CN1125752A - Water-base propenoic acid antirust paint and its preparation method - Google Patents
Water-base propenoic acid antirust paint and its preparation method Download PDFInfo
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Abstract
The watery anti-rust acrylic paint for metal material, building and furniture is prepared from hydrocinnamyl emulsion, auxiliary base material, pigment, filler and assistant through mixing, grinding, dispersing and filter, and features no poison and explosion, no return rusting, and high lustre.
Description
The invention belongs to paint, coating class, is a kind of waterborne anti-rust lacquer and preparation technology thereof.
At present, mostly the most frequently used metal rust preventing lacquer is the oiliness alcohol acid antirust paint, wherein contains a large amount of dimethylbenzene, No. 200 solvent oil equal solvents, and these solvents evaporate in the air in the paint application process, cause environmental pollution and waste of material.Alkyd paint water-fast, alkaline-resisting, weathering resistance is also undesirable, phenomenon such as outdoor life-time service easily produces efflorescence, variable color, come off influences protective and decorative effect.In order to protect environment, economize on resources, to increase the benefit; people have carried out the research and development of water-miscible paint; existing aqueous rustproof lacquer mainly contains polyalcohols acid ethene latex, water soluble oils, acrylic latex three by the classification of main body base-material and holds row greatly; the polyvinyl acetate lacquer can be made into wash primer; can application on the rust face; easy construction, strong adhesion are applicable to multiple metal basal plane.Its main drawback is that gloss is low, outdoor weatherability is not strong, should not be used as finish paint and outdoor lacquer, and water soluble oils rust-inhibiting paint cost is low, strong adhesion, gloss height, but also not good because of easily yellowing, weathering resistance, is unsuitable for system outdoor paint and tinted paint.Water soluble acrylic acid lacquer is main base-material with benzene emulsion, nontoxic odorlessness, does not have and fires danger, and construction safety is convenient, fast drying, and acid and alkali-resistance, anti-atmospheric environment corrosion is protected light, is protected look, weathering resistance is strong, and outside durabitity is more than 3 times of alkyd paint.
The water soluble acrylic acid lacquer has obtained more application aspect architecture inside and outside decoration, but uses also seldom aspect metal rust preventing.Because it is external phase with water, all can introduce corrodibility salt material in letex polymerization and pigment manufacturing processed, also contains compositions such as hydrophilic emulsifying agent, dispersion agent, thickening material in the coating.Be coated on the metallic surface and easily cause the sudden strain of a muscle erosion before drying, easily produce after the film forming and return the rust phenomenon, the coating salt water resistance is not good yet.The general method that adds inhibiter and reactive pigment that adopts solves these problems.Inhibiter commonly used mostly is water-soluble salt, and consumption too much can influence paint film water tolerance and gloss.And reactive pigment ionization is strong, and consumption too much can influence package stability.Simple is that the water-miscible paint of base-material during application, is subjected to the restriction of emulsion particle diameter with the benzene emulsion on the rust face, and base-material is difficult to infiltrate rusty scale inside and substrate surface, easily produces the phenomenon of the bad and underfilm corrosion of coating adhesion.Acrylic latex coating is film forming by the emulsion particle coalescence mechanism, and seasoning reaches maximum intensity to be needed more than 3 weeks sometimes, and paint film is water-fast, weather-proof before this, stain resistance is bad.Addressing the above problem, is the key problem in technology of applying water-base propenoic acid antirust paint.
The objective of the invention is on metal, easily produce during application and dodge erosion and return the rust phenomenon at existing water-base propenoic acid antirust paint, be unsuitable for the application of band rust, salt water resistance is not good, film formation at low temp is bad, tinted paint is to problems such as pollutions, and develop a kind of can address the above problem be suitable for multi-purpose water-base propenoic acid antirust paint and preparation technology thereof.
The objective of the invention is to realize in the following manner, water-base propenoic acid antirust paint is by benzene emulsion, auxiliary base-material, pigment, filler, dispersion agent, membrane-forming agent, rust-preventive agent and other auxiliary agent, formulated by a certain percentage at normal temperatures, its composition and weight percent are: benzene emulsion 30-50, auxiliary base-material 5-15, pigment 5.5-32, filler＜talcum powder, fine particle calcium carbonate, process white〉1-15, dispersion agent 0.5-1.5, membrane-forming agent 0.5-2.5 rust-preventive agent 0.1-0.5 ammoniacal liquor 0.3-1.0, other auxiliary agent (thickening material, sanitas, defoamer etc.) 1.2-3.5 water surplus.
Water-base propenoic acid antirust paint of the present invention can be according to different needs, adopts different auxiliary base-materials to change indivedual components and make priming paint, finish paint and paint for priming paint and top lacquer, for improving priming paint rust-preventing characteristic and sticking power, be to assist base-material with the water-base epoxy ester in priming paint; For improving the finish paint film-forming properties, finish paint is auxiliary base-material with the waterborne organic silicon acid modified alcoholic.
Priming paint is composed as follows:
Red iron oxide 15-25, or carbon black 3-8, or carbon black 0.5-2, the white 5-10 of iron, or molybdenum red 15-20, or the blue 15-20 of iron, or medium chrome yellow medium yellow 15-20, zinc oxide 0.5-2.0, phosphorus zinc white 1.5-3.5, zinc-chrome yellow 0.5-1.5, talcum powder 1-10, fine particle calcium carbonate 1-5, dispersion agent 0.5-1.5, rust-preventive agent 0.1-0.5, membrane-forming agent 0.5-2.0, thickening material 1.0-3.0, sanitas 0.1-3.0, defoamer 0.1-0.2, benzene emulsion 30-40, auxiliary base-material 3-10, ammoniacal liquor 0.3-0.8, water surplus.
Finish paint is composed as follows:
Iron oxide red 15-20, or molybdenum red 15-20, or medium chrome yellow medium yellow 15-20, or the blue 15-20 of iron, or titanium white 18-25, process white 5, dispersion agent 0.5-1.5, rust-preventive agent 0.1-0.5, membrane-forming agent 1.0-2.5, thickening material 1.0-3.0, sanitas 0.1-0.3, defoamer 0.1-0.2, benzene emulsion 35-50, auxiliary base-material 5-15, ammoniacal liquor 0.5-1.0, water surplus.
Paint for priming paint and top lacquer is composed as follows:
The red 15-20 of oxidation, or carbon black 3-8, or carbon black 0.5-2, the white 5-10 of iron, or molybdenum red 15-20, or the blue 15-20 of iron, or medium chrome yellow medium yellow 15-20, zinc oxide 0.5-2.0, phosphorus zinc white 1.5-3.5, zinc-chrome yellow 0.5-1.5, talcum powder 1-10, fine particle calcium carbonate 1-2, dispersion agent 0.5-1.5, rust-preventive agent 0.1-0.5, membrane-forming agent 0.5-2.0, thickening material 1.0-3.0, sanitas 0.1-0.3, defoamer 0.1-0.2, benzene emulsion 30-40, water-base epoxy ester 3-7, waterborne organic silicon alkyd 3-7, ammoniacal liquor 0.3-0.8, water surplus.
The preparation method of water-base propenoic acid antirust paint of the present invention is as follows:
Water, dispersion agent, pigment, filler, rust-preventive agent, part defoamer are added the material-compound tank high speed stir, send into sand mill, be ground to fineness 30-60 micron, send into dispersion tank, to wherein adding thickening material, stir evenly, add ammoniacal liquor, stir evenly, add various auxiliary agents and stir evenly, add emulsion and auxiliary base-material, stir evenly, transferring pH value with ammoniacal liquor is 7.5-8.5, gets finished product after filtration.
The preparation of auxiliary base-material
A. the preparation of water-base epoxy ester
Prescription: E-20 Resins, epoxy 15, linolenic acid 37.5, oleum lini 41.5, cis-butenedioic anhydride 11, butanols 20, Monoethanolamine MEA BASF 8-10.
Technology: linolenic acid drops into reactor, is heated with stirring to 120-150 ℃, adds Resins, epoxy, start stirring, feed CO2, continue to be warming up to 240 ℃ and keep esterification, be incubated and begin the viscosimetric of taking a sample after 1 hour, viscosity adds oleum lini during for 35-50S, stops to stir, add cis-butenedioic anhydride, start to stir and be rapidly heated to 240 ℃ and kept 30 minutes, be cooled to rapidly below 120 ℃ and add butanols, stir evenly, add Monoethanolamine MEA BASF below 60 ℃, discharging when regulating this 7.5-8.5 of pH value.
B. the preparation of waterborne organic silicon modified alkyd resin
Proportioning: dehydration trimellitic acid 15.5, Tetra hydro Phthalic anhydride 37, tetramethylolmethane 26.5, soya-bean oil 79.5, yellow lead 0.015, dimethylbenzene 5.0, organosilicon oligopolymer 20, butanols 20, Monoethanolamine MEA BASF 8-10.
Technology: with soya-bean oil, tetramethylolmethane adds in the reactor, stir and heat up, feed carbonic acid gas, be heated to 120 ℃, add yellow lead, continue to be warming up to 230 ℃, keep 2.5-3h, after alcoholysis is intact, be cooled to 180 ℃, stop to stir, add the dehydration trimellitic acid, Tetra hydro Phthalic anhydride keeps esterification, acid number drops to about 80 and adds the organosilicon oligopolymer, continue esterification to acid number and lower the temperature during for 60-65, be cooled to 120 ℃ and add the butanols dissolving, to adding Monoethanolamine MEA BASF below 60 ℃, the adjusting pH value is 7.5-8.5, discharging, products therefrom are transparent thick liquid, available tap water dilution.
2, the preparation of waterborne anti-rust lacquer
A. iron oxide red primer
Water 15, iron oxide red 20, zinc oxide 1.0, phosphorus zinc white 3.0, zinc-chrome yellow 1.0, talcum powder 2.0, fine particle calcium carbonate 1.0, dispersion agent 1.0, rust-preventive agent 0.5, membrane-forming agent 1.5, thickening material 3.0, benzene emulsion 35, water-base epoxy ester 5, sanitas 0.2, defoamer TBP0.2, ammoniacal liquor is an amount of, water surplus.--high shearing mixing emulsor dispersion--sand mill grinding--high-speed stirring dispersion--filtration--packing that technology is batching.
B. orange paint for priming paint and top lacquer
Prescription:
Water 15, zinc oxide 1.0, molybdenum red 5, medium chrome yellow medium yellow 15, talcum powder 2, fine particle calcium carbonate 1, dispersion agent 1.0, rust-preventive agent 0.5, emulsion 40, water-base epoxy 5, waterborne organic silicon acid 5, sanitas 0.2, thickening material 3.0 membrane-forming agents 1.8, defoamer 0.2, ammoniacal liquor is an amount of, water surplus.Technology is the same.
C. grey paint for priming paint and top lacquer in
Prescription: water 15, carbon black 2, iron white powder 10, talcum powder 7, zinc yellow 1.0 phosphorus zinc whites 3.0, zinc oxide 1.0 fine particle calcium carbonates 1.0, rust-preventive agent 0.5, dispersion agent 1.0, thickening material 3.0, benzene emulsion 40, water-base epoxy ester 5. waterborne organic silicon alkyd 5, sanitas 0.2, membrane-forming agent 1.8, defoamer 0.2, ammoniacal liquor is an amount of, water surplus.Technology is the same.
D. sky blue paint for priming paint and top lacquer
Prescription: water 15, titanium white 10, iron orchid 10, zinc oxide 1.0, phosphorus zinc white 3.0, fine particle calcium carbonate 1.0, rust-preventive agent 0.5, dispersion agent 1.0 thickening materials 3.0, benzene emulsion 40, water-base epoxy ester 5, waterborne organic silicon alkyd 5, sanitas 0.2, membrane-forming agent 1.8, defoamer 0.2, ammoniacal liquor is an amount of, water surplus.Technology is the same.
E. white finish paint
Prescription: titanium white 20, process white 2, dispersion agent 1.0, rust-preventive agent 0.3, membrane-forming agent 1.8, thickening material 3.0, benzene emulsion 40, waterborne organic silicon alkyd 10, sanitas 0.2, defoamer 0.2, ammoniacal liquor is an amount of, water surplus.Technology is the same.
Priming paint of the present invention is auxiliary base-material with the water-base epoxy ester, form cross-linked structure after the film forming, have waterproof and anti-permeability preferably, effects such as vegetables oil wherein, vegetable oil acid and cis-butenedioic anhydride affixture thereof can be penetrated into metallic substrate surface and adsorb rusty scale inside, complexing, conversion.Complicated chemical reaction also can take place with base material and rusty scale and generate stable fine and close heteropolyacid salt in rust-stabilising pigment.More than effect is stablized rusty scale, and corrosion is difficult to development, has prevented from effectively to dodge erosion and return the rust phenomenon, has improved resistance to salt water greatly.
Finish paint of the present invention is auxilliary auxiliary base-material with the waterborne organic silicon Synolac, and it is for shortening film formation time, improves face gloss, improves stain resistance and brought into play significant effect.Relevant product performance index is exemplified below:
1, iron oxide red primer
Through the check of Shandong Province's coating inspection center, every index surpasses the alcohol acid antirust paint national standard, sees Table 1
Table 1,
| Project | Index | Measured result | Detection method |
| Color, outward appearance | The smooth unglazed aberration that conforms to | Qualified | ?????GB1729-79 |
| Viscosity (S) | ????60-90 | ????72 | ?????GB1723-79 |
| Fineness (micron) | ????≤60 | ????50 | ?????GB1724-79 |
| Solid content (%) | ????≥40 | ????44 | ?????GB1725-79 |
| Time of drying (h) | Surface drying 0.5 does solid work 24 | ??0.2，15 | ?????GB1728-79 |
| Flexural strength (mm) | ????2 | ?????2 | ?????GB1731-79 |
| Shock strength (N.m) | ????4.9 | ????4.9 | ?????GB1732-79 |
| Sticking power, level | ????1 | ?????1 | ?????GB1720-79 |
| Salt water resistance, 48h | The non-foaming rust that returns | Qualified | ?????GB1733-79 |
2, paint for priming paint and top lacquer of all kinds
Every after testing technical indicator meets company standard, sees Table 2
Table 2
| Project | Index | Measured result b, c, d |
| Color, outward appearance | The smooth aberration that partly meets earlier | Qualified |
| Viscosity (S) | ????60-90 | ??????65，68，67 |
| Fineness (micron) | ????≤40 | ??????35，35，35 |
| Solid content (%) | ????≥40 | ??????48，49，49 |
| Time of drying (h) | Surface drying 1 does solid work 24 | ??????0.5，12 |
| Shock strength (Nm) | ????4.9 | ????????4.9 |
| Sticking power, level | ????1 | ?????????1 |
| Salt water resistance, 48 grams | The non-foaming rust that returns | Qualified |
3, white finish paint
Every after testing index meets company standard, sees Table 3
Table 3
| Project | Index | Measured result |
| The color outward appearance | Smooth have light to meet aberration | Qualified |
| Viscosity (S) | ???????60-90 | ????65 |
| Fineness (micron) | ???????≤30 | ????25 |
| Solid content (%) | ???????≥40 | ????45 |
| Time of drying (h) | Surface drying 0.5 does solid work 24 | ??0.2，10 |
| Crooked (mm) | ????????2 | ????2 |
| Shock strength (N.m) | ???????4.9 | ???4.9 |
| Sticking power (level) | ????????1 | ????1 |
| Salt water resistance (48h) | The non-foaming rust that returns | Qualified |
Annotate: detection method is with table 1.
Claims (8)
1, water-base propenoic acid antirust paint is by benzene emulsion, auxiliary base-material, pigment, filler, dispersion agent, membrane-forming agent, rust-preventive agent and other auxiliary agent, formulated by a certain percentage at normal temperatures, it is characterized in that its percentage composition is: benzene emulsion 30-50, auxiliary base-material 5-15, pigment 5.5-32, filler (talcum powder, fine particle calcium carbonate, process white) 1-15, dispersion agent 0.1-1.5, membrane-forming agent 0.5-2.5, rust-preventive agent 0.1-0.5, ammoniacal liquor 0.3-1.0, other auxiliary agent (thickening material, sanitas, defoamer etc.) 1.2-3.5, water surplus.
2, water-base propenoic acid antirust paint according to claim 1 is characterized in that the composition of rust-proofing primer and per-cent are: red iron oxide 15-25, or carbon black 3-8, or carbon black 0.5-2, titanium white 5-10, or molybdenum red 15-20, or the blue 15-20 of iron, or medium chrome yellow medium yellow 15-20, zinc oxide 0.5-2.0, phosphorus zinc white 1.5-3.5, zinc-chrome yellow 0.5-1.5, talcum powder 1-10, fine particle calcium carbonate 1-5, dispersion agent 0.5-1.5, rust-preventive agent 0.1-0.5, membrane-forming agent 0.5-2.0, thickening material 1.0-3.0, sanitas 0.1-0.3, defoamer 0.1-0.2, benzene emulsion 30-40, auxiliary base-material 3-10, ammoniacal liquor 0.3-0.8, water surplus.
3, water-base propenoic acid antirust paint according to claim 1 is characterized in that the composition of rust-proof top-coat and per-cent are: iron oxide red 15-20, or molybdenum red 15-20, or medium chrome yellow medium yellow 15-20, or the blue 15-20 of iron, or titanium white 18-25, process white 1-5, dispersion agent 0.5-1.5, rust-preventive agent 0.1-0.5, membrane-forming agent 1.0-2.5, thickening material 1.0-3.0, sanitas 0.1-0.3, defoamer 0.1-0.2, benzene emulsion 35-50, auxiliary base-material 5-15, ammoniacal liquor 0.5-1.0, water surplus.
4。Water-base propenoic acid antirust paint according to claim 1 is characterized in that the composition of paint for priming paint and top lacquer and per-cent are: red iron oxide 15-20, or carbon black 3-8, or carbon black 0.5-2, titanium white 5-10, or molybdenum red 15-20, or the blue 15-20 of iron, or medium chrome yellow medium yellow 15-20, zinc oxide 0.5-2.0, phosphorus zinc white 1.5-3.5, zinc-chrome yellow 0.5-1.5, talcum powder 1-10, fine particle calcium carbonate 1-2, dispersion agent 0.5-1.5, rust-preventive agent 0.1-0.5, membrane-forming agent 0.5-2.0, thickening material 1.0-3.0, sanitas 0.1-0.3, defoamer 0.1-0.2, benzene emulsion 30-40, water-base epoxy ester 3-7, waterborne organic silicon alkyd 3-7, ammoniacal liquor 0.3-0.8, water surplus.
5, water-base propenoic acid antirust paint according to claim 1 is characterized in that described auxiliary base-material is water-base epoxy ester and/or waterborne organic silicon modified alkyd resin.
6, the preparation technology of the described water-base propenoic acid antirust paint of claim 1 is: water, dispersion agent, pigment, filler, rust-preventive agent, part defoamer are added the material-compound tank high speed stir, send into sand mill, be ground to fineness 30-60 micron, send into dispersion tank, to wherein adding thickening material, stir evenly, add ammoniacal liquor, stir evenly, add various auxiliary agents, stir evenly and add emulsion and auxiliary base-material stirs evenly, transferring pH value with ammoniacal liquor is 7.5-8.5, filter finished product.
7, according to claim 1,5, described water-base propenoic acid antirust paint, its spy, levy the preparation technology who is water-base epoxy fat and be: prescription: E-20 Resins, epoxy 15, linolenic acid 37.5, oleum lini 41.5, cis-butenedioic anhydride 11, butanols 20, Monoethanolamine MEA BASF 8-10.Technology: linolenic acid drops into reactor, is heated with stirring to 120-150 ℃, adds Resins, epoxy, the feeding carbonic acid gas continues to be warming up to 240 ℃ and keeps esterifications, is incubated to begin the viscosimetric of taking a sample after 1 hour, when viscosity is 35-50S, add oleum lini, stir evenly, stop to stir, add cis-butenedioic anhydride, start to stir and be rapidly heated to 240 ℃ and kept 30 minutes, be cooled to 120 ℃ rapidly, add butanols and stir evenly, add Monoethanolamine MEA BASF below 60 ℃, the adjusting pH value is 7.5-8.5, discharging.
8, according to claim 1,5, described water-base propenoic acid antirust paint, the preparation technology who it is characterized in that waterborne organic silicon alkyd is: prescription: dehydration trimellitic acid 15.5, Tetra hydro Phthalic anhydride 37, tetramethylolmethane 26.5, soya-bean oil 70.5, yellow lead 0.015, dimethylbenzene 5.0, organosilicon oligopolymer 20, butanols 20, Monoethanolamine MEA BASF 8-10.Technology: soya-bean oil, tetramethylolmethane are added in the reactor, stir and heat up, feed carbonic acid gas, be heated to 120 ℃, add yellow lead, continue to be warming up to 230 ℃, keep 2.5-3h, after alcoholysis is intact, be cooled to 180 ℃, stop to stir, add dehydration trimellitic acid, Tetra hydro Phthalic anhydride, keep esterification, acid number drops to about 80 and adds organosilicon oligopolymer things and continue esterifications to acid number and lower the temperature during for 60-65, add butanols to 120 ℃ and dissolve, to adding Monoethanolamine MEA BASF below 60 ℃, regulating pH value is the 7.5-8.5 discharging.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 94114250 CN1125752A (en) | 1994-12-26 | 1994-12-26 | Water-base propenoic acid antirust paint and its preparation method |
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| CN 94114250 CN1125752A (en) | 1994-12-26 | 1994-12-26 | Water-base propenoic acid antirust paint and its preparation method |
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1994
- 1994-12-26 CN CN 94114250 patent/CN1125752A/en active Pending
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