CN112354515A - Method for preparing adsorbent by using product obtained after one-time exothermic bonding reaction and application - Google Patents
Method for preparing adsorbent by using product obtained after one-time exothermic bonding reaction and application Download PDFInfo
- Publication number
- CN112354515A CN112354515A CN202010810466.3A CN202010810466A CN112354515A CN 112354515 A CN112354515 A CN 112354515A CN 202010810466 A CN202010810466 A CN 202010810466A CN 112354515 A CN112354515 A CN 112354515A
- Authority
- CN
- China
- Prior art keywords
- adsorbent
- reaction
- disposable
- product
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003463 adsorbent Substances 0.000 title claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000000047 product Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 16
- 150000002500 ions Chemical class 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 arsenic ions Chemical class 0.000 claims abstract description 8
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 7
- 239000010865 sewage Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000011505 plaster Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 230000005672 electromagnetic field Effects 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000010455 vermiculite Substances 0.000 claims description 3
- 229910052902 vermiculite Inorganic materials 0.000 claims description 3
- 235000019354 vermiculite Nutrition 0.000 claims description 3
- 238000001179 sorption measurement Methods 0.000 abstract description 27
- 229910001868 water Inorganic materials 0.000 abstract description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 208000028659 discharge Diseases 0.000 abstract description 2
- 239000002351 wastewater Substances 0.000 abstract description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 208000008316 Arsenic Poisoning Diseases 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 230000001684 chronic effect Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910021642 ultra pure water Inorganic materials 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- 208000004998 Abdominal Pain Diseases 0.000 description 1
- 208000009304 Acute Kidney Injury Diseases 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- 206010018910 Haemolysis Diseases 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 108010054147 Hemoglobins Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000009525 Myocarditis Diseases 0.000 description 1
- 208000012902 Nervous system disease Diseases 0.000 description 1
- 208000033626 Renal failure acute Diseases 0.000 description 1
- 208000005392 Spasm Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 201000011040 acute kidney failure Diseases 0.000 description 1
- 208000012998 acute renal failure Diseases 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000001495 arsenic compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 210000000748 cardiovascular system Anatomy 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000002526 effect on cardiovascular system Effects 0.000 description 1
- 229940093920 gynecological arsenic compound Drugs 0.000 description 1
- 230000008588 hemolysis Effects 0.000 description 1
- 230000011132 hemopoiesis Effects 0.000 description 1
- 231100000003 human carcinogen Toxicity 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 1
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 206010040882 skin lesion Diseases 0.000 description 1
- 231100000444 skin lesion Toxicity 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 210000004916 vomit Anatomy 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/103—Arsenic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
Abstract
In the method for preparing the adsorbent by using the product after the one-time heat release paste reaction and the application thereof, the residue after the one-time heat release paste reaction with high iron oxide and carbon concentration is used as the adsorbent for wastewater discharge treatment. The adsorbent can adsorb heavy metal substances while purifying water, expands the application of a reaction product of the disposable heat-releasing paste, solves the environmental problem caused by dumping waste of the disposable heat-releasing paste, has low processing and treating cost, has good adsorption capacity on lead ions and arsenic ions in sewage, and realizes the reutilization of resources.
Description
Technical Field
The invention relates to the technical field of waste resource utilization, in particular to a method for preparing an adsorbent by using a product obtained by a one-time exothermic bonding reaction and application thereof.
Background
Lead is a common heavy metal pollution, and the main sources are industries such as mining, metallurgy, coating and the like. The damage of lead and lead compounds to human body is mainly reflected in hematopoiesis, cardiovascular and nervous system, and the like, and mainly influences the physiological function of human body by blocking the synthesis of hemoglobin and hemolysis, spasm and other effects, if the daily intake of lead in the human body is more than 0.3mg, lead can be accumulated in the human body, and further anemia, nervous system diseases and damage to liver and kidney are caused.
Arsenic pollution of water is a global environmental problem to be solved urgently. Arsenic compounds cannot be easily destroyed and can only be converted to different forms or to insoluble compounds. The elemental arsenic itself has low direct toxicity to organisms, and is hardly absorbed and discharged after entering the bodies due to low solubility, but the elemental arsenic has unreasonable harm to the bodies after being oxidized to form highly toxic oxides. The general toxic effects of arsenic and its compounds can be divided into two categories: one is acute or subacute arsenic poisoning, which can cause vomit, abdominal pain, even coma, myocarditis, acute renal failure and other body diseases; the other is chronic arsenic poisoning, mainly chronic systemic diseases which are mainly characterized by skin lesion and canceration and caused by long-term drinking of high-arsenic water by residents in specific geographic environments. In addition, the long-term toxic effects of arsenic and its compounds include carcinogenesis, aberration and mutation. The harm of arsenic and compounds thereof cannot be predicted, is one of the only carcinogens which have not been reproduced on animals until now, and is confirmed as a human carcinogen by the international cancer research institution in 1981.
With the increasing demand of disposable heat release patch on the world, China has reached 100 ten thousand tablets per day nowadays, and the annual sales volume in China is about 5 hundred million tablets. The disposable heat-releasing paste contains polymer synthesized by iron powder, active carbon, inorganic salt, water and the like, and the iron powder in the raw materials has the basic iron powder content of 68-85 percent due to different manufacturer contents. After the disposable heat-release patch is used, the surface of the iron powder can be oxidized, and other components basically can not be changed. At present, the disposable waste heat-releasing plaster is basically in an unsupervised state, unattended state and directly discarded by people as common solid waste.
Disclosure of Invention
The invention aims to provide a method for preparing an adsorbent by using a product obtained after a one-time exothermic adhesive reaction and application thereof.
The technical scheme adopted by the invention for solving the technical problems in the prior art is as follows:
the method for preparing the adsorbent by using the product after the reaction of the disposable heat release patch comprises the following steps:
A. naturally cooling a product obtained after the reaction of the contents of the disposable heat release patch, and fully grinding the product into powder of 100-350 meshes;
B. adding deionized water and soaking the powder for 10min, wherein the weight parts of solid powder is 1-3, and the weight parts of deionized water is 1-10, and dissolving soluble salts;
C. applying a magnetic field with the strength of more than 80mT to the mixture of the powder and the deionized water, separating and sucking unreacted iron powder from the mixture, and carrying out solid-liquid separation on the residual solid and liquid;
D. adding deionized water to clean the residual solid;
E. and drying the residual solid substance to obtain the adsorbent.
The invention can also adopt the following technical measures:
the contents of the disposable heat release patch comprise active carbon, reduced iron powder, sodium chloride and vermiculite.
The magnetic field is an electromagnetic field or is generated by a magnet.
And D, drying at the temperature of 10-300 ℃ in the step E.
The adsorbent prepared by utilizing the product after the disposable exothermic reaction is applied to the treatment of the sewage containing lead ions Pb (II).
The adsorbent prepared by using the product after the disposable exothermic adhesive reaction is applied to the treatment of the sewage containing arsenic ions As (V).
The invention has the advantages and positive effects that:
in the method for preparing the adsorbent by using the product after the disposable exothermic pad reaction, the residue after the disposable exothermic pad reaction with high iron oxide and carbon concentration is used as the adsorbent for wastewater discharge treatment. The adsorbent can adsorb heavy metal substances while purifying water, expands the application of a reaction product of the disposable heat-releasing paste, solves the environmental problem caused by dumping waste of the disposable heat-releasing paste, has low processing and treating cost, has good adsorption capacity on lead ions and arsenic ions in sewage, and realizes the reutilization of resources.
Drawings
FIG. 1 is a thermodynamic diagram of adsorption of lead and arsenic ions by an adsorbent prepared from the reaction product of a disposable exothermic patch;
FIG. 2 is a graph of adsorption kinetics for adsorption of lead and arsenic ions using an adsorbent prepared from the post-reaction product of a disposable exothermic patch;
FIG. 3 is a graph comparing the effect of the adsorbent prepared by using the product of the one-time exothermic reaction for adsorbing lead and arsenic ions under different pH conditions.
In FIG. 1, the abscissa represents ion concentration (mg/L) and the ordinate represents adsorption capacity (mg/g);
in FIG. 2, the abscissa is time (min), and the ordinate is adsorption capacity (mg/g);
in fig. 3, the abscissa represents pH and the ordinate represents adsorption efficiency (%).
Detailed Description
The technical solution of the present invention will be described in detail below with reference to specific examples.
The method for preparing the adsorbent by using the product after the reaction of the disposable heat release patch comprises the following steps:
A. naturally cooling a product obtained after the reaction of the contents of the disposable heat release patch, and fully grinding the product into powder of 100-350 meshes;
B. adding deionized water and soaking the powder for 10min, wherein the weight parts of solid powder is 1-3, and the weight parts of deionized water is 1-10, and dissolving soluble salts;
C. applying a magnetic field with the strength of more than 80mT to the mixture of the powder and the deionized water, separating and sucking unreacted iron powder from the mixture, and carrying out solid-liquid separation on the residual solid and liquid;
D. adding deionized water to clean the residual solid;
E. and drying the residual solid substance to obtain the adsorbent.
The components of the contents of the disposable heat release patch comprise activated carbon, reduced iron powder, sodium chloride and vermiculite.
The magnetic field is an electromagnetic field or generated by a magnet to separate iron powder in the mixture.
And E, drying at the temperature of 10-300 ℃.
The effectiveness of the above adsorbents was verified as follows:
preparation of heavy metal ion solution: 1g of lead nitrate solid was dissolved in 1L of ultrapure water to prepare a Pb (II) base solution having a concentration of 1 g/L. In the following experiments, the base solution was gradually diluted to the desired concentration with ultrapure water. Similarly, the laboratory-available As (V) solution was diluted stepwise to the concentration required for the experiment.
Adsorption thermodynamics experiment: first, in order to investigate the influence of the adsorption capacity, preliminary experiments were performed. A sample of 20mg of 20mL of an initial 1-500 ppm As (V) solution was taken for 48 hours and the pH of the solution was adjusted to 7.0. + -. 0.1 using 1mol L-1 and 0.1mol L-1 NaOH or HCl. A sample of 20mg of 20mL of a Pb (II) solution having an initial concentration of 10 to 800ppm was taken and the solution was adjusted to pH 6.0. + -. 0.1 using 1mol of L-1 and 0.1mol of L-1 NaOH or HCl for 48 hours. After stringent mixing, the tube was continuously shaken with a platform shaker, operating at 200 rpm. The lead remaining in the aqueous phase was then analyzed using a continuous light source atomic absorption spectrometer and the remaining arsenic content was tested using inductively coupled plasma mass spectrometry (ICP-MS).
In fig. 1, the maximum adsorption amount of the material to the ions is determined according to the adsorption thermodynamics of the two ions, and adsorption isotherm data is analyzed by fitting Langmuir and Freundlich isothermal models. The results show that the adsorption process of both ions fits better to the Langmuir model, indicating a uniform monolayer adsorption process. Using the Langmuir model, the maximum adsorption amounts of Pb (II) and As (V) were 588mg/g and 130mg/g, indicating that the warm patch sample in this study has a strong saturated absorption capacity.
Adsorption kinetics experiment: 20mg of the powdery material were taken and put into 20mL sample bottles of 500ppm Pb (II) and 200ppm As (V) ion solutions, respectively, and shaken on a platform shaker. The total reaction time was 12h, samples were taken every 10 minutes for the first hour, followed by samples taken every hour. After completion the sample was tested for remaining ion concentration.
In fig. 2, all samples had fast adsorption kinetics and reached equilibrium within 5 hours. And fitting the adsorption rate experimental data to pseudo-first and pseudo-second order kinetic models, the results being reported as a function of adsorbent adsorption capacity (Qe) and time (t). The results show that the adsorption capacity of the pseudo second order model is very close to the experimental value, which indicates that the kinetics of the adsorption of Pb (II) and As (V) on the warm patch material follow the pseudo second order model, i.e., the adsorption of Pb (II) and As (V) is a chemisorption process.
In fig. 3, the adsorption efficiencies of two ions under different pH conditions are compared. Wherein, the lead ion adsorption effect is best under the condition of pH 5, and the adsorption efficiency is about 75%; the effect of adsorbing arsenic ions under an acidic condition is better, and the adsorption efficiency is about 80 percent.
Although the present invention has been described with reference to the preferred embodiments, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (6)
1. A method for preparing an adsorbent by using a product obtained after a one-time exothermic adhesive reaction is characterized by comprising the following steps of:
A. naturally cooling a product obtained after the reaction of the contents of the disposable heat release patch, and fully grinding the product into powder of 100-350 meshes;
B. adding deionized water and soaking the powder for 10min, wherein the weight parts of solid powder is 1-3, and the weight parts of deionized water is 1-10, and dissolving soluble salts;
C. applying a magnetic field with the strength of more than 80mT to the mixture of the powder and the deionized water, separating and sucking unreacted iron powder from the mixture, and carrying out solid-liquid separation on the residual solid and liquid;
D. adding deionized water to clean the residual solid;
E. and drying the residual solid substance to obtain the adsorbent.
2. The method for preparing the adsorbent by using the post-reaction product of the disposable exothermic plaster according to claim 1, wherein: the components of the contents of the disposable heat release patch comprise activated carbon, reduced iron powder, sodium chloride and vermiculite.
3. The method for preparing the adsorbent by using the post-reaction product of the disposable exothermic plaster according to claim 2, wherein: the magnetic field is an electromagnetic field or generated by a magnet.
4. The method for preparing the adsorbent by using the post-reaction product of the disposable exothermic plaster according to claim 3, wherein: and E, drying at the temperature of 10-300 ℃.
5. An application of an adsorbent prepared by using a product after a one-time exothermic paste reaction in the treatment of sewage containing lead ions Pb (II).
6. An application of an adsorbent prepared by using a product obtained after a disposable exothermic adhesive reaction in the treatment of sewage containing arsenic ions As (V).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010810466.3A CN112354515A (en) | 2020-08-13 | 2020-08-13 | Method for preparing adsorbent by using product obtained after one-time exothermic bonding reaction and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010810466.3A CN112354515A (en) | 2020-08-13 | 2020-08-13 | Method for preparing adsorbent by using product obtained after one-time exothermic bonding reaction and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112354515A true CN112354515A (en) | 2021-02-12 |
Family
ID=74516725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010810466.3A Pending CN112354515A (en) | 2020-08-13 | 2020-08-13 | Method for preparing adsorbent by using product obtained after one-time exothermic bonding reaction and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112354515A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116984341A (en) * | 2023-08-11 | 2023-11-03 | 上海绿帝环保科技有限公司 | Method for removing doxorubicin in waste water by using waste warmer powder |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040089608A1 (en) * | 2001-08-27 | 2004-05-13 | Vo Toan Phan | Adsorbents for removing heavy metals and methods for producing and using the same |
| CN105478081A (en) * | 2016-01-17 | 2016-04-13 | 济南大学 | Composite carbon filtering material prepared from waste heat packs |
| CN105645992A (en) * | 2016-01-17 | 2016-06-08 | 济南大学 | Method for preparing composite vermiculite mineral matter filter material through waste warm patches |
-
2020
- 2020-08-13 CN CN202010810466.3A patent/CN112354515A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040089608A1 (en) * | 2001-08-27 | 2004-05-13 | Vo Toan Phan | Adsorbents for removing heavy metals and methods for producing and using the same |
| CN105478081A (en) * | 2016-01-17 | 2016-04-13 | 济南大学 | Composite carbon filtering material prepared from waste heat packs |
| CN105645992A (en) * | 2016-01-17 | 2016-06-08 | 济南大学 | Method for preparing composite vermiculite mineral matter filter material through waste warm patches |
Non-Patent Citations (6)
| Title |
|---|
| 全汉炎: "《身边的化学》", 30 June 2017, 广东高等教育出版社 * |
| 同济大学材料科学与工程学院: "《材料科学与工程专业实验教学指导书（金属与无机非金属材料分册）》", 31 December 2017, 同济大学出版社 * |
| 张文绘: ""利用"暖宝宝"废渣对墨水脱色的实验探究"", 《化学教与学》 * |
| 李昱秀等: "负载铁氧化物吸附剂水处理除砷研究进展", 《水处理技术》 * |
| 梁潇等: ""废旧暖贴作为吸附剂去除水中Pb(Ⅱ)和As(Ⅴ)"", 《NCEC2019第十届全国环境化学大会论文集》 * |
| 竹涛: "《矿山固体废物处理与处置工程》", 30 June 2016, 冶金工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116984341A (en) * | 2023-08-11 | 2023-11-03 | 上海绿帝环保科技有限公司 | Method for removing doxorubicin in waste water by using waste warmer powder |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Al-Anber | Thermodynamics approach in the adsorption of heavy metals | |
| Alam et al. | Adsorption of As (III) and As (V) from aqueous solution by modified Cassia fistula (golden shower) biochar | |
| Mallampati et al. | Apple Peels A Versatile Biomass for Water Purification? | |
| Shafaei et al. | Equilibrium studies of the sorption of Hg (II) ions onto chitosan | |
| Abu Tarboush et al. | Metal–organic framework-74 for ultratrace arsenic removal from water: experimental and density functional theory studies | |
| Bulut et al. | Adsorption studies on ground shells of hazelnut and almond | |
| Al-Rashdi et al. | Heavy metals removal using adsorption and nanofiltration techniques | |
| Sekar et al. | Kinetics and equilibrium adsorption study of lead (II) onto activated carbon prepared from coconut shell | |
| Das | Recovery of precious metals through biosorption—a review | |
| Zhai et al. | Study of adsorbent derived from sewage sludge for the removal of Cd2+, Ni2+ in aqueous solutions | |
| Staicu et al. | Desulfurization: Critical step towards enhanced selenium removal from industrial effluents | |
| Elwakeel | Removal of arsenate from aqueous media by magnetic chitosan resin immobilized with molybdate oxoanions | |
| Islam et al. | Removal of copper from aqueous solution using orange peel, sawdust and bagasse | |
| CN104258817B (en) | The chitosan magnetic of melamine modification, preparation method and applications | |
| CN101559988B (en) | Treatment method of ammonia nitrogen wastewater | |
| Jiang et al. | Biosorption isotherm study of Cd2+, Pb2+ and Zn2+ biosorption onto marine bacterium Pseudoalteromonas sp. SCSE709-6 in multiple systems | |
| Liu et al. | Highly recyclable cysteamine-modified acid-resistant MOFs for enhancing Hg (II) removal from water | |
| Bediako et al. | Recovery of gold via adsorption-incineration techniques using banana peel and its derivatives: Selectivity and mechanisms | |
| CN102863045A (en) | Method for treating acid uranium-bearing wastewater by utilizing modified chitosan adsorbents | |
| Ramadevi et al. | Agricultural solid waste for the removal of inorganics: adsorption of mercury (II) from aqueous solution by Tamarind nut carbon | |
| Gode et al. | Column study on the adsorption of Cr (III) and Cr (VI) using Pumice, Yarıkkaya brown coal, Chelex-100 and Lewatit MP 62 | |
| Dakroury et al. | Assessment of adsorption performance of chitosan/ZrO2 biosorbent composite towards Cs (I) and Co (II) metal ions from aqueous solution | |
| CN112354515A (en) | Method for preparing adsorbent by using product obtained after one-time exothermic bonding reaction and application | |
| Wang et al. | Synchronous moderate oxidation and adsorption on the surface of γ-MnO2 for efficient iodide removal from water | |
| Kamel | Preparation and characterization of innovative selective imprinted polymer for the removal of hazardous mercury compounds from aqueous solution |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Haitao Inventor after: Liu Yingying Inventor after: Zhan Sihui Inventor after: Liang Xiao Inventor before: Wang Haitao Inventor before: Zhan Sihui Inventor before: Liang Xiao |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210212 |