CN112307605B - Unidirectional ceramic matrix composite thermal expansion coefficient prediction method considering damage evolution - Google Patents
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Abstract
本发明提供了一种考虑损伤演化的单向陶瓷基复合材料热膨胀系数预测方法,在陶瓷基复合材料受热产生变形过程中,组分中会产生热应力从而产生损伤,损伤的演化会进一步改变组分的应力分布,从而改变材料的宏观变形,从而影响热膨胀系数。本发明考虑了基体开裂和界面滑移等损伤,计算了温度变化导致的界面正反向滑移长度,在计算材料宏观变形时考虑了这些损伤演化对组分应力分布的影响,最终计算得到材料的宏观热应变和热膨胀系数,可以大大提高预测结果的精度。
The present invention provides a method for predicting the thermal expansion coefficient of a unidirectional ceramic matrix composite material taking into account the evolution of damage. During the deformation process of the ceramic matrix composite material due to heat, thermal stress will be generated in the component, thereby causing damage. The evolution of the damage will further change the stress distribution of the component, thereby changing the macroscopic deformation of the material, thereby affecting the thermal expansion coefficient. The present invention takes into account damage such as matrix cracking and interface slip, calculates the forward and reverse slip lengths of the interface caused by temperature changes, takes into account the influence of these damage evolutions on the stress distribution of the component when calculating the macroscopic deformation of the material, and finally calculates the macroscopic thermal strain and thermal expansion coefficient of the material, which can greatly improve the accuracy of the prediction results.
Description
技术领域Technical Field
本发明属于复合材料力学性能预测领域,具体涉及一种考虑损伤演化的单向陶瓷基复合材料热膨胀系数预测方法。The invention belongs to the field of prediction of mechanical properties of composite materials, and in particular relates to a method for predicting thermal expansion coefficient of unidirectional ceramic-based composite materials taking damage evolution into consideration.
背景技术Background technique
陶瓷基复合材料由于具有高耐温性和低密度的优点,是航空航天飞行器热端部件的理想材料。作为热端部件,陶瓷基复合材料结构工作时温度变化范围较大,从而引起热变形。因此进行陶瓷基复合材料结构设计要求设计人员能准确预测材料的热膨胀系数。目前单向陶瓷基复合材料热膨胀系数的预测往往采用线弹性方法,这种方法的一般流程为:1)通过试验或理论计算获取组分相的热膨胀系数和弹性模量等性能参数;2)建立能反映细观结构特征的RVE模型;3)将组分相性能参数代入到RVE模型中,通过均匀化计算得到单向陶瓷基复合材料的热膨胀系数。如文献[申诗典.基于XCT技术的陶瓷基复合材料热膨胀系数预测.南京:南京航空航天大学,2017.]和[Michaux A,Sauder C,Camus G,et al.Young′smodulus,thermal expansion coefficient and fracture behavior of selected Si-B-C based carbides in the 20-1200℃ temperature range as derived from thebehavior of carbon fiber reinforced microcomposites[J].Journal ofthe EuropeanCeramic Society,2007,27(12):3551-3560.]。这种预测方法并未考虑陶瓷基复合材料热膨胀过程中的损伤演化,认为复合材料的热膨胀系数仅取决于组分的热膨胀系数和弹性参数。事实上,在陶瓷基复合材料受热变形过程中,组分中会产生热应力从而产生损伤,损伤的演化会进一步改变材料的宏观变形,从而影响热膨胀系数,因此仅采用现有的线弹性方法是无法准确预测单向陶瓷基复合材料热膨胀系数的。Ceramic matrix composites are ideal materials for hot-end components of aerospace vehicles due to their high temperature resistance and low density. As hot-end components, ceramic matrix composite structures have a large temperature variation range during operation, which causes thermal deformation. Therefore, the design of ceramic matrix composite structures requires designers to accurately predict the thermal expansion coefficient of the material. At present, the prediction of the thermal expansion coefficient of unidirectional ceramic matrix composites often uses the linear elastic method. The general process of this method is: 1) Obtain the performance parameters such as the thermal expansion coefficient and elastic modulus of the component phase through experiments or theoretical calculations; 2) Establish an RVE model that can reflect the microstructural characteristics; 3) Substitute the performance parameters of the component phase into the RVE model, and obtain the thermal expansion coefficient of the unidirectional ceramic matrix composite through homogenization calculation. For example, the literature [Shen Shidian. Prediction of thermal expansion coefficient of ceramic matrix composites based on XCT technology. Nanjing: Nanjing University of Aeronautics and Astronautics, 2017.] and [Michaux A, Sauder C, Camus G, et al. Young's modulus, thermal expansion coefficient and fracture behavior of selected Si-B-C based carbides in the 20-1200℃ temperature range as derived from the behavior of carbon fiber reinforced microcomposites [J]. Journal of the European Ceramic Society, 2007, 27 (12): 3551-3560.]. This prediction method does not take into account the damage evolution during the thermal expansion of ceramic matrix composites, and believes that the thermal expansion coefficient of the composite material depends only on the thermal expansion coefficient and elastic parameters of the components. In fact, during the thermal deformation of ceramic matrix composites, thermal stress will be generated in the components, resulting in damage. The evolution of damage will further change the macroscopic deformation of the material, thereby affecting the thermal expansion coefficient. Therefore, it is impossible to accurately predict the thermal expansion coefficient of unidirectional ceramic matrix composites using only the existing linear elastic method.
当前如何准确预测单向陶瓷基复合材料的热膨胀系数,是本领域重要而难以解决的技术问题。Currently, how to accurately predict the thermal expansion coefficient of unidirectional ceramic matrix composites is an important and difficult to solve technical problem in this field.
发明内容Summary of the invention
本发明针对现有技术中的不足,提供一种考虑损伤演化的单向陶瓷基复合材料热膨胀系数预测方法。In view of the deficiencies in the prior art, the present invention provides a method for predicting the thermal expansion coefficient of a unidirectional ceramic matrix composite material taking damage evolution into consideration.
为实现上述目的,本发明采用以下技术方案:To achieve the above object, the present invention adopts the following technical solutions:
考虑损伤演化的单向陶瓷基复合材料热膨胀系数预测方法,其特征在于,包括如下步骤:A method for predicting thermal expansion coefficient of unidirectional ceramic matrix composite materials considering damage evolution is characterized by comprising the following steps:
步骤1:分别计算室温T1下的纤维热应力和基体热应力;Step 1: Calculate the fiber thermal stress and matrix thermal stress at room temperature T1 respectively;
步骤2:由室温T1下的基体热应力计算室温下的基体裂纹间距;Step 2: Calculate the matrix crack spacing at room temperature from the matrix thermal stress at room temperature T1 ;
步骤3:由室温T1下的纤维热应力计算室温下的界面正向滑移长度;Step 3: Calculate the interface forward slip length at room temperature based on the fiber thermal stress at room temperature T1 ;
步骤4:计算温度升高至T2后的纤维热应力;Step 4: Calculate the thermal stress of the fiber after the temperature rises to T 2 ;
步骤5:由室温T1下的界面正向滑移长度和温度T2下的纤维热应力,计算温度升高至T2导致的界面反向滑移长度;Step 5: Calculate the interface reverse slip length caused by the temperature rising to T 2 based on the interface forward slip length at room temperature T 1 and the fiber thermal stress at temperature T 2 ;
步骤6:根据室温T1下的纤维热应力和界面正向滑移长度、温度T2下的纤维热应力和界面反向滑移长度,计算温度由T1升至T2的单向陶瓷基复合材料热应变;Step 6: Calculate the thermal strain of the unidirectional ceramic matrix composite when the temperature rises from T 1 to T 2 based on the fiber thermal stress and interface forward slip length at room temperature T 1 and the fiber thermal stress and interface reverse slip length at temperature T 2 ;
步骤7:根据温度由T1升至T2的单向陶瓷基复合材料热应变,计算温度T1至T2间的单向陶瓷基复合材料热膨胀系数。Step 7: Calculate the thermal expansion coefficient of the unidirectional ceramic matrix composite material between temperatures T 1 and T 2 based on the thermal strain of the unidirectional ceramic matrix composite material when the temperature increases from T 1 to T 2 .
为优化上述技术方案,采取的具体措施还包括:To optimize the above technical solutions, the specific measures taken also include:
进一步地,步骤1中,计算纤维热应力的方法为:Furthermore, in step 1, the method for calculating the fiber thermal stress is:
计算基体热应力的方法为:The method for calculating the thermal stress of the matrix is:
式中,σf,1和σm,1分别为室温T1下纤维和基体的热应力,Ef和Em分别为纤维和基体的弹性模量,vf和vm分别为纤维和基体的体积分数,αf和αm分别为纤维和基体的热膨胀系数,T0为陶瓷基复合材料的制备温度。Wherein, σf ,1 and σm ,1 are the thermal stresses of the fiber and the matrix at room temperature T1 , Ef and Em are the elastic moduli of the fiber and the matrix, vf and vm are the volume fractions of the fiber and the matrix, αf and αm are the thermal expansion coefficients of the fiber and the matrix, and T0 is the preparation temperature of the ceramic matrix composite material.
进一步地,步骤3中,计算界面正向滑移长度的方法为:Furthermore, in step 3, the method for calculating the interface forward slip length is:
式中,d+为室温T1下的界面正向滑移长度,rf为纤维单丝半径,τ为界面剪应力,σf,1为室温T1下的纤维热应力。Where d + is the interface forward slip length at room temperature T1 , rf is the fiber single filament radius, τ is the interface shear stress, and σf ,1 is the fiber thermal stress at room temperature T1 .
进一步地,步骤4中,计算纤维热应力的方法为:Furthermore, in step 4, the method for calculating the fiber thermal stress is:
式中,σf,2为温度T2下的纤维热应力,Ef和Em分别为纤维和基体的弹性模量,vf和vm分别为纤维和基体的体积分数,αf和αm分别为纤维和基体的热膨胀系数,T0为陶瓷基复合材料的制备温度。Wherein, σf ,2 is the thermal stress of the fiber at temperature T2 , Ef and Em are the elastic moduli of the fiber and the matrix, respectively, vf and vm are the volume fractions of the fiber and the matrix, respectively, αf and αm are the thermal expansion coefficients of the fiber and the matrix, respectively, and T0 is the preparation temperature of the ceramic matrix composite material.
进一步地,步骤5中,计算界面反向滑移长度的方法为:Furthermore, in step 5, the method for calculating the interface reverse slip length is:
式中,d-为温度T2下的界面反向滑移长度,rf为纤维单丝半径,τ为界面剪应力,σf,2为温度T2下的纤维热应力,d+为室温T1下的界面正向滑移长度。Wherein, d- is the reverse slip length of the interface at temperature T2 , rf is the radius of the fiber single filament, τ is the interface shear stress, σf ,2 is the fiber thermal stress at temperature T2 , and d + is the forward slip length of the interface at room temperature T1 .
进一步地,步骤6中,计算单向陶瓷基复合材料热应变的方法为:Further, in step 6, the method for calculating the thermal strain of the unidirectional ceramic matrix composite material is:
式中,为温度由T1升至T2时陶瓷基复合材料的热应变,L为室温T1下的基体裂纹间距,Ef为纤维的弹性模量,rf为纤维单丝半径,αf为纤维的热膨胀系数,τ为界面剪应力,d+为室温T1下的界面正向滑移长度,d-为温度T2下的界面反向滑移长度,σf,1为室温T1下的纤维热应力,σf,2为温度T2下的纤维热应力。In the formula, is the thermal strain of the ceramic matrix composite material when the temperature rises from T1 to T2 , L is the matrix crack spacing at room temperature T1 , Ef is the elastic modulus of the fiber, rf is the radius of the fiber single filament, αf is the thermal expansion coefficient of the fiber, τ is the interface shear stress, d + is the interface forward slip length at room temperature T1 , d- is the interface reverse slip length at temperature T2 , σf ,1 is the fiber thermal stress at room temperature T1 , and σf ,2 is the fiber thermal stress at temperature T2 .
进一步地,步骤7中,计算单向陶瓷基复合材料热膨胀系数的方法为:Further, in step 7, the method for calculating the thermal expansion coefficient of the unidirectional ceramic matrix composite material is:
式中,αc为室温T1至温度T2间的单向陶瓷基复合材料热膨胀系数,为温度由T1升至T2时陶瓷基复合材料的热应变。Where αc is the thermal expansion coefficient of the unidirectional ceramic matrix composite material between room temperature T1 and temperature T2 , is the thermal strain of the ceramic matrix composite material when the temperature rises from T1 to T2 .
本发明的有益效果是:本发明提供了一种考虑损伤演化的单向陶瓷基复合材料热膨胀系数预测方法,在陶瓷基复合材料受热产生变形过程中,组分中会产生热应力从而产生损伤,损伤的演化会进一步改变组分的应力分布,从而改变材料的宏观变形,从而影响热膨胀系数。本发明考虑了基体开裂和界面滑移等损伤,计算了温度变化导致的界面正反向滑移长度,在计算材料宏观变形时考虑了这些损伤演化对组分应力分布的影响,最终计算得到材料的宏观热应变和热膨胀系数,可以大大提高预测结果的精度。The beneficial effects of the present invention are as follows: the present invention provides a method for predicting the thermal expansion coefficient of a unidirectional ceramic matrix composite material taking into account the evolution of damage. In the process of deformation of the ceramic matrix composite material caused by heat, thermal stress will be generated in the component, thereby causing damage. The evolution of the damage will further change the stress distribution of the component, thereby changing the macroscopic deformation of the material, thereby affecting the thermal expansion coefficient. The present invention takes into account damage such as matrix cracking and interface slip, calculates the forward and reverse slip lengths of the interface caused by temperature changes, takes into account the influence of these damage evolutions on the stress distribution of the component when calculating the macroscopic deformation of the material, and finally calculates the macroscopic thermal strain and thermal expansion coefficient of the material, which can greatly improve the accuracy of the prediction results.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是本发明预测单向陶瓷基复合材料热膨胀系数的流程图。FIG. 1 is a flow chart of the present invention for predicting the thermal expansion coefficient of a unidirectional ceramic matrix composite material.
图2是室温下基体开裂与界面正向滑移示意图。Figure 2 is a schematic diagram of matrix cracking and interface positive slip at room temperature.
图3是温度升高时界面反向滑移示意图。FIG3 is a schematic diagram of interface reverse slip when the temperature rises.
图4是本发明预测结果与目前线弹性方法预测结果的对比图。FIG. 4 is a comparison diagram of the prediction results of the present invention and the prediction results of the current linear elastic method.
附图标记如下:1-纤维,2-基体,3-正向滑移区域,4-反向滑移区域,5-未滑移区域。The reference numerals are as follows: 1 - fiber, 2 - matrix, 3 - positive slip region, 4 - reverse slip region, 5 - non-slip region.
具体实施方式Detailed ways
现在结合附图对本发明作进一步详细的说明。The present invention will now be described in further detail with reference to the accompanying drawings.
本发明提供一种考虑损伤演化的单向陶瓷基复合材料热膨胀系数预测方法,如图1所示,该方法包括以下步骤:The present invention provides a method for predicting the thermal expansion coefficient of a unidirectional ceramic matrix composite material taking into account damage evolution, as shown in FIG1 , the method comprising the following steps:
步骤1:分别计算室温T1下的纤维热应力σf,1和基体热应力σm,1:Step 1: Calculate the fiber thermal stress σ f,1 and matrix thermal stress σ m,1 at room temperature T 1 respectively:
步骤2:如图2所示,由室温T1下的基体热应力σm,1计算室温下的基体裂纹间距L。Step 2: As shown in FIG2 , the matrix crack spacing L at room temperature is calculated from the matrix thermal stress σ m,1 at room temperature T 1.
步骤3:如图2所示,由室温T1下的纤维热应力计算室温下的界面正向滑移长度 Step 3: As shown in Figure 2, the interface forward slip length at room temperature is calculated from the fiber thermal stress at room temperature T1
步骤4:计算温度升高至T2后的纤维热应力σf,2:Step 4: Calculate the fiber thermal stress σ f,2 after the temperature rises to T 2 :
步骤5:如图3所示,计算温度升高至T2导致的界面反向滑移长度 Step 5: As shown in Figure 3, calculate the interface reverse slip length caused by increasing the temperature to T2
步骤6:计算温度由T1升至T2的陶瓷基复合材料热应变 Step 6: Calculate the thermal strain of the ceramic matrix composite when the temperature rises from T1 to T2
步骤7:计算温度T1至T2间的陶瓷基复合材料热膨胀系数 Step 7: Calculate the thermal expansion coefficient of the ceramic matrix composite between temperatures T 1 and T 2
为了使本领域技术人员更好地理解本申请中的技术方案和有益效果,本申请在实施例中针对单向SiC/SiC陶瓷基复合材料进行不同温度(T2=100、200……1500℃)下热膨胀系数预测。该材料的基本参数如下:Ef=140GPa,Em=350GPa,αf=3.1×10-6/℃,αm=4.6×10-6/℃,vf=0.325,vm=0.675,rf=6.5μm,T0=1000℃,τ=17MPa。In order to enable those skilled in the art to better understand the technical solutions and beneficial effects of the present application, the present application predicts the thermal expansion coefficient of unidirectional SiC/SiC ceramic matrix composite materials at different temperatures (T 2 =100, 200...1500°C) in the embodiments. The basic parameters of the material are as follows: E f =140 GPa, Em =350 GPa, α f =3.1×10 -6 /°C, α m =4.6×10 -6 /°C, v f =0.325, v m =0.675, r f =6.5 μm, T 0 =1000°C, τ =17 MPa.
计算室温T1=25℃下的纤维热应力σf,1和基体热应力σm,1:Calculate the fiber thermal stress σ f,1 and matrix thermal stress σ m,1 at room temperature T 1 = 25°C:
计算室温下的基体裂纹间距L,本实施例中采用常见的Weibull模型计算该基体裂纹间距:The matrix crack spacing L at room temperature is calculated. In this embodiment, the common Weibull model is used to calculate the matrix crack spacing:
式中,模型参数Lsat=0.2mm,σ0=60MPa,m=3。Wherein, the model parameters are L sat =0.2 mm, σ 0 =60 MPa, and m=3.
计算室温下的界面正向滑移长度为 The interface forward slip length at room temperature is calculated as
计算温度升高至T2=100℃后的纤维热应力σf,2:Calculate the fiber thermal stress σ f,2 after the temperature rises to T 2 = 100°C:
计算温度升高至T2=100℃后的界面反向滑移长度 Calculate the reverse slip length of the interface after the temperature rises to T 2 = 100°C
计算温度由T1=25℃升至T2=100℃的单向SiC/SiC陶瓷基复合材料热应变 Calculation of thermal strain of unidirectional SiC/SiC ceramic matrix composites when the temperature rises from T 1 = 25°C to T 2 = 100°C
计算温度T2=100℃时的单向SiC/SiC陶瓷基复合材料热膨胀系数 Calculation of thermal expansion coefficient of unidirectional SiC/SiC ceramic matrix composites at temperature T 2 = 100°C
同理计算得到T2=200、300……1500℃下的单向SiC/SiC陶瓷基复合材料热膨胀系数,如图4所示。Similarly, the thermal expansion coefficient of the unidirectional SiC/SiC ceramic matrix composite material at T2=200, 300...1500°C is calculated, as shown in FIG4 .
本实施例还采用现有的线弹性方法预测了单向SiC/SiC陶瓷基复合材料不同温度下的热膨胀系数,如图4所示。可以看出线弹性方法由于未考虑损伤演化的影响,预测的热膨胀系数明显偏大。This embodiment also uses the existing linear elastic method to predict the thermal expansion coefficient of the unidirectional SiC/SiC ceramic matrix composite material at different temperatures, as shown in Figure 4. It can be seen that the linear elastic method predicts a significantly larger thermal expansion coefficient because it does not consider the influence of damage evolution.
需要注意的是,发明中所引用的如“上”、“下”、“左”、“右”、“前”、“后”等的用语,亦仅为便于叙述的明了,而非用以限定本发明可实施的范围,其相对关系的改变或调整,在无实质变更技术内容下,当亦视为本发明可实施的范畴。It should be noted that the terms such as "upper", "lower", "left", "right", "front", "back", etc. cited in the invention are only for the convenience of description and are not used to limit the scope of implementation of the present invention. Changes or adjustments to their relative relationships should be regarded as the scope of implementation of the present invention without substantially changing the technical content.
以上仅是本发明的优选实施方式,本发明的保护范围并不仅局限于上述实施例,凡属于本发明思路下的技术方案均属于本发明的保护范围。应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理前提下的若干改进和润饰,应视为本发明的保护范围。The above are only preferred embodiments of the present invention. The protection scope of the present invention is not limited to the above embodiments. All technical solutions under the concept of the present invention belong to the protection scope of the present invention. It should be pointed out that for ordinary technicians in this technical field, some improvements and modifications without departing from the principle of the present invention should be regarded as the protection scope of the present invention.
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