CN112251098A - Waterproof heat-insulation exterior wall coating for building and preparation method thereof - Google Patents
Waterproof heat-insulation exterior wall coating for building and preparation method thereof Download PDFInfo
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Abstract
The invention discloses a waterproof heat-insulating exterior wall coating for buildings and a preparation method thereof, wherein the waterproof heat-insulating exterior wall coating comprises the following components: the coating comprises fluorine-silicon modified acrylic emulsion, graphene-acrylic acid composite emulsion, silica sol, activated carbon fiber powder, fluorosilane, titanium dioxide and auxiliaries, wherein the auxiliaries comprise a dispersing agent, a wetting agent, a thickening agent, a defoaming agent, a film-forming auxiliary and an antifreezing agent. The preparation method of the waterproof heat-insulation exterior wall coating for the building comprises the following steps: firstly, uniformly mixing silica sol, activated carbon fiber powder and titanium dioxide, then adding the fluorosilicone modified acrylic emulsion and the graphene-acrylic acid composite emulsion, uniformly mixing, adding the auxiliary agent, uniformly mixing, and finally mixing with fluorosilane. The waterproof heat-insulation exterior wall coating for the building has excellent waterproof and heat-insulation performance, is self-cleaning and washable, and is suitable for various external environments.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a waterproof heat-insulation exterior wall coating for buildings and a preparation method thereof.
Background
The building exterior wall coating is a coating coated on the whole building exterior wall, and has the main functions of decorating and protecting the exterior wall, so that the building looks flat and beautiful, and the building is protected. Exterior wall coatings need to be exposed to outdoor environments and are subject to greater environmental severity than interior wall coatings, especially in certain southern wet areas where the water-resistant function of the exterior wall coating is more demanding.
In the prior art, the acrylic emulsion is often used as a base material, and the prepared water-based acrylic coating has the advantages of moderate cost, good adjustability and the like. However, the water-based acrylic coating on the market is often hot, sticky and cold and brittle, is easy to crack in a dry environment with the temperature lower than 0 ℃ for a long time in winter in the north of China, needs to play a certain heat preservation role, and is easy to permeate water vapor, rainwater and the like into wall surfaces and corrode wall bodies in a warm and humid environment in the south of China, so that the attractiveness of buildings is influenced, and the service life of the buildings is shortened. Therefore, the prepared exterior wall coating with good waterproof and heat-insulating effects and excellent comprehensive performance still has wide application prospect.
Disclosure of Invention
The invention provides the waterproof heat-insulation exterior wall coating for the building, which has the advantages of superior waterproof heat-insulation performance, self-cleaning and washing resistance and is suitable for various external environments, aiming at overcoming the defects of the prior art.
The invention provides a waterproof heat-insulation exterior wall coating for buildings, which comprises the following components: the coating comprises fluorine-silicon modified acrylic emulsion, graphene-acrylic acid composite emulsion, silica sol, activated carbon fiber powder, fluorosilane, titanium dioxide and auxiliaries, wherein the auxiliaries comprise a dispersing agent, a wetting agent, a thickening agent, a defoaming agent, a film-forming auxiliary and an antifreezing agent.
Optionally, the preparation method of the fluorosilicone modified acrylic emulsion comprises the following steps:
(1) uniformly mixing methacrylate, alkyl acrylate, hydroxyalkyl ester and a crosslinking monomer to obtain acrylic emulsion;
(2) dissolving an initiator and an emulsifier with water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (4) adding an organic silicon monomer and a fluorine monomer into the mixture obtained in the step (3), uniformly mixing, and carrying out microwave heating to obtain the fluorine-silicon modified acrylic emulsion.
The preparation method of the graphene-acrylic acid composite emulsion comprises the following steps:
(1) uniformly mixing methacrylate, alkyl acrylate, hydroxyalkyl ester and a crosslinking monomer to obtain acrylic emulsion;
(2) dissolving an initiator and an emulsifier with water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (4) adding graphene into the mixture obtained in the step (3), uniformly mixing, and carrying out microwave heating to obtain the graphene-acrylic acid composite emulsion.
Optionally, the mass parts of the components are as follows: 40-60 parts of fluorine-silicon modified acrylic emulsion; 20-30 parts of graphene-acrylic acid composite emulsion; 10-20 parts of silica sol; 10-20 parts of activated carbon fiber powder; 10-20 parts of fluorosilane; 20-30 parts of titanium dioxide; 1-8 parts of an auxiliary agent; 15-35 parts of water; the mass ratio of the fluorine-silicon modified acrylic emulsion to the graphene-acrylic acid composite emulsion is (1.5-2.5): 1, and the solid content of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic acid composite emulsion is 50-60%.
Alternatively, the methacrylate is one or more of methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate and amyl methacrylate; the alkyl acrylate is one or more of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate and amyl acrylate; the hydroxyalkyl ester is one or more of 2-hydroxyethyl acrylate, 3-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 2-hydroxyethyl methacrylate and 2-hydroxypropyl methacrylate; the crosslinking monomer is one or more of acrylic acid and methacrylic acid; the emulsifier is sodium alkyl benzene sulfonate or ammonium alkyl benzene sulfonate; the initiator is ammonium persulfate, sodium persulfate or potassium persulfate; the organosilicon monomer is one or more of methyl chlorosilane, phenyl chlorosilane, methyl vinyl chlorosilane, ethyl trichlorosilane, propyl trichlorosilane and vinyl trichlorosilane; the fluorine monomer is one or more of m-trifluoromethyl styrene, 3, 5-bis-trifluoromethyl styrene and pentafluorostyrene.
Optionally, in the preparation method of the fluorosilicone modified acrylic emulsion, the components in parts by mass are as follows: 30-50 parts of methacrylate; 10-20 parts of alkyl acrylate; 5-10 parts of hydroxyalkyl ester; 5-10 parts of a crosslinking monomer; 2-5 parts of an initiator; 2-5 parts of an emulsifier; 5-10 parts of an organic silicon monomer; 10-15 parts of a fluorine monomer; 20-40 parts of water;
in the preparation method of the graphene-acrylic acid composite emulsion, the mass parts of the components are 30-50 parts of methacrylate; 10-20 parts of alkyl acrylate; 5-10 parts of hydroxyalkyl ester; 5-10 parts of a crosslinking monomer; 2-5 parts of an initiator; 2-5 parts of an emulsifier; 1-3 parts of graphene; 20-40 parts of water; .
Optionally, the activated carbon fiber powder has an average particle size of 200-400 mesh.
Optionally, in the preparation method of the fluorosilicone modified acrylic emulsion, the microwave heating temperature is 30-50 ℃, the time is 3-5 hours, and the pH is adjusted to 7-9; in the preparation method of the graphene-acrylic acid composite emulsion, the temperature of microwave heating is 30-50 ℃, the time is 1-3h, and the pH value is adjusted to 7-9.
Optionally, the dispersant is sodium hexametaphosphate or dispersant 5040; the wetting agent is CO-630; the thickening agent is hydroxyethyl cellulose; the defoaming agent is mineral oil or organic silicon defoaming agent; the film-forming additive is dodecyl alcohol ester; the antifreezing agent is ethylene glycol.
In addition, the invention also provides a method for preparing the waterproof heat-insulation exterior wall coating for the building, which comprises the following steps: firstly, uniformly mixing silica sol, activated carbon fiber powder and titanium dioxide, then adding the fluorosilicone modified acrylic emulsion and the graphene-acrylic acid composite emulsion, uniformly mixing, adding the auxiliary agent, uniformly mixing, and finally mixing with fluorosilane.
The invention has the following beneficial effects:
(1) the addition of the fluorosilicone modified acrylic emulsion can effectively overcome the self defects of hot stickiness and cold brittleness of the acrylic emulsion, successfully retains the alkali resistance of the acrylic emulsion, has comprehensive weather resistance and water resistance, is suitable for various complex external environments, and can ensure the service life no matter in the north or the south of China. The addition of the graphene-acrylic acid composite emulsion effectively improves the stability and corrosion resistance of the coating, also improves the glossiness of the coating, and is suitable for external walls with strict decoration requirements. The addition of the fluorosilane forms a cross-linked structure with the fluorosilane modified acrylic emulsion and the graphene-acrylic acid composite emulsion, so that a synergistic effect is achieved, and the waterproofness and the strength of the coating are greatly improved.
(2) In the preparation process of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic composite emulsion, the addition of the activated carbon fiber powder provides fine and dense adsorption sites for modification, the modification effect can be achieved under low-temperature microwave heating (30-50 ℃) or even normal temperature, the modification efficiency is improved, and the water resistance of the coating is further ensured.
(3) The activated carbon fiber powder has rich pore channels and many surface active sites, and forms a closed air island structure after being mixed with the fluorine-silicon modified acrylic emulsion, the graphene-acrylic acid composite emulsion and the silica sol, thereby generating an excellent heat preservation effect.
(4) In the preparation method provided by the invention, the addition timing of the fluorosilane can not only promote the formation of the cross-linked structure, but also protect the cross-linked structure from being damaged to the maximum extent.
(5) The waterproof heat-insulating exterior wall coating for buildings provided by the invention does not contain benzene and aldehydes, and is friendly to human body and environment.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the invention, as claimed.
Detailed Description
The invention provides the waterproof heat-insulation exterior wall coating for the building, which has the advantages of superior waterproof heat-insulation performance, self-cleaning and washing resistance and is suitable for various external environments, aiming at overcoming the defects of the prior art. The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The first waterproof heat-insulation exterior wall coating for the building provided by the embodiment comprises the following components in parts by mass:
50 parts of fluorine-silicon modified acrylic emulsion
25 parts of graphene-acrylic acid composite emulsion
Fluorosilane 15 parts
15 portions of silica sol
15 portions of activated carbon fiber powder
Titanium dioxide 25 parts
Auxiliary agent 5 parts
And 25 parts of water.
Wherein: the solid contents of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic acid composite emulsion are 50-60%; the average grain diameter of the activated carbon fiber powder is 200-400 meshes; the dispersant is sodium hexametaphosphate; the wetting agent is CO-630; the thickening agent is hydroxyethyl cellulose; the defoaming agent is mineral oil; the film-forming additive is dodecyl alcohol ester; the antifreezing agent is ethylene glycol.
Example 2
The second waterproof heat-insulation exterior wall coating for the building provided by the embodiment comprises the following components in parts by mass:
50 parts of fluorine-silicon modified acrylic emulsion
20 parts of graphene-acrylic acid composite emulsion
Fluorosilane 20 parts
20 portions of silica sol
20 portions of activated carbon fiber powder
30 parts of titanium dioxide
Auxiliary agent 8 parts
35 parts of water.
Wherein: the solid contents of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic acid composite emulsion are 50-60%; the average grain diameter of the activated carbon fiber powder is 200-400 meshes; the dispersant is dispersant 5040; the wetting agent comprises CO-630; the thickening agent is hydroxyethyl cellulose; the defoaming agent is an organic silicon defoaming agent; the film-forming additive is dodecyl alcohol ester; the antifreezing agent is ethylene glycol.
Example 3
The third waterproof heat-insulating exterior wall coating for buildings provided by the embodiment comprises the following components in parts by mass:
45 parts of fluorine-silicon modified acrylic emulsion
15 parts of graphene-acrylic acid composite emulsion
10 parts of fluorosilane
10 portions of silica sol
10 portions of activated carbon fiber powder
Titanium dioxide 20 parts
Auxiliary agent 1 part
And 15 parts of water.
Wherein: the solid contents of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic acid composite emulsion are 50-60%; the average grain diameter of the activated carbon fiber powder is 200-400 meshes; the dispersant is sodium hexametaphosphate; the wetting agent is CO-630; the thickening agent is hydroxyethyl cellulose; the defoaming agent is mineral oil; the film-forming additive is dodecyl alcohol ester; the antifreezing agent is ethylene glycol.
Example 4
The fourth waterproof heat-insulation exterior wall coating for buildings provided by the embodiment comprises the following components in parts by mass:
60 parts of fluorine-silicon modified acrylic emulsion
28 parts of graphene-acrylic acid composite emulsion
Fluorosilane 13 parts
18 portions of silica sol
18 portions of activated carbon fiber powder
Titanium dioxide 20 parts
Auxiliary agent 5 parts
And 30 parts of water.
Wherein: the solid contents of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic acid composite emulsion are 50-60%; the average grain diameter of the activated carbon fiber powder is 200-400 meshes; the dispersant is sodium hexametaphosphate; the wetting agent is CO-630; the thickening agent is hydroxyethyl cellulose; the defoaming agent is mineral oil; the film-forming additive is dodecyl alcohol ester; the antifreezing agent is ethylene glycol.
Description of preparation methods of fluorosilicone modified acrylic emulsion and graphene-acrylic composite emulsion:
first, description of preparation method:
1. the preparation method of the fluorine-silicon modified acrylic emulsion comprises the following steps:
(1) uniformly mixing methacrylate, alkyl acrylate, hydroxyalkyl ester and a crosslinking monomer to obtain acrylic emulsion;
(2) dissolving an initiator and an emulsifier with water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (4) adding an organic silicon monomer and a fluorine monomer into the mixture obtained in the step (3), uniformly mixing, and carrying out microwave heating to obtain the fluorine-silicon modified acrylic emulsion.
2. The preparation method of the graphene-acrylic acid composite emulsion comprises the following steps:
(1) uniformly mixing methacrylate, alkyl acrylate, hydroxyalkyl ester and a crosslinking monomer to obtain acrylic emulsion;
(2) dissolving an initiator and an emulsifier with water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (4) adding graphene into the mixture obtained in the step (3), uniformly mixing, and carrying out microwave heating to obtain the graphene-acrylic acid composite emulsion.
Second, description of components:
the fluorosilane is heptadecafluorodecyltrimethoxysilane or tridecafluorooctyltrimethoxysilane. The methacrylate is one or more of methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate and amyl methacrylate. The alkyl acrylate is one or more of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate and amyl acrylate. The hydroxyalkyl ester is one or more of 2-hydroxyethyl acrylate, 3-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 2-hydroxyethyl methacrylate and 2-hydroxypropyl methacrylate. The crosslinking monomer is one or more of acrylic acid and methacrylic acid. The emulsifier is sodium alkyl benzene sulfonate or ammonium alkyl benzene sulfonate. The initiator is ammonium persulfate, sodium persulfate or potassium persulfate; the organic silicon monomer is one or more of methyl chlorosilane, phenyl chlorosilane, methyl vinyl chlorosilane, ethyl trichlorosilane, propyl trichlorosilane and vinyl trichlorosilane. The fluorine monomer is one or more of m-trifluoromethyl styrene, 3, 5-bis-trifluoromethyl styrene and pentafluorostyrene. The average grain diameter of the activated carbon fiber powder is 200-400 meshes.
Thirdly, explaining the component proportion:
1. in the preparation method of the fluorine-silicon modified acrylic emulsion, the components in parts by weight are as follows:
30-50 parts of methacrylate
10-20 parts of alkyl acrylate
5-10 parts of hydroxyalkyl ester
5-10 parts of crosslinking monomer
2-5 parts of initiator
2-5 parts of emulsifier
5-10 parts of organic silicon monomer
10-15 parts of fluorine monomer
20-40 parts of water.
2. In the preparation method of the graphene-acrylic acid composite emulsion, the components are as follows in parts by mass:
30-50 parts of methacrylate
10-20 parts of alkyl acrylate
5-10 parts of hydroxyalkyl ester
5-10 parts of crosslinking monomer
2-5 parts of initiator
2-5 parts of emulsifier
1-3 parts of graphene
20-40 parts of water.
Fourth, reaction conditions are described:
1. in the preparation method of the fluorosilicone modified acrylic emulsion, the microwave heating temperature is 30-50 ℃, the time is 3-5h, and the pH is adjusted to 7-9.
2. In the preparation method of the graphene-acrylic acid composite emulsion, the temperature of microwave heating is 30-50 ℃, the time is 1-3h, and the pH value is adjusted to 7-9.
Fifth, the preparation methods of the fluorosilicone modified acrylic emulsion and the graphene-acrylic composite emulsion in the above embodiments 1 to 4 are as follows:
1. the preparation method of the fluorine-silicon modified acrylic emulsion comprises the following steps:
(1) weighing 40 parts of ethyl methacrylate, 10 parts of ethyl acrylate, 10 parts of 2-hydroxyethyl acrylate, 8 parts of methacrylic acid, 3 parts of sodium persulfate, 2 parts of ammonium alkyl benzene sulfonate, 2 parts of graphene and 40 parts of water in parts by mass. Uniformly mixing ethyl methacrylate, ethyl acrylate, 2-hydroxyethyl acrylate and methacrylic acid to obtain an acrylic emulsion;
(2) dissolving sodium persulfate and ammonium alkyl benzene sulfonate in water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (3) adding vinyltrichlorosilane and m-trifluoromethylstyrene into the mixture obtained in the step (3), uniformly mixing, adjusting the pH to 7-9, and heating for 4 hours at 30 ℃ by using microwave to obtain the fluorosilicone modified acrylic emulsion.
2. The preparation method of the graphene-acrylic acid composite emulsion comprises the following steps:
(1) weighing 40 parts of ethyl methacrylate, 10 parts of ethyl acrylate, 10 parts of 2-hydroxyethyl acrylate, 8 parts of methacrylic acid, 3 parts of sodium persulfate, 2 parts of ammonium alkyl benzene sulfonate, 7 parts of vinyl trichlorosilane, 14 parts of m-trifluoromethylstyrene and 40 parts of water in parts by mass. Uniformly mixing ethyl methacrylate, ethyl acrylate, 2-hydroxyethyl acrylate and methacrylic acid to obtain an acrylic emulsion;
(2) dissolving sodium persulfate and ammonium alkyl benzene sulfonate in water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (3) adding graphene into the mixture obtained in the step (3), uniformly mixing, adjusting the pH value to 7-9, and heating for 2 hours at 30 ℃ by using microwaves to obtain the graphene-acrylic acid composite emulsion.
Preparation and detection results of waterproof heat-insulation exterior wall coating for building
The invention also provides a preparation method of the waterproof heat-insulation exterior wall coating for the building, which comprises the following steps: firstly, uniformly mixing silica sol, activated carbon fiber powder and titanium dioxide, then adding the fluorosilicone modified acrylic emulsion and the graphene-acrylic acid composite emulsion, uniformly mixing, adding the auxiliary agent, uniformly mixing, and finally mixing with fluorosilane.
In the preparation method provided by the invention, the addition timing of the fluorosilane can not only promote the formation of the cross-linked structure, but also protect the cross-linked structure from being damaged to the maximum extent. Accordingly, the reliability of the above conclusion can be verified through comparative experiments. Whether the fluorine-silicon modified acrylic emulsion and the graphene-acrylic composite emulsion are added before, or between the fluorine-silicon modified acrylic emulsion and the graphene-acrylic composite emulsion, or between the two acrylic emulsions and the auxiliary agent, the water resistance and heat preservation test results of the coating are lower than those of the coating prepared by the preparation method.
And detection shows that the coating is resistant to washing and brushing: examples 1-4 all had > 8000 times.
Artificial aging resistance test: at 800 hours, examples 1-4 did not blister, peel, or crack.
Water resistance test: examples 1 to 4 all had no abnormality for 96 hours.
Stain resistance test: examples 1 to 4 all had < 10%.
Low-temperature stability: examples 1-43 cycles did not deteriorate.
Coefficient of thermal conductivity: the thermal conductivity of examples 1 to 4 was less than 0.45W/m.k.
The above embodiments of the present invention do not limit the scope of the present invention.
Other embodiments of the invention will be apparent to those skilled in the art from consideration of the specification and practice of the disclosure herein. This invention is intended to cover any variations, uses, or adaptations of the invention following, in general, the principles of the invention and including such departures from the present disclosure as come within known or customary practice within the art to which the invention pertains. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the invention being indicated by the following claims.
Claims (9)
1. The waterproof heat-insulation exterior wall coating for the building is characterized by comprising the following components: the coating comprises fluorine-silicon modified acrylic emulsion, graphene-acrylic acid composite emulsion, silica sol, activated carbon fiber powder, fluorosilane, titanium dioxide and auxiliaries, wherein the auxiliaries comprise a dispersing agent, a wetting agent, a thickening agent, a defoaming agent, a film-forming auxiliary and an antifreezing agent.
2. The waterproof heat-insulating exterior wall coating for buildings according to claim 1, wherein the preparation method of the fluorosilicone modified acrylic emulsion comprises the following steps:
(1) uniformly mixing methacrylate, alkyl acrylate, hydroxyalkyl ester and a crosslinking monomer to obtain acrylic emulsion;
(2) dissolving an initiator and an emulsifier with water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) adding an organic silicon monomer and a fluorine monomer into the mixture obtained in the step (3), uniformly mixing, and carrying out microwave heating to obtain a fluorine-silicon modified acrylic emulsion;
the preparation method of the graphene-acrylic acid composite emulsion comprises the following steps:
(1) uniformly mixing methacrylate, alkyl acrylate, hydroxyalkyl ester and a crosslinking monomer to obtain acrylic emulsion;
(2) dissolving an initiator and an emulsifier with water to obtain an auxiliary agent solution;
(3) dripping the assistant solution into the acrylic emulsion, uniformly mixing, and then adding activated carbon fiber powder;
(4) and (4) adding graphene into the mixture obtained in the step (3), uniformly mixing, and carrying out microwave heating to obtain the graphene-acrylic acid composite emulsion.
3. The waterproof heat-insulation exterior wall coating for buildings according to claim 1 is characterized by comprising the following components in parts by mass: 40-60 parts of fluorine-silicon modified acrylic emulsion; 20-30 parts of graphene-acrylic acid composite emulsion; 10-20 parts of silica sol; 10-20 parts of activated carbon fiber powder; 10-20 parts of fluorosilane; 20-30 parts of titanium dioxide; 1-8 parts of an auxiliary agent; 15-35 parts of water;
the mass ratio of the fluorine-silicon modified acrylic emulsion to the graphene-acrylic acid composite emulsion is (1.5-2.5): 1, and the solid content of the fluorine-silicon modified acrylic emulsion and the graphene-acrylic acid composite emulsion is 50-60%.
4. The waterproof and heat-insulating exterior wall coating for buildings according to claim 2, wherein the methacrylate is one or more of methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate and amyl methacrylate;
the alkyl acrylate is one or more of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate and amyl acrylate;
the hydroxyalkyl ester is one or more of 2-hydroxyethyl acrylate, 3-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 2-hydroxyethyl methacrylate and 2-hydroxypropyl methacrylate;
the crosslinking monomer is one or more of acrylic acid and methacrylic acid;
the emulsifier is sodium alkyl benzene sulfonate or ammonium alkyl benzene sulfonate;
the initiator is ammonium persulfate, sodium persulfate or potassium persulfate;
the organic silicon monomer is one or more of methyl chlorosilane, phenyl chlorosilane, methyl vinyl chlorosilane, ethyl trichlorosilane, propyl trichlorosilane and vinyl trichlorosilane;
the fluorine monomer is one or more of m-trifluoromethyl styrene, 3, 5-bis-trifluoromethyl styrene and pentafluorostyrene.
5. The waterproof heat-insulation exterior wall coating for buildings according to claim 2 is characterized in that in the preparation method of the fluorosilicone modified acrylic emulsion, the mass parts of the components are as follows: 30-50 parts of methacrylate; 10-20 parts of alkyl acrylate; 5-10 parts of hydroxyalkyl ester; 5-10 parts of a crosslinking monomer; 2-5 parts of an initiator; 2-5 parts of an emulsifier; 5-10 parts of an organic silicon monomer; 10-15 parts of a fluorine monomer; 20-40 parts of water;
in the preparation method of the graphene-acrylic acid composite emulsion, the mass parts of the components are 30-50 parts of methacrylate; 10-20 parts of alkyl acrylate; 5-10 parts of hydroxyalkyl ester; 5-10 parts of a crosslinking monomer; 2-5 parts of an initiator; 2-5 parts of an emulsifier; 1-3 parts of graphene; 20-40 parts of water.
6. The waterproof and heat-insulating exterior wall coating for buildings according to claim 2, wherein the activated carbon fiber powder has an average particle size of 200-400 mesh.
7. The waterproof heat-insulating exterior wall coating for buildings according to claim 2, wherein in the preparation method of the fluorosilicone modified acrylic emulsion, the temperature of microwave heating is 30-50 ℃, the time is 3-5h, and the pH is adjusted to 7-9;
in the preparation method of the graphene-acrylic acid composite emulsion, the temperature of microwave heating is 30-50 ℃, the time is 1-3h, and the pH is adjusted to 7-9.
8. The waterproof and heat-insulating exterior wall coating for buildings according to claim 1, wherein the dispersant is sodium hexametaphosphate or 5040; the wetting agent is CO-630; the thickening agent is hydroxyethyl cellulose; the defoaming agent is mineral oil or organic silicon defoaming agent; the film-forming additive is dodecyl alcohol ester; the antifreezing agent is ethylene glycol.
9. The preparation method of the waterproof and heat-insulating exterior wall coating for the building as claimed in any one of claims 1 to 8, characterized by comprising the following steps: firstly, uniformly mixing silica sol, activated carbon fiber powder and titanium dioxide, then adding the fluorosilicone modified acrylic emulsion and the graphene-acrylic acid composite emulsion, uniformly mixing, adding the auxiliary agent, uniformly mixing, and finally mixing with fluorosilane.
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Cited By (2)
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| CN113004732A (en) * | 2021-03-04 | 2021-06-22 | 沪宝新材料科技（上海）股份有限公司 | Formula and preparation method of antibacterial coating |
| CN113999581A (en) * | 2021-11-24 | 2022-02-01 | 集美大学 | Graphene-modified water-based acrylic acid-based corrosion-resistant damping material and preparation method thereof |
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| CN112251098B (en) | 2021-09-21 |
| CN114031996A (en) | 2022-02-11 |
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