CN112430492A - Special hydraulic oil composition for high-efficiency energy-saving injection molding machine - Google Patents

Special hydraulic oil composition for high-efficiency energy-saving injection molding machine Download PDF

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CN112430492A
CN112430492A CN201910790586.9A CN201910790586A CN112430492A CN 112430492 A CN112430492 A CN 112430492A CN 201910790586 A CN201910790586 A CN 201910790586A CN 112430492 A CN112430492 A CN 112430492A
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injection molding
molding machine
composition
hydraulic oil
weight
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张静如
李万英
陈惠卿
贾睿
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/062Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to the field of lubricating oil, in particular to a high-efficiency energy-saving hydraulic oil composition special for an injection molding machine, which comprises the following components in percentage by weight: 0.1-5% of antioxidant, 0.1-2.5% of multifunctional additive of wear-resistant hydraulic oil, 1.0-25% of viscosity index improver, 0-0.05% of anti-foaming agent and the balance of base oil; the base oil is hydrogenated mineral base oil. The high-efficiency energy-saving hydraulic oil composition special for the injection molding machine solves the problems of reducing the pipeline resistance of a hydraulic system and preventing leakage, has good low-temperature fluidity, extremely high viscosity index and excellent oxidation resistance, and has an energy-saving effect of more than 6 percent compared with the common oil special for the injection molding machine (the viscosity index is 100). The product of the invention has reasonable raw material compatibility, simple preparation method, wide application range and easily obtained raw materials.

Description

Special hydraulic oil composition for high-efficiency energy-saving injection molding machine
Technical Field
The invention relates to the field of lubricating oil, in particular to high-efficiency energy-saving hydraulic oil special for an injection molding machine, which is suitable for hydraulic systems of various middle-end and high-end injection molding machines.
Background
The development trend of current mechanical equipment is developing towards small volume, light weight, high benefit and long service life, the lubricating oil products are updated, and polar substances such as efficient additives and the like are added into the oil. The injection molding machine can mold plastic products with complex shapes and precise sizes or with metal inserts in one step, and is widely applied to various fields of national defense, electromechanics, automobiles, transportation, building materials, packaging, agriculture, cultural and educational sanitation and daily life of people, and the quantity of the plastic products accounts for about half of the plastic mechanical industry. Compared with the foreign injection molding machine, the current domestic injection molding machine has the defects of larger volume, low molding precision, large energy consumption and the like, saves energy and is one of the key points of national requirements. Therefore, the energy consumption is reduced, and the added value and the competitiveness of the domestic injection molding machine are improved.
For injection molding machine equipment, the most obvious energy-saving effect is embodied on a hydraulic system and a control system. The hydraulic transmission uses liquid as working medium and uses the pressure of the liquid to realize the transmission and control functions of mechanical movement or energy. In a hydraulic system, hydraulic oil is required to not only complete energy transfer, but also ensure the efficiency of the hydraulic system. And the hydraulic oil with high viscosity index is used, so that the working efficiency of a hydraulic system is higher, and an excellent energy-saving effect is achieved.
The hydraulic oil is used as a working and lubricating medium of a hydraulic system of the injection molding machine, the market demand is large, and the high-efficiency energy-saving hydraulic oil special for the injection molding machine with prominent energy-saving performance is not sold and used in China. In the face of the increasingly serious energy shortage situation in China, the popularization and the use of the high-efficiency energy-saving hydraulic oil special for the injection molding machine have very important significance.
Disclosure of Invention
The invention aims to provide the special hydraulic oil for the injection molding machine, which has an obvious energy-saving effect (more than 6% of the energy-saving effect compared with the common hydraulic oil with the viscosity index of 100), has good low-temperature fluidity, extremely high viscosity index and excellent oxidation resistance, and meets the requirements of users on energy conservation and emission reduction on the premise of not changing the operation parameters of equipment.
In order to realize the purpose of the invention, the invention provides a special hydraulic oil composition for an efficient energy-saving injection molding machine, which comprises the following components in percentage by weight:
Figure BDA0002179428460000021
preferably, the special hydraulic oil composition for the high-efficiency energy-saving injection molding machine comprises the following components in percentage by weight:
Figure BDA0002179428460000022
preferably, the composition further comprises an anti-foaming agent with the mass percentage of 0.001-0.05%.
Further preferably, the composition comprises the following components in percentage by weight:
Figure BDA0002179428460000023
preferably, the high-efficiency energy-saving hydraulic oil composition special for injection molding machines, disclosed by the invention, is one or any combination of a phenol antioxidant and an amine antioxidant, and is mainly characterized by having excellent oxidation resistance and good compatibility, and playing roles in resisting oxidation and preventing gelation in oil products. Such as: liquid phenol, dialkyl diphenylamine, alkylated diphenylamine, methylene 4, 4' -thiobis- (2, 6-di-tert-butylphenol), 2, 6-di-tert-butyl alpha-dimethylamino-p-cresol, wherein the effect of Irganox L118 is better.
Preferably, the high-efficiency energy-saving hydraulic oil composition special for injection molding machines is prepared by adding an antiwear agent, an antirust agent and an antioxidant into the multifunctional additive, and adding a metal deactivator, an anti-emulsifier and an anti-foaming agent into the multifunctional additive. The kinematic viscosity (40 ℃) is 70-90 mm2And/s, 6-8 percent of sulfur (mass fraction), 3-4 percent of phosphorus (mass fraction) and 2-5 percent of zinc (mass fraction), and the appearance is amber transparent liquid. The hydraulic oil prepared by the multifunctional additive not only hasGood rust resistance and oxidation resistance, and outstanding abrasion resistance, can greatly reduce the abrasion of the hydraulic pump and other elements, and prolong the service life of the machine. Such as: hitec 521 from Afton Chemical, LZ 5703 from Lubrizol Corporation, and the like. Typical specifications are given in the following table.
Typical physicochemical data of Hitec 521
Item Typical data Test method
Kinematic viscosity (40 ℃), mm2/s 75 GB/T 265
Density, kg/m3 1030 GB/T 1884
Flash point (closed mouth), deg.C 125 GB/T 3536
Sulfur content,% (mass fraction) 8.4 GB/T 388
Phosphorus content,% (mass fraction) 3.96 SH/T 0296
Zinc content,% (mass fraction) 5.04 SH/T 0226
Typical physicochemical data of LZ 5703
Item Typical value Test method
Kinematic viscosity (40 ℃), mm2/s 86 GB/T 265
Density, kg/m3 1023 GB/T 1884
Flash point (closed mouth), deg.C 110 GB/T 3536
Sulfur content,% (mass fraction) 7.70 GB/T 388
Phosphorus content,% (mass fraction) 3.90 SH/T 0296
Zinc content,% (mass fraction) 4.87 SH/T 0226
Preferably, according to the special hydraulic oil composition for the high-efficiency energy-saving injection molding machine, the viscosity index improver is polymethacrylate, is one of viscosity index improvers which are widely applied, and has the characteristics of good shear resistance, excellent low-temperature performance and high-efficiency improvement of the viscosity index of an oil product. If the addition amount of the viscosity index improver is too small, the viscosity-temperature characteristics of the product are affected, and if the addition amount is too large, the shear resistance of the product is reduced, and the service life of the product is shortened. The invention adopts the test method of (CEC L-45-A-99) KRL20h, and the PSSI is not more than 20(10 percent is dissolved in 100N mineral oil). Most preferred is Viscoplex8-219 manufactured by Evonik Additives GmbH.
Preferably, the hydraulic oil composition special for the high-efficiency energy-saving injection molding machine is one or a mixture of two of silicon type and non-silicon type antifoaming agents. Such as: polymethyl silicone oil (T901) and polyacrylate (T912). If the addition ratio of the antifoaming agent is too small, the foaming properties of the hydraulic oil are affected, and if the addition ratio is too large, the air release properties of the hydraulic oil are affected.
The base oil adopts hydrogenated mineral base oil, and the viscosity index is not less than 120.
The special hydraulic oil composition for the high-efficiency energy-saving injection molding machine can be prepared by adopting a conventional lubricating oil blending method, and specifically, the special hydraulic oil composition is prepared by adding the components into a blending container according to the proportion and stirring for 2-3 hours at 50-65 ℃.
The invention adopts the technical scheme that functional additives such as an antioxidant, a viscosity index improver, an antifoaming agent and the like are added into base oil, the viscosity index of a product reaches more than 185, a Parker-Denison T6C vane pump is adopted for energy-saving test, reference oil is No. 46 hydraulic oil special for an injection molding machine with the viscosity index of 100, and the total energy-saving amount is not less than 6%.
Compared with the prior art, the special hydraulic oil for the high-efficiency energy-saving injection molding machine has the following advantages and effects:
the high-efficiency energy-saving hydraulic oil composition special for the injection molding machine has extremely high viscosity index, has excellent oxidation resistance, and has an energy-saving effect of more than 6 percent compared with the hydraulic oil (the viscosity index is 100) special for the common injection molding machine. The product of the invention has reasonable raw material compatibility, simple preparation method, wide application range and easily obtained raw materials.
The performance of the special hydraulic oil composition for the high-efficiency energy-saving injection molding machine is obviously superior to that of similar products at home and abroad, and the special hydraulic oil composition is suitable for various middle-end and high-end injection molding machine hydraulic systems.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
Examples 1 to 4
The components of the special hydraulic oil composition for the high-efficiency energy-saving injection molding machine in the embodiment are shown in the table 1, and the preparation process is as follows: the preparation method comprises the steps of heating hydrogenated base oil to 60 ℃ in a blending container, adding a viscosity index improver, an anti-wear hydraulic oil multifunctional additive and an antioxidant, stirring until the mixture is uniform and transparent, adding an anti-foaming agent according to a ratio, and stirring for 2-3 hours.
Table 1 examples 1-4 contents of each component
Figure BDA0002179428460000051
Wherein the hydrogenated base oils II +2, II +4 and II +6 of the above examples are produced from the medium petrochemical industry and have typical kinematic viscosities of 8.919mm at 40 deg.C2/s、22.57mm2/s、32.5mm2Typical kinematic viscosities at 40 ℃ of 19.46mm for/S, YU 4 (from SK in Korea) and Ultra-S4 (from Duolone in Korea), respectively2/s、20.58mm2/s。
Irganox L118 is available from BASF, LZ 5703 from Lubrizol Corporation, Hitec 521 from Afton Chemical, Viscoplex8-219 from Evonik Additives GmbH, and T901 from Tianyu Petroleum Additives, Dengyang.
Each performance evaluation was performed on examples 1-4, and the relevant performance of the subjects was tested according to the national standard method. The results are shown in Table 2.
The results are shown in table 2 below:
TABLE 2 analytical data for examples 1-4
Figure BDA0002179428460000061
The viscosity grades of the existing hydraulic oil products special for injection molding machines are mainly 46 grades and 68 grades. Because the working pressure of the hydraulic system of the injection molding machine mainly used in China at present is lower and usually does not exceed 10MPa), and the hydraulic system is in a discontinuous and intermittent working state, the working condition is mild; in addition, the injection molding machine is usually positioned in a factory building, the oil temperature of hydraulic oil is stable during working, and the requirement on the viscosity-temperature performance of the hydraulic oil is not strict. Therefore, the viscosity index of the hydraulic oil special for the existing injection molding machine is not high and is generally about 100. And the higher viscosity index (the viscosity index is not less than 185), so that the hydraulic oil product has good low-temperature starting performance, the working efficiency loss of the hydraulic oil can be reduced, and a certain energy-saving effect is achieved.
The data show that the special hydraulic oil composition for the high-efficiency energy-saving injection molding machine has good viscosity-temperature performance, oxidation resistance, anti-shearing property and obvious energy-saving effect, improves the volumetric efficiency of a system, reduces internal leakage, and emphasizes the energy-saving property of a hydraulic pump of the injection molding machine during normal operation.
Although the invention has been described in detail hereinabove with respect to a general description and specific embodiments thereof, it will be apparent to those skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. A high-efficiency energy-saving hydraulic oil composition special for an injection molding machine comprises the following components in percentage by weight:
Figure FDA0002179428450000011
2. the composition according to claim 1, characterized by comprising the following components in percentage by weight:
Figure FDA0002179428450000012
3. the composition according to claim 1 or 2, characterized in that the composition further comprises an antifoaming agent in an amount of 0.001-0.05% by weight.
4. The composition according to any one of claims 1 to 3, which comprises the following components in percentage by weight:
Figure FDA0002179428450000013
5. the composition as claimed in any one of claims 1 to 4, wherein the antioxidant is one or a combination of any of phenolic antioxidant and amine antioxidant; preferably one or a combination of more of liquid phenol, dialkyl diphenylamine, alkylated diphenylamine, methylene 4, 4' -thiobis- (2, 6-di-tert-butylphenol) or 2, 6-di-tert-butyl alpha-dimethylamino-p-cresol; more preferably Irganox L118.
6. According toThe composition as claimed in any one of claims 1 to 4, wherein the antiwear hydraulic fluid multifunctional additive has a kinematic viscosity at 40 ℃ of 70 to 90mm2(s) 6-9% of sulfur, 3-4% of phosphorus and 4-6% of zinc; hitec 521 manufactured by Afton Chemical company or LZ 5703 manufactured by Lubrizol corporation is preferable.
7. The composition of any of claims 1-4, wherein the viscosity index improver is a polymethacrylate, preferably a polymethacrylate having a test method of (CEC L-45-A-99) KRL20h, and a PSSI of no greater than 20; more preferably, Viscoplex8-219 manufactured by Evonik Additives GmbH.
8. The composition according to any one of claims 1 to 4, wherein the anti-foaming agent is a silicon-based or/and non-silicon-based anti-foaming agent; one or more of polymethylsilicone oil or polyacrylate is preferred.
9. The composition of any one of claims 1 to 4, wherein the viscosity index of the base oil is not less than 120.
10. The composition according to any one of claims 1 to 4, which is prepared from the following components in percentage by weight:
Figure FDA0002179428450000021
preferably, the composition is prepared from the following components in percentage by weight:
Figure FDA0002179428450000022
Figure FDA0002179428450000031
or the like, or, alternatively,
Figure FDA0002179428450000032
CN201910790586.9A 2019-08-26 2019-08-26 Special hydraulic oil composition for high-efficiency energy-saving injection molding machine Pending CN112430492A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114958462A (en) * 2021-07-31 2022-08-30 福斯润滑油(中国)有限公司 Synthetic hydraulic oil for wind power generation hydraulic system and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104232252A (en) * 2013-06-06 2014-12-24 中国石油化工股份有限公司 High efficiency hydraulic oil composition
CN107937099A (en) * 2017-11-29 2018-04-20 浙江实美润滑科技有限公司 A kind of dedicated antiwear hydraulic oil of injection molding machine and preparation method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104232252A (en) * 2013-06-06 2014-12-24 中国石油化工股份有限公司 High efficiency hydraulic oil composition
CN107937099A (en) * 2017-11-29 2018-04-20 浙江实美润滑科技有限公司 A kind of dedicated antiwear hydraulic oil of injection molding machine and preparation method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114958462A (en) * 2021-07-31 2022-08-30 福斯润滑油(中国)有限公司 Synthetic hydraulic oil for wind power generation hydraulic system and preparation method thereof

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Application publication date: 20210302