CN112321907A - Corrosion-resistant and heat-resistant rubber - Google Patents

Corrosion-resistant and heat-resistant rubber Download PDF

Info

Publication number
CN112321907A
CN112321907A CN202011235824.9A CN202011235824A CN112321907A CN 112321907 A CN112321907 A CN 112321907A CN 202011235824 A CN202011235824 A CN 202011235824A CN 112321907 A CN112321907 A CN 112321907A
Authority
CN
China
Prior art keywords
parts
corrosion
resistant
rubber
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011235824.9A
Other languages
Chinese (zh)
Inventor
顾建生
顾爱民
顾建军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taixing Jinhui Rubber Products Co ltd
Original Assignee
Taixing Jinhui Rubber Products Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taixing Jinhui Rubber Products Co ltd filed Critical Taixing Jinhui Rubber Products Co ltd
Priority to CN202011235824.9A priority Critical patent/CN112321907A/en
Publication of CN112321907A publication Critical patent/CN112321907A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses corrosion-resistant and heat-resistant rubber, which is characterized in that: the rubber comprises the following components in parts by weight: 80-100 parts of natural rubber, 20-30 parts of nitrile rubber, 15-30 parts of carbon black, 18-24 parts of silicon dioxide, 3-5 parts of paraffin, 15-25 parts of plasticizer, 10-20 parts of vulcanizing agent, 3-9 parts of activator, 10-15 parts of softener, 5-10 parts of accelerator, 6-11 parts of corrosion inhibitor, 10-14 parts of anti-aging agent, 15-18 parts of flame retardant, 4-9 parts of antioxidant and 10-20 parts of antibacterial agent. The anti-corrosion and heat-resistant rubber is prepared by a simple preparation method on the basis of reasonable formula design, has low rubber cost, good corrosion resistance and good heat resistance, is suitable for various environments which are corrosive to rubber materials due to high corrosion resistance of the antioxidant, improves the corrosion resistance of the rubber materials, and can adapt to more complex use environments due to high flame retardance of the flame retardant.

Description

Corrosion-resistant and heat-resistant rubber
Technical Field
The invention relates to the field of rubber materials, in particular to corrosion-resistant and heat-resistant rubber.
Background
The rubber is an elastic polymer, is an important strategic material, is widely applied to the fields of high and new technology, national economy, national defense and military industry and the like, is prepared by taking pure natural rubber as a main body, adding a specific foaming agent together with other raw materials and carrying out hot press molding on the mixture, but the existing rubber material has insufficient corrosion resistance, cannot be used in a specific environment which corrodes rubber materials, and has insufficient heat resistance.
Disclosure of Invention
The invention aims to provide corrosion-resistant and heat-resistant rubber, and solves the problems that the existing rubber is poor in corrosion resistance and heat resistance and cannot meet the requirement of rubber used in the existing life.
In order to achieve the purpose, the invention is realized by the following technical scheme:
the corrosion-resistant and heat-resistant rubber comprises the following components in parts by weight: 80-100 parts of natural rubber, 20-30 parts of nitrile rubber, 15-30 parts of carbon black, 18-24 parts of silicon dioxide, 3-5 parts of paraffin, 15-25 parts of plasticizer, 10-20 parts of vulcanizing agent, 3-9 parts of activator, 10-15 parts of softener, 5-10 parts of accelerator, 6-11 parts of corrosion inhibitor, 10-14 parts of anti-aging agent, 15-18 parts of flame retardant, 4-9 parts of antioxidant and 10-20 parts of antibacterial agent.
Furthermore, the nitrile rubber can be prepared by mixing butadiene, acrylonitrile, fatty hydrochloric acid, diisopropylbenzene hydroperoxide, tert-dodecyl mercaptan and water according to a certain proportion.
Furthermore, the plasticizer is formed by combining one or more of phthalate, aliphatic dibasic acid ester, fatty acid ester, benzene polyacid ester, polyol ester, epoxy hydrocarbon and alkyl sulfonate, and the plasticizer mainly has the effects of weakening the secondary valence bonds among resin molecules, increasing the mobility of resin molecular bonds, reducing the crystallinity of the resin molecules, increasing the plasticity of the resin molecules, enhancing the flexibility and facilitating the processing.
Further, the vulcanizing agent is one of sulfur and dicumyl peroxide or a composition of the sulfur and the dicumyl peroxide.
Further, the carbon black adopts carbon black N234, the activating agent is zinc oxide, stearic acid or zinc stearate, and the softening agent is hydroxyl silicone oil.
Further, the accelerator is one or a combination of thiuram accelerators, thiazole accelerators and sulfenamide accelerators.
Furthermore, the anti-aging agent is prepared by mixing the anti-aging agent 4010NA and the anti-aging agent RD in proportion.
Furthermore, the flame retardant is composed of one or more of dibromomethane, trichlorobromomethane, dichlorobromomethane, octabromodiphenyl oxide and pentabromoethylbenzene, and the material processed by the flame retardant can effectively prevent, delay or stop the propagation of flame when being attacked by an external fire source, thereby achieving the flame retardant effect.
Further, putting natural rubber, nitrile rubber, carbon black, silicon dioxide, paraffin, a plasticizer, an activator, a softener, an accelerant and a vulcanizing agent with different contents into an internal mixer for low-temperature uniform mixing, vacuumizing and heating to 170 ℃ for treatment for 3 hours, cooling, adding a corrosion-resistant agent, an anti-aging agent, a flame retardant, an antioxidant and an antibacterial agent into the internal mixer, and performing low-temperature uniform mixing to obtain the corrosion-resistant and heat-resistant rubber.
The invention has the beneficial effects that: the corrosion-resistant and heat-resistant rubber is prepared by a simple preparation method on the basis of reasonable formula design, has low rubber cost, good corrosion resistance and good heat resistance, is suitable for various environments which are corrosive to rubber materials due to high corrosion resistance of the antioxidant, improves the corrosion resistance of rubber materials, improves the heat resistance of the rubber materials due to high flame retardance of the flame retardant, and can be suitable for more complex use environments due to the cooperation of silica, carbon black, paraffin and other flame-retardant raw materials and the flame retardant, so that the rubber material has better application prospect.
Detailed Description
The following further describes embodiments of the present invention with reference to examples. The following examples are only for illustrating the technical solutions of the present invention more clearly, and the protection scope of the present invention is not limited thereby.
Example 1
80 parts of natural rubber, 20 parts of nitrile rubber, 15 parts of carbon black, 18 parts of silicon dioxide, 3 parts of paraffin, 15 parts of plasticizer, 10 parts of vulcanizing agent, 3 parts of activator, 10 parts of softener, 5 parts of accelerator, 6 parts of corrosion inhibitor, 10 parts of anti-aging agent, 15 parts of flame retardant, 4 parts of antioxidant and 10 parts of antibacterial agent.
Firstly, putting natural rubber, nitrile rubber, carbon black, silicon dioxide, paraffin, a plasticizer, an activator, a softener, an accelerant and a vulcanizing agent with different contents into an internal mixer for low-temperature uniform mixing, vacuumizing and heating to 170 ℃ for processing for 3h, cooling, then adding an anti-corrosion agent, an anti-aging agent, a flame retardant, an antioxidant and an antibacterial agent into the internal mixer, and performing low-temperature uniform mixing to obtain the anti-corrosion and heat-resistant rubber.
Example 2
The corrosion-resistant and heat-resistant rubber comprises the following components in parts by weight: 90 parts of natural rubber, 15 parts of nitrile rubber, 25 parts of carbon black, 20 parts of silicon dioxide, 4 parts of paraffin, 20 parts of plasticizer, 15 parts of vulcanizing agent, 6 parts of activator, 13 parts of softener, 8 parts of accelerator, 8 parts of corrosion inhibitor, 12 parts of anti-aging agent, 16 parts of flame retardant, 7 parts of antioxidant and 15 parts of antibacterial agent.
Firstly, putting natural rubber, nitrile rubber, carbon black, silicon dioxide, paraffin, a plasticizer, an activator, a softener, an accelerant and a vulcanizing agent with different contents into an internal mixer for low-temperature uniform mixing, vacuumizing and heating to 170 ℃ for processing for 3h, cooling, then adding an anti-corrosion agent, an anti-aging agent, a flame retardant, an antioxidant and an antibacterial agent into the internal mixer, and performing low-temperature uniform mixing to obtain the anti-corrosion and heat-resistant rubber.
Example 3
The corrosion-resistant and heat-resistant rubber comprises the following components in parts by weight: 100 parts of natural rubber, 30 parts of nitrile rubber, 30 parts of carbon black, 24 parts of silicon dioxide, 5 parts of paraffin, 25 parts of plasticizer, 20 parts of vulcanizing agent, 9 parts of activator, 15 parts of softener, 10 parts of accelerator, 11 parts of corrosion inhibitor, 14 parts of anti-aging agent, 18 parts of flame retardant, 9 parts of antioxidant and 20 parts of antibacterial agent.
Firstly, putting natural rubber, nitrile rubber, carbon black, silicon dioxide, paraffin, a plasticizer, an activator, a softener, an accelerant and a vulcanizing agent with different contents into an internal mixer for low-temperature uniform mixing, vacuumizing and heating to 170 ℃ for processing for 3h, cooling, then adding an anti-corrosion agent, an anti-aging agent, a flame retardant, an antioxidant and an antibacterial agent into the internal mixer, and performing low-temperature uniform mixing to obtain the anti-corrosion and heat-resistant rubber.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical scope of the present invention and the equivalent alternatives or modifications according to the technical solution and the inventive concept of the present invention within the technical scope of the present invention.

Claims (9)

1. A corrosion-resistant and heat-resistant rubber is characterized in that: the rubber comprises the following components in parts by weight: 80-100 parts of natural rubber, 20-30 parts of nitrile rubber, 15-30 parts of carbon black, 18-24 parts of silicon dioxide, 3-5 parts of paraffin, 15-25 parts of plasticizer, 10-20 parts of vulcanizing agent, 3-9 parts of activator, 10-15 parts of softener, 5-10 parts of accelerator, 6-11 parts of corrosion inhibitor, 10-14 parts of anti-aging agent, 15-18 parts of flame retardant, 4-9 parts of antioxidant and 10-20 parts of antibacterial agent.
2. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the nitrile rubber can be prepared by mixing butadiene, acrylonitrile, fatty hydrochloric acid, hydrogen peroxide diisopropylbenzene, tert-dodecyl mercaptan and water according to a certain proportion.
3. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the plasticizer is formed by combining one or more of phthalate, aliphatic dibasic acid ester, fatty acid ester, benzene polyacid ester, polyol ester, epoxy hydrocarbon and alkyl sulfonate, and has the functions of weakening the secondary bond among resin molecules, increasing the mobility of the molecular bond of the resin, reducing the crystallinity of the resin molecules, increasing the plasticity of the resin molecules, enhancing the flexibility and being easy to process.
4. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the vulcanizing agent is one of sulfur and dicumyl peroxide or a composition of the sulfur and the dicumyl peroxide.
5. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the carbon black is carbon black N234, the activating agent is zinc oxide, stearic acid or zinc stearate, and the softening agent is hydroxyl silicone oil.
6. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the accelerator is one or a composition of thiuram accelerators, thiazole accelerators and sulfenamide accelerators.
7. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the anti-aging agent is prepared by mixing the anti-aging agent 4010NA and the anti-aging agent RD in proportion.
8. The corrosion-resistant heat-resistant rubber according to claim 1, wherein: the flame retardant is composed of one or more of dibromomethane, trichlorobromomethane, dichlorobromomethane, octabromodiphenyl oxide and pentabromoethylbenzene, and the material processed by the flame retardant can effectively prevent, delay or stop the propagation of flame when being attacked by an external fire source, thereby achieving the flame retardant effect.
9. The process for preparing a corrosion-resistant heat-resistant rubber according to any one of claims 1 to 8, wherein: putting natural rubber, nitrile rubber, carbon black, silicon dioxide, paraffin, a plasticizer, an activator, a softener, an accelerator and a vulcanizing agent with different contents into an internal mixer, uniformly mixing at a low temperature, vacuumizing, heating to 170 ℃, treating for 3 hours, cooling, adding an anti-corrosion agent, an anti-aging agent, a flame retardant, an antioxidant and an antibacterial agent into the internal mixer, and uniformly mixing at a low temperature to obtain the anti-corrosion and heat-resistant rubber.
CN202011235824.9A 2020-11-09 2020-11-09 Corrosion-resistant and heat-resistant rubber Pending CN112321907A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011235824.9A CN112321907A (en) 2020-11-09 2020-11-09 Corrosion-resistant and heat-resistant rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011235824.9A CN112321907A (en) 2020-11-09 2020-11-09 Corrosion-resistant and heat-resistant rubber

Publications (1)

Publication Number Publication Date
CN112321907A true CN112321907A (en) 2021-02-05

Family

ID=74315736

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011235824.9A Pending CN112321907A (en) 2020-11-09 2020-11-09 Corrosion-resistant and heat-resistant rubber

Country Status (1)

Country Link
CN (1) CN112321907A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214546A (en) * 2021-05-31 2021-08-06 七彩新型材料集团有限公司 Novel heat-insulating flame-retardant rubber material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107841000A (en) * 2017-12-08 2018-03-27 成都米利得科技有限公司 A kind of environment-friendly rubber of corrosion-and high-temp-resistant
CN108059739A (en) * 2017-12-08 2018-05-22 成都米利得科技有限公司 A kind of preparation method of the environment-friendly rubber of corrosion-and high-temp-resistant
CN111675858A (en) * 2020-07-20 2020-09-18 江苏永辉橡胶有限公司 Formula and preparation method of corrosion-resistant rubber material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107841000A (en) * 2017-12-08 2018-03-27 成都米利得科技有限公司 A kind of environment-friendly rubber of corrosion-and high-temp-resistant
CN108059739A (en) * 2017-12-08 2018-05-22 成都米利得科技有限公司 A kind of preparation method of the environment-friendly rubber of corrosion-and high-temp-resistant
CN111675858A (en) * 2020-07-20 2020-09-18 江苏永辉橡胶有限公司 Formula and preparation method of corrosion-resistant rubber material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214546A (en) * 2021-05-31 2021-08-06 七彩新型材料集团有限公司 Novel heat-insulating flame-retardant rubber material

Similar Documents

Publication Publication Date Title
CN107325357B (en) A kind of transparent high thermoplasticity neoprene pipe and preparation method thereof
CN112321952B (en) Ethylene propylene diene monomer composite rubber material and preparation method thereof
KR101444577B1 (en) Latex composition for dip-forming
CN109694505B (en) Rubber composition containing organic acid zinc phenolic resin compound and preparation method and application thereof
CN112321907A (en) Corrosion-resistant and heat-resistant rubber
CN105111533A (en) Anti-aging, oil resistant and high strength composite cable material
CN105367958A (en) Antibacterial modified fluororubber composite material
CN111675858A (en) Formula and preparation method of corrosion-resistant rubber material
CN112480506A (en) Preparation method of graphene hydrogel modified latex and graphene modified hydrogel rubber glove
CN110330786B (en) Heat-conducting nylon composite material and preparation method thereof
CN108623844A (en) DOPO-LDH composite fire retardants and preparation method thereof and halogen-free flame retardant ethylene propylene diene monomer (EPDM) material and its application
CN103497384B (en) A kind of ageing-resistant rubber composition containing metallic salts of unsaturated carboxylate vulcanizing agent
CN106916380A (en) Modified CABLE MATERIALS of a kind of potter's clay and preparation method thereof
CN110128698B (en) Environment-friendly flame-retardant smoke suppressant and preparation method thereof
CN111117016A (en) Low-corrosivity rubber and plastic product and preparation method thereof
CN105622998A (en) Production process of cushion rubber gasket
KR101373121B1 (en) Rubber composition of gasket for inverter case of a hybrid vehicle
CN113930021A (en) Light-color flame-retardant low-odor environment-friendly ethylene propylene diene monomer composition and preparation method thereof
US2676944A (en) Rubber processing in the presence of carbon black and an organic peroxide
CN111961289A (en) High-hardness EPDM rubber composition and preparation method thereof
CN110746669A (en) Novel high-temperature-resistant flame-retardant rubber material and production process thereof
CN110862622A (en) High-flame-retardancy new energy automobile wire harness rubber sleeve and preparation method thereof
CN110564027A (en) preparation method of halogen-free flame-retardant rubber composite material
CN103467869B (en) Cable sheath material for wind power generation
Lo et al. Influence of clay, silicate and carbon black on the environmental resistance properties of hard rubber

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20210205