CN1125757A - Anticorrosion petrolatum belt and its manufacturing process and impregnator - Google Patents

Anticorrosion petrolatum belt and its manufacturing process and impregnator Download PDF

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Publication number
CN1125757A
CN1125757A CN 94114068 CN94114068A CN1125757A CN 1125757 A CN1125757 A CN 1125757A CN 94114068 CN94114068 CN 94114068 CN 94114068 A CN94114068 A CN 94114068A CN 1125757 A CN1125757 A CN 1125757A
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China
Prior art keywords
rubber
petroleum jelly
resin
belt
dressing
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Pending
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CN 94114068
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Chinese (zh)
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张斌
李青峰
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JINJIANG FINE CHEMICAL WORKS SHANGHAI
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JINJIANG FINE CHEMICAL WORKS SHANGHAI
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Priority to CN 94114068 priority Critical patent/CN1125757A/en
Publication of CN1125757A publication Critical patent/CN1125757A/en
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Abstract

The invention relates to a petrolatum belt, which relates to a metal anticorrosive material and mainly comprises the following substances in parts by weight: mineral oil 0.4-18, rubber 14-47, resin 15-27, wax 5-14, and right amount of filler and adjuvant, and is coated on the fabric in a special dipping machine. The mineral fat belt of the invention has good moisture resistance, acid and alkali corrosion resistance and good adhesion performance to metal base materials, can be widely applied to metal components, in particular to the rust prevention of metal parts contacting with acid, alkali and saline water, has simple preparation process and special equipment structure, is convenient to operate, and has low product cost.

Description

Anticorrosion petroleum jelly belt and manufacturing process thereof and cement dipping machine
Anticorrosion petroleum jelly belt relates to the anti-corrosion of metal material.
The metallic surface is corrosion easily under the effect of acid, alkali, salt and damp atmosphere, this is the difficult problem that electromechanical product and many metal productss are exerting to capture, petroleum jelly belt is that a kind of metallic surface that is wrapped in Any shape is also pasted on it securely, form the isolated moisture of one deck, acid, alkali, salt fog and microorganism to the anti-corrosion of metal material of the corrosive nature of metal base, be combined into the dressing coated by elasticity and adhesion material and form in fabric.
Since the eighties, petroleum jelly belt begins to try out at some national shipbuilding industries of Europe as metallic antirust material, Japan also begins to have successively product patent open in recent years, disclosing April 20 Japanese clear 6 286079 in 1984 a kind of is that dressing is coated in the petroleum jelly belt of making on the base materials such as paper, tNonwovens, cloth or foam film by natural rubber, terpine resin, potassium oleate, aluminum oxide dispersion thing, the diffusing thing of sulphur content, vulcanization accelerator, the breaking tenacity of its product performance is 3.5 Ns/centimetre, and other performance data is not seen specifically and disclosed; Japan has seen the commercially available petroleum jelly belt product that productions such as ponding chemical industrial company are arranged at present, but does not see the introduction of concrete component and production technique.
Existing commercially available petroleum jelly belt commodity all exist and cost an arm and a leg, and problem that performance is also not fully up to expectations such as work-ing life are short, hardening easy to change etc.
The objective of the invention is to provide a kind of new, cost is lower, and work-ing life is longer, the petroleum jelly belt and the manufacture method thereof of better performances such as not easy to change and change.
The present invention is achieved in that petroleum jelly belt mainly adds an amount of filler again by mineral oil, rubber, resin and auxiliary agent is combined into vaseline dressing, and then the dressing coated is formed in fabric.Wherein:
Mineral oil, for black petroleum products through underpressure distillation, refining get the oily substance that viscosity is the long carbochain alkane of 10~15cp (25 ℃), in the vaseline material, mainly play anticorrosion, act on every wetting, also play diluting effect in addition.
Resin, mainly be to make dressing have stronger sticking power to metal, it can be Resins, epoxy, modified terpene resin, petroleum resin, Gum Rosin, coumarone-indene resin, modified phenolic resins, polyolefin resin, alkyd resin, urethane resin or the like, preferably modified resin.Because of it can have better adhesivity and water tolerance, temperature tolerance, weather resistance.
Rubber mainly is to make dressing have certain elasticity, makes vaseline have certain flexibility, waterproof, preservative property and easy application property.They can be isobutene rubber, styrene-butadiene rubber(SBR), natural rubber, fluid rubber, paracril, cis-1,4-polybutadiene rubber, ethylene-propylene rubber(EPR), silicon rubber etc., preferably modified rubber.
The weight proportion of described dressing each component is: mineral oil 0.4~18, rubber 14~47, resin 15~27, wax 5~14, filler 3~32, other auxiliary agents 0.7~5 such as sanitas, anti-aging agent.
The blending process of vaseline dressing is:
(1) allotment rubber: with described rubber 40~45 weight parts, wax 2~90 weight parts are inserted in the reactor of band heating and whipping appts, and at 50~105 ℃, 800 rev/mins of stirrings are reacted after 16 hours down and must be prepared body A;
(2), telomerize resin: get gained preparation body A100 weight part, with described resin 25.5~~13 weight parts, mineral oil 10~13 weight parts, at 100~180 ℃, 800 rev/mins of stirrings are reacted after 4 hours down and are cooled to 80 ℃, take advantage of heat filtering, remove filter residue, filtrate is cooled to 40 ℃ with bottom discharge, promptly gets petroleum jelly belt dressing of the present invention.
Petroleum jelly belt dressing of the present invention optionally also can add an amount of mineral filler such as wilkinite, lime carbonate, precipitated silica when telomerizing resin; The sanitas hexahydroaniline, antioxidant D etc.
The moulding process of petroleum jelly belt:
The above-mentioned petroleum jelly belt dressing for preparing is contained in the steeping vat, be warming up to 100~120 ℃, smooth fabric base band is sent in the steeping vat by motor floods, the transfer rate of base band is 8~12 meters/hour, belt is after steeping vat output, go up volume through being chilled to 45 ℃, promptly get the petroleum jelly belt finished product.
Make the special dipping machine of petroleum jelly belt of the present invention:
This cement dipping machine comprises that one places the steeping vat that petroleum jelly belt dressing can be contained on the support in wherein heating, is located at the tape-feed of steeping vat front end, the tape mechanism of tail end top.Tape-feed comprises the supply roll that is driven two synchronous rollings by motor; Be equipped with the heating unit of a temperature adjustable at the bottom of the steeping vat in the interlayer, several parallel being located in the steeping vat of infiltration axle that are used for base band is pressed into glue; The below of tape mechanism and steeping vat are connected to one and are used for the glue that tape surface is unnecessary and squeeze a pair of plastic squeeze axle go, place a side of plastic squeeze axle, also have an accent crack plate that is used for regulating two plastic squeeze between centers cracks; Tape mechanism is by last roll support, upper winding shaft and prevent that the unexpected upper winding shaft cap that falls of the roll coil of strip from forming.
Petroleum jelly belt performance index of the present invention are suitable with Japan commercially available petroleum jelly belt under the same test condition, and indivedual indexs are better than japanese product, and the result of materiology is as follows:
Interventions Requested (unit) Main test conditions Assay
Japanese product Product of the present invention
Water-intake rate, % 23±2℃,24h 1.1 1.3
Thermotolerance 85℃,5h Fricton-tight and centrality bubble Fricton-tight and centrality bubble
Low temperature flexibility -20℃,2h,φ25mm Flawless Flawless
Corrosion-resistant 25%HCl liquid soaks 24h 25%NaOH liquid and soaks 2h 25%NaCl liquid and soak 24h No abnormal no abnormal No abnormal no abnormal
The right angle tear strength, N/mm 23±2℃ 7.6 27.3
Petroleum jelly belt of the present invention is because its dressing has well damp proof and antiacid caustic corrosion and to the good adhesive performance of metal base, can be widely used in hardware, particularly the metal parts that contacts with acid, alkali, salt solution is antirust, and preparation technology and special dipping machine structure are all convenient than simple operations, so that product cost is also cheaper.
The following drawings and embodiment will be described further technical characterictic of the present invention:
Fig. 1 is a special dipping machine structure front elevational schematic of the present invention.
Fig. 2 is the schematic side view of Fig. 1.
Embodiment 1, the structure of the special dipping machine of petroleum jelly belt of the present invention:
This cement dipping machine comprises that one places the steeping vat 1 that petroleum jelly belt dressing can be contained on the support 2,3 in wherein heating, is located at the tape-feed of steeping vat 1 front end, the tape mechanism of tail end top.Tape-feed comprises the supply roll 4,5 that is driven two synchronous rollings by motor; 1 end of steeping vat interlayer is equipped with the heating unit 10 of a temperature adjustable, several infiltration axle 6 parallel being located in the steeping vat 1 that are used for base band is pressed into glue; The below of tape mechanism and steeping vat 1 are connected to one and are used for the glue that tape surface is unnecessary and squeeze a pair of plastic squeeze axle 7 go, place a side of plastic squeeze axle 7, also have an accent crack plate 9 that is used for regulating two plastic squeeze axles, 7 gaps; Tape mechanism is by last roll support 8, upper winding shaft 11 and prevent that the unexpected upper winding shaft cap 12 that falls of the roll coil of strip from forming.
Embodiment 2, the preparation of petroleum jelly belt dressing:
Get isoprene-isobutylene rubber 40 gram, Chinese wax 32 grams, yellow wax 58 grams, in reactor, warming while stirring, at 50~105 ℃, preferably 60~95 ℃ of following stirring reactions are 16 hours, make preparation body A; Get preparation body A100 gram then, modified epoxy 15 grams, petroleum resin 15 grams, Gum Rosin 5 grams, mineral oil 10 gram plays thin lime carbonate (or wilkinite, precipitated silica) 8 grams, warming while stirring to 120~180 ℃, preferably 130~150 ℃, react and be cooled to 80 ℃ after 4 hours, take advantage of heat filtering, remove filter residue, filtrate is chilled to 40 ℃ of dischargings, promptly gets petroleum jelly belt dressing of the present invention.
Embodiment 3, the preparation of petroleum jelly belt dressing:
Get isoprene-isobutylene rubber 40 grams, silicon rubber 5 grams, wax 2 grams are in reactor, warming while stirring is stirred down at 50~105 ℃, reacts 16 hours, makes preparation body A, get the A100 gram then, cured 20 grams of tree oil, resol 5.5 grams, mineral oil 13 grams, calcium carbonate superfine powder 5 grams, sanitas hexahydroaniline 3 grams, antioxidant D 2 grams, warming while stirring to 120~180 ℃ are reacted and are cooled to 80 ℃ after 4 hours, take advantage of heat filtering, remove filter residue, filtrate is chilled to 40 ℃ of dischargings, promptly gets petroleum jelly belt dressing of the present invention.
Embodiment 4, the preparation of petroleum jelly belt dressing:
Get isobutene rubber 15 grams, silicon rubber 5 grams, wax 2 grams, natural rubber 5 grams, in reactor, warming while stirring, stir down at 50~105 ℃, reacted 16 hours, make preparation body A, get the A100 gram then, coumarone-indene resin 7.5 grams, cured 7 grams of tree oil, Gum Rosin 2.5 grams, naphthenic oil 6 grams, wilkinite 4 grams, sanitas hexahydroaniline 0.5 gram, precipitated silica 3 grams, antioxidant D 1 gram, warming while stirring to 120~180 ℃ are reacted and are cooled to 80 ℃ after 4 hours, take advantage of heat filtering, remove filter residue, filtrate is chilled to 40 ℃ of dischargings, promptly gets petroleum jelly belt dressing of the present invention.
Embodiment 5, the preparation of petroleum jelly belt dressing:
Get styrene-butadiene rubber(SBR) (or butyronitrile, ethylene-propylene rubber(EPR)) 8 grams, wax 3 grams, in reactor, warming while stirring, stir down at 50~105 ℃, reacted 16 hours, make preparation body A, get the A100 gram then, vibrin 6 grams, Gum Rosin 6 grams, naphthenic oil 10 grams, wilkinite 20 grams, sanitas hexahydroaniline 1.8 grams, antioxidant D 2 grams, warming while stirring to 120~180 ℃ are reacted and are cooled to 80 ℃ after 4 hours, take advantage of heat filtering, remove filter residue, filtrate is chilled to 40 ℃ of dischargings, promptly gets petroleum jelly belt dressing of the present invention.
Embodiment 6, the moulding of petroleum jelly belt:
1, choose closely knit, smooth polyamide fibre non-woven fabrics as base band,
2, embodiment 2~5 prepared petroleum jelly belt dressing are contained in the steeping vat of Li Faming specific equipment, under 100~120 ℃, above-mentioned base band is sent in the steeping vat by motor floods, the transfer rate of base band is 8~12 meters/hour, belt is rolled up on being chilled to below 45 ℃ the petroleum jelly belt finished product after steeping vat output.Look and choose base material width difference, can make the petroleum jelly belt product of 100 centimetres of 5 cm x and 1000 centimetres of two kinds of different sizes of 10 cm x.
Embodiment 7, and the reparation technology of petroleum jelly belt, defeated tape speed are 15~26 meters/hour, and dipping temperature is 70~100 ℃, and all the other are with embodiment 1.
Embodiment 8, and the reparation technology of petroleum jelly belt, defeated tape speed are 22~30 meters/hour, and dipping temperature is 80~105 ℃, and all the other are with embodiment 1.
Embodiment 9, and the reparation technology of petroleum jelly belt, defeated tape speed are 20~25 meters/hour, and dipping temperature is 100~120 ℃, and all the other are with embodiment 1.

Claims (4)

1, a kind of petroleum jelly belt is mainly formed in fabric every the elasticity of wet antiacid alkali and the vaseline dressing coated that adhesion material is made by tool, it is characterized in that petroleum jelly belt dressing has following component:
Mineral oil is the fraction of black petroleum products through underpressure distillation, and gained viscosity is 10~15cp (oily substance of the long carbochain alkane that (25 ℃) get after making with extra care again;
Resin mainly is Resins, epoxy, modified terpene resin, petroleum resin, Gum Rosin, coumarone-indene resin, modified phenolic resins, polyolefin resin, alkyd resin, urethane resin etc., preferably modified resin;
Rubber mainly is isobutene rubber, styrene-butadiene rubber(SBR) natural rubber, fluid rubber, paracril, cis-1,4-polybutadiene rubber, ethylene-propylene rubber(EPR), silicon rubber or the like, preferably modified rubber.
The weight proportion of the each component of dressing:
10~13 parts in mineral oil, 40~45 parts of rubber, 25.5~35 parts of resins.
2, petroleum jelly belt according to claim 1 is characterized in that, also includes an amount of mineral filler in the component of petroleum jelly belt dressing, as wilkinite, lime carbonate, precipitated silica etc. and other auxiliary agent, and as the sanitas hexahydroaniline, antioxidant D etc.
3, a kind of production technique of petroleum jelly belt is characterized in that:
(1) preparation of dressing:
A, allotment rubber: with above-mentioned mineral oil 10~13 weight parts, rubber 40~45 weight parts, wax 2~90 weight parts are at 50~105 ℃, and preferably 60~95 ℃, 800 rev/mins of stirrings are reacted after 16 hours down and must be prepared body A;
B, telomerize resin: get preparation body A100 weight part, described resin 25.5~35 weight parts, mineral oil 10~13 weight parts are at 120~180 ℃, preferably 130~150 ℃, 800 rev/mins of stirring reactions are cooled to 80 ℃ after 4 hours, take advantage of heat filtering, remove filter residue, filtrate is cooled to 40 ℃ of bottom discharges, promptly gets petroleum jelly belt dressing of the present invention.
(2) the above-mentioned petroleum jelly belt dressing for preparing is contained in the steeping vat, under 100~120 ℃, smooth base band is sent in the steeping vat by motor floods, the transfer rate of base band is 8~12 meters/hour, belt is gone up volume through being cooled to below 45 ℃ after steeping vat output.
4 one kinds of cement dipping machines that are used to make petroleum jelly belt, it is characterized in that cement dipping machine comprises that one places support (2), petroleum jelly belt dressing can be contained steeping vat (1) on (3) in wherein heating, be located at the tape-feed of steeping vat (1) front end, the tape mechanism of tail end top.Tape-feed comprises the supply roll (4) that is driven two synchronous rollings by motor, (5); Steeping vat (1) end interlayer is equipped with the heating unit (10) of a temperature adjustable, several parallel being located in the steeping vat (1) of infiltration axle (6) that are used for base band is pressed into glue; The below of tape mechanism and steeping vat (1) are connected to one and are used for the glue that tape surface is unnecessary and squeeze a pair of plastic squeeze axle (7) go, place a side of plastic squeeze axle (7), also have an accent crack plate (9) that is used for regulating two plastic squeeze axle (7) gaps; Tape mechanism is by last roll support (8), upper winding shaft (11) and prevent that the unexpected upper winding shaft cap (12) that falls of the roll coil of strip from forming.
CN 94114068 1994-12-29 1994-12-29 Anticorrosion petrolatum belt and its manufacturing process and impregnator Pending CN1125757A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 94114068 CN1125757A (en) 1994-12-29 1994-12-29 Anticorrosion petrolatum belt and its manufacturing process and impregnator

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Application Number Priority Date Filing Date Title
CN 94114068 CN1125757A (en) 1994-12-29 1994-12-29 Anticorrosion petrolatum belt and its manufacturing process and impregnator

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103314039A (en) * 2010-12-09 2013-09-18 第一工业制药株式会社 Method for manufacturing aqueous-dispersion composition of coumarone-indene resin, and said aqueous-dispersion composition
CN103921455B (en) * 2014-04-23 2016-06-08 山东大学 A kind of double flute body cement dipping machine being suitable to long-term production
CN106753625A (en) * 2016-11-09 2017-05-31 安徽启东热能科技有限公司 A kind of buried oily preparing natural gas feeding mechanism and its control method
CN111073594A (en) * 2019-12-30 2020-04-28 苏州赛伍应用技术股份有限公司 Hot-melt anti-corrosion adhesive, hot-melt anti-corrosion adhesive tape and preparation method thereof
CN111978866A (en) * 2020-09-02 2020-11-24 蓝色海洋(天津)工程技术有限公司 Epoxy modified high-temperature petrolatum anti-corrosion paste and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103314039A (en) * 2010-12-09 2013-09-18 第一工业制药株式会社 Method for manufacturing aqueous-dispersion composition of coumarone-indene resin, and said aqueous-dispersion composition
CN103314039B (en) * 2010-12-09 2015-04-01 第一工业制药株式会社 Method for manufacturing aqueous-dispersion composition of coumarone-indene resin, and said aqueous-dispersion composition
CN103921455B (en) * 2014-04-23 2016-06-08 山东大学 A kind of double flute body cement dipping machine being suitable to long-term production
CN106753625A (en) * 2016-11-09 2017-05-31 安徽启东热能科技有限公司 A kind of buried oily preparing natural gas feeding mechanism and its control method
CN111073594A (en) * 2019-12-30 2020-04-28 苏州赛伍应用技术股份有限公司 Hot-melt anti-corrosion adhesive, hot-melt anti-corrosion adhesive tape and preparation method thereof
CN111978866A (en) * 2020-09-02 2020-11-24 蓝色海洋(天津)工程技术有限公司 Epoxy modified high-temperature petrolatum anti-corrosion paste and preparation method thereof

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