CN112408664A - Catalytic cracking catalyst production wastewater pretreatment system and method - Google Patents

Catalytic cracking catalyst production wastewater pretreatment system and method Download PDF

Info

Publication number
CN112408664A
CN112408664A CN202011278987.5A CN202011278987A CN112408664A CN 112408664 A CN112408664 A CN 112408664A CN 202011278987 A CN202011278987 A CN 202011278987A CN 112408664 A CN112408664 A CN 112408664A
Authority
CN
China
Prior art keywords
wastewater
tank
catalytic cracking
cracking catalyst
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011278987.5A
Other languages
Chinese (zh)
Inventor
李长刚
叶芳芳
谢文玉
詹彤
李德豪
刘志森
王儒珍
张帅
毛玉凤
殷旭东
朱越平
刘文意
李清华
黎冰
吴楠婷
林依敏
余颖晓
钟伟涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong University of Petrochemical Technology
Original Assignee
Guangdong University of Petrochemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong University of Petrochemical Technology filed Critical Guangdong University of Petrochemical Technology
Priority to CN202011278987.5A priority Critical patent/CN112408664A/en
Publication of CN112408664A publication Critical patent/CN112408664A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02Softening water by precipitation of the hardness

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Catalysts (AREA)

Abstract

The invention provides a pretreatment system and a pretreatment method for catalytic cracking catalyst production wastewater, which comprises the following steps: 1) the wastewater enters a sedimentation tank, caustic soda is added into the sedimentation tank to adjust the pH value of the wastewater to 8-9, and soda ash is added to enable calcium and magnesium ions of the calcium and magnesium in the wastewater to generate Mg (OH)2 and CaCO3Precipitating, and staying the wastewater in a precipitation tank for 30-60 min; 2) the wastewater passing through the sedimentation tank enters an electrolytic oxidation tank, an electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, the voltage of the anode plate is 4V-8V, and the retention time is 30min-60 min; 3) the wastewater passing through the electrolytic oxidation tank enters a sand filter, and the water inlet pressure is 0.3-0.6 Mpa. The wastewater enters a sedimentation tank, ph is adjusted, and the hardness of the wastewater is reduced; impurities in the sewage are effectively reduced after precipitation; effectively removing ammonia nitrogen in the sewage through an electrolytic oxidation tank; suspended matters in the sewage are further removed through the sand filter, better water quality is provided for the biochemical treatment of the sewage, the biochemical treatment speed is increased, and the treatment cost is reduced.

Description

Catalytic cracking catalyst production wastewater pretreatment system and method
Technical Field
The invention relates to the field of wastewater treatment, in particular to a pretreatment system and a pretreatment method for catalytic cracking catalyst production wastewater.
Background
The water quality characteristics of the wastewater generated in the production process of the petroleum catalytic cracking catalyst are as follows: the conductivity is 40-50ms/cm, the organic matter content is low, and the organic matter contains a large amount of ammonia nitrogen, nitrate nitrogen, suspended matters containing Si, Cl < - >, metal ions and a small amount of nitrite nitrogen and organic nitrogen. The quality of sewage is poor, and the accepting requirement of biochemical influent water cannot be met, so that the pretreatment is required. The existing pretreatment technology mainly removes suspended matters through 'electric flocculation and multi-medium filtration', can not reduce ammonia nitrogen treatment load in sewage, and causes the problems of high energy consumption, large alkalinity consumption, high operation cost and the like of a subsequent biochemical treatment device.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a pretreatment method for wastewater produced by catalytic cracking catalyst, which can effectively remove suspended matters and ammonia nitrogen, provide optimal inlet water quality for subsequent biochemical treatment and has low cost for the subsequent biochemical treatment.
The technical purpose of the invention is realized by the following technical scheme: a pretreatment method for wastewater produced by catalytic cracking catalyst is characterized by sequentially comprising the following steps:
1) the wastewater enters a sedimentation tank, caustic soda is added into the sedimentation tank to adjust the pH value of the wastewater to 8-9, and soda ash is added to enable calcium and magnesium ions of the calcium and magnesium in the wastewater to generate Mg (OH)2And CaCO3Precipitating, and staying the wastewater in a precipitation tank for 30-60 min;
2) the wastewater passing through the sedimentation tank enters an electrolytic oxidation tank, an electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, the voltage of the anode plate is 4V-8V, and the retention time is 30min-60 min;
3) the wastewater passing through the electrolytic oxidation tank enters a sand filter, and the water inlet pressure is 0.3-0.6 Mpa.
The wastewater enters a sedimentation tank, ph is adjusted by adding caustic soda, and meanwhile, the content of calcium and magnesium ions in the wastewater is reduced, so that the hardness of the wastewater is effectively reduced; after precipitation, impurities in the sewage are effectively reduced, and meanwhile, the scaling of the polar plate in the step 2) is also prevented; effectively removing ammonia nitrogen in the sewage through an electrolytic oxidation tank; and finally, suspended matters in the sewage are further removed through a sand filter, so that better water quality is provided for the biochemical treatment of the sewage, the biochemical treatment speed is increased, and the treatment cost is reduced.
Further setting, the wastewater in the step 1) stays in a sedimentation tank for 30 min.
Further setting, 2) middle electrode plate voltage 5V.
Further setting, the retention time of the waste water in the step 2) is 45 min.
Further setting, 3) the water inlet pressure is 0.4 Mpa.
The invention also aims to provide a pretreatment system for the catalytic cracking catalyst production wastewater, which is specially used for the pretreatment method for the catalytic cracking catalyst production wastewater, and comprises a sedimentation tank, an electrolytic oxidation tank and a sand filter which are sequentially communicated, wherein the sand filter comprises a tank body, a water inlet positioned at the upper end of the tank body and a water outlet positioned at the bottom of the tank body, a flow blocking net is arranged at the water outlet, a supporting net is fixed at the bottom in the tank body, a gravel supporting layer, a coarse sand layer, a fine sand layer and a smokeless coal layer are sequentially arranged above the supporting net from bottom to top, the water inlet is connected with a horizontally arranged water distribution pipe, and the water distribution pipe is connected with a plurality of water distributors; the supporting net and the bottom of the tank body form a buffer space, the two side edges of the tank body are respectively connected with a water replenishing tank and a vacuum pump, the water replenishing tank and the vacuum pump are communicated with the buffer space, the buffer space is provided with a ball float valve used for controlling the opening and closing of the water replenishing tank, and the bottom of the tank body is provided with a pressure release valve.
According to the scheme, water is supplemented through the ball float valve and the water supplementing tank, and water is discharged through the pressure release valve when the water level is too high, so that a certain water level is always kept in the buffer space; the arrangement of the flow blocking net is used for reducing the speed of the wastewater flowing out of the water outlet, so that the water level can be conveniently controlled. The air in the buffer space is discharged out of the buffer space through the vacuum pump, so that the wastewater flows downwards in an accelerated manner, and the filtering speed of the wastewater is increased.
The pressure relief valve is further arranged to be connected with a return pipe, the water outlet is connected with a water outlet pipe, and the return pipe is communicated with the water outlet pipe.
In conclusion, the invention has the following beneficial effects: the invention effectively removes suspended matters and ammonia nitrogen, provides the optimal water quality of the inlet water for the subsequent biochemical treatment and has low cost for the subsequent biochemical treatment; the speed of water treatment is accelerated by arranging a special wastewater treatment system.
Drawings
Fig. 1 is a schematic structural view of a sand filter of the embodiment.
Reference numerals: 1. a tank body; 11. a water inlet; 12. a water outlet; 13. a current blocking net; 14. a buffer space; 2. a support net; 31. a gravel support layer; 32. a coarse sand layer; 33. a fine sand layer; 34. a smokeless coal seam; 41. a water distribution pipe; 42. a water distributor; 51. a water replenishing tank; 52. a float valve; 6. a vacuum pump; 71. a pressure relief valve; 8. a return pipe; 9. and (5) discharging a water pipe.
Detailed Description
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.
Example 1: a pretreatment system for wastewater generated in catalytic cracking catalyst production comprises a sedimentation tank, an electrolytic oxidation tank and a sand filter which are sequentially communicated. An electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, and the voltage of the anode plate is 4V-8V.
Example 2: the sand filter comprises a tank body 1, a water inlet 11 positioned at the upper end of the tank body 1 and a water outlet 12 positioned at the bottom of the tank body 1, wherein a flow blocking net 13 is arranged at the position of the water outlet 12, a supporting net 2 is fixed at the bottom in the tank body 1, a gravel supporting layer 31, a coarse sand layer 32, a fine sand layer 33 and a smokeless coal layer 34 are sequentially arranged above the supporting net 2 from bottom to top, the water inlet 11 is connected with a horizontally arranged water distribution pipe 41, and the water distribution pipe 41 is connected with a plurality of water distributors 42; the supporting net 2 and the bottom of the tank body 1 form a buffer space 14, the two side edges of the tank body 1 are respectively connected with a water replenishing tank 51 and a vacuum pump 6, the water replenishing tank 51 and the vacuum pump 6 are both communicated with the buffer space 14, the buffer space 14 is provided with a ball float valve 52 for controlling the opening and closing of the water replenishing tank 51, and the bottom of the tank body 1 is provided with a pressure release valve 71. The pressure release valve 71 is connected with a return pipe 8, the water outlet 12 is connected with a water outlet pipe 9, and the return pipe 8 is communicated with the water outlet pipe 9.
Example 2: a pretreatment method for wastewater produced by catalytic cracking catalyst sequentially comprises the following steps: 1) the wastewater enters a sedimentation tank, caustic soda is added into the sedimentation tank to adjust the pH value of the wastewater to be 8.5, and soda ash is added to ensure that calcium and magnesium ions of calcium and magnesium in the wastewater generate Mg (OH)2And CaCO3Precipitating, and allowing the wastewater to stay in a precipitation tank for 30 min;
2) the wastewater passing through the sedimentation tank enters an electrolytic oxidation tank, an electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, the voltage of the anode plate is 5V, and the retention time is 45 min;
3) the wastewater passing through the electrolytic oxidation tank enters a sand filter, and the water inlet pressure is 0.4 Mpa.
Example 3: a pretreatment method for wastewater produced by catalytic cracking catalyst sequentially comprises the following steps: 1) the wastewater enters a sedimentation tank, caustic soda is added into the sedimentation tank to adjust the pH value of the wastewater to be 8, and soda ash is added to enable calcium and magnesium ions of calcium and magnesium in the wastewater to generate Mg (OH)2And CaCO3Precipitating, and allowing the wastewater to stay in a precipitation tank for 40 min;
2) the wastewater passing through the sedimentation tank enters an electrolytic oxidation tank, an electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, the voltage of the anode plate is 5V, and the retention time is 60 min;
3) the wastewater passing through the electrolytic oxidation tank enters a sand filter, and the water inlet pressure is 0.6 Mpa.
Example 4: a pretreatment method for wastewater produced by catalytic cracking catalyst sequentially comprises the following steps: 1) the wastewater enters a sedimentation tank, caustic soda is added into the sedimentation tank to adjust the pH value of the wastewater to 9, and soda ash is added to enable calcium and magnesium ions of calcium and magnesium in the wastewater to generate Mg (OH)2And CaCO3Precipitating, and allowing the wastewater to stay in a precipitation tank for 50 min;
2) the wastewater passing through the sedimentation tank enters an electrolytic oxidation tank, an electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, the voltage of the anode plate is 7V, and the retention time is 30 min;
3) the wastewater passing through the electrolytic oxidation tank enters a sand filter, and the water inlet pressure is 0.5 Mpa.
Example 5: a pretreatment method of wastewater from catalytic cracking catalyst production is different from that of example 2 in that 1) the wastewater stays in a sedimentation tank for 40 min.
Example 6: a pretreatment method of wastewater from catalytic cracking catalyst production is different from that of example 2 in that 1) the wastewater stays in a sedimentation tank for 50 min.
Example 7: a pretreatment method of wastewater from catalytic cracking catalyst production is different from that of example 2 in that 1) the wastewater stays in a sedimentation tank for 60 min.
Experiment: raw water is selected to be pretreated according to the embodiment 2-7; raw water: 257mg/L of ammonia nitrogen, 1243mg/L of hardness and 8544mg/L of suspended matters.
Effluent quality of example 2: 3.5mg/L of ammonia nitrogen, 96mg/L of hardness and 83mg/L of suspended matters.
Effluent quality of example 3: 3.2mg/L of ammonia nitrogen, 95mg/L of hardness and 84mg/L of suspended matters.
Effluent quality of example 4: 3.4mg/L of ammonia nitrogen, 94mg/L of hardness and 83mg/L of suspended matters.
Effluent quality of example 5: 3.5mg/L of ammonia nitrogen, 95mg/L of hardness and 84mg/L of suspended matters.
Effluent quality of example 6: 3.5mg/L of ammonia nitrogen, 93mg/L of hardness and 83mg/L of suspended matters.
Effluent quality of example 7: 3.5mg/L of ammonia nitrogen, 92mg/L of hardness and 83mg/L of suspended matters.
The above experiments show that the treated water quality is obviously improved, and the retention time (30min-60min) of the wastewater in the sedimentation tank is not obviously changed, so that the 30min wastewater treatment speed is higher.

Claims (7)

1. A pretreatment method for wastewater produced by catalytic cracking catalyst is characterized by sequentially comprising the following steps: 1) the wastewater enters a sedimentation tank, caustic soda is added into the sedimentation tank to adjust the pH value of the wastewater to 8-9, and soda ash is added to enable calcium and magnesium ions of the calcium and magnesium in the wastewater to generate Mg (OH)2And CaCO3The precipitate is formed by the precipitation of the mixture,the wastewater stays in the sedimentation tank for 30min-60 min;
2) the wastewater passing through the sedimentation tank enters an electrolytic oxidation tank, an electrocatalytic oxidation device is arranged in the electrolytic oxidation tank, the anode of the electrocatalytic oxidation device is a ruthenium iridium titanium anode plate, the cathode of the electrocatalytic oxidation device is a titanium plate, the distance between the anode plates is 1.5cm, the voltage of the anode plate is 4V-8V, and the retention time is 30min-60 min;
3) the wastewater passing through the electrolytic oxidation tank enters a sand filter, and the water inlet pressure is 0.3-0.6 Mpa.
2. The pretreatment method of catalytic cracking catalyst production wastewater according to claim 1, characterized in that: 1) the wastewater stays in the sedimentation tank for 30 min.
3. The pretreatment method of catalytic cracking catalyst production wastewater according to claim 1, characterized in that: 2) the middle electrode plate voltage is 5V.
4. The pretreatment method of catalytic cracking catalyst production wastewater according to claim 1, characterized in that: 2) the retention time of the medium wastewater is 45 min.
5. The pretreatment method of catalytic cracking catalyst production wastewater according to claim 1, characterized in that: 3) the medium water inlet pressure is 0.4 Mpa.
6. A catalytic cracking catalyst production wastewater pretreatment system special for a catalytic cracking catalyst production wastewater pretreatment method is characterized in that: the device comprises a sedimentation tank, an electrolytic oxidation tank and a sand filter which are sequentially communicated, wherein the sand filter comprises a tank body, a water inlet positioned at the upper end of the tank body and a water outlet positioned at the bottom of the tank body, a flow blocking net is arranged at the water outlet, a supporting net is fixed at the bottom in the tank body, a gravel supporting layer, a coarse sand layer, a fine sand layer and a smokeless coal layer are sequentially arranged above the supporting net from bottom to top, the water inlet is connected with a horizontally arranged water distribution pipe, and the water distribution pipe is connected with a plurality of water distributors; the supporting net and the bottom of the tank body form a buffer space, the two side edges of the tank body are respectively connected with a water replenishing tank and a vacuum pump, the water replenishing tank and the vacuum pump are communicated with the buffer space, the buffer space is provided with a ball float valve used for controlling the opening and closing of the water replenishing tank, and the bottom of the tank body is provided with a pressure release valve.
7. The pretreatment system for wastewater from catalytic cracking catalyst production according to claim 6, wherein said pretreatment system comprises: the pressure release valve is connected with a return pipe, the water outlet is connected with a water outlet pipe, and the return pipe is communicated with the water outlet pipe.
CN202011278987.5A 2020-11-16 2020-11-16 Catalytic cracking catalyst production wastewater pretreatment system and method Pending CN112408664A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011278987.5A CN112408664A (en) 2020-11-16 2020-11-16 Catalytic cracking catalyst production wastewater pretreatment system and method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011278987.5A CN112408664A (en) 2020-11-16 2020-11-16 Catalytic cracking catalyst production wastewater pretreatment system and method

Publications (1)

Publication Number Publication Date
CN112408664A true CN112408664A (en) 2021-02-26

Family

ID=74831930

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011278987.5A Pending CN112408664A (en) 2020-11-16 2020-11-16 Catalytic cracking catalyst production wastewater pretreatment system and method

Country Status (1)

Country Link
CN (1) CN112408664A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115504637A (en) * 2022-11-14 2022-12-23 江苏方天电力技术有限公司 Integration treatment of domestic sewage equipment
CN115784470A (en) * 2022-12-28 2023-03-14 广东省源天工程有限公司 Method for removing nitrate nitrogen in sewage by combining electric enhanced biological membrane

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1958471A (en) * 2005-10-31 2007-05-09 中国石油化工股份有限公司 Method for treating ammonia nitrogen wastewater
CN101717164A (en) * 2009-10-20 2010-06-02 无锡殷达尼龙有限公司 Method for treating and recycling waste water of cyanation technique and device thereof
CN202529957U (en) * 2012-05-16 2012-11-14 赵月 Wastewater treating device
CN105967408A (en) * 2016-07-14 2016-09-28 河南能源化工集团研究院有限公司 Industrial wastewater treatment process of copper-based hydrogenation catalyst
CN207330537U (en) * 2017-06-30 2018-05-08 江苏亚峰科技集团有限公司 A kind of more medium filter
CN207659224U (en) * 2017-11-30 2018-07-27 中国石油化工股份有限公司 A kind of containing wastewater from catalyst integrated processing system
CN209530305U (en) * 2019-02-13 2019-10-25 成都市长江水处理设备有限公司 A kind of chemistry station-service multimedium effluent filter
CN110921972A (en) * 2019-10-26 2020-03-27 宜兴市申生催化剂有限公司 Treatment method of metal catalyst production wastewater
CN214422426U (en) * 2020-11-16 2021-10-19 广东石油化工学院 Catalytic cracking catalyst production wastewater pretreatment system

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1958471A (en) * 2005-10-31 2007-05-09 中国石油化工股份有限公司 Method for treating ammonia nitrogen wastewater
CN101717164A (en) * 2009-10-20 2010-06-02 无锡殷达尼龙有限公司 Method for treating and recycling waste water of cyanation technique and device thereof
CN202529957U (en) * 2012-05-16 2012-11-14 赵月 Wastewater treating device
CN105967408A (en) * 2016-07-14 2016-09-28 河南能源化工集团研究院有限公司 Industrial wastewater treatment process of copper-based hydrogenation catalyst
CN207330537U (en) * 2017-06-30 2018-05-08 江苏亚峰科技集团有限公司 A kind of more medium filter
CN207659224U (en) * 2017-11-30 2018-07-27 中国石油化工股份有限公司 A kind of containing wastewater from catalyst integrated processing system
CN209530305U (en) * 2019-02-13 2019-10-25 成都市长江水处理设备有限公司 A kind of chemistry station-service multimedium effluent filter
CN110921972A (en) * 2019-10-26 2020-03-27 宜兴市申生催化剂有限公司 Treatment method of metal catalyst production wastewater
CN214422426U (en) * 2020-11-16 2021-10-19 广东石油化工学院 Catalytic cracking catalyst production wastewater pretreatment system

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张招贤等: "《涂层钛电极》", 冶金工业出版社, pages: 453 - 454 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115504637A (en) * 2022-11-14 2022-12-23 江苏方天电力技术有限公司 Integration treatment of domestic sewage equipment
CN115784470A (en) * 2022-12-28 2023-03-14 广东省源天工程有限公司 Method for removing nitrate nitrogen in sewage by combining electric enhanced biological membrane

Similar Documents

Publication Publication Date Title
CN109437454B (en) Enhanced physicochemical treatment method and device for refined high-salt high-ammonia special oily sewage
CN112408664A (en) Catalytic cracking catalyst production wastewater pretreatment system and method
CN202953895U (en) Electrocoagulation sewage treatment system
CN111285531A (en) Method and system for concentrating high-salinity mine water
CN102910786B (en) Method and equipment for high-concentration alcohol waste water treatment
CN105439335A (en) Chemical copper precipitation wastewater copper removing treatment process and chemical copper precipitation wastewater copper removing treatment system
CN112028372B (en) Advanced treatment process for entrained flow coal gasification black water
CN205133286U (en) Full automatic processing equipment of nickeliferous waste water of high concentration
CN112794500B (en) Coking wastewater strong brine near-zero emission treatment system and treatment method thereof
CN112645498A (en) Treatment method of reverse osmosis concentrated solution of high-magnesium landfill leachate
CN113003845B (en) Zero-emission treatment process and system for sewage with high sulfate content and high COD (chemical oxygen demand)
CN214422426U (en) Catalytic cracking catalyst production wastewater pretreatment system
CN111777220A (en) Novel softening treatment method for high-salinity and high-permanent-hardness wastewater
CN112093965A (en) Moderate stepwise cooperative pretreatment process for mine water treatment
CN210176671U (en) High-salt high-concentration degradation-resistant organic wastewater treatment equipment
CN117902692A (en) Pretreatment method for wastewater of high suspended matters and high concentration organic matters
CN112479445A (en) Process and equipment for treating coal gasification ash water
CN117023919A (en) Multistage treatment system and multistage treatment process for gas field produced water
CN107963761A (en) A kind of Zero discharging system and method for high salt cyanide wastewater
CN102060417B (en) Process and device for treating waste water in CLT acid production
CN112591978B (en) Advanced treatment method for wastewater generated in catalytic cracking catalyst production
CN107216006B (en) Leather wastewater treatment system and method
CN114044587B (en) Manganese oxide film loaded expanded bed filter and method for removing thallium by adsorption by using same
CN110885119A (en) Method for harmless treatment of gas field water evaporation mother liquor by coagulating sedimentation and activated carbon adsorption
CN114516689A (en) Calcium carbide method polyvinyl chloride mercury-containing wastewater treatment and recycling method and application device thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20210226

WD01 Invention patent application deemed withdrawn after publication