CN112341026A - Copper tailings modifier and preparation method and application thereof - Google Patents
Copper tailings modifier and preparation method and application thereof Download PDFInfo
- Publication number
- CN112341026A CN112341026A CN202011220945.6A CN202011220945A CN112341026A CN 112341026 A CN112341026 A CN 112341026A CN 202011220945 A CN202011220945 A CN 202011220945A CN 112341026 A CN112341026 A CN 112341026A
- Authority
- CN
- China
- Prior art keywords
- copper tailings
- copper
- modifier
- tailings
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 84
- 239000010949 copper Substances 0.000 title claims abstract description 84
- 239000003607 modifier Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 75
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 46
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 46
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 29
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 29
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 29
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 24
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 24
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 24
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 23
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 23
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 150000001879 copper Chemical class 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 9
- 230000004913 activation Effects 0.000 claims abstract description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- 238000005056 compaction Methods 0.000 abstract description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 8
- 239000011707 mineral Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- -1 halogen ions Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/141—Slags
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B5/00—Treatment of metallurgical slag ; Artificial stone from molten metallurgical slag
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a copper tailings modifier and a preparation method and application thereof, wherein the copper tailings modifier is prepared from the following raw materials: 12-39% of water glass, 24-31% of sodium silicate, 21-30% of calcium nitrate, 12-19% of sodium hydroxide, 1-3% of sodium carboxymethyl cellulose, 3-5% of hydroxypropyl methyl cellulose and 100% of total amount; the percentages are mass percentages. When the copper tailing powder is applied, the copper tailing powder is subjected to primary activation treatment, namely, triethanolamine serving as a grinding aid is added into the copper tailing powder and is ground into fine powder with uniform particle size to obtain activated copper tailing powder, and then the activated copper tailing powder and a copper tailing powder modifier are uniformly mixed. The use of sodium carboxymethyl cellulose and hydroxypropyl methyl cellulose can improve the hydrophobicity and cohesive force of the copper tailings, and further improve the compaction characteristic and structural stability of the doped copper tailings mixture. The silicate component in the copper tailings can be excited by alkali by adding the sodium hydroxide, so that the pavement performances such as strength, durability and the like of the copper tailings are improved.
Description
Technical Field
The invention belongs to the technical field of comprehensive utilization of copper tailings, and particularly relates to a copper tailing modifier as well as a preparation method and application thereof.
Background
As is well known, scientific and reasonable development and utilization of mineral resources are important basic stones for human survival and social development, and the production and manufacture of most industrial products, consumer products, energy sources and raw materials depend on the development and utilization of mineral resources. Copper is widely applied to industries such as electricity, light industry, mechanical manufacturing, building industry, national defense industry and the like as a mineral resource with huge demand, wherein the usage amount of copper in China is second to aluminum in consumption of non-ferrous metal materials. However, copper ore mined from mines must go through a series of mineral separation processes before being refined into high-purity refined copper and copper products, wherein most gangue minerals in the copper ore become copper tailings after being crushed and refined. The data show that about 400 tons of copper tailings are generated for every 1 ton of refined copper produced under the current process technology. According to the statistical analysis of China's national resource economic research institute, the total emission amount of the copper tailings in China reaches 24 hundred million tons between 1949 and 2007, and the emission amount is continuously increased. The annual output of the copper tailings in China in 2013 reaches 3.19 hundred million tons, and the quantity is incredible.
A huge amount of copper tailings serving as solid waste are generally directly discharged into a tailings pond in a slurry form for stockpiling in China, few copper tailings serving as filling materials are backfilled into an excavated mine, and the comprehensive utilization level of the copper tailings is low. The stockpiling of a large amount of copper tailings can cause various disadvantages: (1) occupies a large amount of agriculture and forestry land, and causes land resource imbalance. Meanwhile, the tailings pond often has collapse and leakage accidents, or the excessive drainage and the like can also damage a large amount of land. (2) Increasing the operating cost of the enterprise. The tailings treatment facility is a building with higher requirement on neutralization performance of mineral separation enterprises, and the capital investment of the tailings treatment facility is up to 5-40%. And the routine maintenance and operation management of the tailings pond are also considerable expenses. (3) And the environment is polluted. The tailings generally contain a lot of heavy metal ions, and various chemical agents can be introduced in the processing process of copper ores, so that the tailings can seriously pollute the ecological environment of nearby areas once the tailings are poorly treated and enter the surrounding natural world. In conclusion, the accumulation of copper tailings brings about a nuisance and no advantage.
The mineral composition of the copper tailings is mainly silicate minerals such as quartz, mica, sodium/potassium feldspar and the like or carbonate minerals such as calcite and the like, and the copper tailings have obvious resource attributes. Due to the limitations of a series of factors such as the technical level, equipment performance, economic conditions, manual operation of actual production and the like of the past and capital industry, the copper tailings cannot be well utilized.
Disclosure of Invention
The purpose is as follows: in order to overcome the defects of the prior art, the invention provides a copper tailings modifier and a preparation method and application thereof.
The technical scheme is as follows: in order to solve the technical problems, the technical scheme adopted by the invention is as follows:
a copper tailings modifier is prepared from the following raw materials: 12-39% of water glass, 24-31% of sodium silicate, 21-30% of calcium nitrate, 12-19% of sodium hydroxide, 1-3% of sodium carboxymethyl cellulose, 3-5% of hydroxypropyl methyl cellulose and 100% of total amount; the percentages are mass percentages;
according to the formula proportion, uniformly mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethyl cellulose and the hydroxypropyl methyl cellulose to obtain the sodium carboxymethyl cellulose.
In some embodiments, the copper tailings modifier is prepared from the following raw materials: 12% of water glass, 31% of sodium silicate, 30% of calcium nitrate, 19% of sodium hydroxide, 3% of sodium carboxymethyl cellulose and 5% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
In some embodiments, the copper tailings modifier is prepared from the following raw materials: 39% of water glass, 24% of sodium silicate, 21% of calcium nitrate, 12% of sodium hydroxide, 1% of sodium carboxymethyl cellulose and 3% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
In some embodiments, the copper tailings modifier is prepared from the following raw materials: 27% of water glass, 28% of sodium silicate, 25% of calcium nitrate, 14% of sodium hydroxide, 2% of sodium carboxymethyl cellulose, 4% of hydroxypropyl methyl cellulose and 100% of total amount; the percentages are mass percentages.
In some embodiments, the copper tailings modifier is prepared from the following raw materials: 30% of water glass, 29% of sodium silicate, 25% of calcium nitrate, 12% of sodium hydroxide, 1% of sodium carboxymethyl cellulose and 3% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
The invention also provides a preparation method of the copper tailings modifier, which comprises the following steps: according to the formula proportion, uniformly mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethyl cellulose and the hydroxypropyl methyl cellulose to obtain the sodium carboxymethyl cellulose.
The invention also provides application of the copper tailings modifier in improving the performance (strength and durability) of the copper tailings.
In some embodiments, the application comprises: and (3) carrying out primary activation treatment on the copper tailings to obtain activated copper tailings, and uniformly mixing the activated copper tailings and the copper tailings modifier.
Further, the copper tailings are subjected to primary activation treatment, which comprises the following steps:
after the copper tailings are put into a ball mill, a certain amount of triethanolamine serving as a grinding aid is added to grind into fine powder with uniform particle size, so that the activated copper tailings are obtained.
More preferably, in the preliminary activation treatment of the copper tailings, the adding amount of triethanolamine serving as a grinding aid is one thousandth of the mass of the copper tailings.
Has the advantages that: according to the copper tailing modifier provided by the invention, triethanolamine is used as a grinding aid during preliminary activation treatment of copper tailings in the early stage, so that the copper tailings can be ground by a machine and the activity of the copper tailings can be enhanced. The use of sodium carboxymethyl cellulose and hydroxypropyl methyl cellulose can improve the hydrophobicity and cohesive force of the copper tailings, and further improve the compaction characteristic and structural stability of the doped copper tailings mixture. The silicate component in the copper tailings can be excited by alkali by adding the sodium hydroxide, so that the pavement performances such as strength, durability and the like of the copper tailings are improved. Not only saves the resources and achieves the reasonable utilization of the resources, but also protects the environment. The copper tailing modifier has good chemical stability, does not contain halogen ions for corroding equipment, and obviously improves the activity and durability of the copper tailing.
Detailed Description
The present invention is specifically illustrated below with reference to examples: the percentages in the invention are mass percentages.
Example 1
A copper tailings modifier comprises the following raw materials: 12% of water glass, 31% of sodium silicate, 30% of calcium nitrate, 19% of sodium hydroxide, 3% of sodium carboxymethyl cellulose and 5% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
The mass percentages are all mass percentages, according to the formula proportion, the product 1 is obtained by stirring and mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethylcellulose and the hydroxypropyl methylcellulose uniformly.
Example 2
A copper tailings modifier comprises the following raw materials: 39% of water glass, 24% of sodium silicate, 21% of calcium nitrate, 12% of sodium hydroxide, 1% of sodium carboxymethyl cellulose and 3% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
The mass percentages are the mass percentages, according to the formula proportion, the product 2 is obtained by stirring and mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethyl cellulose and the hydroxypropyl methyl cellulose uniformly.
Example 3
A copper tailings modifier comprises the following raw materials: 27% of water glass, 28% of sodium silicate, 25% of calcium nitrate, 14% of sodium hydroxide, 2% of sodium carboxymethyl cellulose and 100% of total amount; the percentages are mass percentages.
The product 3 is obtained by uniformly stirring and mixing water glass, sodium silicate, calcium nitrate, sodium hydroxide, sodium carboxymethylcellulose and hydroxypropyl methylcellulose according to the formula ratio.
Example 4
A copper tailings modifier comprises the following raw materials: 30% of water glass, 29% of sodium silicate, 25% of calcium nitrate, 12% of sodium hydroxide, 1% of sodium carboxymethyl cellulose and 3% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
The mass percentages are all mass percentages, and according to the formula proportion, the product 4 is obtained by stirring and mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethylcellulose and the hydroxypropyl methylcellulose uniformly.
Performance testing
The addition amount of the copper tailing modifier is one percent of the copper tailing ingredients.
The activated copper tailings doped with the copper tailing modifier are used as an active mineral admixture for preparing concrete, wherein the doping amount of the modified copper tailings is 30%, and the performance results of the tested concrete are shown in the following table:
the present invention has been disclosed in terms of the preferred embodiment, but it is not intended to be limited to the embodiment, and all technical solutions obtained by substituting or converting the equivalent embodiments fall within the scope of the present invention.
Claims (10)
1. The copper tailings modifier is characterized by being prepared from the following raw materials: 12-39% of water glass, 24-31% of sodium silicate, 21-30% of calcium nitrate, 12-19% of sodium hydroxide, 1-3% of sodium carboxymethyl cellulose, 3-5% of hydroxypropyl methyl cellulose and 100% of total amount; the percentages are mass percentages;
according to the formula proportion, uniformly mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethyl cellulose and the hydroxypropyl methyl cellulose to obtain the sodium carboxymethyl cellulose.
2. The copper tailings modifier of claim 1, wherein the copper tailings modifier is prepared from the following raw materials: 12% of water glass, 31% of sodium silicate, 30% of calcium nitrate, 19% of sodium hydroxide, 3% of sodium carboxymethyl cellulose and 5% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
3. The copper tailings modifier of claim 1, wherein the copper tailings modifier is prepared from the following raw materials: 39% of water glass, 24% of sodium silicate, 21% of calcium nitrate, 12% of sodium hydroxide, 1% of sodium carboxymethyl cellulose and 3% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
4. The copper tailings modifier of claim 1, wherein the copper tailings modifier is prepared from the following raw materials: 27% of water glass, 28% of sodium silicate, 25% of calcium nitrate, 14% of sodium hydroxide, 2% of sodium carboxymethyl cellulose, 4% of hydroxypropyl methyl cellulose and 100% of total amount; the percentages are mass percentages.
5. The copper tailings modifier of claim 1, wherein the copper tailings modifier is prepared from the following raw materials: 30% of water glass, 29% of sodium silicate, 25% of calcium nitrate, 12% of sodium hydroxide, 1% of sodium carboxymethyl cellulose and 3% of hydroxypropyl methyl cellulose, wherein the total amount is 100%; the percentages are mass percentages.
6. The method for preparing a copper tailings modifier according to any one of claims 1 to 5, comprising: according to the formula proportion, uniformly mixing the water glass, the sodium silicate, the calcium nitrate, the sodium hydroxide, the sodium carboxymethyl cellulose and the hydroxypropyl methyl cellulose to obtain the sodium carboxymethyl cellulose.
7. Use of the copper tailings modifier of any of claims 1 to 5 for improving the properties of copper tailings.
8. The use according to claim 7, comprising: and (3) carrying out primary activation treatment on the copper tailings to obtain activated copper tailings, and uniformly mixing the activated copper tailings and the copper tailings modifier.
9. The use according to claim 8, wherein the copper tailings are subjected to a preliminary activation treatment comprising:
after the copper tailings are put into a ball mill, a certain amount of triethanolamine serving as a grinding aid is added to grind into fine powder with uniform particle size, so that the activated copper tailings are obtained.
10. The use of claim 9, wherein in the preliminary activation treatment of the copper tailings, the grinding aid triethanolamine is added in an amount of one thousandth of the mass of the copper tailings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011220945.6A CN112341026A (en) | 2020-11-05 | 2020-11-05 | Copper tailings modifier and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011220945.6A CN112341026A (en) | 2020-11-05 | 2020-11-05 | Copper tailings modifier and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112341026A true CN112341026A (en) | 2021-02-09 |
Family
ID=74429845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011220945.6A Pending CN112341026A (en) | 2020-11-05 | 2020-11-05 | Copper tailings modifier and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112341026A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113772999A (en) * | 2021-08-31 | 2021-12-10 | 武汉理工大学 | Asphalt filler and preparation method thereof |
| CN114163156A (en) * | 2021-12-24 | 2022-03-11 | 南京永能新材料有限公司 | Formula of copper tailings modified concrete and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1457937A (en) * | 2002-05-16 | 2003-11-26 | 尹小林 | Phosphorous slag activation modifier |
| CA2684155A1 (en) * | 2008-10-29 | 2010-04-29 | E. I. Du Pont De Nemours And Company | Improved bitumen extraction process |
| CN104628416A (en) * | 2015-01-30 | 2015-05-20 | 淮安市建筑工程检测中心有限公司 | Aerated concrete prepared from copper smelting water quenching slag and titanium white slag and preparation method thereof |
-
2020
- 2020-11-05 CN CN202011220945.6A patent/CN112341026A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1457937A (en) * | 2002-05-16 | 2003-11-26 | 尹小林 | Phosphorous slag activation modifier |
| CA2684155A1 (en) * | 2008-10-29 | 2010-04-29 | E. I. Du Pont De Nemours And Company | Improved bitumen extraction process |
| CN104628416A (en) * | 2015-01-30 | 2015-05-20 | 淮安市建筑工程检测中心有限公司 | Aerated concrete prepared from copper smelting water quenching slag and titanium white slag and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113772999A (en) * | 2021-08-31 | 2021-12-10 | 武汉理工大学 | Asphalt filler and preparation method thereof |
| CN114163156A (en) * | 2021-12-24 | 2022-03-11 | 南京永能新材料有限公司 | Formula of copper tailings modified concrete and preparation method thereof |
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