CN112551678A - Treatment device for impurity organic matters in methyl tin mercaptide production wastewater - Google Patents
Treatment device for impurity organic matters in methyl tin mercaptide production wastewater Download PDFInfo
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- CN112551678A CN112551678A CN202011392659.8A CN202011392659A CN112551678A CN 112551678 A CN112551678 A CN 112551678A CN 202011392659 A CN202011392659 A CN 202011392659A CN 112551678 A CN112551678 A CN 112551678A
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- 239000002351 wastewater Substances 0.000 title claims abstract description 48
- 239000012535 impurity Substances 0.000 title claims abstract description 36
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000001179 sorption measurement Methods 0.000 claims abstract description 91
- 230000007246 mechanism Effects 0.000 claims abstract description 53
- 238000004140 cleaning Methods 0.000 claims description 76
- 238000003860 storage Methods 0.000 claims description 43
- 239000000463 material Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 238000010521 absorption reaction Methods 0.000 claims description 24
- 239000012286 potassium permanganate Substances 0.000 claims description 9
- 230000002146 bilateral effect Effects 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 6
- 239000002699 waste material Substances 0.000 claims description 3
- 239000005416 organic matter Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims 1
- 238000004065 wastewater treatment Methods 0.000 abstract description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 16
- 235000019270 ammonium chloride Nutrition 0.000 description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 6
- 235000017491 Bambusa tulda Nutrition 0.000 description 6
- 241001330002 Bambuseae Species 0.000 description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 6
- 239000011425 bamboo Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 108091006146 Channels Proteins 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 102000004257 Potassium Channel Human genes 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000010405 clearance mechanism Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 108020001213 potassium channel Proteins 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/16—Halides of ammonium
- C01C1/164—Ammonium chloride
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/14—Maintenance of water treatment installations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/16—Regeneration of sorbents, filters
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a treatment device for impurity organic matters in methyl tin mercaptide production wastewater, which comprises a machine body and is characterized in that: the waste water treatment device comprises a machine body, a power mechanism and an adsorption mechanism, wherein the machine body is internally provided with a power space, the power mechanism is used for providing power for the device, the lower side of the power space is provided with an operation space, a functional box body is connected in the operation space in a sliding manner, and the adsorption mechanism is used for adsorbing impurities and removed organic matters in the waste water.
Description
Technical Field
The invention belongs to the field of circuit board production, and particularly relates to a treatment device for impurity organic matters in methyl tin mercaptide production wastewater.
Background
Methyl tin mercaptide, also known as methyl tin or methyl tin stabilizer, is one of the organotin stabilizers, and is a colorless and transparent oily substance. The heat stabilizer has the advantages of no toxicity, high efficiency, good coloring property and the like, and is widely used as a plastic heat stabilizer at home and abroad in recent years. PVC plastic products obtained by using methyl tin mercaptide as a stabilizer have unique processing performance and the characteristics of transparency, environmental protection, safety and the like, and are widely used as packaging, decoration and engineering materials;
in the process of producing methyl tin mercaptide, a large amount of waste water is generated, the waste water has great harm to both human and environment, but some substances in the waste water can be recycled, and organic matters in the waste water need to be removed firstly.
Disclosure of Invention
The invention aims to solve the problems in the prior art and provides a device for treating impurity organic matters in methyl tin mercaptide production wastewater.
The purpose of the invention can be realized by the following technical scheme: the utility model provides a processing apparatus for methyl tin mercaptide waste water impurity organic matter, includes the organism, its characterized in that: the machine body is provided with a power space, the power space is provided with a power mechanism, the power mechanism is used for providing power for the device, the lower side of the power space is provided with an operation space, the operation space is connected with a functional box body in a sliding way, the functional box body is provided with a circular feeding space, the feeding spaces are respectively provided with a feeding mechanism, the feeding mechanisms are used for feeding potassium permanganate for removing organic matters in wastewater, the functional box body is provided with a main energy space, the main energy space is internally provided with an adsorption mechanism, the adsorption mechanism is used for adsorbing impurities and removed organic matters in the wastewater, the main energy space is internally provided with a cleaning mechanism, the cleaning mechanism is used for cleaning an adsorption material, the lower side of the main energy space is provided with two collecting spaces, and the two collecting spaces are distributed in bilateral symmetry about the central line of the main energy space, and each collecting space is provided with a collecting mechanism respectively, and the collecting mechanism is used for collecting waste generated by cleaning.
Preferably, the power mechanism comprises a power motor fixedly mounted on the upper side wall of the power space, the output end of the power motor is fixedly connected with a power rotating shaft, the power rotating shaft extends downwards to penetrate through the lower side wall of the power space and the upper end face of the function box body to enter the main energy space, a power rotating shaft cavity is formed in the power rotating shaft, and the function box body is fixedly connected with the power rotating shaft.
Preferably, the feeding mechanism comprises storage spaces arranged on the left side and the right side of the power space, the two storage spaces are bilaterally and symmetrically distributed about the central line of the power space, the upper side wall of the operation space is fixedly connected with two communicating T-shaped rods, the two communicating T-shaped rods are bilaterally and symmetrically distributed about the central line of the power space, each communicating T-shaped rod is provided with a communicating cavity which penetrates up and down, each communicating cavity is respectively communicated with the corresponding storage space, the lower ends of the two communicating T-shaped rods are both in sliding connection with the upper side wall of the feeding space, the lower side walls of the two communicating cavities are both communicated with the feeding space, the lower side wall of the feeding space is communicated with two feeding runners, the two feeding runners are bilaterally and symmetrically distributed about the central line of the functional box body, the left side wall and the right side wall of each feeding runner are respectively communicated with a feeding chute, each feeding chute is internally and respectively connected with a control sliding plate in a sliding mode, each control sliding plate extends and penetrates into the main energy space in a direction close to the main energy space, each control sliding plate is internally and respectively provided with a sliding plate opening which penetrates through the control sliding plate from top to bottom, the sliding plate opening is communicated with the corresponding feeding runner, two feeding leakage nets are fixedly connected to the lower end face of the functional box body and are distributed in a bilateral symmetry mode relative to the central line of the functional box body, the feeding leakage nets are formed by surrounding porous leakage nets, each feeding leakage net is internally and respectively provided with a leakage net cavity, and each leakage net cavity is respectively communicated with the corresponding feeding runner.
In an initial state, the opening of the sliding plate is communicated with the feeding runner, when wastewater treatment is needed, wastewater is added into the operation space through the opening on the left side of the operation space, potassium permanganate is added into the storage space, the power motor is started at the moment, so that the power rotating shaft is driven to rotate, the functional box body is driven to rotate, the feeding leakage net is driven to rotate, the potassium permanganate in the storage space enters the feeding space, enters the leakage net cavity through the feeding runner and simultaneously follows the functional box body to rotate, the wastewater is stirred and simultaneously and uniformly reacts with organic matters in the wastewater, the organic matters in the wastewater are fully removed, and the subsequent extraction of ammonium chloride in the wastewater is greatly facilitated.
Preferably, the adsorption mechanism comprises two driving motors fixedly mounted on the upper side wall of the main energy space, the two driving motors are bilaterally and symmetrically distributed about the central line of the main energy space, the output end of each driving motor is fixedly connected with a driving lead screw, each driving lead screw is respectively sleeved with a driving slider, the driving slider is in threaded connection with the driving lead screw, each driving slider is respectively provided with a driving chute, each driving chute is respectively connected with an adsorption slider in a sliding manner, each adsorption slider is respectively hinged with an upper adsorption arm, each upper adsorption arm is respectively connected with a lower adsorption arm in a sliding manner, an adsorption spring is connected between the lower adsorption arm and the upper adsorption arm, the rear side wall of the main energy space is rotatably connected with two adsorption rotating shafts, and each adsorption rotating shaft is respectively fixedly connected with the corresponding lower adsorption arm, every the terminal surface difference sliding connection has the absorption traveller under the arm of adsorbing down, every respectively fixedly connected with traveller fixture block on the absorption traveller, every the cover is equipped with reset spring on the absorption traveller respectively, reset spring one end and corresponding terminal surface fixed connection under the arm of adsorbing down, the other end respectively with traveller fixture block up end fixed connection, two it articulates there is the absorption fixed block to adsorb the traveller, terminal surface sliding connection has the adsorption material post under the absorption fixed block, the adsorption material post for the terminal surface slides from top to bottom and can not break away from under the absorption fixed block adsorb the fixed block.
In an initial state, the adsorption spring is in a stretching state, the reset spring is in a stretching state, when the adsorption material column adsorbs organic matters and other impurities removed from the wastewater, two driving motors are started, so that the left side of the adsorption material column is driven, the left side of the adsorption material column rotates anticlockwise, the right side of the adsorption material column rotates clockwise, the driving slide block is driven to slide downwards, the adsorption slide block is driven to slide downwards, the upper adsorption arm is driven to slide downwards, the adsorption spring is compressed, the upper adsorption arm slides into the lower adsorption arm, and the adsorption rotating shaft is controlled to move upwards so as to drive the adsorption slide column to move upwards, so that the adsorption material column moves upwards to enter the main energy space, and the upper end surface of the adsorption fixed block abuts against the upper side wall of the main energy space, and after the cleaning mechanism finishes cleaning the adsorption material column, driving the driving motor to enable the adsorption material column to move into the operation space.
Preferably, the cleaning mechanism comprises a water storage tank body sleeved on the power rotating shaft, the water storage tank body is connected with the power rotating shaft in a sliding manner, a water storage space is arranged in the water storage tank body and is communicated with the power rotating shaft, the lower end face of the water storage tank body is connected with two cleaning rotating shafts in a rotating manner, the two cleaning rotating shafts are distributed in bilateral symmetry about the central line of the water storage tank body, a cleaning rotating shaft cavity is respectively arranged in each cleaning rotating shaft and is communicated with the water storage space, the cleaning rotating shafts extend downwards to penetrate through the lower side wall of the power space and the upper end face of the functional tank body to enter the main energy space, each cleaning rotating shaft is respectively sleeved with a cleaning gear, each cleaning gear is respectively fixedly connected with the corresponding cleaning rotating shaft, and the lower side of the power rotating shaft is sleeved with a power gear, the power gear with power pivot sliding connection, two dead levers of power gear up end fixedly connected with, two the dead lever up end with side wall fixed connection on the operation space, power gear and two wash gear engagement, every wash under the pivot terminal surface fixedly connected with wash the cylinder, every be provided with the cylinder space in the washing cylinder respectively, every the cylinder space respectively with correspond wash the pivot chamber and be linked together, every the cover is equipped with respectively on the main energy space and washs a brush section of thick bamboo, wash a brush section of thick bamboo with wash cylinder fixed connection, it is used for wasing the adsorption material to wash a brush section of thick bamboo.
In an initial state, the water storage space is filled with cleaning liquid, when the adsorption material column needs to enter the main energy space, the cleaning liquid in the water storage space enters the cleaning rotating shaft cavity and enters the column space, and then permeates the brush outside the cleaning brush cylinder through the cleaning brush cylinder, the cleaning rotating shaft is driven to rotate around the power rotating shaft due to the rotation of the functional box body, so that the cleaning gear is driven to rotate around the power rotating shaft, the cleaning gear is driven to rotate around the power rotating shaft due to the meshing of the cleaning gear and the power gear, so that the cleaning rotating shaft is driven to rotate, the cleaning column is driven to rotate, and the cleaning brush cylinder is driven to rotate to comprehensively clean the adsorption material column, and removing the adsorbed impurities, so that the impurities fall into a collecting mechanism to be collected and centralized.
Preferably, the collecting mechanism comprises screw sliders which are slidably connected and mounted on each driving screw, a connecting arm is connected between each screw slider and the corresponding control slide plate, one end of each connecting arm is hinged to the control slide plate, the other end of each connecting arm is hinged to the screw slider, the lower side wall of the main energy space is communicated with a through opening with a downward opening, the through opening is communicated with the two collecting spaces, a collecting box body is slidably connected in each collecting space, a collecting slider is slidably connected to the groove surface of each collecting box body, a large friction force exists between each collecting slider and the collecting box body, each collecting slider extends to the direction far away from the through opening and penetrates through the functional box body, and each collecting slider is slidably connected with the corresponding end surface of the machine body, the corresponding collecting slide blocks can be drawn out from the left end surface and the right end surface of the machine body, a collecting chute is arranged at the upper side of each collecting space, each collecting chute is communicated with the main energy space, a limiting slide block is respectively and slidably connected in each collecting chute, the lower end surface of each limiting slide block is respectively and fixedly connected with the corresponding collecting box body, a collecting spring is respectively sleeved on each driving lead screw, one end of each collecting spring is fixedly connected with the lead screw slide block, the other end of each collecting spring is fixedly connected with the corresponding limiting slide block, two limiting slide columns are respectively and slidably connected on the lower side wall of the main energy space, the two limiting slide columns are respectively and bilaterally symmetrical about the central line of the through opening, each limiting slide column respectively extends downwards to penetrate into the corresponding collecting chute, and the upper end surface of each limiting slide column is respectively and fixedly connected with a limiting, every be equipped with spacing spring on the spacing traveller respectively, spacing spring one end with spacing fixed block fixed connection, the other end with lateral wall fixed connection under the main energy space, lateral wall intercommunication has the decurrent feed opening of opening under the operation space, fixedly connected with interception strainer in the feed opening, impurity in the interception strainer class interception waste water fixedly connected with check valve in the feed opening.
In an initial state, the limiting spring is in a compressed state, the collecting spring is in a compressed state, when the driving slide block moves downwards to abut against the upper end face of the corresponding lead screw slide block, the collecting spring is compressed, when the driving slide block continues to move downwards, the connecting arm is driven to move downwards, the control slide plate is driven to slide towards the direction far away from the central line of the main energy space, so that the opening of the dead slide plate is disconnected with the feeding flow channel, potassium permanganate does not enter the net leaking cavity any more, the collecting spring is compressed at the moment to push the limiting slide block to slide towards the direction close to the central line of the main energy space, so that the limiting slide block abuts against the limiting slide column, when the collecting spring is compressed more and more, the limiting slide block pushes the limiting slide column to slide upwards when the elastic force of the limiting spring is exceeded, thereby make spacing slider continues toward being close to main ability space center line direction slides, thereby drives collection box toward being close to main ability space center line direction slides, thereby drives collection slider moves together up to two collect box terminal surface butt, thereby makes clearance mechanism will adsorb impurity clearance on the adsorption material post drops collect the slider up end, the adsorption material post resets, thereby makes when collecting the box resets, follow the organism left and right sides will collect the slider and take out, handle the impurity of collecting in the slider, will at last the check valve is opened the waste water discharge that will handle and is carried out ammonium chloride and draws.
In conclusion, the beneficial effects of the invention are as follows: the method can effectively remove organic matters and other impurities in the wastewater generated in the production of the methyl tin mercaptide, compared with the traditional wastewater treatment, the method not only removes the organic matters and other impurities, but also retains the ammonium chloride in the solution, provides great convenience for the subsequent ammonium chloride treatment of the treated wastewater, extracts useful substances from the wastewater, and greatly reduces the cost of the wastewater treatment of enterprises.
Drawings
FIG. 1 is a sectional view of the whole structure of the treatment device for the impurity organic matters in the methyl tin mercaptide production wastewater.
Fig. 2 is a partially enlarged schematic view of the invention at a in fig. 1.
Fig. 3 is a partially enlarged schematic view of the invention at B in fig. 1.
Fig. 4 is an enlarged partial schematic view of the invention at C in fig. 1.
Fig. 5 is an enlarged partial schematic view of the invention at D in fig. 1.
Fig. 6 is an enlarged partial schematic view at E of fig. 1 of the present invention.
Fig. 7 is an enlarged partial schematic view of the invention at F in fig. 1.
In the figure, a machine body 10; a storage space 11; an operating space 13; a power space 14; a power motor 15; a power shaft 16; a power shaft cavity 17; a water storage space 18; a water storage tank body 19; a fixing bar 20; a power gear 21; cleaning the gear 22; cleaning the rotating shaft 23; a communicating T-shaped rod 24; a communication chamber 25; a function box 26; a charging space 27; a main energy space 28; a drive motor 29; a drive screw 30; a drive chute 31; a feeding screen 32; a screen leaking chamber 33; an adsorption fixing block 34; a column of adsorbent material 35; a feed opening 36; intercepting the leakage net 37; a check valve 38; a through opening 39; a collection space 40; a collection tank 41; a collection slider 42; a lead screw slider 43; a collection spring 44; a feeding chute 45; a feeding runner 46; the spindle cavity 47 is cleaned; cleaning the column 48; cleaning the brush drum 49; a cylindrical space 50; a driving slider 51; an adsorption slider 52; an upper adsorption arm 53; an adsorption spring 54; a lower adsorption arm 55; an adsorption rotating shaft 56; a collection chute 57; a limit spring 58; a limit slide 59; a limit fixing block 60; a limiting slide block 61; a connecting arm 62; a control slide 63; a slide plate opening 64; an adsorption spool 65; spool catches 66; a return spring 67.
Detailed Description
The following are specific embodiments of the present invention and are further described with reference to the drawings, but the present invention is not limited to these embodiments.
As shown in figure 1, a treatment device for impurity organic matters in methyl tin mercaptide production wastewater comprises a machine body 10, and is characterized in that: the machine body 10 is provided with a power space 14, the power space 14 is provided with power mechanisms, the power mechanisms are used for providing power for the device, the lower side of the power space 14 is provided with an operation space 13, the operation space 13 is connected with a functional box body 26 in a sliding manner, the functional box body 26 is provided with a circular feeding space 27, the feeding spaces 27 are respectively provided with a feeding mechanism, the feeding mechanism is used for feeding potassium permanganate for removing organic matters in wastewater, the functional box body 26 is provided with a main energy space 28, the main energy space 28 is provided with an adsorption mechanism, the adsorption mechanism is used for adsorbing impurities and removed organic matters in the wastewater, the main energy space 28 is provided with a cleaning mechanism, the cleaning mechanism is used for cleaning an adsorption material, the lower side of the main energy space 28 is provided with two collecting spaces 40, and the two collecting spaces 40 are distributed in a left-right symmetrical manner relative to the central line of the main energy space 28, each of the collecting spaces 40 is provided therein with a collecting mechanism for collecting waste generated by the washing.
As shown in fig. 1, the power mechanism includes a power motor 15 fixedly mounted on the upper side wall of the power space 14, an output end of the power motor 15 is fixedly connected with a power rotating shaft 16, the power rotating shaft 16 extends downward to penetrate through the lower side wall of the power space 14 and the upper end surface of the function box 26 to enter the main energy space 28, a power rotating shaft cavity 17 is arranged in the power rotating shaft 16, and the function box 26 is fixedly connected with the power rotating shaft 16.
Referring to fig. 1 and 6, the feeding mechanism includes storage spaces 11 disposed on the left and right sides of the power space 14, the two storage spaces 11 are symmetrically disposed on the left and right sides with respect to the center line of the power space 14, the upper side wall of the operation space 13 is fixedly connected with two communicating T-shaped rods 24, the two communicating T-shaped rods 24 are symmetrically disposed on the left and right sides with respect to the center line of the power space 14, a communicating cavity 25 passing through the upper and lower portions is disposed in each communicating T-shaped rod 24, each communicating cavity 25 is communicated with the corresponding storage space 11, the lower ends of the two communicating T-shaped rods 24 are slidably connected with the upper side wall of the feeding space 27, the lower side walls of the two communicating cavities 25 are communicated with the feeding space 27, the lower side wall of the feeding space 27 is communicated with two feeding flow channels 46, and the two feeding flow channels 46 are symmetrically disposed on the left and right sides with respect to the center line of the functional, the left side wall and the right side wall of each feeding runner 46 are respectively communicated with a feeding chute 45, each feeding chute 45 is respectively connected with a control sliding plate 63 in a sliding manner, each control sliding plate 63 respectively extends towards the direction close to the main energy space 28 to penetrate into the main energy space 28, each control sliding plate 63 is respectively provided with a sliding plate opening 64 which penetrates up and down, each sliding plate opening 64 is communicated with the corresponding feeding runner 46, the lower end face of the functional box body 26 is fixedly connected with two feeding leakage nets 32, the two feeding leakage nets 32 are distributed in bilateral symmetry relative to the central line of the functional box body 26, the feeding leakage nets 32 are defined by porous leakage nets, each feeding leakage net 32 is respectively provided with a leakage net cavity 33, and each leakage net cavity 33 is respectively communicated with the corresponding feeding runner 46.
In the initial state, the slide plate opening 64 is in communication with the feed channel 46, and when wastewater treatment is required, wastewater is added into the operation space 13 through the left opening of the operation space 13, when potassium permanganate is added into the storage space 11, the power motor 15 is started, thereby driving the power rotating shaft 16 to rotate, thereby driving the functional box body 26 to rotate, thereby driving the feeding leakage net 32 to rotate, so that the potassium permanganate in the storage space 11 enters the feeding space 27 and enters the screen leaking cavity 33 through the feeding runner 46 and simultaneously rotates along with the functional box body 26 to stir the wastewater and simultaneously uniformly react with organic matters in the wastewater, thereby fully removing the organic matters in the wastewater, and greatly facilitating the subsequent extraction of ammonium chloride in the wastewater.
Referring to fig. 1, 3, 5 and 7, the adsorption mechanism includes two driving motors 29 fixedly mounted on the upper side wall of the main energy space 28, the two driving motors 29 are symmetrically distributed about the central line of the main energy space 28, the output end of each driving motor 29 is fixedly connected with a driving lead screw 30, each driving lead screw 30 is sleeved with a driving slider 51, the driving slider 51 is in threaded connection with the driving lead screw 30, each driving slider 51 is provided with a driving sliding chute 31, each driving sliding chute 31 is connected with an adsorption slider 52 in a sliding manner, each adsorption slider 52 is hinged with an upper adsorption arm 53, each upper adsorption arm 53 is connected with a lower adsorption arm 55 in a sliding manner, an adsorption spring 54 is connected between the lower adsorption arm 55 and the upper adsorption arm 53, the rear side wall of the main energy space 28 is connected with two adsorption rotating shafts 56 in a rotating manner, every adsorb pivot 56 respectively with correspond lower absorption arm 55 fixed connection, every there is absorption traveller 65, every absorption traveller 65 goes up respectively fixedly connected with traveller fixture block 66, every absorption traveller 65 goes up respectively the cover is equipped with reset spring 67 respectively, reset spring 67 one end and corresponding under the arm 55 end fixed connection down, the other end respectively with traveller fixture block 66 up end fixed connection, two absorption traveller 65 articulates there is absorption fixed block 34, end sliding connection has absorption material post 35 under the absorption fixed block 34, absorption material post 35 for the end surface slides from top to bottom and can not break away from under the absorption fixed block 34.
In an initial state, the adsorption spring 54 is in a stretched state, the return spring 67 is in a stretched state, when the adsorption material column 35 completely adsorbs organic matters and other impurities removed from the wastewater, the two driving motors 29 are started, so as to drive the left driving screw 30 to rotate counterclockwise, the right driving screw 30 to rotate clockwise, so as to drive the driving slider 51 to slide downward, so as to drive the adsorption slider 52 to slide downward, so as to drive the upper adsorption arm 53 to slide downward, so as to compress the adsorption spring 54, so as to slide the upper adsorption arm 53 into the lower adsorption arm 55, and due to the left and right adsorption rotating shaft 56, the adsorption sliding column 65 moves upward, so as to drive the adsorption fixing block 34 to move upward, so as to allow the adsorption material column 35 to move upward and enter the main energy space 28, so that the upper end surface of the adsorption fixing block 34 abuts against the upper side wall of the main energy space 28, and when the cleaning mechanism cleans the adsorption material column 35, the driving motor 29 is driven to move the adsorption material column 35 into the operation space 13.
Referring to fig. 1 and 2, the cleaning mechanism includes a water storage tank 19 sleeved on the power shaft 16, the water storage tank 19 is connected with the power shaft 16 in a sliding manner, a water storage space 18 is arranged in the water storage tank 19, the water storage space 18 is communicated with the power shaft 16, two cleaning shafts 23 are rotatably connected to the lower end surface of the water storage tank 19, the two cleaning shafts 23 are distributed in bilateral symmetry about the central line of the water storage tank 19, a cleaning shaft cavity 47 is respectively arranged in each cleaning shaft 23, the cleaning shaft cavity 47 is communicated with the water storage space 18, the cleaning shafts 23 extend downwards to penetrate through the lower side wall of the power space 14 and the upper end surface of the functional tank 26 to enter the main energy space 28, each cleaning shaft 23 is sleeved with a cleaning gear 22, and each cleaning gear 22 is fixedly connected with the corresponding cleaning shaft 23, the side cover is equipped with power gear 21 under the power pivot 16, power gear 21 with power pivot 16 sliding connection, two dead lever 20 of power gear 21 up end fixedly connected with, two the dead lever 20 up end with side wall fixed connection on the operation space 13, power gear 21 and two wash the meshing of gear 22, every wash terminal surface fixedly connected with washing cylinder 48 under the pivot 23, every be provided with cylinder space 50 in the washing cylinder 48 respectively, every cylinder space 50 respectively with correspond wash the pivot chamber 47 and be linked together, every the cover is equipped with respectively on the main energy space 28 and washs brush section of thick bamboo 49, wash brush section of thick bamboo 49 with wash cylinder 48 fixed connection, it is used for wasing the adsorbing material to wash brush section of thick bamboo 49.
In an initial state, the water storage space 18 is filled with cleaning liquid, when the adsorbing material column 35 needs to enter the main energy space 28, the cleaning liquid in the water storage space 18 enters the cleaning rotating shaft cavity 47 due to the rotation of the power rotating shaft 16, and then enters the column space 50, and further permeates the brush outside the cleaning brush drum 49 through the cleaning brush drum 49, the cleaning rotating shaft 23 is driven to rotate around the power rotating shaft 16 due to the rotation of the functional box body 26, so that the cleaning gear 22 is driven to rotate around the power rotating shaft 16, the cleaning gear 22 is driven to rotate around the power rotating shaft 16 due to the meshing of the cleaning gear 22 and the power gear 21, so that the cleaning rotating shaft 22 is driven to rotate, so that the cleaning column 48 is driven to rotate, so that the cleaning brush drum 49 is driven to rotate to carry out comprehensive cleaning on the adsorbing material column 35, and removing the adsorbed impurities, so that the impurities fall into a collecting mechanism to be collected and centralized.
Referring to fig. 1 and 5, the collecting mechanism includes a screw slider 43 slidably connected to each of the driving screws 30, a connecting arm 62 is connected between each of the screw sliders 43 and the corresponding control slide plate 63, one end of the connecting arm 62 is hinged to the control slide plate 63, the other end of the connecting arm 62 is hinged to the screw slider 43, a through opening 39 with a downward opening is communicated with a lower side wall of the main energy space 28, the through opening 39 is communicated with two of the collecting spaces 40, a collecting box 41 is slidably connected to each of the collecting spaces 40, a collecting slider 42 is slidably connected to a groove surface of each of the collecting boxes 41, a large friction force exists between the collecting slider 42 and the collecting box 41, and each of the collecting sliders 42 extends through the function box 26 in a direction away from the through opening 39, each collecting slide block 42 is slidably connected with a corresponding end surface of the machine body 10, the corresponding collecting slide block 42 can be drawn out from the left and right end surfaces of the machine body 10, a collecting chute 57 is arranged on the upper side of each collecting space 40, each collecting chute 57 is communicated with the main energy space 28, a limiting slide block 61 is respectively and slidably connected in each collecting chute 57, the lower end surface of each limiting slide block 61 is respectively and fixedly connected with the corresponding collecting box body 41, a collecting spring 44 is respectively sleeved on each driving lead screw 30, one end of each collecting spring 44 is fixedly connected with the lead screw slide block 43, the other end of each collecting spring 44 is fixedly connected with the corresponding limiting slide block 61, two limiting slide posts 59 are slidably connected with the lower side wall of the main energy space 28, and the two limiting slide posts 59 are respectively in bilateral symmetry with the central line of the through opening 39, every spacing traveller 59 downwardly extending respectively runs through the entering correspondence collect spout 57, every spacing traveller 59 up end difference fixedly connected with spacing fixed block 60, every the cover is equipped with spacing spring 58 respectively on the spacing traveller 59, spacing spring 58 one end with spacing fixed block 60 fixed connection, the other end with lateral wall fixed connection under the main energy space 28, lateral wall intercommunication has the decurrent feed opening 36 of opening under the operation space 13, fixedly connected with interception strainer 37 in the feed opening 36, the impurity in interception strainer 37 class interception waste water fixedly connected with check valve 38 in the feed opening 36.
In an initial state, the limiting spring 58 is in a compressed state, the collecting spring 44 is in a compressed state, when the driving slider 51 moves downward to abut against the upper end face of the corresponding lead screw slider 43, the collecting spring 44 is compressed, when the driving slider 51 continues to move downward, the connecting arm 62 is driven to move downward, the control sliding plate 63 is driven to slide in a direction away from the central line of the main energy space 28, the dead sliding plate opening 64 is disconnected from the feeding runner 46, potassium permanganate does not enter the net leaking cavity 33 any more, at this time, the collecting spring 44 is compressed to push the limiting slider 61 to slide in a direction close to the central line of the main energy space 28, so that the limiting slider 61 abuts against the limiting sliding column 59, when the collecting spring 44 is compressed to be larger and larger, when the elasticity of the limit spring 58 is exceeded, the limit slide block 61 pushes the limit slide column 59 to slide upwards, so that the limit slider 61 continues to slide toward the central line of the main energy space 28, thereby driving the collecting box 41 to slide towards the central line of the main energy space 28, thereby driving the collecting slide block 42 to move together until the end surfaces of the two collecting boxes 41 are abutted, so that the cleaning mechanism cleans the impurities adsorbed on the adsorbing material column 35 and drops the impurities onto the upper end surface of the collecting slide block 42 for collection, the adsorbing material column 35 resets, so that when the collection box 41 is reset, the collection sliders 42 are drawn out from the left and right sides of the machine body 10, and (3) treating impurities collected in the collection sliding block 42, and finally opening the one-way valve 38 to discharge treated wastewater for ammonium chloride extraction.
In conclusion, the beneficial effects of the invention are as follows: the method can effectively remove organic matters and other impurities in the wastewater generated in the production of the methyl tin mercaptide, compared with the traditional wastewater treatment, the method not only removes the organic matters and other impurities, but also retains the ammonium chloride in the solution, provides great convenience for the subsequent ammonium chloride treatment of the treated wastewater, extracts useful substances from the wastewater, and greatly reduces the cost of the wastewater treatment of enterprises.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention, and that various changes and modifications may be made without departing from the spirit and scope of the invention as defined by the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (6)
1. The utility model provides a processing apparatus for methyl tin mercaptide waste water impurity organic matter, includes organism (10), its characterized in that: the machine body (10) is provided with a power space (14), the power space (14) is provided with a power mechanism, the power mechanism is used for providing power for the device, the lower side of the power space (14) is provided with an operation space (13), the operation space (13) is connected with a functional box body (26) in a sliding manner, the functional box body (26) is provided with a circular feeding space (27), the feeding spaces (27) are respectively provided with a feeding mechanism, the feeding mechanism is used for feeding potassium permanganate for removing organic matters in wastewater, the functional box body (26) is provided with a main energy space (28), the main energy space (28) is provided with an adsorption mechanism, the adsorption mechanism is used for adsorbing impurities and organic matters in the wastewater, the main energy space (28) is provided with a cleaning mechanism, and the cleaning mechanism is used for cleaning adsorption materials, the main energy space (28) downside is provided with two and collects space (40), two collect space (40) about main energy space (28) central line is bilateral symmetry and distributes, every be provided with respectively in collecting space (40) and collect the mechanism, it is used for collecting the waste matter that washs the production to collect the mechanism.
2. The device for treating the impurity organic matters in the methyl tin mercaptide production wastewater according to claim 1, characterized in that: the power mechanism comprises a power motor (15) fixedly mounted on the upper side wall of the power space (14), the output end of the power motor (15) is fixedly connected with a power rotating shaft (16), the power rotating shaft (16) extends downwards to penetrate through the lower side wall of the power space (14) and the upper end face of the function box body (26) to enter the main energy space (28), a power rotating shaft cavity (17) is formed in the power rotating shaft (16), and the function box body (26) is fixedly connected with the power rotating shaft (16).
3. The device for treating the impurity organic matters in the methyl tin mercaptide production wastewater according to claim 1, characterized in that: the feeding mechanism comprises storage spaces (11) arranged on the left side and the right side of the power space (14), the two storage spaces (11) are bilaterally and symmetrically distributed relative to the center line of the power space (14), the upper side wall of the operation space (13) is fixedly connected with two communicated T-shaped rods (24), the two communicated T-shaped rods (24) are bilaterally and symmetrically distributed relative to the center line of the power space (14), each communicated T-shaped rod (24) is respectively provided with a vertically-penetrating communicated cavity (25), each communicated cavity (25) is respectively communicated with the corresponding storage space (11), the lower ends of the two communicated T-shaped rods (24) are respectively connected with the upper side wall of the feeding space (27) in a sliding manner, the lower side walls of the two communicated cavities (25) are both communicated with the feeding space (27), and the lower side wall of the feeding space (27) is communicated with two feeding flow passages (46), the two feeding flow channels (46) are bilaterally and symmetrically distributed relative to the central line of the functional box body (26), the left side wall and the right side wall of each feeding flow channel (46) are respectively communicated with a feeding sliding groove (45), each feeding sliding groove (45) is respectively connected with a control sliding plate (63) in a sliding manner, each control sliding plate (63) respectively extends towards the direction close to the main energy space (28) to penetrate into the main energy space (28), each control sliding plate (63) is respectively provided with a sliding plate opening (64) which penetrates up and down, the sliding plate opening (64) is communicated with the corresponding feeding flow channel (46), the lower end surface of the functional box body (26) is fixedly connected with two feeding leakage nets (32), the two feeding leakage nets (32) are bilaterally and symmetrically distributed relative to the central line of the functional box body (26), and the feeding leakage nets (32) are formed by enclosing of porous leakage nets, each feeding leakage net (32) is provided with a net leakage cavity (33), and each net leakage cavity (33) is communicated with the corresponding feeding flow channel (46).
4. The device for treating the impurity organic matters in the methyl tin mercaptide production wastewater according to claim 1, characterized in that: the adsorption mechanism comprises two driving motors (29) fixedly mounted on the upper side wall of the main energy space (28), the two driving motors (29) are symmetrically distributed on the left and right of the central line of the main energy space (28), each driving motor (29) is fixedly connected with a driving lead screw (30) in the output end distribution, each driving lead screw (30) is sleeved with a driving slider (51), each driving slider (51) is in threaded connection with the driving lead screw (30), each driving slider (51) is provided with a driving sliding groove (31), each driving sliding groove (31) is respectively connected with an adsorption slider (52) in a sliding manner, each adsorption slider (52) is hinged with an upper adsorption arm (53) in a sliding manner, each upper adsorption arm (53) is respectively connected with a lower adsorption arm (55) in a sliding manner, and an adsorption spring (54) is connected between the lower adsorption arm (55) and the upper adsorption arm (53), main can space (28) rear side wall rotate to be connected with two absorption pivot (56), every absorption pivot (56) respectively with correspond down absorption arm (55) fixed connection, every under absorption arm (55) terminal surface sliding connection respectively have absorption traveller (65), every on absorption traveller (65) respectively fixedly connected with traveller fixture block (66), every the cover is equipped with reset spring (67) respectively on absorption traveller (65), reset spring (67) one end and corresponding terminal surface fixed connection under absorption arm (55), the other end respectively with terminal surface fixed connection, two on traveller fixture block (66) adsorption traveller (65) articulate and adsorb fixed block (34), terminal surface sliding connection has adsorption material post (35) under adsorption fixed block (34), adsorption material post (35) for the terminal surface slides from top to bottom and can not break away from under adsorption fixed block (34) .
5. The device for treating the impurity organic matters in the methyl tin mercaptide production wastewater according to claim 2, characterized in that: the cleaning mechanism comprises a water storage tank body (19) sleeved on the power rotating shaft (16), the water storage tank body (19) is in sliding connection with the power rotating shaft (16), a water storage space (18) is arranged in the water storage tank body (19), the water storage space (18) is communicated with the power rotating shaft (16), two cleaning rotating shafts (23) are rotatably connected to the lower end face of the water storage tank body (19), the two cleaning rotating shafts (23) are distributed in a bilateral symmetry mode about the central line of the water storage tank body (19), a cleaning rotating shaft cavity (47) is respectively arranged in each cleaning rotating shaft (23), the cleaning rotating shaft cavity (47) is communicated with the water storage space (18), and the cleaning rotating shafts (23) extend downwards to penetrate through the lower side wall of the power space (14) and the upper end face of the functional tank body (26) to enter the main energy space (28), every wash on the pivot (23) overlap respectively and be equipped with washing gear (22), every wash gear (22) respectively with correspond wash pivot (23) fixed connection, power pivot (16) downside cover is equipped with power gear (21), power gear (21) with power pivot (16) sliding connection, power gear (21) up end fixedly connected with two dead levers (20), two dead lever (20) up end with side wall fixed connection on operation space (13), power gear (21) with two wash gear (22) meshing, every wash pivot (23) down end fixedly connected with and wash cylinder (48), every be provided with cylinder space (50) in the washing cylinder (48) respectively, every cylinder space (50) respectively with correspond wash pivot chamber (47) and be linked together, each main energy space (28) is sleeved with a cleaning brush cylinder (49), each cleaning brush cylinder (49) is fixedly connected with the cleaning column body (48), and each cleaning brush cylinder (49) is used for cleaning an adsorbing material.
6. The device for treating the impurity organic matters in the methyl tin mercaptide production wastewater according to claim 4, characterized in that: the collecting mechanism comprises lead screw sliding blocks (43) which are installed on each driving lead screw (30) in a sliding connection mode, each lead screw sliding block (43) is connected with a corresponding control sliding plate (63) in a corresponding mode, one end of each connecting arm (62) is hinged to the corresponding control sliding plate (63), the other end of each connecting arm is hinged to the corresponding lead screw sliding block (43), a through opening (39) with a downward opening is communicated with the lower side wall of the main energy space (28), the through opening (39) is communicated with the two collecting spaces (40), each collecting space (40) is internally provided with a collecting box body (41) in a sliding connection mode, each groove face of the collecting box body (41) is respectively connected with a collecting sliding block (42) in a sliding mode, large friction force exists between the collecting sliding blocks (42) and the collecting box bodies (41), and each collecting sliding block (42) is respectively far away from the through opening (39) and extends and penetrates through the function box body (39 26) Each collecting slide block (42) is in sliding connection with the corresponding end face of the machine body (10), the corresponding collecting slide block (42) can be drawn out from the left end face and the right end face of the machine body (10), a collecting slide groove (57) is arranged on the upper side of each collecting space (40), each collecting slide groove (57) is communicated with the main energy space (28), a limiting slide block (61) is respectively and slidably connected in each collecting slide groove (57), the lower end face of each limiting slide block (61) is respectively and fixedly connected with the corresponding collecting box body (41), a collecting spring (44) is respectively sleeved on each driving lead screw (30), one end of each collecting spring (44) is fixedly connected with the lead screw slide block (43), the other end of each collecting spring is fixedly connected with the corresponding limiting slide block (61), and two limiting slide columns (59) are slidably connected on the lower side wall of the main energy space (28), the two limiting sliding columns (59) are bilaterally symmetrical about the central line of the through opening (39), each limiting sliding column (59) extends downwards to penetrate into the corresponding collecting chute (57), the upper end face of each limiting sliding column (59) is fixedly connected with a limiting fixed block (60), each limiting sliding column (59) is sleeved with a limiting spring (58), one end of the limiting spring (58) is fixedly connected with the limiting fixed block (60), the other end of the limiting spring is fixedly connected with the lower side wall of the main energy space (28), a feed opening (36) with a downward opening is communicated with the lower side wall of the operation space (13), fixedly connected with interception hourglass net (37) in feed opening (36), impurity in interception hourglass net (37) class interception waste water fixedly connected with check valve (38) in feed opening (36).
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