CN112552846A - Water-based adhesive and preparation method thereof - Google Patents
Water-based adhesive and preparation method thereof Download PDFInfo
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- CN112552846A CN112552846A CN202011375098.0A CN202011375098A CN112552846A CN 112552846 A CN112552846 A CN 112552846A CN 202011375098 A CN202011375098 A CN 202011375098A CN 112552846 A CN112552846 A CN 112552846A
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- sodium
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- acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1803—C3-(meth)acrylate, e.g. (iso)propyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1805—C5-(meth)acrylate, e.g. pentyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/064—Copolymers with monomers not covered by C09J133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/068—Copolymers with monomers not covered by C09J133/06 containing glycidyl groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a water-based adhesive and a preparation method thereof, wherein the water-based adhesive comprises the following components in parts by weight: 187-219 parts of deionized water, 0.8-2.5 parts of anionic emulsifier, 0.2-2 parts of reactive emulsifier, 0.8-3 parts of initiator, 100 parts of acrylate monomer, 0.5-5 parts of styrene, 6-15 parts of carboxylic acid monomer, 2-12 parts of functional monomer and 3-9 parts of alkaline substance. The water-based adhesive obtained by free radical polymerization has better stability and long storage time, does not relate to an organic solvent when used, and is more environment-friendly; on the other hand, a small amount of sizing can provide excellent bonding effect.
Description
Technical Field
The invention relates to the field of adhesives, and particularly relates to a water-based adhesive and a preparation method thereof.
Background
The stretchable adhesive tape is a pressure-sensitive adhesive tape with excellent performance, not only has strong adhesive force, but also can be easily separated from an adherend without remaining adhesive after being stretched or stretched after being heated properly. Chinese patent CN110964457A discloses a method for preparing methacrylate ester oily adhesive composition, the prepared composition has good bonding strength and stretch debonding effect when applied to stretch debonding tapes, however, when the prepared product is applied to stretch debonding tapes, more organic solvents are used, the residual quantity of the solvents is large, the environment is not protected, and the coating weight is large.
Disclosure of Invention
The invention aims to provide a water-based adhesive and a preparation method thereof aiming at the defects in the prior art.
In order to achieve the purpose, the invention adopts the technical scheme that:
the invention provides a water-based adhesive which comprises the following components in parts by weight:
further, the anionic emulsifier is one or more of sodium alkyl sulfate, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, sodium alkyl diphenyl ether disulfonate, ammonium alkyl phenol ether sulfate and sodium alkyl phenol ether sulfosuccinate.
Further, the reactive emulsifier is one or more of sodium p-styrene sulfonate, 2-acrylamide-2, 2-dimethyl ethanesulfonic acid sodium salt, allyl succinic acid alkyl ester sodium sulfonate, acrylamide isopropyl sodium sulfonate and alkyl acrylic acid-2-ethanesulfonic acid sodium salt.
Further, the initiator is one or more of sodium persulfate, ammonium persulfate and potassium persulfate.
Further, the acrylate monomer is one or more of n-propyl acrylate, n-butyl acrylate, n-hexyl acrylate and n-pentyl acrylate.
Further, the carboxylic acid monomer is one or more of acrylic acid, methacrylic acid, maleic acid, fumaric acid or itaconic acid.
Further, the functional monomer is one or more of hydroxyethyl methacrylate, hydroxypropyl methacrylate, tetrahydrofuran methacrylate, glycidyl methacrylate and N-hydroxymethyl acrylamide.
The second aspect of the present invention provides a method for preparing the above aqueous gel, comprising the following steps: and (2) vacuumizing a polymerization kettle, adding deionized water, an anionic emulsifier, a reactive emulsifier and an initiator, heating to 70-90 ℃, dropwise adding a mixture solution of an acrylate monomer, styrene, a carboxylic acid monomer and a functional monomer for free radical emulsion polymerization, wherein the dropwise adding time is 3-6 hours, heating to 80-90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 5-9 by using an alkaline substance, and filtering to obtain the water-based adhesive.
By adopting the technical scheme, compared with the prior art, the invention has the following technical effects:
the water-based adhesive obtained by free radical polymerization has better stability and long storage time, does not relate to an organic solvent when used, and is more environment-friendly; on the other hand, a small amount of sizing can provide excellent bonding effect.
Detailed Description
The present invention is further illustrated by the following examples, which are not to be construed as limiting the invention. It should be noted that the embodiments and features of the embodiments may be combined with each other without conflict.
Example 1
The water-based adhesive comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps: and (2) vacuumizing a polymerization kettle, adding deionized water, sodium alkyl diphenyl ether disulfonate, 2-acrylamide-2, 2-dimethyl ethyl sulfonate and sodium persulfate, starting stirring, heating to 70 ℃, dropwise adding a mixture solution of n-propyl acrylate, styrene, acrylic acid and hydroxyethyl methacrylate for free radical emulsion polymerization, heating to 80 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 5-9 by using a sodium hydroxide alkaline substance, and filtering to obtain the water-based adhesive.
Example 2
The water-based adhesive comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps: and (2) vacuumizing a polymerization kettle, adding deionized water, sodium alkylsulfonate, sodium alkyl benzene sulfonate, sodium styrene sulfonate, acrylamide isopropyl sulfonate and ammonium persulfate, stirring, heating to 90 ℃, dropwise adding a mixture solution of n-butyl acrylate, styrene, maleic acid, itaconic acid and hydroxypropyl methacrylate for free radical emulsion polymerization, heating to 90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH value to 5-9 by using a potassium hydroxide alkaline substance, and filtering to obtain the water-based adhesive.
Example 3
The water-based adhesive comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps: and (2) after the polymerization kettle is vacuumized, adding deionized water, sodium alkyl sulfate, sodium alkylphenol ether sulfosuccinate, sodium allyl sulfosuccinate alkyl ester sulfonate, sodium alkyl acrylic acid-2-ethyl sulfonate and potassium persulfate, starting stirring, heating to 80 ℃, dropwise adding a mixture solution of N-hexyl acrylate, styrene, methacrylic acid, fumaric acid, glycidyl methacrylate and N-hydroxymethyl acrylamide, carrying out free radical emulsion polymerization, wherein the dropwise adding time is 4.5 hours, heating to 85 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 5-9 by using a sodium hydroxide alkaline substance, and filtering to obtain the water-based adhesive.
Example 4
The water-based adhesive comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps: and (2) vacuumizing a polymerization kettle, adding deionized water, alkyl sodium sulfate, alkylphenol ether ammonium sulfate, sodium p-styrene sulfonate, ammonium persulfate and sodium persulfate, starting stirring, heating to 85 ℃, dropwise adding a mixture solution of n-butyl acrylate, n-amyl acrylate, styrene, fumaric acid, acrylic acid and tetrahydrofuran methacrylate to perform free radical emulsion polymerization, wherein the dropwise adding time is 5 hours, heating to 90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 5-9 by using a potassium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive.
The method for preparing the stretched debonding adhesive tape by using the waterborne adhesive comprises the following steps:
coating the waterborne adhesive with the thickness of 100 micrometers and 150 micrometers by using a transparent PET release film with the thickness of 75 micrometers through a knife coater, setting the temperature gradients of an oven to be 50, 60, 70, 85, 105 and 110 ℃, setting the time of each temperature gradient to be 3min, and attaching the release film with the thickness of 20 micrometers to obtain the stretched debonding adhesive tape.
Comparative example
A methacrylate composition and various amounts of applied stretch release tapes were prepared according to the protocol described in example 1 of CN110964457A, and the 180 DEG peel force (gf/25mm) of the stretch release tapes to a steel plate was measured. Tensile debonding tapes of different coating weights were prepared from the water-based adhesives prepared in examples 1 to 4, respectively, and the 180 ° peel force to a steel plate was tested under the same conditions, with the test results shown in table 1:
TABLE 1
From the results in table 1, it can be seen that the aqueous adhesive prepared in examples 1 to 4 of the present invention has more excellent performance in low coating weight, and can achieve the bonding performance equivalent to chinese patent CN110964457A in high coating weight.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention.
Claims (8)
1. The water-based adhesive is characterized by comprising the following components in parts by weight:
2. the aqueous glue of claim 1, wherein the anionic emulsifier is one or more of sodium alkyl sulfate, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, sodium alkyl diphenyl ether disulfonate, ammonium alkyl phenol ether sulfate, and sodium alkyl phenol ether sulfosuccinate.
3. The aqueous glue of claim 1, wherein the reactive emulsifier is one or more of sodium p-styrenesulfonate, sodium 2-acrylamide-2, 2-dimethylethanesulfonate, sodium alkyl sulfosuccinate, sodium acrylamidoisopropyl sulfonate, and sodium alkyl acrylate-2-ethanesulfonate.
4. The waterborne glue of claim 1, wherein the initiator is one or more of sodium persulfate, ammonium persulfate, and potassium persulfate.
5. The water-based adhesive according to claim 1, wherein the acrylate monomer is one or more of n-propyl acrylate, n-butyl acrylate, n-hexyl acrylate and n-pentyl acrylate.
6. The aqueous glue of claim 1, wherein the carboxylic acid monomer is one or more of acrylic acid, methacrylic acid, maleic acid, fumaric acid, and itaconic acid.
7. The aqueous glue of claim 1, wherein the functional monomer is one or more of hydroxyethyl methacrylate, hydroxypropyl methacrylate, tetrahydrofuran methacrylate, glycidyl methacrylate and N-methylol acrylamide.
8. A process for the preparation of an aqueous glue according to any of claims 1 to 7, characterized in that it comprises the following steps: and (2) vacuumizing a polymerization kettle, adding deionized water, an anionic emulsifier, a reactive emulsifier and an initiator, heating to 70-90 ℃, dropwise adding a mixture solution of an acrylate monomer, styrene, a carboxylic acid monomer and a functional monomer for free radical emulsion polymerization, wherein the dropwise adding time is 3-6 hours, heating to 80-90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 5-9 by using an alkaline substance, and filtering to obtain the water-based adhesive.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011375098.0A CN112552846A (en) | 2020-11-30 | 2020-11-30 | Water-based adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011375098.0A CN112552846A (en) | 2020-11-30 | 2020-11-30 | Water-based adhesive and preparation method thereof |
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| CN112552846A true CN112552846A (en) | 2021-03-26 |
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| CN202011375098.0A Pending CN112552846A (en) | 2020-11-30 | 2020-11-30 | Water-based adhesive and preparation method thereof |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101153208A (en) * | 2007-09-12 | 2008-04-02 | 西安向阳航天材料股份有限公司 | Method of producing emulsion pressure sensitive adhesive and surface protective film for heat and moisture-proof protective film |
| CN106349980A (en) * | 2016-08-26 | 2017-01-25 | 江苏国胶化学科技有限公司 | Preparation method of water-based pressure-sensitive adhesive |
| CN106832106A (en) * | 2017-01-23 | 2017-06-13 | 杭州传化精细化工有限公司 | A kind of water polyacrylic acid emulsion and preparation method thereof |
| CN107163181A (en) * | 2017-06-29 | 2017-09-15 | 台昌树脂(佛山)有限公司 | acrylic emulsion and preparation method thereof |
| CN107267094A (en) * | 2017-05-25 | 2017-10-20 | 江苏艾萨斯新型肥料工程技术有限公司 | A kind of novel high-performance Acrylate pressure-sensitive adhesive emulsion and its preparation technology |
| CN107602760A (en) * | 2017-08-07 | 2018-01-19 | 无锡海特新材料研究院有限公司 | A kind of electronic protective film pressure-sensitive polyacrylate emulsion glue, its preparation method and its application |
| CN107746692A (en) * | 2017-11-21 | 2018-03-02 | 江门新时代包装材料有限公司 | A kind of formula and preparation method of water-borne pressure sensitive adhesive emulsion |
| CN108102025A (en) * | 2017-11-16 | 2018-06-01 | 广东佰合新材料科技股份有限公司 | A kind of embossing compound special-purpose aqueous glue of PE and preparation method thereof |
| CN110305266A (en) * | 2019-06-25 | 2019-10-08 | 广州化工研究设计院 | It is a kind of with the acrylic emulsion from wetting effect and the emulsion-type pressure-sensitive comprising the lotion |
| CN110511700A (en) * | 2019-09-18 | 2019-11-29 | 湖北航天化学技术研究所 | A kind of one-component acrylic acid ester emulsion Laminating adhesive and preparation method thereof |
-
2020
- 2020-11-30 CN CN202011375098.0A patent/CN112552846A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101153208A (en) * | 2007-09-12 | 2008-04-02 | 西安向阳航天材料股份有限公司 | Method of producing emulsion pressure sensitive adhesive and surface protective film for heat and moisture-proof protective film |
| CN106349980A (en) * | 2016-08-26 | 2017-01-25 | 江苏国胶化学科技有限公司 | Preparation method of water-based pressure-sensitive adhesive |
| CN106832106A (en) * | 2017-01-23 | 2017-06-13 | 杭州传化精细化工有限公司 | A kind of water polyacrylic acid emulsion and preparation method thereof |
| CN107267094A (en) * | 2017-05-25 | 2017-10-20 | 江苏艾萨斯新型肥料工程技术有限公司 | A kind of novel high-performance Acrylate pressure-sensitive adhesive emulsion and its preparation technology |
| CN107163181A (en) * | 2017-06-29 | 2017-09-15 | 台昌树脂(佛山)有限公司 | acrylic emulsion and preparation method thereof |
| CN107602760A (en) * | 2017-08-07 | 2018-01-19 | 无锡海特新材料研究院有限公司 | A kind of electronic protective film pressure-sensitive polyacrylate emulsion glue, its preparation method and its application |
| CN108102025A (en) * | 2017-11-16 | 2018-06-01 | 广东佰合新材料科技股份有限公司 | A kind of embossing compound special-purpose aqueous glue of PE and preparation method thereof |
| CN107746692A (en) * | 2017-11-21 | 2018-03-02 | 江门新时代包装材料有限公司 | A kind of formula and preparation method of water-borne pressure sensitive adhesive emulsion |
| CN110305266A (en) * | 2019-06-25 | 2019-10-08 | 广州化工研究设计院 | It is a kind of with the acrylic emulsion from wetting effect and the emulsion-type pressure-sensitive comprising the lotion |
| CN110511700A (en) * | 2019-09-18 | 2019-11-29 | 湖北航天化学技术研究所 | A kind of one-component acrylic acid ester emulsion Laminating adhesive and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 兰云军 编著: "反应型乳化剂", 《皮革化学品的制备-理论与实践》 * |
| 李红强 主编: "乳化剂", 《胶粘原理、技术及应用》 * |
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Application publication date: 20210326 |
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