CN112442721A - Electrophoresis painting process for heat-insulation bridge-cut-off aluminum profile - Google Patents
Electrophoresis painting process for heat-insulation bridge-cut-off aluminum profile Download PDFInfo
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- CN112442721A CN112442721A CN202011265481.0A CN202011265481A CN112442721A CN 112442721 A CN112442721 A CN 112442721A CN 202011265481 A CN202011265481 A CN 202011265481A CN 112442721 A CN112442721 A CN 112442721A
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- aluminum profile
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Links
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 68
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 238000001962 electrophoresis Methods 0.000 title claims abstract description 59
- 238000007591 painting process Methods 0.000 title claims abstract description 16
- 238000009413 insulation Methods 0.000 title claims abstract description 15
- 239000003973 paint Substances 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000010422 painting Methods 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 229910000831 Steel Inorganic materials 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000005342 ion exchange Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 230000003472 neutralizing effect Effects 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 229920005906 polyester polyol Polymers 0.000 claims description 8
- 239000010959 steel Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- 238000007865 diluting Methods 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000004519 grease Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000005498 polishing Methods 0.000 claims description 4
- 229920001225 polyester resin Polymers 0.000 claims description 4
- 239000004645 polyester resin Substances 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000004040 coloring Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000012797 qualification Methods 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007739 conversion coating Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/20—Pretreatment
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/22—Servicing or operating apparatus or multistep processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an electrophoresis painting process for a heat-insulation bridge-cut-off aluminum profile, which comprises the following steps of; step one, pretreatment of painting; step two, preparing electrophoretic paint; step three, putting the electrophoretic paint obtained in the step two into an electrophoresis tank, and adjusting related parameters to 7-9% of solid content, 20-25 ℃, pH8.0-8.8, and 1500-2500 of resistivity pi omega cm (20 ℃); and step four, taking out the aluminum profile processed in the step one, putting the aluminum profile into an electrophoresis tank, and carrying out electrophoresis treatment on the aluminum profile and the electrophoretic paint, wherein the parameters of the electrophoresis treatment are voltage of 80-250V (DC), electrophoresis time of 1-3min and current density of 15-50A pi m2 until the coating thickness of the aluminum profile reaches 7-12 mu m. The invention is easy to realize automatic production, because the electrophoretic coating is carried out in the water-based electrophoretic bath, similar to the anodic oxidation and electrolytic coloring process, the treatment time is short, the utilization rate of the coating is high, the coating is uniform and compact, the coating quality is good, the thickness of the coating can be freely controlled, the processing technology of the aluminum profile is improved, and the qualification rate of the electrophoretic profile is improved.
Description
Technical Field
The invention relates to the technical field of aluminum profile electrophoresis, in particular to an electrophoretic painting process for a heat-insulation bridge-cut-off aluminum profile.
Background
The traditional surface treatment process of the aluminum section is oxidation, coloring and sealing treatment, and a conversion coating of the aluminum is easy to corrode and has poor durability when being used outdoors for a long time, particularly in acid rain or marine environment, so that a coating method is tried to improve the decorative performance and the service life of the architectural aluminum section since the 70 s, and at present, electrophoretic coating, powder coating and fluorocarbon spraying are used industrially and successfully.
Among the surface treatment technologies, electrocoating is the most developed technology. The aluminum profile is subjected to electrophoresis coating after anodization and electrolytic coloring, and has double-layer protection. The coating has high transparency, high metal texture, high corrosion resistance and high weather resistance, is more decorative than spray painting and powder spraying, is deeply loved by users, is widely used for home decoration, has high decoration and can highlight the metal luster of the aluminum profile, has great potential market, and therefore, the electrophoretic coating is increasingly used on the building aluminum profile; however, in practice, the electrophoretic painting process of the heat-insulating bridge-cut-off section bar in the actual production process is troublesome, the utilization rate of the coating is low, the coating is uniform and not dense, and the coating is not thick and uniform, so that the product quality is influenced.
Disclosure of Invention
The invention aims to provide an electrophoretic painting process for a heat-insulation bridge-cut-off aluminum profile, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: an electrophoresis painting process for a heat-insulation bridge-cut aluminum profile comprises the following steps;
step one, pretreatment before painting: polishing the surface of the aluminum profile to remove oxide skin and burrs, putting the aluminum profile into ultrasonic equipment, mixing the aluminum profile with cleaning fluid to perform surface grease treatment, cleaning the aluminum profile with warm water after treatment, and drying the aluminum profile;
step two, preparing electrophoretic paint;
s1, mixing the resin, the polyester polyol and the deionized water, fully dissolving the mixture with the nonionic surfactant, and dropwise adding a 5-10% NaOH solution until the pH value of the solution is 6-6.5;
s2, adding the modified amine curing agent, the cross-linking agent and the flatting agent, stirring, diluting with a neutralizing agent, and stirring and emulsifying at a high speed for 1-1.5h to obtain the electrophoretic paint;
step three, putting the electrophoretic paint obtained in the step two into an electrophoresis tank, and adjusting related parameters to 7-9% of solid content, 20-25 ℃, pH8.0-8.8, and 1500-2500 of resistivity pi omega cm (20 ℃);
taking out the aluminum profile processed in the step one, putting the aluminum profile into an electrophoresis tank, and carrying out electrophoresis treatment on the aluminum profile and electrophoretic paint, wherein the parameters of the electrophoresis treatment are voltage of 80-250V (DC), electrophoresis time of 1-3min and current density of 15-50A pi m2 until the coating thickness of the aluminum profile reaches 7-12 mu m;
and step five, drying the electrophoretic painted aluminum section in a radiation convection mode, wherein the anode electrophoretic paint film needs to be baked at the temperature of 140-170 ℃.
Preferably, the electrophoresis tank is a rectangular tank, the tank body is made of a 4-6mm steel plate, the lining of the electrophoresis tank is made of polypropylene or epoxy glass steel, and the electrophoresis tank is provided with an overflow tank.
Preferably, in the second step, the electrophoretic paint is composed of the following raw materials in parts by weight: 40-60 parts of resin, 20-30 parts of polyester polyol, 15-20 parts of modified amine curing agent, 10-18 parts of deionized water, 8-15 parts of cross-linking agent, 5-8 parts of flatting agent, 5-8 parts of neutralizing agent and 2-5 parts of nonionic surfactant.
Preferably, in the second step, the resin is any one or more of polyester resin, epoxy resin or olefine acid resin.
Preferably, in the fourth step, an ion exchange treatment system is arranged in the electrophoresis tank, the pH value of the cathode is increased continuously during the anode electrophoresis, impurities in the tank liquor can be removed by adopting the ion exchange treatment system, and the pH value of the tank liquor is stabilized by adopting anions and cations.
Preferably, in the fourth step, the electrophoresis of the electrophoresis is direct current, the direct current is required to be arbitrarily adjustable from 0A to 250A, and the ripple factor of the power supply is less than 6%.
The electrophoresis painting process for the heat-insulation bridge-cut-off aluminum profile, provided by the invention, has the beneficial effects that: the invention is easy to realize automatic production, because the electrophoretic coating is carried out in the water-based electrophoretic bath, is similar to the anodic oxidation and electrolytic coloring process, has short treatment time, is easy to realize the flow line operation of the whole process, has high utilization rate of the coating, uniform and compact coating and good coating quality, can freely control the thickness of the coating, improves the processing technology of the aluminum profile and improves the qualification rate of the electrophoretic profile.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Embodiment 1, the present invention provides a technical solution: an electrophoresis painting process for a heat-insulation bridge-cut aluminum profile comprises the following steps; step one, pretreatment before painting: polishing the surface of the aluminum profile to remove oxide skin and burrs, putting the aluminum profile into ultrasonic equipment, mixing the aluminum profile with cleaning fluid to perform surface grease treatment, cleaning the aluminum profile with warm water after treatment, and drying the aluminum profile; step two, preparing electrophoretic paint; s1, mixing the resin, the polyester polyol and the deionized water, fully dissolving the mixture with the nonionic surfactant, and dropwise adding 8% NaOH solution until the pH value of the solution is 6.2; s2, adding the modified amine curing agent, the cross-linking agent and the flatting agent, stirring, diluting with a neutralizing agent, and stirring at a high speed for emulsifying for 1.2h to obtain the electrophoretic paint; the electrophoretic paint is prepared from the following raw materials in parts by weight: 50 parts of resin, 25 parts of polyester polyol, 18 parts of modified amine curing agent, 15 parts of deionized water, 13 parts of crosslinking agent, 7 parts of flatting agent, 6 parts of neutralizing agent and 3 parts of nonionic surfactant, wherein the resin is polyester resin and epoxy resin; step three, putting the electrophoretic paint obtained in the step two into an electrophoresis tank, and adjusting related parameters to 8% of solid content, 23 ℃, pH8.6 and 2000 of resistivity pi omega cm (20 ℃); the electrophoresis tank is a rectangular tank, the tank body is made of a 5mm steel plate, the lining of the electrophoresis tank is made of polypropylene or epoxy glass steel, the overflow tank is internally provided with an ion exchange treatment system, the pH value of a cathode is continuously increased during anode electrophoresis, the ion exchange treatment system is adopted to remove impurities in the tank liquor, and anions and cations stabilize the pH value of the tank liquor; taking out the aluminum profile processed in the step one, putting the aluminum profile into an electrophoresis tank, and carrying out electrophoresis treatment on the aluminum profile and electrophoretic paint, wherein the parameters of the electrophoresis treatment are voltage 220V (DC), electrophoresis time 2min and current density 35A pi m2 until the coating thickness of the aluminum profile reaches 8 mu m, the electrophoresis of the electrophoresis adopts direct current, the direct current is required to be 0-250A and can be adjusted freely, and the ripple factor of a power supply is less than 6%; and step five, drying the electrophoretic painted aluminum section in a radiation convection mode, wherein the anodic electrophoretic paint film needs to be baked at the temperature of 150 ℃.
Embodiment 2, the present invention provides another technical solution: an electrophoresis painting process for a heat-insulation bridge-cut aluminum profile comprises the following steps; step one, pretreatment before painting: polishing the surface of the aluminum profile to remove oxide skin and burrs, putting the aluminum profile into ultrasonic equipment, mixing the aluminum profile with cleaning fluid to perform surface grease treatment, cleaning the aluminum profile with warm water after treatment, and drying the aluminum profile; step two, preparing electrophoretic paint; s1, mixing the resin, the polyester polyol and the deionized water, fully dissolving the mixture with the nonionic surfactant, and dropwise adding 6% NaOH solution until the pH value of the solution is 6.5; s2, adding the modified amine curing agent, the cross-linking agent and the flatting agent, stirring, diluting with a neutralizing agent, and stirring at a high speed for emulsifying for 1.5h to obtain the electrophoretic paint; the electrophoretic paint is prepared from the following raw materials in parts by weight: 45 parts of resin, 23 parts of polyester polyol, 18 parts of modified amine curing agent, 15 parts of deionized water, 12 parts of cross-linking agent, 8 parts of flatting agent, 6 parts of neutralizing agent and 4 parts of nonionic surfactant, wherein the resin is polyester resin and olefine acid resin; step three, putting the electrophoretic paint obtained in the step two into an electrophoresis tank, and adjusting related parameters to 7.4% of solid content, 22 ℃, pH8.8 and 2300 of resistivity pi omega cm (20 ℃); the electrophoresis tank is a rectangular tank, the tank body is made of a 6mm steel plate, the lining of the electrophoresis tank is made of polypropylene or epoxy glass steel, the overflow tank is internally provided with an ion exchange treatment system, the pH value of a cathode is increased continuously during anode electrophoresis, the ion exchange treatment system is adopted to remove impurities in the tank liquor, and anions and cations stabilize the pH value of the tank liquor; taking out the aluminum profile processed in the step one, putting the aluminum profile into an electrophoresis tank, and carrying out electrophoresis treatment on the aluminum profile and electrophoretic paint, wherein the parameters of the electrophoresis treatment are voltage of 180V (DC), electrophoresis time of 2.5min and current density of 40A pi m2 until the thickness of a coating film of the aluminum profile reaches 9 mu m, the electrophoresis of the electrophoresis adopts direct current, the direct current is required to be freely adjustable at 0-250A, and the ripple factor of a power supply is less than 6%; and step five, drying the electrophoretic painted aluminum section in a radiation convection mode, wherein the anodic electrophoretic paint film needs to be baked at the temperature of 155 ℃.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (6)
1. The electrophoresis painting process of the heat-insulation bridge-cut-off aluminum profile is characterized by comprising the following steps of: comprises the following steps;
step one, pretreatment before painting: polishing the surface of the aluminum profile to remove oxide skin and burrs, putting the aluminum profile into ultrasonic equipment, mixing the aluminum profile with cleaning fluid to perform surface grease treatment, cleaning the aluminum profile with warm water after treatment, and drying the aluminum profile;
step two, preparing electrophoretic paint;
s1, mixing the resin, the polyester polyol and the deionized water, fully dissolving the mixture with the nonionic surfactant, and dropwise adding a 5-10% NaOH solution until the pH value of the solution is 6-6.5;
s2, adding the modified amine curing agent, the cross-linking agent and the flatting agent, stirring, diluting with a neutralizing agent, and stirring and emulsifying at a high speed for 1-1.5h to obtain the electrophoretic paint;
step three, putting the electrophoretic paint obtained in the step two into an electrophoresis tank, and adjusting related parameters to 7-9% of solid content, 20-25 ℃, pH8.0-8.8, and 1500-2500 of resistivity pi omega cm (20 ℃);
taking out the aluminum profile processed in the step one, putting the aluminum profile into an electrophoresis tank, and carrying out electrophoresis treatment on the aluminum profile and electrophoretic paint, wherein the parameters of the electrophoresis treatment are voltage of 80-250V (DC), electrophoresis time of 1-3min and current density of 15-50A pi m2 until the coating thickness of the aluminum profile reaches 7-12 mu m;
and step five, drying the electrophoretic painted aluminum section in a radiation convection mode, wherein the anode electrophoretic paint film needs to be baked at the temperature of 140-170 ℃.
2. The electrophoretic painting process for the heat-insulation bridge-cut-off aluminum profile according to claim 1, which is characterized in that: the electrophoresis tank is a rectangular tank, the tank body is made of a 4-6mm steel plate, the lining of the electrophoresis tank is made of polypropylene or epoxy glass steel, and an overflow tank is arranged.
3. The electrophoretic painting process for the heat-insulation bridge-cut-off aluminum profile according to claim 1, which is characterized in that: in the second step, the electrophoretic paint is composed of the following raw materials in parts by weight: 40-60 parts of resin, 20-30 parts of polyester polyol, 15-20 parts of modified amine curing agent, 10-18 parts of deionized water, 8-15 parts of cross-linking agent, 5-8 parts of flatting agent, 5-8 parts of neutralizing agent and 2-5 parts of nonionic surfactant.
4. The electrophoretic painting process for the heat-insulation bridge-cut-off aluminum profile according to claim 1, which is characterized in that: in the second step, the resin is any one or more of polyester resin, epoxy resin or olefine acid resin.
5. The electrophoretic painting process for the heat-insulation bridge-cut-off aluminum profile according to claim 1, which is characterized in that: and in the fourth step, an ion exchange treatment system is arranged in the electrophoresis tank, the pH value of the cathode can be continuously increased during the anode electrophoresis, impurities in the tank liquor can be removed by adopting the ion exchange treatment system, and the pH value of the tank liquor is stable due to anions and cations.
6. The electrophoresis painting process of the heat-insulation bridge-cut-off aluminum profile according to claim 2, characterized in that: in the fourth step, the electrophoresis of the electrophoresis adopts direct current, the direct current is required to be arbitrarily adjustable from 0A to 250A, and the ripple factor of a power supply is less than 6 percent.
Priority Applications (1)
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CN202011265481.0A CN112442721A (en) | 2020-11-13 | 2020-11-13 | Electrophoresis painting process for heat-insulation bridge-cut-off aluminum profile |
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CN202011265481.0A CN112442721A (en) | 2020-11-13 | 2020-11-13 | Electrophoresis painting process for heat-insulation bridge-cut-off aluminum profile |
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CN202011265481.0A Pending CN112442721A (en) | 2020-11-13 | 2020-11-13 | Electrophoresis painting process for heat-insulation bridge-cut-off aluminum profile |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113529153A (en) * | 2021-07-29 | 2021-10-22 | 江阴南方新能源科技有限公司 | High-brightness corrosion-resistant electrophoresis process for photovoltaic aluminum profile |
CN114250495A (en) * | 2022-01-18 | 2022-03-29 | 安徽科蓝特铝业有限公司 | Environment-friendly aluminum profile processing technology |
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CN113529153A (en) * | 2021-07-29 | 2021-10-22 | 江阴南方新能源科技有限公司 | High-brightness corrosion-resistant electrophoresis process for photovoltaic aluminum profile |
CN114250495A (en) * | 2022-01-18 | 2022-03-29 | 安徽科蓝特铝业有限公司 | Environment-friendly aluminum profile processing technology |
CN114250495B (en) * | 2022-01-18 | 2023-08-04 | 安徽科蓝特铝业股份有限公司 | Environment-friendly aluminum profile machining process |
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