CN112467080A - Preparation method of embedded tab groove - Google Patents

Preparation method of embedded tab groove Download PDF

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Publication number
CN112467080A
CN112467080A CN202011317700.5A CN202011317700A CN112467080A CN 112467080 A CN112467080 A CN 112467080A CN 202011317700 A CN202011317700 A CN 202011317700A CN 112467080 A CN112467080 A CN 112467080A
Authority
CN
China
Prior art keywords
pole piece
embedded
groove
tab
lug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011317700.5A
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Chinese (zh)
Inventor
刘海
戈志敏
王乾
韦向红
黎莉
危璐雅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Ganfeng Lithium Technology Co ltd
Original Assignee
Huizhou Ganfeng Lithium Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huizhou Ganfeng Lithium Technology Co ltd filed Critical Huizhou Ganfeng Lithium Technology Co ltd
Priority to CN202011317700.5A priority Critical patent/CN112467080A/en
Publication of CN112467080A publication Critical patent/CN112467080A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention discloses a preparation method of an embedded tab groove. The preparation method of the embedded tab groove comprises the following steps: the method comprises the following steps: determining the specific position and size of a lug groove on a pole piece; step two: heating and melting the thermoplastic resin with the low softening point, coating the thermoplastic resin on the pole piece at the position of the lug groove determined in the first step, and carrying out the next step after the thermoplastic resin is cooled; step three: coating the pole piece obtained in the second step with active substances; step four: drying the pole piece obtained in the step three, and melting the low-softening-point thermoplastic resin so as to fall off the foil, thereby forming an embedded pole lug groove on the pole piece; step five: and welding a tab in the tab groove to obtain the pole piece with the embedded tab. The preparation method of the embedded tab groove has the advantages of simple equipment, low investment cost, high pole piece production goodness and the like.

Description

Preparation method of embedded tab groove
Technical Field
The invention relates to the technical field of lithium ion batteries, in particular to a preparation method of an embedded tab groove.
Background
At present, in the preparation process of a lithium ion battery pole piece, a pole lug groove for welding a pole lug position is usually reserved on the pole piece, and the current common method for preparing the pole lug groove comprises the following steps: intermittent coating is adopted: in the coating process, a certain area is selected and not coated, so that the tab groove can be formed, but the method cannot be applied to the embedded tab. Cleaning the coating by laser: the coating is subjected to photophysical reaction by adopting high-intensity laser to realize the cleaning effect of the coating, but the high-intensity laser easily burns a pole piece, particularly a positive aluminum foil to oxidize the aluminum foil or cause perforation of the aluminum foil. In addition, the cost of the laser equipment is high, which causes the manufacturing cost of the lithium ion battery to be increased. Removing the coating by adopting a scraping blade: the method for directly scraping the coating by using the scraper has the advantages that the speed of the scraper, the force of the scraper and the distance between the scraper and the base foil are difficult to control, the foil is easily scratched or the coating is not uniformly removed, so that the production yield of the pole piece is influenced. Removing the coating by adopting foaming glue: and adhering foaming glue to the reserved position of the pole piece, coating and baking, wherein the foaming glue can expand and separate from the foil in the baking process, so that a lug groove is formed. However, the foaming adhesive used by the method is unstable, and expands during baking to easily cause extrusion deformation on the surrounding coating, thereby affecting the quality of the pole piece and reducing the production yield. Cleaning the coating with a solvent: and coating a layer of solvent for cleaning the coating on the coating to strip the coating. The method has the advantages of wide solvent diffusion range and high diffusion speed, and the sizes of the lug grooves are difficult to control.
Disclosure of Invention
Therefore, in order to solve the above problems, it is necessary to provide a method for manufacturing an embedded tab groove, where the method has the advantages of simple equipment, low investment cost, high yield of pole piece production, and the like:
in order to achieve the above object, the present invention provides the following technical solutions
A preparation method of an embedded tab groove comprises the following steps:
the method comprises the following steps: determining the specific position and size of a lug groove on a pole piece;
step two: heating and melting the thermoplastic resin with the low softening point, coating the thermoplastic resin on the pole piece at the position of the lug groove determined in the first step, and carrying out the next step after the thermoplastic resin is cooled;
step three: coating the pole piece obtained in the second step with active substances;
step four: drying the pole piece obtained in the step three, and melting the low-softening-point thermoplastic resin so as to fall off the foil, thereby forming an embedded pole lug groove on the pole piece;
step five: and welding a tab in the tab groove to obtain the pole piece with the embedded tab.
Furthermore, the position of the lug groove is any position of the pole piece.
Furthermore, the position of the lug groove is the middle position of the pole piece.
Further, the low softening point thermoplastic resin is any one of a vinyl acetate resin, a polyethylene resin, a polypropylene resin, and a polycarbonate resin.
Further, the low softening point thermoplastic resin is a vinyl acetate resin or a polyvinyl alcohol resin.
Further, the drying temperature is 50 to 200 ℃.
Further, the drying temperature of the pole piece is 80-120 ℃.
Further, the length of the tab groove is greater than that of the tab, and the width of the tab groove is greater than that of the tab.
Compared with the prior art, the preparation method of the embedded tab groove has the following advantages: 1. by adopting the invention, the quantity of active substances on the pole piece can be further improved by utilizing the embedded pole lug, so that the energy density of the lithium ion battery is improved; 2. the equipment used for preparing the embedded pole lug can be replaced with the existing equipment for preparing the pole piece, and only the coating of the thermoplastic resin with low softening point is needed to be added, so that the process is simple, the input cost is low, and the excellent rate of the pole piece production is high. 3. The process for preparing the embedded lug groove by using the method is more controllable, and the foil is not damaged.
Drawings
Fig. 1 is a flowchart illustrating a conventional method for manufacturing a groove of an embedded tab;
fig. 2 is a schematic structural view of a pole piece of the method for manufacturing the embedded tab groove shown in fig. 1;
fig. 3 is a schematic structural view of a multi-pole piece of the method for manufacturing the embedded tab groove shown in fig. 1.
Description of the figures
The tab glue comprises a tab glue 1, a tab 2, a tab groove 3 and a pole piece 4.
Detailed Description
To facilitate an understanding of the invention, the invention will now be described more fully with reference to the accompanying drawings. Preferred embodiments of the present invention are shown in the drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
It will be understood that when an element is referred to as being "secured to" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
Referring to fig. 1 to 3, the present invention provides a method for manufacturing a groove of an embedded tab, which is characterized by comprising the following steps:
the method comprises the following steps: and determining the specific position and size of the lug groove 3 on the pole piece 4.
Step two: and (3) heating and melting the thermoplastic resin with the low softening point, coating the thermoplastic resin on the pole piece at the position of the lug groove determined in the first step, and carrying out the next step after the thermoplastic resin is cooled.
Step three: and D, coating the pole piece obtained in the step two with active substances.
Step four: and (4) drying the pole piece obtained in the step three, and melting the thermoplastic resin with the low softening point so as to fall off the foil, thereby forming an embedded pole lug groove on the pole piece.
Step five: and welding the lug 2 in the lug groove to obtain the pole piece with the embedded lug.
And the tab is also provided with tab glue 1.
The position of the lug groove can be any position of the pole piece, and the size can be adjusted according to the size of the lug.
Wherein, any one of vinyl acetate resin, polyethylene resin, polypropylene resin and polycarbonate resin.
Wherein, the drying temperature is as follows: 50 to 200 ℃.
The length of the lug groove is greater than that of the lug, and the width of the lug groove is greater than that of the lug.
Wherein, L is the length of utmost point ear recess, and D is the degree of depth of utmost point ear recess, and H is utmost point ear length, and D is utmost point ear width.
Preferably, the position of the lug groove in the first step is the middle part of the pole piece;
preferably, the thermoplastic resin having a low softening point is a vinyl acetate resin or polyvinyl alcohol.
Preferably, the drying temperature of the pole piece is 80-120 ℃.
Preferably, the molten thermoplastic resin remaining on the pole piece may be further washed using a cleaning device.
Please refer to the following embodiments:
example 1
As shown in fig. 1 and fig. 2, the method for manufacturing the embedded tab groove of the present embodiment includes the following steps:
the method comprises the following steps: selecting the embedded pole lug position as one third of the pole piece, wherein the width of the embedded pole lug position is 10mm, and the length of the embedded pole lug position is 25 mm;
step two: heating the vinyl acetate resin to 120 ℃ for melting, coating the vinyl acetate resin on the position of the lug groove determined in the first step on the pole piece by using a brushing method, and carrying out the next step after the thermoplastic resin is naturally cooled;
step three: coating the pole piece obtained in the step two with a lithium cobaltate active substance;
step four: drying the pole piece obtained in the third step at the temperature of 100 ℃ to melt the vinyl acetate resin, so that the vinyl acetate resin falls off from the foil, and an embedded lug groove is formed on the pole piece;
step five: carrying out secondary cleaning on the pole pieces by utilizing brush dust removal on the residual vinyl acetate resin on the four pole pieces in the step to ensure that no residue exists on the pole pieces, and then carrying out the next step;
step six: and welding a lug with the width of 5mm and the length of 25mm in a lug groove, and exposing the lug for 7mm to obtain the pole piece with the embedded lug.
Example 2
As shown in fig. 3, the method for manufacturing the multi-pole-piece embedded tab groove of the embodiment includes the following steps:
the method comprises the following steps: selecting the embedded pole lug position as one third of the pole piece, wherein the width of the embedded pole lug position is 10mm, and the length of the embedded pole lug position is 25 mm;
step two: heating the polyethylene resin to 100 ℃ for melting, coating the polyethylene resin on the pole piece at the position of the lug groove determined in the first step by using a brushing method, and carrying out the next step after the polyethylene resin is naturally cooled;
step three: coating the pole piece obtained in the step two with a lithium cobaltate active substance;
step four: drying the pole piece obtained in the third step at the temperature of 100 ℃ to melt the polyethylene resin, so that the polyethylene resin falls off from the foil, and an embedded pole lug groove is formed on the pole piece;
step five: carrying out secondary cleaning on the pole pieces by utilizing brush dust removal on the residual vinyl acetate resin on the four pole pieces in the step to ensure that no residue exists on the pole pieces, and then carrying out the next step;
step six: and welding a 5mm wide and 25mm long tab in a tab groove, and exposing the tab for 7mm to obtain the multi-pole piece with the embedded tab.
Compared with the prior art, the preparation method of the embedded tab groove has the following advantages: 1. by adopting the invention, the quantity of active substances on the pole piece can be further improved by utilizing the embedded pole lug, so that the energy density of the lithium ion battery is improved; 2. the equipment used for preparing the embedded pole lug can be replaced with the existing equipment for preparing the pole piece, and only the coating of the thermoplastic resin with low softening point is needed to be added, so that the process is simple, the input cost is low, and the excellent rate of the pole piece production is high. 3. The process for preparing the embedded lug groove by using the method is more controllable, and the foil is not damaged.
The above description is only for the purpose of illustrating specific embodiments of the present invention, and should not be construed as limiting the scope of the present invention, and all equivalent changes and modifications made in accordance with the spirit of the present invention should be considered as falling within the scope of the present invention.

Claims (8)

1. A preparation method of an embedded tab groove is characterized by comprising the following steps: the method comprises the following steps:
the method comprises the following steps: determining the specific position and size of a lug groove on a pole piece;
step two: heating and melting the thermoplastic resin with the low softening point, coating the thermoplastic resin on the pole piece at the position of the lug groove determined in the first step, and carrying out the next step after the thermoplastic resin is cooled;
step three: coating the pole piece obtained in the second step with active substances;
step four: drying the pole piece obtained in the step three, and melting the low-softening-point thermoplastic resin so as to fall off the foil, thereby forming an embedded pole lug groove on the pole piece;
step five: and welding a tab in the tab groove to obtain the pole piece with the embedded tab.
2. The method for manufacturing the embedded tab groove according to claim 1, wherein: the position of the lug groove is any position of the pole piece.
3. The method for manufacturing the embedded tab groove according to claim 1, wherein: the position of the lug groove is the middle position of the pole piece.
4. The method for manufacturing the embedded tab groove according to claim 1, wherein: the low-softening-point thermoplastic resin is any one of a vinyl acetate resin, a polyethylene resin, a polypropylene resin and a polycarbonate resin.
5. The method for manufacturing the embedded tab groove according to claim 1, wherein: the low-softening-point thermoplastic resin is vinyl acetate resin or polyvinyl alcohol resin.
6. The method for manufacturing the embedded tab groove according to claim 1, wherein: the drying temperature is 50 to 200 ℃.
7. The method for manufacturing the embedded tab groove according to claim 1, wherein: the drying temperature of the pole piece is 80-120 ℃.
8. The method for manufacturing the embedded tab groove according to claim 1, wherein: the length of the lug groove is greater than that of the lug, and the width of the lug groove is greater than that of the lug.
CN202011317700.5A 2020-11-23 2020-11-23 Preparation method of embedded tab groove Pending CN112467080A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023036267A1 (en) * 2021-09-09 2023-03-16 珠海冠宇电池股份有限公司 Battery electrode plate, battery, and method for manufacturing battery electrode plate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6152971A (en) * 1996-11-06 2000-11-28 Dai Nippon Printing Co., Ltd. Electrode plate for secondary battery with nonaqueous electrolyte and process for producing same
JP2000331674A (en) * 1999-05-20 2000-11-30 Dainippon Printing Co Ltd Electrode plate for nonaqueous electrolyte secondary battery and intermediate product thereof, and manufacture thereof
US6162264A (en) * 1996-06-17 2000-12-19 Dai Nippon Printing Co., Ltd. Process for producing porous coating layer electrode plate for secondary battery with nonaqueous electrolyte process for producing same and sheet for peeling active material layer
JP2001043848A (en) * 1999-07-28 2001-02-16 Sony Corp Manufacture of polymer battery and peeling device
CN109414907A (en) * 2016-06-06 2019-03-01 昭和电工包装株式会社 The manufacturing method of laminate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6162264A (en) * 1996-06-17 2000-12-19 Dai Nippon Printing Co., Ltd. Process for producing porous coating layer electrode plate for secondary battery with nonaqueous electrolyte process for producing same and sheet for peeling active material layer
US6152971A (en) * 1996-11-06 2000-11-28 Dai Nippon Printing Co., Ltd. Electrode plate for secondary battery with nonaqueous electrolyte and process for producing same
JP2000331674A (en) * 1999-05-20 2000-11-30 Dainippon Printing Co Ltd Electrode plate for nonaqueous electrolyte secondary battery and intermediate product thereof, and manufacture thereof
JP2001043848A (en) * 1999-07-28 2001-02-16 Sony Corp Manufacture of polymer battery and peeling device
CN109414907A (en) * 2016-06-06 2019-03-01 昭和电工包装株式会社 The manufacturing method of laminate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023036267A1 (en) * 2021-09-09 2023-03-16 珠海冠宇电池股份有限公司 Battery electrode plate, battery, and method for manufacturing battery electrode plate

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Application publication date: 20210309

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