CN112461763A - Multi-parameter water quality detector and detection method thereof - Google Patents
Multi-parameter water quality detector and detection method thereof Download PDFInfo
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- CN112461763A CN112461763A CN202011510177.8A CN202011510177A CN112461763A CN 112461763 A CN112461763 A CN 112461763A CN 202011510177 A CN202011510177 A CN 202011510177A CN 112461763 A CN112461763 A CN 112461763A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 238000001514 detection method Methods 0.000 title claims abstract description 48
- 230000003287 optical effect Effects 0.000 claims abstract description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001301 oxygen Substances 0.000 claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 9
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000010365 information processing Effects 0.000 claims abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 6
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 5
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- 230000008569 process Effects 0.000 claims abstract description 5
- 238000012790 confirmation Methods 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004155 Chlorine dioxide Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 3
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 230000004044 response Effects 0.000 claims description 3
- 238000012360 testing method Methods 0.000 abstract description 4
- 230000006870 function Effects 0.000 description 11
- 239000000126 substance Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000010295 mobile communication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920013657 polymer matrix composite Polymers 0.000 description 1
- 239000011160 polymer matrix composite Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000012372 quality testing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
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- Life Sciences & Earth Sciences (AREA)
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- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
The invention provides a multi-parameter water quality detector, which comprises: a calibration module configured to calibrate the detector intrinsic parameters prior to detection; a receiving module: the receiving module is configured to receive optical information after the built-in parameters are calibrated; an information processing module: the information processing module is configured to process the received optical information to obtain numerical information; an information output module: the information output module is configured to output the numerical information to the display screen after obtaining the numerical information, the invention can test various test items such as pH, nitrite, ammonia nitrogen, phosphate or dissolved oxygen, and the like, and has the advantages of small volume, light weight, good portability, simple operation, easy operation, external battery and internal power supply support, stable energy supply and backlight display function, so that the invention is suitable for dark or direct sunlight environment.
Description
Technical Field
The invention relates to the field of water quality detection, in particular to a multi-parameter water quality detector and a detection method thereof.
Background
For water quality detection, various parameters are usually required to be detected, such as COD, BOD, ammonia nitrogen, total phosphorus, total nitrogen, temperature, pH value, conductivity, dissolved oxygen, turbidity and other conventional characteristic parameters in water. COD defines chemical oxygen demand, which is the amount of oxidant required for the oxidative decomposition of reducing substances in water under certain stringent conditions, expressed in mg/L of oxygen, and reflects the degree of pollution of the water by the reducing substances. BOD (Biochemical Oxygen demand): biochemical oxygen demand orBiochemical oxygen consumption is a comprehensive indicator of the content of aerobic pollutants such as organic matters in water. It shows that the organic matters in the water are oxidized and decomposed by the action of microorganisms, so that the total amount of dissolved oxygen in the water is consumed during mineralization or gasification. Ammonia nitrogen refers to free ammonia (NH) in water3) And ammonium ion (NH)4 +) Nitrogen in the form present. The nitrogen content of the animal organic matter is generally higher than that of the plant organic matter. The total phosphorus is the result of the determination after various forms of phosphorus are converted into orthophosphate by digestion of a water sample, and is measured by the mg of phosphorus contained in each liter of water sample. The pH value represents the degree of acidity or alkalinity of the aqueous solution. Conductivity is a tensor, which is the ability of a solution to conduct current in a digital representation in water quality testing. The content of dissolved oxygen in water has close relation with the partial pressure of oxygen in air and the temperature of water, and the amount of dissolved oxygen in water is an index for measuring the self-purification capacity of water. Turbidity is the degree of obstruction that occurs when suspended matter in water passes through to light.
The detection of parameters such as COD, BOD, ammonia nitrogen, total phosphorus, total nitrogen and the like can be carried out by a spectrophotometer, and the conditions of the absorption or emission spectrum wavelength, intensity, polarization state and the like of substance molecules under different conditions have inherent relation with the structural characteristics of the substance. Different substances differ in their molecular structure, corresponding to different absorption and emission spectra; when the concentration of the same substance is different, the absorption intensity at the same absorption peak position is different. Therefore, the concentration of a substance in water can be determined by detecting the degree of absorption of the substance in water to light of a particular wavelength. In the water quality detection, corresponding reagents are required to be dripped and then pretreated, and at the moment, water quality samples and the reagents need to be measured accurately and quantitatively, so that a more accurate detection result can be obtained. In addition, a water quality detector can only detect one characteristic parameter of a water sample at present, so that a plurality of water quality detectors are needed for detecting a plurality of characteristic parameters of water quality.
The existing multifunctional water quality detector has a series of problems that the size is too large, the water quality detector is inconvenient to carry, the practical steps are complex and the like.
Disclosure of Invention
The invention aims to provide a water quality detector, which is used for solving at least one of the problems of the existing water quality detector:
in a first aspect, the invention provides a detection method of a water quality detector, which comprises the following steps:
receiving the confirmation detection information, extracting detection content of the detection information, and calibrating the detection content by using corresponding built-in parameters; receiving optical information, and processing the received optical information to obtain numerical information; and outputting the obtained numerical value information to a display screen.
Preferably, the detecting content includes: pH, nitrite, ammonia nitrogen, phosphate, dissolved oxygen, copper, total iron, manganese, nickel, hexavalent chromium, residual chlorine, chlorine dioxide, ozone and hydrogen sulfide.
Preferably, after outputting the obtained numerical information to a display screen, the method further comprises:
and receiving a backlight request, and outputting an execution backlight instruction to the display screen.
Through selecting the detection content, then calibrating the corresponding built-in parameters, waiting for receiving the optical information after calibration, processing the optical information to obtain specific parameters, then displaying the parameters through a display screen, wherein the items which can be detected comprise pH, nitrite, ammonia nitrogen, phosphate, dissolved oxygen, copper, total iron, manganese, nickel, hexavalent chromium, residual chlorine, chlorine dioxide, ozone, hydrogen sulfide and the like, and the problems that reading cannot be realized and the like can be solved through a backlight function in a dark environment or when sunlight is directly irradiated.
In a second aspect, the present invention provides a water quality detector, the detector comprising:
a calibration module configured to calibrate the detector intrinsic parameters prior to detection; a receiving module: the receiving module is configured to receive optical information after the built-in parameters are calibrated; an information processing module: the information processing module is configured to process the received optical information to obtain numerical information; an information output module: the information output module is configured to output the numerical information to the display screen after the numerical information is obtained.
Preferably, the detector further comprises:
a function switching module configured to receive a signal to be detected before calibration in response to a detection function corresponding to the detection signal.
Preferably, the detector comprises a colorimetric pool, a light shielding plate, a display screen and a function key.
Preferably, the detector further comprises: and a power supply and a battery cabin are arranged in the device.
Preferably, the function key includes: an on-off key, a direction key, a confirmation key, a return key and a backlight key.
In a third aspect, an electronic device is provided, comprising: the detection device comprises at least one processor and a memory which is connected with the at least one processor in a communication mode, wherein the memory stores instructions which can be executed by the at least one processor, and the instructions are executed by the at least one processor so as to enable the at least one processor to execute the detection method of any embodiment of the invention.
Has the advantages that:
the invention can test various test items such as pH, nitrite, ammonia nitrogen, phosphate or dissolved oxygen, has small volume, light weight, good portability, simple operation and easy operation, supports an external battery and an internal power supply, supplies energy stably, and has a backlight display function, so that the invention is suitable for darker or direct sunlight environments.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the description of the embodiments are briefly introduced below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on the drawings without creative efforts.
FIG. 1 is a schematic flow chart of a water quality detecting method according to an embodiment of the present invention;
FIG. 2 is a schematic flow chart of a detection method of a water quality detector according to another embodiment of the present invention;
FIG. 3 is a schematic structural diagram of a water quality detector according to an embodiment of the present invention;
FIG. 4 is a schematic structural diagram of another water quality detector according to an embodiment of the present invention;
fig. 5 is a schematic structural diagram of a water quality detector according to another embodiment of the present invention.
In the figure: 1. a colorimetric pool; 2. a light-shielding cover; 3. a display screen; 4. a function key; 5. anti-skid lines; 6. a battery compartment; 6. and a USB interface.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, it shows a schematic flow chart of the detection method of the water quality detector of the present application, for solving the problem of single detection item of the detector,
102, receiving optical information, and processing the received optical information to obtain numerical information;
and 103, outputting the obtained numerical information to a display screen.
In step 101, determining items to be detected according to the obtained detection information, and then performing self-calibration of built-in parameters on the corresponding detection items to improve the accuracy of detection data;
in step 102, the built-in parameters are calibrated, the optical information is received, and then the optical information is processed to obtain numerical information;
in step 103, the obtained numerical information is transmitted to a display screen and displayed by the display screen.
In the process, items needing to be detected are selected firstly, and then the corresponding parameters are used for detecting the water quality, so that the requirement that a single instrument detects multiple detection items is met.
Please refer to fig. 2, which shows a schematic flow chart of the detection method of the water quality detector of the present application, for solving the problems of tedious calibration of the detector and no data reading in a special environment;
step 202, receiving optical information, and processing the received optical information to obtain numerical information;
In step 201, receiving the confirmation detection information, first determining whether calibration is required, and if not, directly entering step 202;
step 202, directly receiving optical information to obtain numerical information;
Referring to fig. 3, fig. 3 is a schematic structural diagram of a water quality detector, which is used for solving the problem that the existing water quality detector is complex to use;
as can be seen from figure 3, the water quality detector comprises a colorimetric pool, a light screen, a display screen and function keys, the whole shell of the water quality detector can be made of light materials, such as polymer matrix composite materials, and the like, so that the problem of the weight of the water quality detector is solved, then the water quality detector can be designed into a mobile phone size and is easy to carry, the colorimetric pool is used for placing a colorimetric bottle in figure 3, the light screen is used for opening or closing the colorimetric pool, so that the accuracy in detection and the protection of the colorimetric pool are guaranteed, the function keys are arranged, the function keys comprise an on-off key, a direction key, a confirmation key, a return key and a backlight key, the water quality detector is simple.
Referring to fig. 4, fig. 4 is a schematic structural diagram of a water quality detector for solving the problems of slippery hands and power source in the use of the existing water quality detector;
as can be seen from figure 4, the water quality detector also comprises anti-skid lines, a battery bin and a USB structure thereof, wherein an internal power supply is arranged in the water quality detector, the internal power supply is charged through the USB, and meanwhile, a dry battery can be directly used as the power supply, so that the problem that the internal power supply is not electrified is solved, and the problem that hands are slippery when in use is also solved.
Referring to fig. 5, fig. 5 shows a schematic structural diagram of a water quality detector;
501: a calibration module configured to calibrate the detector intrinsic parameters prior to detection;
502: a receiving module: the receiving module is configured to receive optical information after the built-in parameters are calibrated;
503: an information processing module: the information processing module is configured to process the received optical information to obtain numerical information;
504: an information output module: the information output module is configured to output the numerical information to the display screen after the numerical information is obtained.
The non-volatile computer-readable storage medium may include a storage program area and a storage data area, wherein the storage program area may store an operating system, an application program required for at least one function; the storage data area can store data and the like acquired by the water quality detector. Further, the non-volatile computer-readable storage medium may include high speed random access memory, and may also include non-volatile memory, such as at least one magnetic disk storage device, flash memory device, or other non-volatile solid state storage device. In some embodiments, the non-transitory computer readable storage medium optionally includes memory located remotely from the processor, examples of which include, but are not limited to, the internet, an intranet, a local area network, a mobile communications network, and combinations thereof.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (8)
1. A multi-parameter water quality detector is characterized in that the detector comprises:
a calibration module configured to calibrate the detector intrinsic parameters prior to detection;
a receiving module: the receiving module is configured to receive optical information after the built-in parameters are calibrated;
an information processing module: the information processing module is configured to process the received optical information to obtain numerical information;
an information output module: the information output module is configured to output the numerical information to the display screen after the numerical information is obtained.
2. The meter of claim 1, further comprising:
a function switching module configured to receive a signal to be detected before calibration in response to a detection function corresponding to the detection signal.
3. The meter of claim 1, wherein the meter comprises a cuvette, a bezel, a display screen and function keys.
4. The meter of claim 1, further comprising: and a power supply and a battery cabin are arranged in the device.
5. The meter of claim 3, wherein the function keys comprise: an on-off key, a direction key, a confirmation key, a return key and a backlight key.
6. A method of detecting a detector according to any one of claims 1 to 5, comprising the steps of:
receiving the confirmation detection information, extracting detection content of the detection information, and calibrating the detection content by using corresponding built-in parameters;
receiving optical information, and processing the received optical information to obtain numerical information;
and outputting the obtained numerical value information to a display screen.
7. The detection method according to claim 6, wherein the detecting the content comprises: pH, nitrite, ammonia nitrogen, phosphate, dissolved oxygen, copper, total iron, manganese, nickel, hexavalent chromium, residual chlorine, chlorine dioxide, ozone and hydrogen sulfide.
8. The detection method according to claim 6, wherein, when outputting the obtained numerical information to a display screen, the method further comprises:
and receiving a backlight request, and outputting an execution backlight instruction to the display screen.
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CN203561586U (en) * | 2013-10-14 | 2014-04-23 | 杭州陆恒生物科技有限公司 | Ammonia nitrogen-total phosphorus integrated rapid detector |
CN104122376A (en) * | 2014-06-30 | 2014-10-29 | 南京领先环保技术有限公司 | Multi-parameter water quality analyzer |
CN110007056A (en) * | 2019-04-16 | 2019-07-12 | 量准(上海)医疗器械有限公司 | A kind of Novel low power consumption portable wireless water quality detection system |
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2020
- 2020-12-18 CN CN202011510177.8A patent/CN112461763A/en active Pending
Patent Citations (7)
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US20040257235A1 (en) * | 2003-06-18 | 2004-12-23 | Robert Right | Ambient condition detector with multi-function test |
US20090001262A1 (en) * | 2003-10-22 | 2009-01-01 | Erik Visser | System and Method for Spectral Analysis |
CN202471685U (en) * | 2011-12-05 | 2012-10-03 | 天津亚微电子材料科技有限公司 | Portable handheld tester for dissolved oxygen |
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