CN112521249A - Low-carbon olefin and aromatic hydrocarbon yield increasing method and system - Google Patents
Low-carbon olefin and aromatic hydrocarbon yield increasing method and system Download PDFInfo
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- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
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- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
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- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
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Abstract
The invention discloses a method and a system for increasing the yield of low-carbon olefin and aromatic hydrocarbon, which comprises the following steps: (1) passing the light naphtha to an orthoisomerization separation unit to produce normal components and non-normal components; (2) sending the non-normal components to a hydrocracking unit and separating to obtain propane, normal butane and isobutane; sending the non-normal components to an aromatization unit, and separating to obtain propane, n-butane, isobutane and C5+ components; (3) propane, n-butane and isobutane are treated in different ways to obtain ethylene and propylene. The preparation method provided by the invention greatly improves the yield of the low-carbon olefin and the aromatic hydrocarbon, obviously improves the utilization efficiency of naphtha and realizes reasonable allocation of resources.
Description
Technical Field
The invention belongs to the field of preparation of low-carbon olefins and aromatic hydrocarbons, and particularly relates to a process and a system for increasing yields of low-carbon olefins such as ethylene and propylene and aromatic hydrocarbons.
Background
As petroleum resources are exploited in large quantities, the petroleum resources become increasingly scarce, and therefore, how to optimally utilize the petroleum resources becomes a problem of increasing concern for many oil refining researchers. The capacity of the production plants of aromatic hydrocarbons and ethylene and propylene and their production are among the most important indicators of the development level of the petrochemical industry. Aromatic hydrocarbons mainly come from catalytic reforming units in the oil refining industry, and with the development of national economy and the development of petrochemical industry, the demand for aromatic hydrocarbons is also sharply increased.
At present, raw materials for industrially producing aromatic hydrocarbon and light olefin are mainly naphtha, naphtha is a mixture of normal alkane, isoparaffin, cycloparaffin and aromatic hydrocarbon, at present, the naphtha is processed by mixing a plurality of components with different properties, the product yield obtained by the method is low, the waste of energy and resources is caused, and simultaneously, all the components in the naphtha can not be fully utilized.
Disclosure of Invention
Aiming at the technical problems, the invention provides a method and a system for increasing the yield of low-carbon olefins such as ethylene, propylene and the like and aromatic hydrocarbons, which can realize the comprehensive utilization of light naphtha and maximize the production of ethylene and propylene products.
The technical scheme of the invention is as follows:
in one aspect, the invention provides a method for increasing yields of low-carbon olefins and aromatics, comprising the following steps:
(1) passing the light naphtha to an orthoisomerization separation unit to produce normal components and non-normal components;
(2) sending the non-normal components to a hydrocracking unit, and further separating the hydrocracking product to obtain refinery dry gas, propane, normal butane and isobutane respectively; and/or, sending non-normal components to an aromatization unit and further separating the aromatization products to obtain refinery dry gas, propane, n-butane and isobutane, and C5+ components, respectively;
(3) sending the propane to a propane dehydrogenation unit to produce propylene and the n-butane to a steam cracking unit to produce ethylene, propylene; sending the isobutane to a normal reforming unit to produce n-butane and the produced n-butane to a steam cracking unit to produce ethylene, propylene;
(4) the refinery-related dry gas is sent to a cryogenic separation unit to produce ethane and a fuel gas comprising C1, the ethane produced being sent to a steam cracking unit to produce ethylene.
Based on the scheme, preferably, the light naphtha comprises C5-C6 alkane; the normal component comprises normal C5-C6 alkane; the non-normal components comprise isomeric C5-C6 alkanes, and the C1 fuel gas comprises methane.
Based on the above scheme, preferably, the normal components produced in step (1) are sent to a steam cracking unit to produce ethylene and propylene.
Based on the above scheme, preferably, the C5+ component comprises benzene, toluene and C8-C10 aromatic hydrocarbons.
Based on the scheme, the refinery dry gas preferably comprises components of C1-C2.
Based on the scheme, the light naphtha is preferably subjected to normal isomerization separation by a distillation method or an adsorption method.
Based on the scheme, preferably, the raw material of the cryogenic separation unit also comprises dry gas generated by other devices in a refinery; the feed to the normal isomerization unit also includes isomeric C4 produced by other units of the refinery; the feedstock to the propane dehydrogenation unit also includes propane produced by other refinery units, which refer to refinery units other than those used in the normal isomerization separation unit and the aromatization unit.
Based on the above scheme, preferably, the other refinery devices include: atmospheric and vacuum distillation unit, aviation kerosene hydrogenation unit, wax oil hydrogenation unit (containing cracking), diesel oil hydrogenation unit (containing cracking), residual oil hydrogenation unit (containing cracking), reforming unit, disproportionation unit, alkylation unit and MTBE unit.
In another aspect, the present invention provides a system for use in the above process, the system comprising an normal isomerization separation unit, a hydrocracking unit, an aromatization unit, a normal isomerization unit, a steam cracking unit, a propane dehydrogenation unit, and a cryogenic separation unit;
the normal and heterogeneous separation device comprises a light naphtha feeding hole, a normal component outlet and a heterogeneous component outlet; the isomeric component outlet is respectively communicated with the feed inlets of the hydrocracking device and the aromatization device;
the hydrocracking device comprises a hydrocracking unit and a cracked product separation unit which are sequentially communicated; the cracking product separation unit comprises a refinery dry gas outlet I, a propane outlet I, an n-butane outlet I and an isobutane outlet I;
the aromatization device comprises an aromatization unit and an aromatization product separation unit which are sequentially communicated; the aromatization product separation unit comprises a refinery dry gas outlet II, a propane outlet II, an n-butane outlet II, an isobutane outlet II and a C5+ component outlet;
the first propane outlet and the second propane outlet are communicated with a feed inlet of a propane dehydrogenation device;
the n-butane outlet I and the n-butane outlet II are communicated with a feed inlet of the steam cracking device;
the isobutane outlet I and the isobutane outlet II are communicated with a feed inlet of a normal structuring device, and a discharge hole of the normal structuring device is communicated with a feed inlet of a steam cracking device;
the first refinery dry gas outlet and the second refinery dry gas outlet are communicated with a feed inlet of the cryogenic separation device; the cryogenic separation device further comprises a fuel gas outlet and an ethane outlet; the ethane outlet is communicated with the feed inlet of the steam cracking device.
Based on the scheme, preferably, the system further comprises other devices of the refinery, and discharge ports of the other devices of the refinery are communicated with feed ports of one or more devices of the cryogenic separation device, the normal structuring device and the propane dehydrogenation device; the other devices of the refinery comprise an aviation kerosene hydrogenation device, a wax oil hydrocracking device, a diesel oil hydrocracking device, a residual oil hydrocracking device, a reforming device, a disproportionation device, an alkylation device and an MTBE device.
In the above device, the normal isomerization separation device can adopt a device used for realizing normal isomerization separation of light naphtha in the prior art; the hydrocracking device can adopt a device which is used for realizing hydrocracking of non-normal components in light naphtha and can further separate hydrocracking products in the prior art; the steam cracking device can adopt a device used for cracking the low-carbon hydrocarbon steam into ethylene in the prior art; the aromatization device can adopt a device used for aromatizing non-normal components and further separating aromatization products in the prior art; the normal structuring device can adopt a device used for normal structuring isobutane in the prior art; the propane dehydrogenation unit can adopt a unit used for dehydrogenating propane to produce propylene in the prior art; the cryogenic separation device can adopt a device which is used for separating dry gas generated by a refinery into ethane and fuel gas of C1 through a cryogenic separation process in the prior art. The other units of the refinery may be units of the prior art.
Advantageous effects
The invention firstly separates the light naphtha into normal alkane and non-normal alkane, and the normal alkane is directly used as the raw material for steam cracking, thus improving the yield of ethylene; meanwhile, the non-normal alkane component is further separated into refinery dry gas, propane, normal butane and isobutane through hydrocracking reaction; the yield of the propylene can be improved by preparing the propylene from the propane through dehydrogenation reaction, the isobutane is converted into the normal butane through normal structure, and the normal butane is used as a raw material for preparing low-carbon olefin, so that the yield of the ethylene and the propylene can be further improved; the refinery dry gas contains part of ethane, and the method separates the ethane by adopting a cryogenic separation process and takes the ethane as a raw material for preparing ethylene by steam cracking, so that the ethylene can be increased and the resources can be fully utilized.
The invention separates the C5-C6 isoparaffin in the light naphtha, aromatizes the isoparaffin, can produce C5+ products while further separating refinery dry gas, propane, n-butane and isobutane, fully and effectively utilizes various components in the naphtha, and improves the aromatic hydrocarbon yield of the light naphtha.
According to the invention, the C5-C6 isoparaffin in the light naphtha is separated out and subjected to hydrocracking, so that the saturation of the components is improved, the content of aromatic hydrocarbon is reduced, and the yield of low-carbon olefin in the steam cracking process is improved.
The process combination provided by the application comprehensively utilizes naphtha from the molecular perspective, and separates mixture components from the molecular perspective, namely from the specific requirements of different products on raw material molecules, so as to make the best use of the components, thereby greatly improving the yield of low-carbon olefins and aromatic hydrocarbons, remarkably improving the utilization efficiency of naphtha and realizing reasonable allocation of resources.
Drawings
FIG. 1 is a flow diagram of a general process for increasing the yields of lower olefins and aromatics provided by the present invention;
FIG. 2 is a flow chart of a process for increasing the yield of light olefins according to example 2 of the present invention;
FIG. 3 is a flow chart of a process for increasing the yields of light olefins and aromatics as provided in example 3 of the present invention;
FIG. 4 is a flow chart of a process for increasing the yield of light olefins according to example 4 of the present invention;
FIG. 5 is a flow chart of a process for increasing yields of light olefins and aromatics as provided in example 5 of the present invention.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
In the following examples and comparative examples, the yield of lower olefins was calculated according to the following formula:
ethylene yield (wt%)/. wt. of ethylene in the steam cracking reaction product ÷ total weight of light naphtha × 100%;
the propylene yield (% by weight) is (weight of propylene in the steam cracking reaction product + weight of propylene in the propane dehydrogenation reaction product) ÷ total weight of light naphtha × 100%;
the yield (wt%) of each component of C5+ is the weight of each component of C5+ in the aromatization reaction product ÷ total weight of light naphtha × 100%.
Example 1
A method and a system for increasing the yield of low-carbon olefin are disclosed, as shown in figure 1, the system comprises a normal isomerization separation device, a hydrocracking device, an aromatization device, a normal formation device, a steam cracking device, a propane dehydrogenation device and a cryogenic separation device; the normal and heterogeneous separation device comprises a light naphtha feeding hole, a normal component outlet and a heterogeneous component outlet; the isomeric component outlet is respectively communicated with the feed inlets of the hydrocracking device and the aromatization device; the hydrocracking device comprises a hydrocracking unit and a cracked product separation unit which are sequentially communicated; the cracking product separation unit comprises a refinery dry gas outlet I, a propane outlet I, an n-butane outlet I and an isobutane outlet I; the aromatization device comprises an aromatization unit and an aromatization product separation unit which are sequentially communicated; the aromatization product separation unit comprises a refinery dry gas outlet II, a propane outlet II, an n-butane outlet II, an isobutane outlet II and a C5+ component outlet;
the first propane outlet and the second propane outlet are communicated with a feed inlet of a propane dehydrogenation device;
the n-butane outlet I and the n-butane outlet II are communicated with a feed inlet of the steam cracking device;
the isobutane outlet I and the isobutane outlet II are communicated with a feed inlet of a normal structuring device, and a discharge hole of the normal structuring device is communicated with a feed inlet of a steam cracking device; the first refinery dry gas outlet and the second refinery dry gas outlet are communicated with a feed inlet of the cryogenic separation device; the cryogenic separation device further comprises a fuel gas outlet and an ethane outlet; the ethane outlet is communicated with the feed inlet of the steam cracking device.
The method comprises the following steps:
(1) passing the light naphtha to an orthoisomerization separation unit to produce normal components and non-normal components;
(2) sending part of non-normal components to a hydrocracking unit, and further separating the hydrocracking product to obtain refinery dry gas, propane, normal butane and isobutane respectively; simultaneously sending the other part of non-normal components to an aromatization unit, and further separating aromatization products to respectively obtain refinery dry gas, propane, normal butane and isobutane and C5+ components;
(3) sending the propane to a propane dehydrogenation unit to produce propylene and the n-butane to a steam cracking unit to produce ethylene, propylene; sending the isobutane to a normal reforming unit to produce n-butane and the produced n-butane to a steam cracking unit to produce ethylene, propylene;
(4) sending the refinery-related dry gas to a cryogenic separation unit to produce ethane and a fuel gas comprising C1, the ethane produced being sent to a steam cracking unit to produce ethylene;
(5) sending the normal component produced in the step (1) to a steam cracking unit to produce ethylene and propylene.
In the above steps, the temperature of the hydrocracking device is 330-360 ℃, and the pressure is 6-8 MPa (gauge pressure); the temperature of the aromatization device is 380-400 ℃, and the pressure is 0.4-1.0 MPa (gauge pressure).
In the above steps, the contents of each component are as follows: the proportion of C5-C6 alkane in the light naphtha is 99%, after normal isomerization separation, the proportion of normal C5-C6 and non-normal C5-C6 in C5-C6 alkane is 35% and 65%, wherein 30% of non-normal C5-C6 hydrocracking unit and 35% of non-normal C5-C6 entering the aromatization unit.
After passing through a hydrocracking unit and separation, the proportion of refinery dry gas, propane, n-butane and isobutane in non-normal C5-C6 entering a hydrocracking unit is respectively 6%, 31%, 29% and 34%, and the proportion of ethane separated by cryogenic separation in refinery dry gas is 82%.
After the separation by an aromatization unit, the proportion of refinery dry gas, propane, n-butane, isobutane and C5+ components in non-normal C5-C6 is 5%, 49%, 11% and 24%, and the proportion of ethane separated by cryogenic cooling in refinery dry gas is 80%.
In the obtained product, the total yield of ethylene is 35%, wherein the yield of ethylene derived from normal C5-C6 is about 18%, and the yield of ethylene derived from isomeric C5-C6 is about 17%.
In the obtained product, the total yield of the propylene is 40 percent, wherein the yield of the propylene derived from normal C5-C6 is about 9 percent, and the yield of the propylene derived from isomeric C5-C6 is about 31 percent.
In the obtained product, the total yield of propylene is 43 percent, wherein the yield of propylene generated by steam cracking of normal C5-C6 is about 9 percent, the yield of propylene generated by propane dehydrogenation is about 30.5 percent, and the yield of propylene generated by steam cracking of normal butane and iso-butane after normal structuring is about 3.5 percent.
In the obtained product, the total yield of C5+ components is 14%, wherein the total yield of benzene and toluene is 8.4%, and the total yield of C8-C10 aromatic hydrocarbons is 2.8%.
Example 2
A method and system for increasing the yield of low-carbon olefin is disclosed, as shown in figure 2, the system comprises a normal isomerization separation device, a hydrocracking device, a normal structuring device, a steam cracking device, a propane dehydrogenation device and a cryogenic separation device; the normal and heterogeneous separation device comprises a light naphtha feeding hole, a normal component outlet and a heterogeneous component outlet; the heterogeneous component outlet is communicated with a feed inlet of the hydrocracking device; the hydrocracking device comprises a hydrocracking unit and a cracked product separation unit which are sequentially communicated; the cracking product separation unit comprises a refinery dry gas outlet I, a propane outlet I, an n-butane outlet I and an isobutane outlet I; the first propane outlet is communicated with a feed inlet of a propane dehydrogenation device; the first n-butane outlet is communicated with a feed inlet of the steam cracking device; and the first isobutane outlet is communicated with the feeding hole of the normal structuring device, and the discharge hole of the normal structuring device is communicated with the feeding hole of the steam cracking device. The first refinery dry gas outlet is communicated with a feed inlet of the cryogenic separation device; the cryogenic separation device further comprises a fuel gas outlet and an ethane outlet; the ethane outlet is communicated with the feed inlet of the steam cracking device.
The method comprises the following steps:
(1) passing the light naphtha to an orthoisomerization separation unit to produce normal components and non-normal components;
(2) sending the non-normal components to a hydrocracking unit, and further separating the hydrocracking product to obtain refinery dry gas, propane, normal butane and isobutane respectively;
(3) sending the propane to a propane dehydrogenation unit to produce propylene and the n-butane to a steam cracking unit to produce ethylene, propylene; sending the isobutane to a normal reforming unit to produce n-butane and the produced n-butane to a steam cracking unit to produce ethylene, propylene;
(4) sending the normal components produced in the step (1) to a steam cracking unit to produce ethylene and propylene;
(5) sending the refinery-related dry gas produced in step (2) to a cryogenic separation unit to produce ethane and a fuel gas comprising C1, the ethane being sent to a steam cracking unit to produce ethylene.
In the above step, the temperature of the hydrocracking device is 330 to 360 ℃, and the pressure is 6 to 8MPa (gauge pressure).
In the above steps, the contents of each component are as follows: the proportion of C5-C6 alkane in the light naphtha is 98 percent, and after normal isomerization separation, the proportion of normal C5-C6 and non-normal C5-C6 in C5-C6 alkane is 34 percent and 66 percent respectively; after being separated by a hydrocracking unit, the proportion of refinery dry gas, propane, n-butane and isobutane in non-normal C5-C6 is respectively 6%, 30% and 34%, and the proportion of ethane separated by cryogenic separation in refinery dry gas is 80%.
In the obtained product, the total yield of the ethylene is 44.5 percent, wherein the yield of the ethylene generated by steam cracking of normal C5-C6 is about 18 percent, the yield of the ethane generated by steam cracking of refinery dry gas cryogenically separated is about 3.5 percent, and the yield of the ethylene generated by steam cracking of normal butane and iso-butane after normal structuring is about 23 percent.
In the obtained product, the total yield of the propylene is 36.5 percent, wherein the yield of the propylene generated by steam cracking of normal C5-C6 is about 9.5 percent, the yield of the propylene generated by propane dehydrogenation is about 19 percent, and the yield of the propylene generated by steam cracking of n-butane and isobutane is about 8 percent.
Example 3
A method and system for increasing the yield of light olefins and aromatics, as shown in fig. 3, the system used is as follows:
the system comprises a normal isomerization separation device, an aromatization device, a normal structuring device, a steam cracking device, a propane dehydrogenation device and a cryogenic separation device; the normal and heterogeneous separation device comprises a light naphtha feeding hole, a normal component outlet and a heterogeneous component outlet; the isomeric component outlet is communicated with a feed inlet of the aromatization device; the aromatization device comprises an aromatization unit and an aromatization product separation unit which are sequentially communicated; the aromatization product separation unit comprises a refinery dry gas outlet II, a propane outlet II, an n-butane outlet II, an isobutane outlet II and a C5+ component outlet; the second propane outlet is communicated with a feed inlet of the propane dehydrogenation device; the second n-butane outlet is communicated with a feed inlet of the steam cracking device; and the second isobutane outlet is communicated with a feed inlet of the normal structuring device, and a discharge hole of the normal structuring device is communicated with a feed inlet of the steam cracking device.
The second refinery dry gas outlet is communicated with a feed inlet of the cryogenic separation device; the cryogenic separation device further comprises a fuel gas outlet and an ethane outlet; the ethane outlet is communicated with the feed inlet of the steam cracking device.
The method comprises the following steps:
(1) passing the light naphtha to an orthoisomerization separation unit to produce normal components and non-normal components;
(2) sending the non-normal components to an aromatization unit, and further separating aromatization products to respectively obtain refinery dry gas, propane, normal butane, isobutane and C5+ components;
(3) sending the propane to a propane dehydrogenation unit to produce propylene and the n-butane to a steam cracking unit to produce ethylene, propylene; sending the isobutane to a normal reforming unit to produce n-butane and the produced n-butane to a steam cracking unit to produce ethylene, propylene;
(4) sending the normal components produced in the step (1) to a steam cracking unit to produce ethylene and propylene;
(5) sending the refinery-related dry gas produced in step (2) to a cryogenic separation unit to produce ethane and a fuel gas comprising C1, the ethane being sent to a steam cracking unit to produce ethylene.
In the above step, the temperature of the aromatization device is 380-400 ℃, and the pressure is 0.4-1.0 MPa (gauge pressure).
In the above steps, the contents of each component are as follows: the proportion of C5-C6 alkane in the light naphtha is 98 percent, and after normal isomerization separation, the proportion of normal C5-C6 and non-normal C5-C6 in C5-C6 alkane is 34 percent and 66 percent respectively; after the separation by an aromatization unit, the proportion of refinery dry gas, propane, n-butane, isobutane and C5+ components in non-normal C5-C6 is 5%, 50%, 10% and 25%, and the proportion of ethane separated by deep cooling in refinery dry gas is 80%.
In the obtained product, the total yield of the ethylene is 27 percent, wherein the yield of the ethylene generated by steam cracking of normal C5-C6 is about 18 percent, the yield of the ethane generated by steam cracking of refinery dry gas cryogenically separated is about 3 percent, and the yield of the ethylene generated by steam cracking of normal butane and normal isobutane is about 6 percent.
In the obtained product, the total yield of propylene is 43 percent, wherein the yield of propylene generated by steam cracking of normal C5-C6 is about 9 percent, the yield of propylene generated by propane dehydrogenation is about 30.5 percent, and the yield of propylene generated by steam cracking of normal butane and iso-butane after normal structuring is about 3.5 percent.
In the obtained product, the total yield of C5+ components is 25%, wherein the total yield of benzene and toluene is 15%, and the total yield of C8-C10 aromatic hydrocarbons is 5%.
Example 4
The difference from example 2 is that step (5) is not included;
in the obtained product, the total yield of ethylene is 41 percent, and the total yield of propylene is 36.5 percent.
Example 5
The difference from example 3 is that step (5) is not included;
in the obtained product, the total yield of ethylene is 24%; the total yield of propylene is 43 percent; the total yield of the C5+ components was 44%. The total yield of the C5+ components is 25%, wherein the total yield of benzene and toluene is 15%, and the total yield of C8-C10 aromatic hydrocarbons is 5%.
Comparative example 1
The difference from the example 1 is that the light naphtha is directly fed into a steam cracking device to produce ethylene and propylene;
in the obtained product, the yield of ethylene is 32%; the propylene yield was 13%.
Comparative example 2
The difference from example 2 is that the light naphtha is fed directly to the aromatization unit to produce C5+ components; in the obtained product, the total yield of C5+ components is 42%, wherein the total yield of benzene and toluene is 14%, and the total yield of C8-C10 aromatic hydrocarbons is 4%.
Claims (6)
1. A preparation method of low-carbon olefin and aromatic hydrocarbon is characterized by comprising the following steps:
(1) passing the light naphtha to an orthoisomerization separation unit to produce normal components and non-normal components;
(2) sending the non-normal components to a hydrocracking unit, and further separating the hydrocracking product to obtain propane, normal butane and isobutane respectively; and/or, sending the non-normal components to an aromatization unit and further separating the aromatization product to obtain propane, n-butane and isobutane, and C5+ components, respectively;
(3) sending the propane to a propane dehydrogenation unit to produce propylene and the n-butane to a steam cracking unit to produce ethylene, propylene; sending the isobutane to a normal structuring unit to produce n-butane and sending the produced n-butane to a steam cracking unit to produce ethylene, propylene.
2. The method of claim 1, wherein the light naphtha comprises C5-C6 alkanes; the normal component comprises normal C5-C6 alkane; the non-normal component comprises isomeric C5-C6 alkane.
3. The method of claim 1, wherein the normal components produced in step (1) are sent to a steam cracking unit to produce ethylene and propylene.
4. The method of claim 1, wherein the C5+ component includes benzene, toluene, C8-C10 aromatics.
5. The method according to claim 1, wherein the light naphtha is subjected to normal isomerization separation by distillation or adsorption.
6. A system for use in the process of claim 1, wherein the system comprises a normal isomerization separation unit, a hydrocracking unit, an aromatization unit, a normal isomerization unit, a steam cracking unit, a propane dehydrogenation unit;
the normal and heterogeneous separation device comprises a light naphtha feeding hole, a normal component outlet and a heterogeneous component outlet; the isomeric component outlet is respectively communicated with the feed inlets of the hydrocracking device and the aromatization device;
the hydrocracking device comprises a hydrocracking unit and a cracked product separation unit which are sequentially communicated; the cracked product separation unit comprises a propane outlet I, an n-butane outlet I and an isobutane outlet I;
the aromatization device comprises an aromatization unit and an aromatization product separation unit which are sequentially communicated; the aromatization product separation unit comprises a second propane outlet, a second n-butane outlet, a second isobutane outlet and a C5+ component outlet;
the first propane outlet and the second propane outlet are communicated with a feed inlet of a propane dehydrogenation device;
the n-butane outlet I and the n-butane outlet II are communicated with a feed inlet of the steam cracking device;
the first isobutane outlet and the second isobutane outlet are communicated with a feeding hole of the normal structuring device, and a discharging hole of the normal structuring device is communicated with a feeding hole of the steam cracking device.
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| CN202011413693.9A Pending CN112521249A (en) | 2020-12-02 | 2020-12-02 | Low-carbon olefin and aromatic hydrocarbon yield increasing method and system |
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| CN115505419A (en) * | 2021-06-23 | 2022-12-23 | 中国石化工程建设有限公司 | Light naphtha positive structuring method |
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| CN115505419A (en) * | 2021-06-23 | 2022-12-23 | 中国石化工程建设有限公司 | Light naphtha positive structuring method |
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Inventor after: Peng Guangqin Inventor after: Feng Xu Inventor after: Zhen Xu Inventor after: Li Wei Inventor after: Wang Wenqiang Inventor after: Shi Xinhao Inventor after: Yang Shuxian Inventor after: Hong Chenglong Inventor after: Shang Jibing Inventor after: Dou Zhijun Inventor after: Li Tao Inventor after: Xu Qinghui Inventor after: Wen Jiancheng Inventor after: Wang Xiaomeng Inventor after: Hu Haiming Inventor before: Peng Guangqin Inventor before: Feng Xu Inventor before: Zhen Xu Inventor before: Li Wei Inventor before: Wang Wenqiang Inventor before: Shi Xinghao Inventor before: Yang Shuxian Inventor before: Hong Chenglong Inventor before: Shang Jibing Inventor before: Dou Zhijun Inventor before: Li Tao Inventor before: Xu Qinghui Inventor before: Wen Jiancheng Inventor before: Wang Xiaomeng Inventor before: Hu Haiming |