CN112267126B - Electrolysis chamber structure and have its electrolysis water disinfection spray bottle - Google Patents
Electrolysis chamber structure and have its electrolysis water disinfection spray bottle Download PDFInfo
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- CN112267126B CN112267126B CN202011147192.0A CN202011147192A CN112267126B CN 112267126 B CN112267126 B CN 112267126B CN 202011147192 A CN202011147192 A CN 202011147192A CN 112267126 B CN112267126 B CN 112267126B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/13—Ozone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/0005—Components or details
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention discloses an electrolytic chamber structure and an electrolyzed water disinfection spray bottle with the same, the electrolytic chamber structure comprises an electrode chip mounting seat, an electrolytic cavity with an upward opening is arranged in the electrode chip mounting seat, a positive electrode chip, a proton exchange membrane and a negative electrode chip are sequentially fixed in the electrolytic cavity from top to bottom, an inlet and an outlet are arranged on the positive electrode chip, a convergence cavity is arranged above the positive electrode chip, a water inlet gap is arranged between the positive electrode chip and the convergence cavity, the convergence cavity is communicated with the inlet and the outlet, an electrolyzed water outlet is arranged at the top of the convergence cavity, a circulation hole which is coaxial with the inlet and the outlet is arranged on the negative electrode chip, and an annular groove is arranged at one end of the circulation hole facing to the proton exchange membrane. The electrolytic chamber structure can electrolyze to generate stable high-concentration ozone water, and the ozone water has stable and excellent disinfection and sterilization effects. Only the push type spray nozzle is pressed, the ozone water spray with excellent disinfection effect can be sprayed out from the electrolytic water disinfection spray bottle.
Description
Technical Field
The invention belongs to the technical field of electrolyzed water, and particularly relates to an electrolysis chamber structure and an electrolyzed water disinfection spray bottle with the same.
Background
Ozone, also known as active oxygen, has extremely strong oxidation characteristics, is one of the strongest oxidants, and is widely recognized as a broad-spectrum efficient sterilization disinfectant in the world. The ozone can remove and kill toxic substances and bacteria in air, water and food, remove odor, and kill common Escherichia coli, streptococcus, Pseudomonas aeruginosa, Staphylococcus aureus, and mold. Ozone is dissolved in water to prepare ozone water which has strong sterilization and disinfection effects, fruits, vegetables, clothes, appliances and the like are cleaned by the ozone water, so that the sterilization can be realized, pesticide, chemical hormone, germs, peculiar smell and the like remained on the surface can be effectively removed, and the freshness date of food can be prolonged.
Chinese patent CN202010150913.7 discloses an ozone water disinfection spray bottle, which comprises a spray head and a bottle body connected with each other, wherein a water storage cavity and an ozone generation cavity are arranged in the bottle body, a partition plate is arranged between the water storage cavity and the ozone generation cavity, an opening is arranged on the partition plate to communicate the water storage cavity with the ozone generation cavity, an ozone generator is arranged in the ozone generation cavity, the spray head is connected with a suction pipe, and the suction pipe extends into the ozone generation cavity through the opening; wherein, the diamond anode plate, the proton exchange membrane and the stainless steel cathode plate of the ozone generator are sequentially fixed in an electrode plate seat from top to bottom. Although the spray bottle can obtain high-concentration ozone water by arranging the partition plate, due to the structural problems of the ozone generation cavity and the ozone generator, ozone and hydrogen generated by the ozone generator are discharged to the ozone generation cavity together, and the concentration of the ozone water is unstable due to the existence of the hydrogen, so that the disinfection effect is not good enough.
Disclosure of Invention
The invention aims to provide an electrolytic chamber structure and an electrolytic water disinfection spray bottle with the same, so as to solve the problems in the background technology.
The technical scheme adopted for solving the technical problems is as follows: the utility model provides an electrolysis chamber structure, includes the electrode chip mount pad, be equipped with opening electrolysis chamber up in the electrode chip mount pad, be fixed with positive electrode chip, proton exchange membrane and negative electrode chip in proper order from top to bottom in the electrolysis chamber, be equipped with the business turn over hole on the positive electrode chip, the top of positive electrode chip is equipped with assembles the chamber, the positive electrode chip with it is equipped with into water clearance to assemble between the chamber, assemble the chamber with the business turn over hole switches on, the top of assembling the chamber is equipped with the electrolysis water export, be equipped with on the negative electrode chip with the circulation hole of the coaxial setting in business turn over hole, the circulation hole is in the orientation proton exchange membrane's one end is provided with the ring channel.
Further, the positive electrode chip is a diamond electrode chip, and the negative electrode chip is a stainless steel electrode chip.
Further, the height of the water inlet gap is 0.7-1.5 mm.
Furthermore, the convergence cavity is in a circular truncated cone shape.
Furthermore, an elastic component is arranged in the gathering cavity, and two ends of the elastic component are respectively abutted to the positive electrode chip and the bottom surface of the top of the gathering cavity.
Further, it is equipped with a plurality of fixed archs to assemble the interval on the periphery wall in chamber, the interval is equipped with a plurality of fixed recesses on the inner wall in electrolysis chamber, it passes through to assemble the chamber fixed protruding with fixed recess's inlay card is connected and is realized fixedly.
The invention also provides an electrolyzed water disinfection spray bottle which comprises a shell, wherein a water storage cavity and an equipment cavity are arranged in the shell, an electrolysis chamber structure, a control circuit board and a power supply are arranged in the equipment cavity, the electrolysis chamber structure is the electrolysis chamber structure, the electrolysis chamber structure is communicated with the water storage cavity, a press type spray nozzle is arranged at the top of the shell and is connected with a suction pipe, the suction pipe extends into the gathering cavity through an electrolyzed water outlet of the electrolysis chamber structure, the control circuit board is respectively and electrically connected with the power supply and the electrolysis chamber structure, and the press type spray nozzle is pressed or loosened to connect or cut off a circuit between the control circuit board and the power supply.
Furthermore, a water level probe is arranged in an electrolysis cavity of the electrolysis chamber structure, and the water level probe is respectively electrically connected with the control circuit board and the power supply.
Further, an electrolyzed water outlet of the electrolysis chamber structure is provided with an inverted truncated cone inclined surface.
Compared with the prior art, the technical scheme of the invention has the following advantages:
according to the electrolytic chamber structure and the electrolyzed water disinfection spray bottle with the same, the structure of the electrolytic chamber structure is improved, the position relation of the positive electrode chip and the negative electrode chip is adjusted, the annular groove is formed, so that most of ozone gas generated by the positive electrode chip can be concentrated in the convergence cavity through the inlet and outlet holes, and hydrogen gas generated by the negative electrode chip directly enters the electrolytic cavity and cannot enter the convergence cavity, so that stable high-concentration ozone water (electrolyzed water) can be formed in the convergence cavity, and the ozone water has stable and excellent disinfection and sterilization effects.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the structures shown in the drawings without creative efforts.
FIG. 1 is a schematic perspective view of an electrolytic cell structure according to the present invention;
FIG. 2 is a schematic view of the internal structure of an electrolytic cell structure according to the present invention;
FIG. 3 is a schematic view of the structure of a negative electrode chip in an electrolytic cell structure according to the present invention;
FIG. 4 is a schematic diagram of the connection between the structure of the electrolytic chamber of the electrolyzed water sterilizing spray bottle and the suction pipe and the water level probe.
The reference numbers illustrate: 1-electrode chip mounting base; 2-an electrolysis chamber; 3-positive electrode chip; 4-a proton exchange membrane; 5-a negative electrode chip; 6-access hole; 7-a convergence cavity; 8-water inlet gap; 9-an electrolyzed water outlet; 10-flow-through holes; 11-an annular groove; 12-an elastic member; 13-fixing the projection; 14-fixing the groove; 15-suction pipe; 16-water level probe.
The implementation, functional features and advantages of the objects of the present invention will be further explained with reference to the accompanying drawings.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It should be noted that, if directional indications (such as up, down, left, right, front, and back … …) are involved in the embodiment of the present invention, the directional indications are only used to explain the relative positional relationship between the components, the movement situation, and the like in a specific posture (as shown in the drawing), and if the specific posture is changed, the directional indications are changed accordingly.
Referring to fig. 1 to 3, the invention relates to an electrolytic chamber structure which adopts a low-voltage electrolysis method to generate ozone and comprises an electrode chip mounting seat 1, wherein an electrolytic cavity 2 with an upward opening is arranged in the electrode chip mounting seat 1, a positive electrode chip 3, a proton exchange membrane 4 and a negative electrode chip 5 are sequentially fixed in the electrolytic cavity 2 from top to bottom, an inlet and outlet hole 6 is formed in the positive electrode chip 3, a gathering cavity 7 is arranged above the positive electrode chip 3, a water inlet gap 8 is formed between the positive electrode chip 3 and the gathering cavity 7, the gathering cavity 7 is communicated with the inlet and outlet hole 6, and an electrolyzed water outlet 9 is formed in the top of the gathering cavity 7. When the electrolysis chamber structure carries out electrolysis reaction, water in the electrolysis chamber 2 passes through the water inlet gap 8 and the inlet and outlet holes 6 between the positive electrode chip 3 and the proton exchange membrane 4, most of ozone generated by the electrolysis of the positive electrode chip 3 is concentrated in the convergence chamber 7 through the inlet and outlet holes 6 due to the existence of the inlet and outlet holes 6, and high-concentration ozone water (electrolyzed water) is formed, while the rest of ozone is discharged into the electrolysis chamber 2 from gaps around the positive electrode chip 3 and the proton exchange membrane 4, and hydrogen generated by the electrolysis of the negative electrode chip 5 cannot enter the convergence chamber 7 through the inlet and outlet due to the blockage of the proton exchange membrane 4, but directly enters the electrolysis chamber 2. The ozone water formed in the converging cavity 7 has high and stable concentration and excellent disinfection effect because no intervention of hydrogen exists. In addition, the negative electrode chip 5 is provided with a circulation hole 10 which is coaxial with the inlet and outlet hole 6, and the arrangement of the circulation hole 10 is beneficial to discharging hydrogen generated by electrolysis between the negative electrode chip 5 and the proton exchange membrane 4 and preventing scale from forming on the negative electrode chip 5. The annular groove 11 is arranged at one end of the circulation hole 10 facing the proton exchange membrane 4, and the annular groove 11 enables the pressure of the joint between the area corresponding to the annular groove 11 on the positive electrode chip 3 and the proton exchange membrane 4 to be smaller than the pressure of the joint between other areas, so that ozone between the positive electrode chip 3 and the proton exchange membrane 4 and hydrogen between the negative electrode chip 5 and the proton exchange membrane 4 can be easily discharged from the inlet and outlet hole 6 and the circulation hole 10 respectively, and high-concentration ozone water can be formed in the convergence cavity 7. Further, in another embodiment, the same effect can be achieved by disposing the flow hole 10 and the access hole 6 coaxially, and making the hole diameter of the flow hole 10 larger than that of the access hole 6.
As a preferable aspect of the present invention, the positive electrode chip 3 is a diamond electrode chip, and the negative electrode chip 5 is a stainless steel electrode chip, wherein the diamond electrode chip is formed by lining a diamond chip on a substrate. Diamond electrode chip and stainless steel electrode chip are difficult to cause the loss at the electrolysis in-process, can effectively improve the life of electrolysis chamber structure, and the accessory ingredient such as more efficient hydroxyl free radical, oxygen atom in addition to the accessory ingredient that the electrolysis generated can make the whole disinfection effect of brineelectrolysis more environmental protection and more effective.
Preferably, the height of the water inlet gap 8 is 0.7-1.5 mm. In the present embodiment, the height of the water inlet gap 8 is preferably 1mm, which can ensure both the water amount required for the electrolysis reaction between the positive electrode chip 3 and the proton exchange membrane 4 and the small amount of generated ozone to escape from the water inlet gap 8 to the electrolysis chamber 2, thereby maintaining the high concentration of ozone water formed in the convergence chamber 7.
Preferably, the converging cavity 7 is in a circular truncated cone shape, and the converging cavity 7 with a large lower part and a small upper part is beneficial to collecting ozone coming out of the inlet and outlet holes 6.
In a preferred embodiment of the present invention, the collecting chamber 7 is provided with an elastic member 12 therein, and both ends of the elastic member 12 are respectively in contact with the positive electrode chip 3 and the top bottom surface of the collecting chamber 7. The elastic member 12 may preferably be a tower spring, a spring, or a leaf spring. In the present embodiment, the elastic component 12 is a spring, and the spring enables the positive electrode chip 3 and the negative electrode chip 5 to elastically return after a severe electrolytic reaction occurs, so as to ensure the accuracy and reliability of the position.
Preferably, a plurality of fixing protrusions 13 are arranged on the outer peripheral wall of the convergence cavity 7 at intervals, a plurality of fixing grooves 14 are arranged on the inner wall of the electrolysis cavity 2 at intervals, and the convergence cavity 7 is fixed by the clamping connection of the fixing protrusions 13 and the fixing grooves 14.
The invention also provides an electrolyzed water disinfection spray bottle which comprises a shell, wherein a water storage cavity and an equipment cavity are arranged in the shell, an electrolysis chamber structure, a control circuit board and a power supply are arranged in the equipment cavity, the electrolysis chamber structure is the electrolysis chamber structure, the electrolysis chamber structure is communicated with the water storage cavity, a press type spray nozzle is arranged at the top of the shell, the press type spray nozzle is connected with a suction pipe 15, the suction pipe 15 extends into the gathering cavity 7 through an electrolyzed water outlet 9 of the electrolysis chamber structure, the control circuit board is respectively and electrically connected with the power supply and the electrolysis chamber structure, and the press type spray nozzle is pressed or loosened to connect or disconnect a circuit between the control circuit board and the power supply. Referring to fig. 4, in the present embodiment, a rounded-off slope is provided at the electrolyzed water outlet 9 for positioning insertion of the suction pipe 15. Before using this electrolytic water disinfection spray bottle, earlier put into water storage chamber, press the push type spray nozzle afterwards, the circuit between electrolysis room structure and the control circuit board and the power forms the closure, and the electrolysis room structure carries out the electrolysis to the water in electrolysis chamber 2 to form stable and high concentration's ozone water (electrolysis water) in assembling chamber 7, the ozone water is atomized under the effect of straw 15 and push type spray nozzle and is spouted, and its disinfection effect is splendid and stable.
Referring to fig. 4, a water level probe 16 is further disposed in the electrolytic chamber 2 of the electrolytic cell structure, and the water level probe 16 is electrically connected to the control circuit board and the power supply, respectively. Specifically, the water level probe 16, the positive electrode chip 3 of the electrolytic chamber structure, the control circuit board and the power supply form a closed loop under the condition that water exists in the electrolytic chamber 2, when the water in the electrolytic chamber 2 is exhausted, the loop is in an open state, and the control circuit board receives an open signal of the loop to control the electrolytic chamber structure to stop working, so that the situation of dry burning without water is avoided.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and all modifications and equivalents of the present invention, which are made by the contents of the present specification and the accompanying drawings, or directly/indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (7)
1. An electrolytic cell structure characterized by: the electrolytic cell comprises an electrode chip mounting seat, wherein an electrolytic cavity with an upward opening is arranged in the electrode chip mounting seat, a positive electrode chip, a proton exchange membrane and a negative electrode chip are sequentially fixed in the electrolytic cavity from top to bottom, an inlet and an outlet are formed in the positive electrode chip, a gathering cavity is arranged above the positive electrode chip, a water inlet gap is formed between the positive electrode chip and the gathering cavity, the gathering cavity is communicated with the inlet and the outlet, an electrolyzed water outlet is formed in the top of the gathering cavity, a circulation hole which is coaxial with the inlet and the outlet is formed in the negative electrode chip, and an annular groove is formed in one end, facing the proton exchange membrane, of the circulation hole; the height of the water inlet gap is 0.7-1.5 mm; the convergence cavity is in a round table shape.
2. An electrolysis cell structure according to claim 1, wherein: the positive electrode chip is a diamond electrode chip, and the negative electrode chip is a stainless steel electrode chip.
3. An electrolysis cell structure according to claim 1, wherein: the inner of the gathering cavity is provided with an elastic component, and two ends of the elastic component are respectively abutted to the positive electrode chip and the bottom surface of the top of the gathering cavity.
4. An electrolysis cell structure according to claim 1, wherein: the periphery wall of the gathering cavity is provided with a plurality of fixing protrusions at intervals, the inner wall of the electrolysis cavity is provided with a plurality of fixing grooves at intervals, and the gathering cavity is fixed by the aid of the fixing protrusions and the clamping and embedding connection of the fixing grooves.
5. An electrolytic water disinfection spray bottle, which is characterized in that: the electrolytic cell structure is any one of claims 1 to 4, the electrolytic cell structure is communicated with the water storage cavity, a pressing type spray nozzle is arranged at the top of the casing and connected with a straw, the straw extends into the aggregation cavity through an electrolytic water outlet of the electrolytic cell structure, the control circuit board is respectively electrically connected with the power supply and the electrolytic cell structure, and the pressing type spray nozzle is connected with a switch-on or a switch-off circuit between the control circuit board and the power supply through pressing or loosening.
6. The electrolyzed water sterilization spray bottle according to claim 5, characterized in that: and a water level probe is also arranged in the electrolytic cavity of the electrolytic chamber structure and is respectively and electrically connected with the control circuit board and the power supply.
7. The electrolyzed water sterilization spray bottle according to claim 5, characterized in that: and an electrolyzed water outlet of the electrolysis chamber structure is provided with an inverted circular truncated cone inclined surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011147192.0A CN112267126B (en) | 2020-10-23 | 2020-10-23 | Electrolysis chamber structure and have its electrolysis water disinfection spray bottle |
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| CN202011147192.0A CN112267126B (en) | 2020-10-23 | 2020-10-23 | Electrolysis chamber structure and have its electrolysis water disinfection spray bottle |
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| CN112267126A CN112267126A (en) | 2021-01-26 |
| CN112267126B true CN112267126B (en) | 2022-03-15 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113913850A (en) * | 2021-12-01 | 2022-01-11 | 广州德百顺蓝钻科技有限公司 | Electrolytic cell with electrode with elastic structure |
| CN115554441A (en) * | 2022-09-28 | 2023-01-03 | 江苏瑞之康智能科技发展有限公司 | Innovative purification, disinfection and killing equipment system |
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| CN111254453A (en) * | 2020-03-27 | 2020-06-09 | 广州市德百顺电气科技有限公司 | Ozone electrolysis chamber and ozone electrolysis chamber application module |
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| CN101250710A (en) * | 2008-03-28 | 2008-08-27 | 陕西科技大学 | Electrolytic ozone generator and preparation technique for cathode catalysis layer thereof |
| CN101698942A (en) * | 2009-02-11 | 2010-04-28 | 徐名勇 | Ozone generator for use in membrane electrode electrolysis |
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