CN112251100A - High-flame-retardant artistic coating and preparation thereof - Google Patents
High-flame-retardant artistic coating and preparation thereof Download PDFInfo
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- CN112251100A CN112251100A CN202011029555.0A CN202011029555A CN112251100A CN 112251100 A CN112251100 A CN 112251100A CN 202011029555 A CN202011029555 A CN 202011029555A CN 112251100 A CN112251100 A CN 112251100A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a high flame-retardant art paint which is prepared from the following raw materials in parts by weight: 10-50 parts by weight of acrylic copolymer; 0.1-5 parts of rheological additive; 0.1 to 0.6 weight portion of dispersant; 0.1-0.6 part by weight of wetting agent; 2-10 parts of a film-forming assistant; 1-5 parts of an antifreeze agent; 0.1-0.5 part by weight of defoaming agent; 0.1-0.3 part by weight of preservative; 0.1-0.5 part of mildew preventive; 0.1-0.8 part of pH regulator; 1-40 parts of water; 10-30 parts of filler; 10-20 parts by weight of pearly-lustre material; the dispersant is flame-retardant polyether polyol, and is prepared from 100 parts of halogen-containing epoxy compound monomer 150 parts, 2-5 parts of initiator and 5-20 parts of flame-retardant catalyst; the halogen-containing epoxy compound monomer is selected from one or more of 4,4, 4-trichloro-1, 2-epoxybutane, 4,4, 4-tribromo-1, 2-epoxybutane or epichlorohydrin; the flame-retardant catalyst is selected from one or more of phosphorus oxychloride, antimony pentoxide and tetrakis (hydroxymethyl) phosphonium chloride; the initiator is selected from propylene glycol. The invention has excellent scratch resistance, high hardness, good hand feeling and strong layering.
Description
Technical Field
The invention relates to the field of art coatings, in particular to a pearlescent art coating, and belongs to the field of blending and construction application of architectural art decorative materials.
Background
With the increasing personalized requirements of the public on the color, the effect and the like of interior wall decorative materials, the white color and the simple color blending of the traditional latex paint are difficult to meet the personalized decorative requirements of consumers. Therefore, the pearlescent art paint is produced at the same time, can be customized in a personalized way, has the decorative effect of wallpaper, becomes the most popular type of art paint, and can present rich and colorful decorative effects, novel effects and luxurious texture according to different types, different colors, different particle sizes and different dosages of pearlescent powder. But the common pearlescent art paint is easy to burn and damaged.
Disclosure of Invention
The invention provides an environment-friendly artistic coating with flame retardance aiming at the problem that a product is easy to burn and damage.
The invention provides a high flame-retardant art paint which is prepared from the following raw materials in parts by weight: 10-50 parts by weight of acrylic copolymer emulsion; 0.1-5 parts of rheological additive; 0.1 to 0.6 weight portion of dispersant; 0.1-0.6 part by weight of wetting agent; 2-10 parts of a film-forming assistant; 1-5 parts of an antifreeze agent; 0.1-0.5 part by weight of defoaming agent; 0.1-0.3 part by weight of preservative; 0.1-0.5 part of mildew preventive; 0.1-0.8 part of pH regulator; 1-40 parts of water; 10-30 parts of filler; 10-20 parts by weight of pearly-lustre material; the dispersing agent is flame-retardant polyether polyol which is prepared from 100-150 parts of halogen-containing epoxy compound monomer, 2-5 parts of initiator and 5-20 parts of flame-retardant catalyst; the halogen-containing epoxy compound monomer is selected from one or more of 4,4, 4-trichloro-1, 2-epoxybutane, 4,4, 4-tribromo-1, 2-epoxybutane or epichlorohydrin; the flame-retardant catalyst is selected from one or more of phosphorus oxychloride, antimony pentoxide and tetrakis (hydroxymethyl) phosphonium chloride; the initiator is selected from propylene glycol.
Further, the filler is selected from one or more of talcum powder, heavy calcium carbonate, kaolin, mica powder, silicon micropowder, sand flour and ground stone powder.
Further, the high flame-retardant art coating also comprises 1-5 parts by weight of fluorine-containing polyether polyol.
Further, the pearly-lustre material is mica pearly-lustre, and the particle size is 10-80 microns.
Further, the rheological additive is one or more of hydroxyethyl cellulose, bentonite, a hydrophobically modified alkali swelling thickener and a polyurethane thickener.
Further, the wetting agent is a non-ionic alkoxylated alcohol surfactant; the film-forming auxiliary agent is a high-boiling-point film-forming auxiliary agent; the defoaming agent is one or more of a mineral oil defoaming agent and an organic silicon surfactant.
Further, the antifreeze agent is FT-68.
Further, the preservative is one or more of cason and BIT; the mildew preventive is one or more of IPBC/BCM/OIT.
Further, the pH regulator is one of ammonia water, NaOH and AMP 95.
Further, the pearlescent effect material is colorful artistic resin, the colorful artistic resin comprises resin particles, a base material and a pigment are wrapped in the resin particles, the resin particles are selected from one or more of polypropylene resin, polycarbonate resin, nylon resin, polyether ether ketone resin and polyether sulfone resin, the base material is nano inorganic particles, and the particle size of the nano inorganic particles is 1-100 nm.
Further, the nano inorganic particles are mica powder.
Still further, the pigment is selected from one or more of inorganic pigment and organic pigment, the inorganic pigment is selected from one or more of carbon black, iron oxide red and Prussian blue, and the organic pigment is selected from one or more of azo pigment, phthalocyanine pigment and quinacridone pigment.
Still further, the pigment may further comprise a fluorescent dye.
Further, the preparation method of the multicolor art resin comprises the following steps:
step 1: taking resin particle monomer raw materials into the solution, adding the base materials, and oscillating to form uniform mixed solution;
step 2: coating and curing the mixed solution to form a coating;
and step 3: crushing and grinding the coating to obtain resin particles with 300-400 meshes;
and 4, step 4: soaking resin particles in the solution, adding pigment and resin particle monomer raw materials, and oscillating to form uniform mixed solution;
and 5: coating and curing the mixed solution to form a coating;
step 6: the coating is crushed and ground to obtain 50-100 meshes of resin particles, namely the colorful artistic resin.
Furthermore, the preparation method of the colorful art resin comprises the following steps:
step 1: taking 50-100 parts by weight of resin particle monomer raw material into 10-30 parts by weight of solution, adding 1-5 parts by weight of base material, and oscillating to form uniform mixed solution;
step 2: coating and curing the mixed solution to form a coating;
and step 3: crushing and grinding the coating to obtain resin particles with 300-400 meshes;
and 4, step 4: soaking resin particles in 10-50 parts by weight of solution, adding 2-10 parts by weight of pigment and 100-200 parts by weight of resin particle monomer raw materials, and oscillating to form uniform mixed solution;
and 5: coating and curing the mixed solution to form a coating;
step 6: the coating is crushed and ground to obtain 50-100 meshes of resin particles, namely the colorful artistic resin.
Further, the solution in the step 1 is water.
Further, the resin particle monomer in step 1 is one or more of a monomer with a hydroxyl group and a monomer with an amino group, and 10-20% by weight of the resin particle monomer in step 4 is a diisocyanate monomer.
Further, the solution in the step 4 is acetone.
The invention also discloses a preparation method of the high-flame-retardant artistic coating, which comprises the following steps:
step 1, fully mixing water and 40-60% of rheological additive for 5-10 min;
step 2, adding a wetting agent, a dispersing agent, a defoaming agent, a film-forming additive and a pH regulator into the liquid obtained in the step 1 in sequence, and mixing and stirring for 5-10 min;
step 3, adding 20-60% of filler into the mixture obtained in the step 2, dispersing for 15-20 minutes, adding the pearlescent effect material, and stirring for 5-10 minutes;
and 4, sequentially adding the preservative, the mildew preventive, the antifreeze, the emulsion, the residual rheological additive and the residual effect filler into the mixture obtained in the step 3, and stirring for 10-15 min.
The artistic coating suitable for interior decoration provided by the invention has the advantages of strong flame retardance, simple construction, capability of being coated by patting, excellent scratch resistance, high hardness, good hand feeling and strong layering, can be randomly matched with conventional water-based color paste when being applied to interior wall decoration construction, and can achieve protection and good decoration and beautification effects through easy construction.
Detailed Description
In order to make the technical solutions of the present invention better understood by those skilled in the art, the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
The specific preparation method of the high flame-retardant artistic coating provided by the embodiment of the invention comprises the following steps:
step 1, fully mixing water and 40% of rheological additive for 10 min;
step 2, adding a wetting agent, a dispersing agent, a defoaming agent, a film-forming additive and a pH regulator into the liquid obtained in the step 1 in sequence, and mixing and stirring for 10 min; wherein, the dispersant comprises 150 parts of epichlorohydrin 100-;
step 3, adding 60% of filler into the mixture obtained in the step 2, dispersing for 15-20 minutes, adding the pearlescent effect material, and stirring for 10 minutes;
and 4, sequentially adding the preservative, the mildew preventive, the antifreeze, the emulsion, the residual rheological additive and the residual effect filler into the mixture obtained in the step 3, and stirring for 15 min.
The compositions of examples 1 to 4 of the present invention are specifically shown in the following table (unit: kg).
The pearly luster effect materials of the embodiments 1 and 2 are mica pearly luster, the pearly luster effect material of the embodiment 3 is mica pearly luster and fluorescent green powder, and the weight ratio of the mica pearly luster to the fluorescent green powder is 10: 1 weight ratio.
The pearlescent effect material of embodiment 4 is colorful artistic resin, and the specific preparation method is as follows:
the preparation method of the colorful art resin provided by the embodiment of the invention comprises the following steps:
step 1: taking 25 parts by weight of hydroxyl acrylate and 25 parts by weight of amino acrylate into 30 parts by weight of water, adding 5 parts by weight of 1-100nm mica powder, and oscillating to form uniform mixed liquid;
step 2: coating and curing the mixed solution, and drying at 150 ℃ for 4 hours to form a coating;
and step 3: crushing, grinding and sieving the coating to obtain 300-400 mesh resin particles;
and 4, step 4: soaking resin particles in 50 parts by weight of water, adding 10 parts by weight of pigment and 100 parts by weight of hydroxyl acrylate, and uniformly oscillating; wherein, the pigment is titanium dioxide and fluorescent green powder according to the weight ratio of 1: 0.5 weight ratio.
And 5: coating and curing the mixed solution, and drying at 150 ℃ for 4 hours to form a coating;
step 6: the coating is crushed, ground and sieved to obtain resin particles of 50-100 meshes, namely the colorful artistic resin of the embodiment 3 of the invention.
The coatings of examples 1 to 4 of the invention were applied to a thickness of 1 to 2mm and cured to give coatings of examples 1 to 3 of the invention. The coatings of examples 1-4 of the present invention were tested for performance, and the results are shown in the following table:
the high-flame-retardant artistic coating disclosed by the embodiment of the invention is simple in construction and strong in flame retardance, can effectively reduce the combustion risk of the artistic coating, and is outstanding in environmental protection performance: meets the standard of JG/T481-2015 low-Volatility Organic Compound (VOC) aqueous interior wall coating material, and belongs to a low-emission product; the construction is extremely simple: the pearly luster effect with strong layering can be easily realized through a simple coating method and random coating and zero process.
In the embodiment 4 of the present invention, the base material and the pigment are wrapped in the resin particles, so as to provide a stable storage environment for the pigment, and compared with the embodiment 3, the corrosion of corrosive substances such as tetrakis (hydroxymethyl) phosphonium chloride to the fluorescent dye is avoided, the stability of the pigment is improved, and when the finish paint is not used, the good protection effect can be provided, and the possibility of pigment falling off is reduced. Meanwhile, in the embodiment 4 of the invention, the functional group structure of the resin particles is utilized, and the resin and the rest components of the coating can be utilized for secondary polymerization during coating, so that the stability of the pigment in the coating is improved, and the color fading risk is reduced. In addition, in the embodiment 4 of the present invention, the isophorone diisocyanate is used, and the fast polymerization reaction can be performed with the hydroxyl group and the amino group on the surface of the fine particle, so that the pigment is fixed in the fine particle, and the possibility that the pigment falls off from the fine particle is reduced.
Finally, it should be noted that the above-mentioned embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the same, and although the present invention is described in detail with reference to the above-mentioned embodiments, it should be understood by those skilled in the art that the modifications and equivalents of the specific embodiments of the present invention can be made by those skilled in the art after reading the present specification, but these modifications and variations do not depart from the scope of the claims of the present application.
Claims (10)
1. The high-flame-retardant art paint is characterized by comprising the following raw materials in parts by weight: 10-50 parts by weight of acrylic copolymer emulsion; 0.1-5 parts of rheological additive; 0.1 to 0.6 weight portion of dispersant; 0.1-0.6 part by weight of wetting agent; 2-10 parts of a film-forming assistant; 1-5 parts of an antifreeze agent; 0.1-0.5 part by weight of defoaming agent; 0.1-0.3 part by weight of preservative; 0.1-0.5 part of mildew preventive; 0.1-0.8 part of pH regulator; 1-40 parts of water; 10-30 parts of filler; 10-20 parts by weight of pearly-lustre material; the dispersing agent is flame-retardant polyether polyol which is prepared from 100-150 parts of halogen-containing epoxy compound monomer, 2-5 parts of initiator and 5-20 parts of flame-retardant catalyst; the halogen-containing epoxy compound monomer is selected from one or more of 4,4, 4-trichloro-1, 2-epoxybutane, 4,4, 4-tribromo-1, 2-epoxybutane or epichlorohydrin; the flame-retardant catalyst is selected from one or more of phosphorus oxychloride, antimony pentoxide and tetrakis (hydroxymethyl) phosphonium chloride; the initiator is selected from propylene glycol.
2. The high flame retardant art paint as claimed in claim 1, wherein the filler is selected from one or more of talcum powder, heavy calcium carbonate, kaolin, mica powder, silica powder, sand flour and ground stone powder.
3. The high flame retardant art paint as claimed in claim 1, wherein the pearlescent effect is mica pearlescent, and the particle size is 10-80 μm.
4. The high flame retardant art paint according to claim 1, wherein the rheological additive is one or more of hydroxyethyl cellulose, bentonite, a hydrophobically modified alkali swelling thickener and a polyurethane thickener.
5. The high flame retardant art coating according to claim 1, wherein the wetting agent is a nonionic alkoxylated alcohol surfactant; the film-forming auxiliary agent is a high-boiling-point film-forming auxiliary agent; the defoaming agent is one or more of a mineral oil defoaming agent and an organic silicon surfactant.
6. The high flame retardant art paint according to claim 1, wherein the antifreeze agent is FT-68.
7. The high flame retardant artistic coating according to claim 1, wherein the preservative is one or more of cason and BIT; the mildew preventive is one or more of IPBC/BCM/OIT.
8. The high fire retardant art paint as claimed in claim 1, wherein the pH regulator is one of ammonia, NaOH and AMP 95.
9. The high flame retardant art paint as claimed in claim 1, wherein the high flame retardant art paint further comprises 1-5 parts by weight of fluorine-containing polyether polyol.
10. The method for preparing the high flame-retardant artistic coating according to any one of claims 1 to 9, comprising the steps of:
step 1, fully mixing water and 40-60% of rheological additive for 5-10 min;
step 2, adding a wetting agent, a dispersing agent, a defoaming agent, a film-forming additive and a pH regulator into the liquid obtained in the step 1 in sequence, and mixing and stirring for 5-10 min;
step 3, adding 20-60% of filler into the mixture obtained in the step 2, dispersing for 15-20 minutes, adding the pearlescent effect material, and stirring for 5-10 minutes;
and 4, sequentially adding the preservative, the mildew preventive, the antifreeze, the emulsion, the residual rheological additive and the residual effect filler into the mixture obtained in the step 3, and stirring for 10-15 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011029555.0A CN112251100B (en) | 2020-09-27 | 2020-09-27 | High-flame-retardant artistic coating and preparation thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011029555.0A CN112251100B (en) | 2020-09-27 | 2020-09-27 | High-flame-retardant artistic coating and preparation thereof |
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| CN112251100A true CN112251100A (en) | 2021-01-22 |
| CN112251100B CN112251100B (en) | 2022-01-28 |
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|---|---|---|---|---|
| US20170183514A1 (en) * | 2013-05-02 | 2017-06-29 | Melior Innovations, Inc. | Black ceramic additives, pigments, and formulations |
| CN106947380A (en) * | 2017-03-15 | 2017-07-14 | 广东中星科技股份有限公司 | A kind of environmental protection flame retardant anticorrosive paint based on polyurethane |
| CN107663399A (en) * | 2017-11-16 | 2018-02-06 | 中山市阿里大师新材料有限公司 | One kind batch scratch-type pearl effect art coatings and preparation method thereof |
| CN109608972A (en) * | 2018-11-14 | 2019-04-12 | 广东嘉宝莉科技材料有限公司 | Functional art coatings and its preparation method and application |
| CN109679427A (en) * | 2018-12-25 | 2019-04-26 | 广东美涂士建材股份有限公司 | Low-volatile water-soluble pearlescent effect art coatings and preparation method thereof |
-
2020
- 2020-09-27 CN CN202011029555.0A patent/CN112251100B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170183514A1 (en) * | 2013-05-02 | 2017-06-29 | Melior Innovations, Inc. | Black ceramic additives, pigments, and formulations |
| CN106947380A (en) * | 2017-03-15 | 2017-07-14 | 广东中星科技股份有限公司 | A kind of environmental protection flame retardant anticorrosive paint based on polyurethane |
| CN107663399A (en) * | 2017-11-16 | 2018-02-06 | 中山市阿里大师新材料有限公司 | One kind batch scratch-type pearl effect art coatings and preparation method thereof |
| CN109608972A (en) * | 2018-11-14 | 2019-04-12 | 广东嘉宝莉科技材料有限公司 | Functional art coatings and its preparation method and application |
| CN109679427A (en) * | 2018-12-25 | 2019-04-26 | 广东美涂士建材股份有限公司 | Low-volatile water-soluble pearlescent effect art coatings and preparation method thereof |
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| CN112251100B (en) | 2022-01-28 |
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