CN112376125A - Flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and preparation method thereof - Google Patents
Flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and preparation method thereof Download PDFInfo
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- CN112376125A CN112376125A CN202010888676.4A CN202010888676A CN112376125A CN 112376125 A CN112376125 A CN 112376125A CN 202010888676 A CN202010888676 A CN 202010888676A CN 112376125 A CN112376125 A CN 112376125A
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- molecular weight
- weight polyethylene
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- retardant
- ultrahigh molecular
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Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 56
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 title claims abstract description 45
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 title claims abstract description 45
- 239000000835 fiber Substances 0.000 title claims abstract description 27
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 19
- 239000003607 modifier Substances 0.000 claims abstract description 13
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 11
- 239000010439 graphite Substances 0.000 claims abstract description 11
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 7
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 7
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 5
- 229920000388 Polyphosphate Polymers 0.000 claims abstract description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001205 polyphosphate Substances 0.000 claims abstract description 5
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 238000009987 spinning Methods 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 235000019198 oils Nutrition 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000010008 shearing Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000010775 animal oil Substances 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 230000003993 interaction Effects 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 238000010907 mechanical stirring Methods 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 230000008961 swelling Effects 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002064 nanoplatelet Substances 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 1
- 239000002657 fibrous material Substances 0.000 abstract description 2
- 238000007792 addition Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000001804 emulsifying effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- COAPBYURHXLGMG-UHFFFAOYSA-N azane;1,3,5-triazine-2,4,6-triamine Chemical compound N.NC1=NC(N)=NC(N)=N1 COAPBYURHXLGMG-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Abstract
The invention provides a flame-retardant high-performance ultra-high molecular weight polyethylene composite fiber and a preparation method thereof, wherein the flame-retardant high-performance ultra-high molecular weight polyethylene composite fiber comprises ultra-high molecular weight polyethylene powder, a flame retardant and an inorganic modifier; the dosage of the fire retardant is 10-50 wt.% of the ultra-high molecular weight polyethylene powder, and the dosage of the inorganic modifier is 0.5-20 wt.% of the ultra-high molecular weight polyethylene powder. The flame retardant is any one or the combination of two or more of aluminum hydroxide, magnesium hydroxide, ammonium polyphosphate, melamine polyphosphate and red phosphorus; the inorganic modifier is any one or the combination of two or more of graphene, nano graphite flakes, expanded graphite, graphene oxide and reduced graphene oxide. The flame-retardant high-performance ultrahigh molecular weight polyethylene fiber and the preparation method provided by the invention reduce the addition amount of the flame retardant, and avoid the technical problem that the performance of the ultrahigh molecular weight polyethylene fiber material is obviously reduced due to the addition of a large amount of the flame retardant.
Description
Technical Field
The invention relates to the technical field of new polymer materials, in particular to a flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and a preparation method thereof.
Background
Graphene is known as a star material of the 21 st century, and is a nano material in a honeycomb structure only consisting of one layer of carbon atoms. The graphene is of a sheet structure, has stable property, good heat resistance and large specific surface area, and the properties enable the graphene to effectively reduce mass transfer and heat transfer in the material combustion process, thereby improving the flame retardant property of the polymer material. Graphene has a barrier effect to the smallest gas helium, making it unable to penetrate through graphene.
The graphene can improve the thermal stability of related flame retardants, and the addition of the graphene improves the flame retardant performance, so that the addition amount of the graphene is less than that of a single traditional flame retardant, and the problem of the reduction of the mechanical properties of the ultra-high molecular weight polyethylene fibers caused by the addition of a large amount of flame retardants is remarkably improved.
For example, Mg (OH)2The flame retardant effect can be achieved only when the amount of the flame retardant is up to 50% in the polyolefin material, and the mechanical property of the resin matrix material is seriously influenced. Due to the addition of the graphene, the graphene and the graphene have a synergistic effect and are low in addition, so that the ultrahigh molecular weight polyethylene fiber has flame retardant property and good mechanical property. In order to overcome the problem that the mechanical property of a matrix material is obviously reduced due to the addition of a large amount of flame retardant, the patent provides a flame-retardant scheme of the high-performance ultrahigh molecular weight polyethylene composite fiber.
Disclosure of Invention
The invention aims to provide a flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and a preparation method thereof, and solves the technical problem that the mechanical properties of an ultrahigh molecular weight polyethylene fiber material are obviously reduced due to the addition of a large amount of flame retardant.
A flame-retardant high-performance ultra-high molecular weight polyethylene composite fiber comprises ultra-high molecular weight polyethylene powder, a flame retardant and an inorganic modifier;
the dosage of the flame retardant is 10-50 wt.% of the ultra-high molecular weight polyethylene powder, and the dosage of the inorganic modifier is 0.5-20 wt.% of the ultra-high molecular weight polyethylene powder.
The flame retardant is any one or the combination of two or more of aluminum hydroxide, magnesium hydroxide, ammonium polyphosphate, melamine polyphosphate and red phosphorus;
the particle size of the aluminum hydroxide is 0.5-20 μm, the particle size of the magnesium hydroxide is 1-15 μm, the particle size of the ammonium polyphosphate is 3-25 μm, the particle size of the melamine polyphosphate is 1-25 μm, and the size of the red phosphorus is 5-30 μm.
The inorganic modifier is any one or the combination of two or more of graphene, nano graphite flakes, expanded graphite, graphene oxide and reduced graphene oxide.
The planar size of the graphene, the nano graphite sheet, the graphene oxide and the reduced graphene oxide is 0.5-30 mu m, the thickness is 0.335-30 nm, and the expanded graphite is 200-500 times.
Traditionally, flame retardants are added separately in relatively high amounts, e.g., Mg (OH)2The flame retardant effect can be achieved only when the amount of the flame retardant is up to 50% in the polyolefin material, and the mechanical property of the resin matrix material is seriously influenced. Due to the addition of the graphene, the graphene and the graphene have a synergistic effect, the ultra-high molecular weight polyethylene fiber is low in addition, and the ultra-high molecular weight polyethylene fiber can keep good performance.
The graphene is of a sheet structure, has stable property, strong heat resistance and large specific surface area, can effectively reduce mass transfer and heat transfer in the material combustion process, improves the flame retardant property of a polymer material, and has good barrier effect even on the minimum helium.
A preparation method of flame-retardant high-performance ultrahigh molecular weight polyethylene composite fibers comprises the following specific preparation steps:
step S01: adding a flame retardant, a nano additive and an inorganic modifier into an organic solvent, and dispersing and mixing uniformly through mechanical stirring and shearing interaction to obtain a mixture;
step S02: adding ultra-high molecular weight polyethylene powder into the mixture, stirring, and heating for swelling;
step S03: dissolving and homogenizing the prepared raw materials at high temperature by a double-screw extruder, metering, and spinning by a filter and a spinning manifold;
step S04: and then a series of processes of cleaning/extraction, drying and hot drawing are carried out to obtain the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber.
In step S01, the dispersing and mixing method includes one or more of mechanical shearing or ultrasonic cavitation, ball milling, sand milling, emulsification or ultrasound.
In the step S01, the time required for the mixing treatment of the flame retardant and the inorganic modifier is 2h to 12 h.
In the step S01, the solvent is one or a combination of white oil, decalin, kerosene, animal oil, and vegetable oil, and the amount of the solvent is 1-25 times of the ultrahigh molecular weight polyethylene powder.
The patent of the invention achieves the following remarkable effects:
the textile prepared from the high-performance ultrahigh molecular weight polyethylene composite fiber has an oxygen index higher than 30%, belongs to a flame-retardant material, and has good flame retardant property.
Detailed Description
In order to clearly illustrate the technical features of the present solution, the present solution is described below by way of specific embodiments.
Example 1
2.5kg of melamine ammonium polyphosphate with the size range of 3-25 mu m and 750g of 400 times of expanded graphite are respectively added into 100kg of white oil serving as an organic solvent, and are circularly treated for 8 hours by sanding to obtain a fully and uniformly mixed solution. Mixing 10kg of ultra-high molecular weight polyethylene powder with the solution by an emulsifying mode of an emulsifying machine, and heating to complete the preparation of the raw materials;
the prepared raw materials are dissolved at high temperature through a double-screw extruder, spun by a spinning manifold, and subjected to a series of processes such as bundling, pre-drawing, cleaning (extraction), drying, drawing and the like to obtain the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber.
Example 2
900g of aluminum hydroxide powder with the size range of 1-15 μm, 300g of powder with the red phosphorus granularity of 1-20 μm and 240g of graphene oxide with the thickness of 1-5 nm and the plane size of 3-20 μm are respectively added into 25kg of white oil serving as an organic solvent, and are circularly treated for 1 hour by sanding to obtain a fully and uniformly mixed solution. Mixing 3kg of ultra-high molecular weight polyethylene powder with the solution by an emulsifying mode of an emulsifying machine, and heating to complete the preparation of the raw materials;
the prepared raw materials are dissolved at high temperature through a double-screw extruder, spun by a spinning manifold, and subjected to a series of processes such as bundling, pre-drawing, cleaning (extraction), drying, drawing and the like to obtain the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber.
Example 3
1kg of ammonium polyphosphate powder with the size range of 1-15 mu m and 5-25 mu m of graphene powder with the average thickness of 3nm are respectively added into 50kg of white oil serving as an organic solvent, and are subjected to ball milling treatment for 2 hours to obtain a fully and uniformly mixed solution. Mixing 10kg of ultra-high molecular weight polyethylene powder with the solution by an emulsifying mode of an emulsifying machine, and heating to complete the preparation of the raw materials;
the prepared raw materials are dissolved at high temperature through a double-screw extruder, spun by a spinning manifold, and subjected to a series of processes such as bundling, pre-drawing, cleaning (extraction), drying, drawing and the like to obtain the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber.
Note:
flame retardant evaluation criteria: the oxygen index is more than 27 percent, belongs to a flame-retardant material and has flame-retardant effect.
Features of the invention which are not described in the present patent application can be implemented by or using the prior art, and are not described herein again, it is to be understood that the above description is not intended to limit the invention, and the invention is not limited to the above examples, and those skilled in the art can make changes, modifications, additions or substitutions within the spirit and scope of the invention.
Claims (8)
1. The flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber is characterized by comprising ultrahigh molecular weight polyethylene powder, a flame retardant and an inorganic modifier;
the dosage of the flame retardant is 10-50 wt.% of the ultra-high molecular weight polyethylene powder, and the dosage of the inorganic modifier is 0.5-20 wt.% of the ultra-high molecular weight polyethylene powder.
2. The flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber according to claim 1, wherein the flame retardant is any one or a combination of two or more of aluminum hydroxide, magnesium hydroxide, ammonium polyphosphate, melamine polyphosphate and red phosphorus;
the particle size of the aluminum hydroxide is 0.5-20 μm, the particle size of the magnesium hydroxide is 1-15 μm, the particle size of the ammonium polyphosphate is 3-25 μm, the particle size of the melamine polyphosphate is 1-25 μm, and the size of the red phosphorus is 5-30 μm.
3. The flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber according to claim 2, wherein the inorganic modifier is any one of graphene, graphite nanoplatelets, expanded graphite, graphene oxide, reduced graphene oxide, or a combination of two or more thereof.
4. The flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber according to claim 3, wherein the planar dimensions of the graphene, graphite nanoplatelets, graphene oxide and reduced graphene oxide are all 0.5 to 30 μm, the thickness is 0.335 to 30nm, and the expanded graphite is 200 to 500 times.
5. A preparation method of flame-retardant high-performance ultrahigh molecular weight polyethylene composite fibers is characterized by comprising the following specific preparation steps:
step S01: adding a flame retardant, a nano additive and an inorganic modifier into an organic solvent, and dispersing and mixing uniformly through mechanical stirring and shearing interaction to obtain an organic solution mixture;
step S02: adding ultra-high molecular weight polyethylene powder into the organic solution mixture, stirring and heating for swelling;
step S03: dissolving and homogenizing the prepared raw materials at high temperature by a double-screw extruder, metering, and spinning by a filter and a spinning box;
step S04: and then a series of processes of cleaning/extraction, drying and hot drawing are carried out to obtain the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber.
6. The method for preparing the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber according to claim 5, wherein in the step S01, the dispersion mixing method comprises one or more of mechanical shearing or ultrasonic cavitation, ball milling, sand milling, emulsification or ultrasound.
7. The method for preparing the flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber according to claim 6, wherein the time required for the mixing treatment of the flame retardant and the inorganic modifier in step S01 is 2 to 12 hours.
8. The method according to claim 7, wherein in step S01, the solvent is one or a combination of white oil, decalin, kerosene, animal oil, and vegetable oil, and the amount of the solvent is 1-25 times of the amount of the ultrahigh molecular weight polyethylene powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010888676.4A CN112376125A (en) | 2020-08-28 | 2020-08-28 | Flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010888676.4A CN112376125A (en) | 2020-08-28 | 2020-08-28 | Flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and preparation method thereof |
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| CN112376125A true CN112376125A (en) | 2021-02-19 |
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| CN202010888676.4A Pending CN112376125A (en) | 2020-08-28 | 2020-08-28 | Flame-retardant high-performance ultrahigh molecular weight polyethylene composite fiber and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113604897A (en) * | 2021-05-14 | 2021-11-05 | 盐城优和博新材料有限公司 | Production method of flame-retardant ultrahigh-strength polyethylene |
| CN115895088A (en) * | 2022-12-09 | 2023-04-04 | 上海材料研究所有限公司 | Low-smoke low-toxicity halogen-free flame-retardant ultra-high molecular weight polyethylene composite material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105568421A (en) * | 2014-10-15 | 2016-05-11 | 西安艾菲尔德复合材料科技有限公司 | Preparation method of flame-retardant carbon nanotube enhanced ultra-high molecular weight polyethylene fiber |
| CN106867076A (en) * | 2017-02-15 | 2017-06-20 | 九江学院 | A kind of mining Graphene enhancing dual anti-tubing preparation method of ultra-high molecular weight polyethylene |
| CN109354736A (en) * | 2018-09-20 | 2019-02-19 | 福建师范大学 | A kind of preparation method of modified expansible graphite collaboration ammonium polyphosphate flame-retardant ultra-high molecular weight polyvinyl material |
-
2020
- 2020-08-28 CN CN202010888676.4A patent/CN112376125A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105568421A (en) * | 2014-10-15 | 2016-05-11 | 西安艾菲尔德复合材料科技有限公司 | Preparation method of flame-retardant carbon nanotube enhanced ultra-high molecular weight polyethylene fiber |
| CN106867076A (en) * | 2017-02-15 | 2017-06-20 | 九江学院 | A kind of mining Graphene enhancing dual anti-tubing preparation method of ultra-high molecular weight polyethylene |
| CN109354736A (en) * | 2018-09-20 | 2019-02-19 | 福建师范大学 | A kind of preparation method of modified expansible graphite collaboration ammonium polyphosphate flame-retardant ultra-high molecular weight polyvinyl material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113604897A (en) * | 2021-05-14 | 2021-11-05 | 盐城优和博新材料有限公司 | Production method of flame-retardant ultrahigh-strength polyethylene |
| CN115895088A (en) * | 2022-12-09 | 2023-04-04 | 上海材料研究所有限公司 | Low-smoke low-toxicity halogen-free flame-retardant ultra-high molecular weight polyethylene composite material and preparation method thereof |
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Application publication date: 20210219 |