CN112341175A - Low-cost and environment-friendly through white brick and preparation method thereof - Google Patents

Low-cost and environment-friendly through white brick and preparation method thereof Download PDF

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CN112341175A
CN112341175A CN202011180361.0A CN202011180361A CN112341175A CN 112341175 A CN112341175 A CN 112341175A CN 202011180361 A CN202011180361 A CN 202011180361A CN 112341175 A CN112341175 A CN 112341175A
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cost
parts
friendly
environment
low
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赵勇
袁富祥
赵一波
曹普银
李政
黄庆鹏
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Guangxi Mona Lisa New Material Co Ltd
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Guangxi Mona Lisa New Material Co Ltd
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite

Abstract

The invention relates to a low-cost and environment-friendly through white brick, which takes pyrophyllite and diopside as main raw materials, and changes a potassium-sodium system into a calcium-magnesium system, so that the use amounts of high-cost ball clay and high-white potash-sodium feldspar are reduced, zirconium silicate whitening agents in the traditional formula are removed, the firing temperature is reduced, the whiteness of the produced product is over 53 ℃, the firing temperature can be reduced due to the melting assistance of the calcium-magnesium system, and the fuel cost is synchronously saved, thereby reducing the production cost; pyrophyllite and diopside are used as main raw materials, the problem that the firing range is narrowed can be solved at the moment, the temperature range of the former high-temperature zone is more than 3 ℃, the temperature range of the current high-temperature zone is within 3 ℃, the oxidation zone is elongated by optimizing the firing curve, gas is exhausted before the brick surface is leveled, pores do not exist on the brick surface of the finished brick obtained at the moment, the brick surface is not easy to store dirt, the antifouling effect of the brick surface of the finished brick is greatly improved, and the problem that the antifouling capacity of the calcium-magnesium through white brick is poor can be effectively solved.

Description

Low-cost and environment-friendly through white brick and preparation method thereof
Technical Field
The invention relates to the technical field of building ceramics, in particular to a low-cost and environment-friendly through white brick and a preparation method thereof.
Background
The whole white brick is one of selling points of a plurality of ceramic manufacturers and is also a critical aspect of wide buyers. The formula of the body-through white brick blank excessively depends on chemical auxiliary materials zirconium silicate or a whitening agent to improve whiteness, the zirconium silicate is a key control raw and auxiliary material of the white brick, the blank cost is greatly increased, the environment is not protected, the radioactivity exceeds the standard easily when the addition amount exceeds 2%, and the traditional body-through white brick excessively depends on a potassium-sodium system to cool the blank, so that the blank cost and the fuel cost are both greatly increased.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a low-cost and environment-friendly through white brick with high whiteness, energy conservation, environmental protection, low production cost and good antifouling property and a preparation method thereof.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows: the low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 33-37 parts of pyrophyllite, 8-12 parts of potash feldspar, 28-32 parts of diopside, 4-6 parts of talc, 4-6 parts of kaolin, 8-12 parts of ball clay and 4-6 parts of bentonite;
the soaking whiteness of the bentonite is more than 55 degrees.
Further, the low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 35 parts of pyrophyllite, 10 parts of potash feldspar, 30 parts of diopside, 5 parts of talc, 5 parts of kaolin, 10 parts of ball clay and 5 parts of bentonite;
the soaking whiteness of the bentonite is more than 55 degrees.
Further, the low-cost and environment-friendly through white brickThe raw materials comprise the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
Furthermore, the whiteness of the low-cost and environment-friendly through white brick is over 53 degrees.
Furthermore, the soaking whiteness of the bentonite is 56-58 degrees.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product;
(5) and polishing and grading the primary finished product to obtain the low-cost and environment-friendly through white brick.
Further, the water content of the mixture in the step (2) is 6.5-7.2%.
Further, in the step (3), the mixture is pressed and formed by a secondary material distributor, and the green body is obtained; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.2-12.8 mm.
Further, the firing area of the firing process in the step (4) comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 42 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 36 th area of the sintering area are heat preservation areas, the heat preservation areas are 13 areas in total, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃.
Further, in the step (5), rough polishing, middle polishing, fine polishing, edge polishing, waxing, grading, packaging and warehousing are carried out.
The invention relates to a low-cost and environment-friendly through white brick, which takes pyrophyllite and diopside as main raw materials, changes potassium-sodium series into calcium-magnesium series, reduces the using amount of high-cost ball clay and high-white potash-sodium feldspar, removes zirconium silicate whitening agents in the traditional formula, reduces the firing temperature, ensures that the whiteness of the produced product is over 53 ℃, reduces the firing temperature due to the melting assistance of the calcium-magnesium series, synchronously saves the fuel cost, reduces the production cost, saves at least 100 yuan/ton of the cost compared with a blank with the same whiteness, is green and environment-friendly, and has higher application value. The general polished white brick produced in the traditional thinking has the main structure of a potassium-sodium system, and pores in the firing process cannot be controlled because the content of calcium and magnesium is too high, so that the antifouling effect of the finished brick is not over-critical; the invention relates to a low-cost and environment-friendly through body white brick and a preparation method thereof, which break through the traditional thinking, pyrophyllite and diopside are taken as main raw materials, the problem that the sintering range is narrowed at the moment can be solved, the temperature range of the former high-temperature region is more than 3 ℃, and the temperature range of the current high-temperature region is within 3 ℃.
Detailed Description
The following examples may help one skilled in the art to more fully understand the present invention, but are not intended to limit the invention in any way.
The soaking whiteness of the bentonite in the invention is as follows: and (3) soaking the cake to be measured for whiteness in clean clear water for 10-20s, and taking out the cake to be wiped clean to measure the whiteness data value, namely the whiteness of soaking.
The green body of the invention can be prepared from known ceramic raw materials by a conventional method, such as sequentially carrying out blank ball milling, powder spraying granulation, green body drying to obtain a dried blank, then firing, polishing, grading and packaging.
The invention can be ball milled by using ingredients in a traditional mode, a 40T ball mill is used, the fineness of raw materials before entering balls is controlled below 8mm, the ball milling fineness is controlled to be 0.5-0.8% of the sieved materials passing through 250 meshes, the water content is controlled to be 35-38%, the specific gravity is controlled to be 1.68-1.72 g/cm3, the flow rate is controlled to be 30-60 s, the materials are sieved for removing iron after being discharged, at least three screens are required to pass, and the mesh number of the screens is 80-120 meshes.
After the ball-milled slurry is obtained, the layout of other colors needs to be adjusted according to the requirements of products except for the white layout, if the yellow layout is needed, the required dry material amount of the slurry needs to be calculated according to a production scheduling plan, color paste is aligned in a paste pool, common pigments of the yellow layout are praseodymium yellow, orange yellow and orange red, the color is adjusted and then the slurry pool and a spray tower need to be cleaned before and after powder spraying, and the pollution of miscellaneous materials is prevented.
The invention needs to be formed by cloth at a press, and requires that the water content is controlled to be 6.8-7.5 percent and the screen residue below 100 meshes is less than or equal to 5 percent.
The invention is dried in the drying kiln after the press is formed, the moisture content before the pressing is fired in the kiln is required to be controlled below 0.5 percent, and the pressing plate can be polished, graded and packed after being taken out of the kiln and cooled.
The firing profile of the present invention is shown in table 1 below:
TABLE 1
Figure DEST_PATH_IMAGE001
Example 1 (example of 600X 600mm production)
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 33 parts of pyrophyllite, 8 parts of potash feldspar, 28 parts of diopside, 4 parts of talc, 4 parts of kaolin, 8 parts of ball clay and 4 parts of bentonite; the soaking whiteness of the bentonite is 56 degrees;
the whole body white with low cost and environmental protectionThe brick comprises the following raw materials in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: pressure of 3000KN, speed of 6 times/min, thickness of 12.2 mm;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product; the firing area of the firing procedure comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 42 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 36 th area of the sintering area are heat preservation areas, the number of the heat preservation areas is 13, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
Example 2 (production of 600X 600mm products as an example)
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 37 parts of pyrophyllite, 12 parts of potash feldspar, 32 parts of diopside, 6 parts of talc, 6 parts of kaolin, 12 parts of ball clay and 6 parts of bentonite; the soaking whiteness of the bentonite is 58 degrees;
the low-cost and environment-friendly through white brick comprises the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.8 mm;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product; the firing area of the firing procedure comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 42 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 36 th area of the sintering area are heat preservation areas, the number of the heat preservation areas is 13, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
Example 3 (production of 600X 600mm products as an example)
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 35 parts of pyrophyllite, 10 parts of potash feldspar, 30 parts of diopside, 5 parts of talc, 5 parts of kaolin, 10 parts of ball clay and 5 parts of bentonite; the soaking whiteness of the bentonite is 57 degrees;
the low-cost and environment-friendly through white brick comprises the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: pressure of 3000KN, speed of 6 times/min, thickness of 12.6 mm;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product; the firing area of the firing procedure comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 42 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 36 th area of the sintering area are heat preservation areas, the number of the heat preservation areas is 13, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
Example 4 (production of 600X 600mm products as an example)
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 36 parts of pyrophyllite, 9 parts of potash albite, 29 parts of diopside, 5.5 parts of talc, 5 parts of kaolin, 11 parts of ball clay and 5.5 parts of bentonite; the soaking whiteness of the bentonite is 58 degrees;
the raw materials of the low-cost and environment-friendly through white brick are calculated by weight percentage,comprises the following chemical components: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.4 mm;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product; the firing area of the firing procedure comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 42 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 36 th area of the sintering area are heat preservation areas, the number of the heat preservation areas is 13, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
Comparative example 1
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 36 parts of pyrophyllite, 9 parts of potash albite, 29 parts of diopside, 5.5 parts of talc, 5 parts of kaolin, 11 parts of ball clay and 5.5 parts of bentonite; the soaking whiteness of the bentonite is 58 degrees;
the low-cost and environment-friendly through white brick comprises the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.4 mm;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product; the firing area of the firing procedure comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 41 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 35 th area of the sintering area are heat preservation areas, the number of the heat preservation areas is 12, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
Comparative example 2
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 36 parts of pyrophyllite, 9 parts of potash albite, 29 parts of diopside, 5.5 parts of talc, 5 parts of kaolin, 11 parts of ball clay and 5.5 parts of bentonite; the soaking whiteness of the bentonite is 58 degrees;
the low-cost and environment-friendly through white brick comprises the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.4 mm;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product; the firing area of the firing procedure comprises a preheating area and a firing area, wherein the preheating area comprises 8 areas, the temperature range of the preheating area is 322-914 ℃, the firing area comprises 40 areas, the surface temperature range of the firing area is 881-1227 ℃, and the bottom temperature range of the firing area is 959-1253 ℃; wherein, the 24 th area to the 34 th area of the sintering area are heat preservation areas, the number of the heat preservation areas is 11, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
Comparative example 3
The low-cost and environment-friendly through white brick is prepared from the following raw materials in parts by weight: 36 parts of pyrophyllite, 9 parts of potash albite, 29 parts of diopside, 5.5 parts of talc, 5 parts of kaolin, 11 parts of ball clay and 5.5 parts of bentonite; the soaking whiteness of the bentonite is 58 degrees;
the low-cost and environment-friendly through white brick comprises the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
The invention also provides a preparation method of the through white brick with low cost and environmental protection, which comprises the following steps:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture, wherein the water content of the mixture is 6.5-7.2%;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.4 mm;
(4) sending the blank into a firing process, and obtaining a primary finished product by using a firing curve of the potassium-sodium series full body white brick;
(5) and (3) roughly polishing, middle polishing, finely polishing, edging, waxing, grading, packaging and warehousing the primary finished product to obtain the low-cost and environment-friendly through white brick.
In the step (1) of the embodiment, a water reducing agent is also added during the water adding and ball milling, and the water reducing agent is a dispergator produced by lotus saint pottery limited company;
the pyrophyllite used in the embodiment is pyrophyllite with dry white of more than 80 degrees, which is produced by Anda ceramics materials Co., Ltd;
the origin of the talc used in this example is Haicheng Liaoning, the loss on ignition of the talc is about 5%, and the whiteness is 90-95 ℃;
the secondary cloth machine that this embodiment used is the secondary cloth press of saxometer, and the tonnage of secondary cloth machine is 3800 KN.
The following table 1 shows the performance measurement results of the through white bricks which are prepared in the examples 1 to 4 and the comparative examples 1 to 3 and have low cost and environmental protection.
The test method comprises the following steps:
water absorption: measuring the water absorption of the product by adopting the method for measuring the water absorption in the No. 3 ceramic tile detection method of GB/T3810.3-2006;
breaking strength: detecting the breaking strength by using a force measuring controller with the model of KSF 003;
serial number Percent pass of product (%) Flexural strength (MPa) Water absorption (%) Whiteness (degree) of product
Example 1 92.5 38.48 0.018-0.030 53
Example 2 92.8 39.59 0.025-0.028 53
Example 3 93.5 42.01 0.019-0.027 53
Example 4 92.0 42.23 0.017-0.025 53
Comparative example 1 86.5 36.43 0.026-0.031 53
Comparative example 2 87.6 34.05 0.018-0.024 53
Comparative example 3 88.3 35.43 0.021-0.029 53
The antifouling test is carried out on the through body white bricks which are prepared in the examples 1 to 4 and the comparative examples 1 to 3 and have low cost and environmental protection, and the antifouling test method comprises the following steps: respectively taking 20 whole-body white bricks which are prepared in the embodiments 1-4 and the comparative examples 1-3 and have low cost and environmental protection, performing tests, smearing cement on the brick surface, wiping the brick surface with cloth, comparing the brick surface with the brick surface, and if the cleanliness of the brick surface does not change obviously, proving that the antifouling property is qualified;
the results are summarized below:
all 20 through white bricks prepared in example 1 pass the antifouling test, and therefore, the through white bricks prepared in example 1 are qualified in antifouling performance;
all 20 through white bricks prepared in example 2 pass the antifouling test, and therefore, the through white bricks prepared in example 1 are qualified in antifouling performance;
all 20 through white bricks prepared in example 3 pass the antifouling test, and therefore, the through white bricks prepared in example 1 are qualified in antifouling performance;
all 20 through white bricks prepared in example 4 pass the antifouling test, and therefore, the through white bricks prepared in example 1 are qualified in antifouling performance;
the 20 through white bricks prepared in the comparative example 1 failed the antifouling test, and thus it can be seen that the through white bricks prepared in the example 1 failed in antifouling performance;
the 20 through white bricks prepared in the comparative example 2 failed the antifouling test, and thus it can be seen that the through white bricks prepared in the example 1 failed in antifouling performance;
in the 20 through white bricks prepared in comparative example 3, none of them passed the antifouling test, and it was found that the through white brick prepared in example 1 failed in antifouling property.
According to the performance test result and the antifouling test result, the low-cost and environment-friendly through white brick and the preparation method thereof have the advantages that the qualification rate is more than 90%, the breaking strength is more than 35MPa, the water absorption is less than 0.05%, the whiteness of the product is more than 53 ℃, and the product meets the national and internal control standards; pyrophyllite and diopside are used as main raw materials, a potassium-sodium system is changed into a calcium-magnesium system, the consumption of high-cost ball clay and high-white potash-sodium feldspar is reduced, a zirconium silicate whitening agent in the traditional formula is removed, the firing temperature is reduced, the whiteness of the produced product is over 53 ℃, due to the melting assistance effect of the calcium-magnesium system, the firing temperature can be reduced, the fuel cost is synchronously saved, the production cost is reduced, the cost is saved by at least 100 yuan/ton compared with a green body with the same whiteness, and the green environmental protection is realized; the invention relates to a low-cost and environment-friendly through body white brick and a preparation method thereof, which break through the traditional thinking, take pyrophyllite and diopside as main raw materials, adjust a firing curve, elongate an oxidation zone, exhaust gas before the brick surface is melted, have no pores on the brick surface of the finished brick, are not easy to store dirt and deposit on the brick surface, greatly improve the antifouling effect of the brick surface of the finished brick, and effectively solve the problem of poor antifouling capability of the calcium-magnesium through body white brick.
Although the invention has been described in detail hereinabove with respect to a general description and specific embodiments thereof, it will be apparent to those skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. The low-cost and environment-friendly through white brick is characterized by comprising the following raw materials in parts by weight: 33-37 parts of pyrophyllite, 8-12 parts of potash feldspar, 28-32 parts of diopside, 4-6 parts of talc, 4-6 parts of kaolin, 8-12 parts of ball clay and 4-6 parts of bentonite;
the soaking whiteness of the bentonite is more than 55 degrees.
2. The low-cost and environment-friendly all-in-one white brick according to claim 1, characterized in that the low-cost and environment-friendly all-in-one white brick is composed of the following raw materials in parts by weight: 35 parts of pyrophyllite, 10 parts of potash feldspar, 30 parts of diopside, 5 parts of talc, 5 parts of kaolin, 10 parts of ball clay and 5 parts of bentonite;
the soaking whiteness of the bentonite is more than 55 degrees.
3. The low-cost and environment-friendly all-in-one white brick according to claim 1, characterized in that the raw materials of the low-cost and environment-friendly all-in-one white brick comprise the following chemical components in percentage by weight: SiO 22:65~68%、Al2O3:19~22%、Fe2O3:0.2~0.3%、TiO2:0.1~0.15%、CaO:5~7%、MgO:2~3%、K2O:1.5~2.5%、Na22-3% of O, loss on ignition: 5 to 7 percent.
4. The low-cost environment-friendly all-in-one white brick according to claim 1, wherein the whiteness of the low-cost environment-friendly all-in-one white brick is over 53 degrees.
5. The low-cost and environment-friendly all-body white brick as claimed in claim 1, wherein the bentonite has a water immersion whiteness of 56-58 degrees.
6. The method for preparing the low-cost and environment-friendly all-in-one white brick according to any one of claims 1 to 5, which is characterized by comprising the following steps of:
(1) weighing the raw materials for forming the low-cost and environment-friendly through white brick according to the proportion, adding water, ball-milling, and sieving with a 250-mesh sieve to obtain the mixture, wherein the rest is 0.5-0.8%;
(2) mixing slurry, color matching and spraying powder to prepare a mixture;
(3) pressing and molding the mixture by using a secondary material distributor to obtain the blank body;
(4) feeding the green body into a firing process, adjusting a firing curve, lengthening an oxidation zone, and exhausting gas before the brick surface is leveled to obtain a primary finished product;
(5) and polishing and grading the primary finished product to obtain the low-cost and environment-friendly through white brick.
7. The low-cost and environment-friendly all-in-one white brick according to claim 6, characterized in that the water content of the mixture in the step (2) is 6.5-7.2%.
8. The low-cost and environment-friendly through white brick according to claim 6, characterized in that the mixture is pressed and formed by a secondary material distributor in the step (3) to obtain the green body; the secondary material distributor has the following technological parameters: the pressure is 3000KN, the speed is 6 times/min, and the thickness is 12.2-12.8 mm.
9. The low-cost and environment-friendly all-in-one white brick according to claim 6, wherein the firing zone of the firing process in the step (4) comprises a preheating zone and a firing zone, the preheating zone comprises 8 zones, the temperature of the preheating zone is in the range of 322 ℃ to 914 ℃, the firing zone comprises 42 zones, the surface temperature of the firing zone is in the range of 881 ℃ to 1227 ℃, and the bottom temperature of the firing zone is in the range of 959 ℃ to 1253 ℃; wherein, the 24 th area to the 36 th area of the sintering area are heat preservation areas, the heat preservation areas are 13 areas in total, the surface temperature of the heat preservation areas is 1227 ℃, and the bottom temperature is 1253 ℃.
10. The low-cost and environment-friendly full-body white brick according to claim 6, characterized in that in the step (5), the brick is subjected to rough polishing, middle polishing, fine polishing, edge polishing, waxing, grading, packaging and warehousing.
CN202011180361.0A 2020-10-29 2020-10-29 Low-cost and environment-friendly through white brick and preparation method thereof Pending CN112341175A (en)

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Application publication date: 20210209