CN112275123A - Flue gas desulfurization device for sintering by sodium-calcium double-alkali method - Google Patents

Flue gas desulfurization device for sintering by sodium-calcium double-alkali method Download PDF

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Publication number
CN112275123A
CN112275123A CN202011228378.9A CN202011228378A CN112275123A CN 112275123 A CN112275123 A CN 112275123A CN 202011228378 A CN202011228378 A CN 202011228378A CN 112275123 A CN112275123 A CN 112275123A
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pipe
liquid
tank
flue gas
absorption tower
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许常河
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Anhui Haotian Biotechnology Co ltd
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Anhui Haotian Biotechnology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • B01D46/023Pockets filters, i.e. multiple bag filters mounted on a common frame
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a flue gas desulfurization device for sintering by a sodium-calcium double-alkali method, and relates to the technical field of flue gas desulfurization. The device comprises a bag-type dust collector, a fan, an absorption tower, a demisting tower, a first slurry tank, a first lye tank, a sedimentation tank, a second slurry tank, a second lye tank, a filter pressing device and a chimney. The invention solves the problem that in the practical application of the dual-alkali desulphurization device, the circulating spray liquid still contains solid-phase particles such as gypsum and the like, which causes serious scaling and blockage of system equipment and pipelines, and the invention arranges the first slurry tank, the second slurry tank and the stirring device; so that the sodium hydroxide and the calcium oxide are dissolved more fully in the water, and the reaction with the flue gas is more fully realized to connect the first liquid suction pipe and the first liquid pumping pipe; the first suction pipe sucks the supernatant on the surface of the sedimentation tank, so that the solid particle content in the spray liquid is reduced, and the serious structure and blockage of equipment are reduced.

Description

Flue gas desulfurization device for sintering by sodium-calcium double-alkali method
Technical Field
The invention belongs to the technical field of flue gas desulfurization, and particularly relates to a flue gas desulfurization device for sintering by a sodium-calcium double-alkali method.
Background
Sulfur dioxide contained in the flue gas can cause very serious pollution to the atmospheric environment, seriously destroy the ecological balance, cause great harm to the health of animals, plants and human beings, generate acid rain to a great extent, corrode and destroy buildings, and seriously affect the ecological environment and the living environment. Therefore, related treatment technologies are continuously researched and developed by related departments in order to effectively reduce the harm caused by sulfur dioxide. At present, the technical means for treating sulfur dioxide pollution is mainly flue gas desulfurization, and in industry, the technical means is mainly a wet desulfurization technology. Among them, the wet desulfurization technique has the advantages of high desulfurization efficiency and high reaction speed, and is widely applied to the desulfurization field.
The wet flue gas desulfurization mainly refers to desulfurization treatment and desulfurization product treatment performed in a wet state by a slurry absorbent, a liquid absorbent, and the like. The desulfurization method has the advantages of high desulfurization efficiency, high reaction speed and the like, but in the development process, the problems of easy scaling of equipment, incapability of running due to blockage of equipment and pipelines in severe cases, large engineering investment and high running cost exist. The mature wet desulphurization technology mainly comprises dual-alkali desulphurization, calcium-based desulphurization, ammonia desulphurization, magnesium-based desulphurization and the like.
The double alkali method is to adopt sodium-based desulfurizer to carry out in-tower desulfurization, and because the sodium-based desulfurizer has strong alkalinity, the solubility of reaction products is high after sulfur dioxide is absorbed, and the problems of supersaturation crystallization and scaling blockage can not be caused. On the other hand, the desulfurization product is discharged into a regeneration tank to be reduced and regenerated by calcium hydroxide, and the regenerated sodium-based desulfurizer is pumped back to the desulfurization tower to be recycled.
In the practical application process, because solid-liquid separation is generally carried out by adopting a step-by-step sedimentation tank for sedimentation during solid-liquid separation, two-phase media are difficult to completely separate, and returned circulating spray liquid still contains solid-phase particles such as gypsum and the like, serious scaling and blockage of system equipment and pipelines are caused, the system equipment cannot normally operate, and great troubles and troubles are brought to users.
Disclosure of Invention
The invention aims to provide a sodium-calcium dual-alkali sintering flue gas desulfurization device, which solves the problem that in practical application of a dual-alkali desulfurization device, circulating spray liquid still contains solid-phase particles such as gypsum and the like, so that system equipment and pipelines are seriously scaled and blocked by arranging a first slurry tank, a first alkali liquid pool, a sedimentation tank, a second slurry tank, a second alkali liquid pool and a filter pressing device.
In order to solve the technical problems, the invention is realized by the following technical scheme:
the invention relates to a flue gas desulfurization device for sintering by a sodium-calcium double-alkali method, which comprises a bag-type dust remover, a fan, an absorption tower, a demisting tower, a first slurry tank, a first lye tank, a sedimentation tank, a second slurry tank, a second lye tank, a filter pressing device and a chimney, wherein the bag-type dust remover is connected with the fan; one side of the bag-type dust collector is connected with an air inlet pipe; one end of the fan is provided with an air suction pipe; the other end of the fan is provided with a first exhaust pipe; the air suction pipe is connected with the other side of the bag-type dust collector; the lower part of the absorption tower is provided with an air inlet; a liquid inlet is formed in the upper part of the absorption tower; the first exhaust pipe is connected with an air inlet of the absorption tower; a plurality of spray pipes are arranged in the absorption tower; the spray pipes are uniformly distributed from top to bottom; the absorption tower is connected with the demisting tower through a first flue; a second exhaust pipe is arranged between the demisting tower and the chimney; a water inlet pipe is arranged at the top of the first slurry tank; the first slurry tank is connected with the first alkali liquor pool through a first water delivery pipe; a first liquid pump is arranged between the first alkali liquor pool and the sedimentation tank; the first alkali liquor pool is connected with the first liquid pump through a first liquid pumping pipe; a first liquid discharge pipe is arranged between the first liquid pump and the sedimentation tank; a second liquid pump is arranged between the sedimentation tank and the filter pressing device; the sedimentation tank is connected with the second liquid pump through a second liquid pumping pipe; the second liquid pump is connected with the filter pressing device through a second liquid discharge pipe; the second pulping groove is connected with the second lye pool through a second water delivery pipe; a third liquid pump is arranged between the second alkali liquor pool and the absorption tower; the second alkali liquor pool is connected with the third liquid pump through a third liquid pumping pipe; the third liquid pump is connected with the liquid inlet of the absorption tower through a third liquid discharge pipe; the fourth liquid discharge pipe extends into the sedimentation tank; the sedimentation tank is connected with the third liquid pumping pipe through a first liquid suction pipe; a first control valve is arranged on the first liquid suction pipe; and a second control valve is arranged on the third liquid pumping pipe.
Further, a first feeding box is arranged above the first slurry purifying tank; calcium oxide is filled in the first feeding box; the first feed box is connected with the first slurry purifying tank through a first feed pipe; and a first controller is arranged on the first feeding pipe.
Further, a second feeding box is arranged above the second slurry tank; sodium hydroxide is filled in the second feeding box; the second feed box is connected with the second slurry tank through a second feed pipe; and a second controller is arranged on the second feeding pipe.
Further, the spray pipe is positioned below the liquid inlet; the number of the spray pipes is 3-5.
Furthermore, a spray head is arranged at the bottom of the spray pipe; the spray heads are uniformly distributed on the spray pipe.
Further, the filter pressing device is a plate and frame filter press.
Further, stirring devices are arranged in the first slurry mixing tank and the second slurry mixing tank.
The invention has the following beneficial effects:
1. aiming at the problem that the existing circulating spraying liquid still contains solid-phase particles such as gypsum and the like, which causes serious scaling and blockage of system equipment and pipelines, the first liquid suction pipe and the first liquid pumping pipe are connected; the first suction pipe sucks the supernatant on the surface of the sedimentation tank, so that the solid particle content in the spray liquid is reduced, and the serious structure and blockage of equipment are reduced.
2. The invention is provided with a first slurry mixing tank, a second slurry mixing tank and a stirring device; so that the sodium hydroxide and the calcium oxide are dissolved more fully in the water, and the reaction with the flue gas is more fully realized.
Of course, it is not necessary for any product in which the invention is practiced to achieve all of the above-described advantages at the same time.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic structural diagram of a flue gas desulfurization device for sintering by a sodium-calcium double alkali method.
In the drawings, the components represented by the respective reference numerals are listed below:
the device comprises a bag-type dust collector, a fan, an absorption tower, a demisting tower, a chimney, a first chemical slurry tank, a first alkali liquor pool, a sedimentation tank, a plate-and-frame filter press, a second alkali liquor pool, a second chemical slurry tank, a 12-air inlet pipe, a 13-air inlet, a 14-spray pipe, a first flue, a 16-liquid inlet, a 17-water inlet pipe, a 18-stirring device, a first liquid pump, a second liquid pump, a third liquid pump, a first control valve, and a second control valve, wherein the bag-type dust collector comprises 1-a bag-type dust collector, 2-a fan, a 3-an absorption tower, a 4-a demisting tower, a 5-a chimney.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that the terms "one side", "one end", "the other end", "upper", "top", "middle", "length", "inner", "around", etc., indicate an orientation or positional relationship only for the convenience of describing the present invention and simplifying the description, but do not indicate or imply that the referenced components or elements must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention.
Referring to fig. 1, the invention is a flue gas desulfurization device for sintering by a sodium-calcium double alkali method, comprising a bag-type dust collector 1, a fan 2, an absorption tower 3, a demisting tower 4, a first slurry tank 6, a first alkaline liquid pool 7, a sedimentation tank 8, a second slurry tank 11, a second alkaline liquid pool 10, a filter pressing device and a chimney 5; one side of the bag-type dust collector 1 is connected with an air inlet pipe 12; one end of the fan 2 is provided with an air suction pipe; the other end of the fan 2 is provided with a first exhaust pipe; the air suction pipe is connected with the other side of the bag-type dust collector 1; the lower part of the absorption tower 3 is provided with an air inlet 13; a liquid inlet 16 is arranged at the upper part of the absorption tower 3; the first exhaust pipe is connected with an air inlet 13 of the absorption tower 3; a plurality of spray pipes 14 are arranged in the absorption tower 3; the spray pipes 14 are uniformly distributed from top to bottom; the spray pipe 14 is positioned below the liquid inlet 16; the number of the spray pipes 14 is 3-5; the bottom of the spray pipe 14 is also provided with a spray head; the spray heads are uniformly distributed on the spray pipe 14; the absorption tower 3 is connected with the demisting tower 4 through a first flue 15; a second exhaust pipe is arranged between the demisting tower 4 and the chimney 5; the top of the first slurry tank 6 is provided with a water inlet pipe 17; the first slurry tank 6 is connected with the first lye pool 7 through a first water delivery pipe; stirring devices 18 are arranged in the first slurry preparing tank 6 and the second slurry preparing tank 11; a first charging box is arranged above the first slurry tank 6; the filter pressing device is a plate-and-frame filter press 9; calcium oxide is filled in the first feeding box; the first feed box is connected with the first slurry tank 6 through a first feed pipe; a first controller is arranged on the first feeding pipe; a first liquid pump 19 is arranged between the first alkali liquor pool 7 and the sedimentation pool 8; the first alkali liquor pool 7 is connected with the first liquid pump 19 through a first liquid pumping pipe; a first liquid drainage pipe is arranged between the first liquid pump 19 and the sedimentation tank 8; a second liquid pump 20 is arranged between the sedimentation tank 8 and the filter pressing device; the sedimentation tank 8 is connected with the second liquid pump 20 through a second liquid pumping pipe; the second liquid pump 20 is connected with the filter pressing device through a second liquid discharge pipe; the second pulping tank 11 is connected with the second lye pool 10 through a second water delivery pipe; a second charging box is arranged above the second slurry tank 11; sodium hydroxide is filled in the second feeding box; the second feeding box is connected with the second slurry tank 11 through a second feeding pipe; a second controller is arranged on the second feeding pipe; a third liquid pump 21 is arranged between the second alkali liquor pool 10 and the absorption tower 3; the second alkali liquor pool 10 is connected with the third liquid pump 21 through a third liquid pumping pipe; the third liquid pump 21 is connected with the liquid inlet 16 of the absorption tower 3 through a third liquid discharge pipe; the fourth liquid discharge pipe extends into the sedimentation tank 8; the sedimentation tank 8 is connected with the third liquid pumping pipe through a first liquid suction pipe; the first liquid suction pipe is provided with a first control valve 22; a second control valve 23 is arranged on the third extractor tube.
One specific application of this embodiment is:
firstly, injecting a proper amount of clear water into a first slurry tank 6, opening a first controller, pouring a proper amount of calcium oxide, starting a stirring device 18 in the first slurry tank 6 to enable the calcium oxide and the water to fully react to generate calcium hydroxide, and then introducing a calcium hydroxide solution into a first alkali liquor pool 7 through a first water delivery pipe for standby;
similarly, the second controller is opened, and the prepared sodium hydroxide solution is introduced into the second lye pool 10 for standby; discharging the sintering flue gas into a bag-type dust remover 1, removing most dust in the flue gas under the action of the bag-type dust remover 1, and allowing the flue gas to enter an absorption tower 3 from an air inlet 13 at the lower part of the absorption tower 3 under the action of a fan 2;
starting a third liquid pump 21, sending the sodium hydroxide solution into the absorption tower 3, spraying the sodium hydroxide solution from top to bottom through the spraying pipe 14, allowing the flue gas to flow from bottom to top, allowing the flue gas to fully react with the sodium hydroxide solution, and allowing the solution to flow into the sedimentation tank 8 from a fourth liquid discharge pipe at the bottom of the absorption tower 3;
starting a first liquid pump 19, pouring a calcium hydroxide solution into the sedimentation tank 8, and generating a precipitate after the calcium hydroxide solution reacts with the spray liquid; opening a first control valve 22 on the first liquid suction pipe, closing a second control valve 23 on the third liquid suction pipe, and circularly spraying the supernatant in the sedimentation tank 8 into the absorption tower 3, so that the blockage of the absorption tower 3 is reduced;
the flue gas enters the demisting tower 4 from the absorption tower 3 through the first flue 15 and then is discharged into the atmosphere from the chimney 5; and starting the third liquid pump 21, pumping out the precipitate, and carrying out filter pressing to form blocks under the action of the plate-and-frame filter press 9.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims (7)

1. A flue gas desulfurization device for sintering by a sodium-calcium double-alkali method comprises a bag-type dust collector (1), a fan (2), an absorption tower (3), a demisting tower (4), a first slurry tank (6), a first lye tank (7), a sedimentation tank (8), a second slurry tank (11), a second lye tank (10), a filter pressing device and a chimney (5);
the method is characterized in that:
one side of the bag-type dust collector (1) is connected with an air inlet pipe (12); one end of the fan (2) is provided with an air suction pipe; the other end of the fan (2) is provided with a first exhaust pipe; the air suction pipe is connected with the other side of the bag-type dust collector (1);
the lower part of the absorption tower (3) is provided with an air inlet (13); a liquid inlet (16) is arranged at the upper part of the absorption tower (3); the first exhaust pipe is connected with an air inlet (13) of the absorption tower (3); a plurality of spray pipes (14) are arranged in the absorption tower (3); the spray pipes (14) are uniformly distributed up and down;
the absorption tower (3) is connected with the demisting tower (4) through a first flue (15); a second exhaust pipe is arranged between the demisting tower (4) and the chimney (5); a water inlet pipe (17) is arranged at the top of the first slurry tank (6); the first slurry tank (6) is connected with the first lye pool (7) through a first water delivery pipe;
a first liquid pump (19) is arranged between the first alkali liquor pool (7) and the sedimentation pool (8); the first alkali liquor pool (7) is connected with the first liquid pump (19) through a first liquid pumping pipe; a first liquid discharge pipe is arranged between the first liquid pump (19) and the sedimentation tank (8); a second liquid pump (20) is arranged between the sedimentation tank (8) and the filter pressing device;
the sedimentation tank (8) is connected with the second liquid pump (20) through a second liquid pumping pipe; the second liquid pump (20) is connected with the filter pressing device through a second liquid discharge pipe; the second pulping groove (11) is connected with the second lye pool (10) through a second water delivery pipe;
a third liquid pump (21) is arranged between the second alkali liquor pool (10) and the absorption tower (3); the second alkali liquor pool (10) is connected with the third liquid pump (21) through a third liquid pumping pipe; the third liquid pump (21) is connected with the liquid inlet (16) of the absorption tower (3) through a third liquid discharge pipe;
a fourth liquid discharge pipe is arranged at the bottom of the absorption tower (3) and extends into the sedimentation tank (8); the sedimentation tank (8) is connected with the third liquid pumping pipe through a first liquid suction pipe; a first control valve (22) is arranged on the first liquid suction pipe; and a second control valve (23) is arranged on the third liquid extracting pipe.
2. The flue gas desulfurization device for sintering by the soda-lime double alkali method according to claim 1, characterized in that a first feed box is arranged above the first slurry tank (6); calcium oxide is filled in the first feeding box; the first feed box is connected with the first slurry purifying tank (6) through a first feed pipe; and a first controller is arranged on the first feeding pipe.
3. The flue gas desulfurization device for sintering by the soda-lime double alkali method according to claim 1 or 2, characterized in that a second feed box is arranged above the second slurrying tank (11); sodium hydroxide is filled in the second feeding box; the second feed box is connected with the second slurry tank (11) through a second feed pipe; and a second controller is arranged on the second feeding pipe.
4. The flue gas desulfurization device for sintering by the soda-lime dual-alkali method according to claim 3, characterized in that the spray pipe (14) is positioned below the liquid inlet (16); the number of the spray pipes (14) is 3-5.
5. The flue gas desulfurization device for sintering by soda-lime double alkali method as claimed in claim 1, 2 or 4, characterized in that the bottom of the spray pipe (14) is further provided with a spray head; the spray heads are uniformly distributed on the spray pipe (14).
6. The desulphurization device for flue gas generated by sintering with soda-lime dual alkali method according to claim 5, wherein the filter press device is a plate-and-frame filter press (9).
7. The flue gas desulfurization device for sintering by the soda-lime double alkali method according to claim 1, 2, 4 or 6, characterized in that stirring devices (18) are arranged in the first slurry tank (6) and the second slurry tank (11).
CN202011228378.9A 2020-11-06 2020-11-06 Flue gas desulfurization device for sintering by sodium-calcium double-alkali method Withdrawn CN112275123A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999056857A1 (en) * 1998-05-04 1999-11-11 Wiser Oy Desulfurisation of flue gases by dual alkalisation
CN101879406A (en) * 2010-07-15 2010-11-10 煤炭工业济南设计研究院有限公司 Dual-alkali flue gas desulfurization device and desulfurization method
CN204865519U (en) * 2015-06-30 2015-12-16 江西康翔环保有限公司 Dual alkali scrubbing FGD process dust collector
CN111603903A (en) * 2020-06-08 2020-09-01 碧水蓝天环境工程有限公司 Double-alkali desulphurization device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999056857A1 (en) * 1998-05-04 1999-11-11 Wiser Oy Desulfurisation of flue gases by dual alkalisation
CN101879406A (en) * 2010-07-15 2010-11-10 煤炭工业济南设计研究院有限公司 Dual-alkali flue gas desulfurization device and desulfurization method
CN204865519U (en) * 2015-06-30 2015-12-16 江西康翔环保有限公司 Dual alkali scrubbing FGD process dust collector
CN111603903A (en) * 2020-06-08 2020-09-01 碧水蓝天环境工程有限公司 Double-alkali desulphurization device

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Application publication date: 20210129