacitor provided by the present invention under the working condition1A real-time recognition result diagram;
FIG. 5(a) is a comparison graph of the estimation results of the instantaneous peak discharge current of the hybrid capacitor provided by the present invention under operating conditions;
FIG. 5(b) is a comparison graph of the estimation results of the instantaneous peak discharge power of the hybrid capacitor provided by the present invention under operating conditions;
FIG. 6(a) is a comparison graph of the estimation results of the sustained peak discharge current of the hybrid capacitor provided by the present invention at different times under different working conditions;
FIG. 6(b) is a comparison graph of the continuous peak discharge power estimation results of the hybrid capacitor provided by the present invention at different times under working conditions;
FIG. 6(c) is a graph comparing the online and offline continuous peak discharge current estimates for a hybrid capacitor provided in accordance with the present invention under operating conditions;
FIG. 6(d) is a graph comparing the online and offline sustained peak discharge power estimates for a hybrid capacitor provided in accordance with the present invention under operating conditions;
fig. 7(a) is a comparison graph of the estimation result of the instantaneous peak discharge current of the hybrid capacitor under the second working condition;
FIG. 7(b) is a comparison graph of the estimation result of the instantaneous peak discharge power of the hybrid capacitor under the second working condition;
fig. 8(a) is a comparison graph of the continuous peak discharge current estimation result of the hybrid capacitor provided by the present invention under the second working condition;
FIG. 8(b) is a comparison graph of the continuous peak discharge power estimation results of the hybrid capacitor provided by the present invention under the second operating condition;
fig. 8(c) is a comparison graph of the continuous peak discharge current estimation result of the hybrid capacitor provided by the present invention under the second working condition;
fig. 8(d) is a comparison graph of the continuous peak discharge power estimation result of the hybrid capacitor provided by the present invention under the second operating condition.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Fig. 1 is a schematic diagram of a hybrid capacitor first-order multi-model fusion equivalent circuit model provided by the invention.
In one embodiment of the invention, the hybrid capacitor cell tested was a lithium ion capacitor with a rated capacity of 160mAh and a model number of EVE SPC 1550.
In one embodiment of the present invention, n is 1, i.e., a first-order multi-model fusion equivalent circuit model is used to characterize the external characteristics of the tested lithium ion capacitor.
As shown in FIG. 1, the model includes 1 variable capacitor C 01 ohm internal resistance R0And 1 RC circuit. Wherein the variable capacitance C0The hybrid capacitor dual electrochemical energy storage mechanism is characterized. Ohmic internal resistance R0And characterizing electrode materials, electrolyte, diaphragm resistance and contact resistance of parts. The RC circuit is a circuit structure formed by connecting a resistor and a capacitor in parallel and represents the polarization characteristic of the hybrid capacitor.
Fig. 2 is a flow chart of a hybrid capacitor power state online estimation method provided by the invention. The method mainly comprises the following steps:
s1, acquiring a state space equation according to a hybrid capacitor equivalent circuit model, and discretizing the state space equation;
s2, carrying out working condition testing on the hybrid capacitor, collecting a voltage value and a current value of the hybrid capacitor at the moment k, substituting the collected voltage value and current value into a model, and identifying a parameter value of the model at the moment k on line by adopting a recursive augmented least square method with a forgetting factor;
s3, according to the model parameter value at the moment k, the peak current of the hybrid capacitor is calculated firstly by adopting the power state online estimation method provided by the invention, and then the peak power of the hybrid capacitor is calculated.
And S4, at the moment of k +1, repeating the steps S2-S3 until the whole working condition is finished.
Fig. 3(a) and 3(b) are a current curve and a voltage curve, respectively, for the working condition of the hybrid capacitor provided by the present invention.
Preferably, in one embodiment of the present invention, a Dynamic Stress Test (DST) condition is used, as shown, fig. 3(a) is a voltage curve of the hybrid capacitor under the DST condition, and fig. 3(b) is a current curve of the hybrid capacitor under the DST condition.
FIGS. 4(a) -4 (d) are respectively the model parameter variable capacitance C of the hybrid capacitor provided by the present invention under the working condition0And a polarization capacitor C1Ohmic internal resistance R0Internal polarization resistance R1The real-time recognition result is shown schematically.
In one embodiment of the invention, the forgetting factor λ is taken to be 0.996.
Further, the parameters of the first-order multi-model fusion equivalent circuit model of the hybrid capacitor can be obtained by real-time calculation, namely
Figure BDA0002818327310000111
As shown in the figure, by adopting the online parameter identification method provided by the invention, the parameters of the equivalent circuit model are updated online in real time under the DST working condition. Under the influence of factors such as different working conditions, aging states and the like, the model parameters updated in real time can effectively improve the precision of the equivalent circuit model of the hybrid capacitor in the whole life cycle, and further improve the precision of the power state estimation based on the model.
Preferably, the rated parameters of the lithium ion capacitor EVE SPC1550 used in the embodiment of the present invention are as follows:
Figure BDA0002818327310000112
fig. 5(a) and 5(b) are graphs comparing the estimation results of the instantaneous peak discharge current and the peak discharge power of the hybrid capacitor provided by the present invention under the working condition, respectively.
As shown in fig. 5(a), the instantaneous peak current calculated by the online estimation method provided by the present invention is strictly between the upper limit and the lower limit, while the instantaneous peak current calculated by the offline estimation method significantly exceeds the upper limit in the middle of the test condition. Fig. 5(b) shows the instantaneous peak power estimation results, and the instantaneous peak power estimation results obtained by the online power state estimation method provided by the present invention are all between the upper and lower limits, while the offline estimation method is out of range. Therefore, compared with an offline estimation method, the online estimation method effectively improves the reliability and accuracy of the hybrid capacitor power state estimation.
In one embodiment of the invention, continuous power state estimation is performed for the hybrid capacitor for 30s, 60s, 90s, 120s, respectively.
As shown in fig. 6(a) -6 (d), it can be seen that the sustained peak discharge capability of the hybrid capacitor is related to the sustained output time length, i.e., the sustained peak discharge capability decreases with increasing sustained output time. However, the 120s continuous peak power obtained by the offline estimation method is higher than the 30s continuous peak power obtained by the online estimation method provided by the present invention, which means that the power estimation result obtained by the offline estimation method is very unreliable under the condition that the model parameters are not updated in real time, and thus the power state online estimation method provided by the present invention can improve the reliability of the power state estimation of the hybrid capacitor by updating the parameters in real time.
Fig. 7(a) and 7(b) are comparative graphs of the estimation results of the instantaneous peak discharge current and the peak discharge power of the hybrid capacitor provided by the invention under the second working condition.
Fig. 8(a) -8 (d) are comparative graphs of continuous power state estimation results of the hybrid capacitor provided by the invention under the second working condition.
Preferably, in another embodiment of the present invention, the U.S. federal city operating conditions (FUDS) are employed. Under the FUDS working condition, the instantaneous power state estimation result and the continuous power state estimation result obtained by the hybrid capacitor power state online estimation method provided by the invention are still accurate and reliable, and the estimation result obtained by the offline estimation method has larger deviation, so that the hybrid capacitor power state online estimation method provided by the invention has stronger applicability and can effectively improve the reliability and the accuracy of hybrid capacitor power state estimation in practical application.
It will be understood by those skilled in the art that the foregoing is only a preferred embodiment of the present invention, and is not intended to limit the invention, and that any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (9)

1. A hybrid capacitor power state online estimation method is characterized by comprising the following steps:
s1, acquiring a state space equation according to a hybrid capacitor equivalent circuit model, and discretizing the state space equation;
s2, carrying out working condition testing on the hybrid capacitor, collecting a voltage value and a current value of the hybrid capacitor at the moment k, and identifying parameters of the discretized state space equation on line by using a recursive augmented least square method with forgetting factors;
s3, estimating instantaneous peak power estimation and continuous peak power of the hybrid capacitor by using the parameters obtained in real time in S2;
and S4, at the moment of k +1, repeating the steps S2-S3 until the whole working condition is finished.
2. The hybrid capacitor power state online estimation method of claim 1, wherein the hybrid capacitor equivalent circuit model comprises a variable capacitance, an ohmic internal resistance, and a plurality of series-connected RC circuits, and the state space equation is expressed as:
Figure FDA0002818327300000011
wherein, C0Is a variable capacitance, R0Is ohmic internal resistance, RiIs the resistance of the ith RC circuit, CiCapacitance of the ith RC circuit, RCiThe ith RC circuit is shown, I is 1,2,3, …, n, I is the load current, UtTerminal voltage of hybrid capacitor, UC0And URCiAre respectively a variable capacitance C0And the voltage of the ith RC circuit,
Figure FDA0002818327300000012
representing the differential over time.
3. The hybrid capacitor power state online estimation method of claim 2, wherein the discretized state space equation is expressed as:
Figure FDA0002818327300000021
where Δ t is the system sampling period, IkLoad current at time k, Ut,kTerminal voltage of the hybrid capacitor at time k, UC0,kIs a variable capacitance C at time k0Voltage of URCi,kIs the voltage of the ith RC circuit at time k.
4. The hybrid capacitor power state online estimation method of claim 3, wherein the discretized state space equation is subjected to Z transformation and Z inverse transformation to obtain a differential equation with time delay:
Ut,k=θ1Ut,k-1+…+θn+1Ut,k-n-1n+2Ik+…+θ2n+3Ik-n-1+wk+c1wk-1+c2wk-2+…+crwk-r (3)
wherein, thetajIs a variable related to the model parameter, j ═ 1,2,3, …,2n +3, wkWhite noise at time k, r is the order of the white noise moving average model, clIs the coefficient of the model, l ═ 1,2,3, …, r.
5. The hybrid capacitor power state online estimation method of claim 4, wherein the output measurement of the system at time k is represented as:
yk=Hkθk+wk (4)
Figure FDA0002818327300000022
wherein, ykIs the output measurement of the system at time k, HkAnd thetakRespectively a data matrix and a parameter matrix at time k.
6. The hybrid capacitor power state online estimation method of claim 5, wherein the recursive process of the recursive augmented least squares with forgetting factor is as follows:
Figure FDA0002818327300000023
whereinλ is forgetting factor, KkAs a gain matrix, PkIs an error covariance matrix of the parameter estimation values, and I is an identity matrix.
7. The hybrid capacitor power state online estimation method of claim 1, wherein the instantaneous peak power estimation of the hybrid capacitor specifically comprises:
the output voltage equation of the hybrid capacitor equivalent circuit model is expressed as:
Figure FDA0002818327300000031
the current of the hybrid capacitor at time k is:
Figure FDA0002818327300000032
the instantaneous peak current of charging and discharging is:
Figure FDA0002818327300000033
wherein,
Figure FDA0002818327300000034
and
Figure FDA0002818327300000035
instantaneous peak discharge current and instantaneous peak charge current, U, based on voltage limits at time k, respectivelyt,minIs discharge cut-off voltage, Ut,maxIs the charge cut-off voltage, Ut,min≤Ut≤Ut,max
The multi-constraint instantaneous peak current is:
Figure FDA0002818327300000036
in the formula,
Figure FDA0002818327300000037
and
Figure FDA0002818327300000038
respectively the instantaneous peak charge current and the instantaneous peak discharge current at time k satisfying the voltage and current limits,
Figure FDA0002818327300000039
is the minimum pulse charging current that is to be charged,
Figure FDA00028183273000000310
is the maximum pulse of the discharge current of the discharge,
Figure FDA00028183273000000311
the instantaneous peak power is:
Figure FDA0002818327300000041
in the formula,
Figure FDA0002818327300000042
and
Figure FDA0002818327300000043
respectively, the instantaneous peak charging power and the instantaneous peak discharging power at time k.
8. The hybrid capacitor power state online estimation method of claim 1, wherein the continuous peak power estimation of the hybrid capacitor specifically comprises:
xk+1=Akxk+Bkuk (12)
in the formula, xkIs the state vector of the model at time k, ukIs the control vector of the model at time k, AkIs the state matrix of the model at time k, BkThe input matrix of the k-time model is as follows:
Figure FDA0002818327300000044
the inputs to the system are equal during the time T x Δ T, i.e. uk+T=uk+T-1=…=ukThen, then
Figure FDA0002818327300000045
The voltages at this time are:
Figure FDA0002818327300000046
the working current within T multiplied by delta T time is obtained as follows:
Figure FDA0002818327300000047
the peak current based on the voltage limit for the duration of T Δ T is:
Figure FDA0002818327300000051
in the formula,
Figure FDA0002818327300000052
and
Figure FDA0002818327300000053
respectively at time kA sustained peak charging current and a sustained peak discharging current based on the voltage limit;
the multi-constraint sustained peak current is:
Figure FDA0002818327300000054
in the formula,
Figure FDA0002818327300000055
and
Figure FDA0002818327300000056
respectively sustained peak charging current and sustained peak discharging current satisfying voltage and current limits at time k,
Figure FDA0002818327300000057
is the minimum continuous charging current that is to be charged,
Figure FDA0002818327300000058
is the maximum sustained discharge current that is to be discharged,
Figure FDA0002818327300000059
the sustained peak power is:
Figure FDA00028183273000000510
in the formula,
Figure FDA00028183273000000511
and
Figure FDA00028183273000000512
respectively, the sustained peak charging power and the sustained peak discharging power at time k.
9. A hybrid capacitor power state online estimation system, comprising: a computer-readable storage medium and a processor;
the computer-readable storage medium is used for storing executable instructions;
the processor is configured to read executable instructions stored in the computer-readable storage medium and execute the hybrid capacitor power state online estimation method according to any one of claims 1 to 8.
CN202011411591.3A 2020-12-04 2020-12-04 Hybrid capacitor power state online estimation method and system Active CN112580289B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011411591.3A CN112580289B (en) 2020-12-04 2020-12-04 Hybrid capacitor power state online estimation method and system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011411591.3A CN112580289B (en) 2020-12-04 2020-12-04 Hybrid capacitor power state online estimation method and system

Publications (2)

Publication Number Publication Date
CN112580289A true CN112580289A (en) 2021-03-30
CN112580289B CN112580289B (en) 2024-03-19

Family

ID=75128266

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011411591.3A Active CN112580289B (en) 2020-12-04 2020-12-04 Hybrid capacitor power state online estimation method and system

Country Status (1)

Country Link
CN (1) CN112580289B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112580284A (en) * 2020-12-04 2021-03-30 华中科技大学 Hybrid capacitor equivalent circuit model and online parameter identification method
CN113655280A (en) * 2021-08-13 2021-11-16 海南师范大学 Insulation resistance value detection method during connection of power battery of electric automobile
CN114186522A (en) * 2021-12-08 2022-03-15 华中科技大学 Construction method and application of hybrid capacitor power state online estimation model

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103947013A (en) * 2011-10-07 2014-07-23 应用纳米结构解决方案有限责任公司 Hybrid capacitor-battery and supercapacitor with active bi-functional electrolyte
CN104271880A (en) * 2011-05-24 2015-01-07 快帽系统公司 Power system for high temperature applications with rechargeable energy storage
CN105301509A (en) * 2015-11-12 2016-02-03 清华大学 Combined estimation method for lithium ion battery state of charge, state of health and state of function
CN106354964A (en) * 2016-09-08 2017-01-25 厦门理工学院 Charge state estimation method of lithium-ion capacitor for electric automobile
US20180166892A1 (en) * 2013-05-17 2018-06-14 Electro Standards Laboratories Hybrid super-capacitor / rechargeable battery system
GB201907497D0 (en) * 2019-05-28 2019-07-10 Gupta Sanjay An apparatus and method for discharging the hybrid battery modules, and extending the range of the battery pack
CN110361642A (en) * 2019-07-11 2019-10-22 中国科学院电工研究所 A kind of prediction technique, device and the electronic equipment of capacitor state-of-charge
CN110395141A (en) * 2019-06-27 2019-11-01 武汉理工大学 Dynamic lithium battery SOC estimation method based on adaptive Kalman filter method
CN111856178A (en) * 2020-03-31 2020-10-30 同济大学 SOC partition estimation method based on electrochemical characteristics of lithium ion capacitor

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104271880A (en) * 2011-05-24 2015-01-07 快帽系统公司 Power system for high temperature applications with rechargeable energy storage
CN103947013A (en) * 2011-10-07 2014-07-23 应用纳米结构解决方案有限责任公司 Hybrid capacitor-battery and supercapacitor with active bi-functional electrolyte
US20180166892A1 (en) * 2013-05-17 2018-06-14 Electro Standards Laboratories Hybrid super-capacitor / rechargeable battery system
CN105301509A (en) * 2015-11-12 2016-02-03 清华大学 Combined estimation method for lithium ion battery state of charge, state of health and state of function
CN106354964A (en) * 2016-09-08 2017-01-25 厦门理工学院 Charge state estimation method of lithium-ion capacitor for electric automobile
GB201907497D0 (en) * 2019-05-28 2019-07-10 Gupta Sanjay An apparatus and method for discharging the hybrid battery modules, and extending the range of the battery pack
CN110395141A (en) * 2019-06-27 2019-11-01 武汉理工大学 Dynamic lithium battery SOC estimation method based on adaptive Kalman filter method
CN110361642A (en) * 2019-07-11 2019-10-22 中国科学院电工研究所 A kind of prediction technique, device and the electronic equipment of capacitor state-of-charge
CN111856178A (en) * 2020-03-31 2020-10-30 同济大学 SOC partition estimation method based on electrochemical characteristics of lithium ion capacitor

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
岳伟;黄钰强;徐佳宁;朱春波;李晓宇;: "锂离子混合型电容器在线参数辨识方法研究", 电器与能效管理技术, no. 05, pages 106 - 110 *
杨斌;吴慧;胡颂伟;吕惠玲;宋晔;朱绪飞;: "电解-电化学混合电容器的制备与性能", 物理化学学报, vol. 29, no. 05, pages 1013 - 1020 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112580284A (en) * 2020-12-04 2021-03-30 华中科技大学 Hybrid capacitor equivalent circuit model and online parameter identification method
CN113655280A (en) * 2021-08-13 2021-11-16 海南师范大学 Insulation resistance value detection method during connection of power battery of electric automobile
CN113655280B (en) * 2021-08-13 2023-09-26 海南师范大学 Insulation resistance value detection method during connection of power batteries of electric vehicles
CN114186522A (en) * 2021-12-08 2022-03-15 华中科技大学 Construction method and application of hybrid capacitor power state online estimation model

Also Published As

Publication number Publication date
CN112580289B (en) 2024-03-19

Similar Documents

Publication Publication Date Title
CN112526348B (en) Battery model parameter identification method based on multi-innovation recursive Bayesian algorithm
Eddahech et al. Behavior and state-of-health monitoring of Li-ion batteries using impedance spectroscopy and recurrent neural networks
CN107576919A (en) Power battery charged state estimating system and method based on ARMAX models
CN112580289A (en) Hybrid capacitor power state online estimation method and system
CN109633456B (en) Power lithium battery pack SOC estimation method based on segmented voltage identification method
CN105954679A (en) Lithium battery charge state online estimating method
CN103020445A (en) SOC (State of Charge) and SOH (State of Health) prediction method of electric vehicle-mounted lithium iron phosphate battery
CN112580284B (en) Hybrid capacitor equivalent circuit model and online parameter identification method
CN109239602B (en) Method for estimating ohmic internal resistance of power battery
CN111856282B (en) Vehicle-mounted lithium battery state estimation method based on improved genetic unscented Kalman filtering
CN110795851A (en) Lithium ion battery modeling method considering environmental temperature influence
Li et al. A novel state estimation approach based on adaptive unscented Kalman filter for electric vehicles
CN108445422B (en) Battery state of charge estimation method based on polarization voltage recovery characteristics
CN109143097A (en) It is a kind of meter and temperature and cycle-index lithium ion battery SOC estimation method
CN112858920B (en) SOC estimation method of all-vanadium redox flow battery fusion model based on adaptive unscented Kalman filtering
CN115389936A (en) Online prediction method for continuous peak power capability of digital-analog hybrid driven lithium battery
CN111965544B (en) Method for estimating minimum envelope line SOC of vehicle parallel power battery based on voltage and current dual constraints
Shen et al. State of charge, state of health and state of function co-estimation of lithium-ion batteries for electric vehicles
CN113807039A (en) Power state prediction method of series battery system
Wang et al. Lithium-ion battery security guaranteeing method study based on the state of charge estimation
CN112946481A (en) Based on federation H∞Filtering sliding-mode observer lithium ion battery SOC estimation method and battery management system
CN115327415A (en) Lithium battery SOC estimation method based on limited memory recursive least square algorithm
CN116047308A (en) Lithium battery SOC estimation method based on PID control and DEKF
CN114720881A (en) Lithium battery parameter identification method based on improved initial value forgetting factor recursive least square method
Lin et al. Novel polarization voltage model: Accurate voltage and state of power prediction

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant