CN112198275A - Textile and clothing product grey water footprint accounting and evaluating method based on dilution influence - Google Patents
Textile and clothing product grey water footprint accounting and evaluating method based on dilution influence Download PDFInfo
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- 238000010790 dilution Methods 0.000 title claims abstract description 50
- 239000012895 dilution Substances 0.000 title claims abstract description 50
- 239000010797 grey water Substances 0.000 title claims abstract description 50
- 239000004753 textile Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 120
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 51
- 231100000719 pollutant Toxicity 0.000 claims abstract description 51
- 230000007613 environmental effect Effects 0.000 claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 claims abstract description 20
- 239000008239 natural water Substances 0.000 claims abstract description 11
- 238000007865 diluting Methods 0.000 claims abstract description 8
- 239000002351 wastewater Substances 0.000 claims description 36
- 230000000694 effects Effects 0.000 claims description 15
- 238000012851 eutrophication Methods 0.000 claims description 14
- 238000011156 evaluation Methods 0.000 claims description 14
- 230000020477 pH reduction Effects 0.000 claims description 14
- 239000000356 contaminant Substances 0.000 claims description 12
- 231100000584 environmental toxicity Toxicity 0.000 claims description 12
- 238000011160 research Methods 0.000 claims description 6
- 238000011002 quantification Methods 0.000 claims description 5
- 230000001228 trophic effect Effects 0.000 claims 1
- 238000004043 dyeing Methods 0.000 description 14
- 229920000742 Cotton Polymers 0.000 description 12
- 238000004364 calculation method Methods 0.000 description 4
- 238000007730 finishing process Methods 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000013210 evaluation model Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000013139 quantization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
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- G—PHYSICS
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- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/30—Staining; Impregnating ; Fixation; Dehydration; Multistep processes for preparing samples of tissue, cell or nucleic acid material and the like for analysis
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0078—Testing material properties on manufactured objects
- G01N33/0086—Clothes; Hosiery
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Abstract
The invention discloses a textile and clothing product grey water footprint accounting and evaluating method based on dilution influence, which comprises the following specific steps of: (1) defining a grey water footprint based on dilution influence, namely diluting the maximum water quantity required by various potential water environment influences to the water quality of the natural water body by taking the existing environmental water quality standard and the water quality of the natural water body as references; (2) determining an accounting and evaluating boundary, making a pollutant discharge list, classifying pollutants according to influence categories, and determining the amount of discharged pollutants; (3) and constructing a grey water footprint accounting and evaluating model influenced by dilution, and intuitively reflecting the water resource quantity occupied by various water environment influences caused by the production of diluted textile and clothing products. The invention constructs a new grey water footprint accounting and evaluating method based on dilution influence, modifies and perfects the influence which cannot be identified only based on quality in the existing grey water footprint accounting method, and solves the problem that the quantitative index unit of multi-dimensional environmental influence is not uniform through the form of dilution water quantity.
Description
Technical Field
The invention belongs to the field of evaluation of influence on water environment, and particularly relates to a textile and garment product grey water footprint accounting and evaluating method based on dilution influence.
Background
More textile chemicals are used in the production process of textile and clothing products, and the generated wastewater contains residual slurry, toxic reactive dye, COD, ammonia nitrogen, chromium and other pollutants, so that the influence on the water environment is complex and various. The grey water footprint is an important method for quantifying water pollution from a water yield angle, and is defined as the amount of water resource required for diluting the pollutant load to a corresponding water quality standard on the basis of the concentration of natural water and the existing environmental water quality standard on the basis of a dilution theory. The existing grey water footprint accounting method is based on the quality of wastewater pollutants, the influence degree on the water environment cannot be identified, and partial disputes exist in accounting and evaluating the grey water footprint of textile and clothing products from the aspect of quality dilution.
In order to quantify various potential Environmental influences on Water resource environment caused by each life cycle stage of a product, according to different Environmental mechanisms related to pollutants, the international standard ISO 14046:2014 Environmental management-Water fostopprints-Principles, requirements and guideliines describes the Water environment problem as Environmental influences such as Water eutrophication, Water acidification, Water ecological toxicity and the like, and the quantification results are respectively PO4 3-Equivalent weight, SO2Equivalent and water equivalent. The non-uniformity of the quantization index unit leads to difficulty in comparing the influence of different types of water environments caused by different types of pollutants in the wastewater discharged in the production of textile and clothing.
Disclosure of Invention
The invention aims to provide a textile and garment product grey water footprint accounting and evaluating method based on dilution influence, and a new grey water footprint accounting and evaluating method is constructed based on influences of different types of wastewater pollutants on a water environment. Representing the grey water footprint of the textile and clothing products by adopting the water quantity index required for diluting the potential water environment influence to the water quality of the natural water body; through the form of the volume of the dilution water, the unification of different influence type units is realized when the multiple potential environmental influences of textile garment production are quantized. So that different influence types of different production processes of different types of textile garment products or different production processes of the same type of textile garment products on the water environment can be compared.
In order to solve the technical problems, the following technical scheme is adopted:
the textile and clothing product grey water footprint accounting and evaluating method based on dilution influence is characterized by comprising the following steps of:
(1) defining a grey water footprint based on dilution effects;
(2) determining an accounting and evaluation boundary; classifying the wastewater pollutants according to environmental impact categories, and determining the amount of the wastewater pollutants to be discharged, wherein the environmental impact categories comprise water eutrophication, water acidification and water ecotoxicity;
(3) constructing a dilution-influenced grey water footprint accounting and evaluating model:
based on the dilution theory, the potential influence of the production of textile and clothing products on the water environment is quantified by adopting a formula 1:
in the formula, GWFinFor grey water footprint based on dilution effects, m3(ii) a k is the environmental impact category, (k is water eutrophication, water acidification, water ecotoxicity);a characteristic factor of a pollutant i in a k-th influence category; miKg, mass of contaminant i; cmax,iThe maximum allowable concentration of the pollutant i in the existing environmental water quality standard is mg/L; cnat,iIs the natural background concentration of the pollutant i, mg/L.
Preferably, said step (1) then defines a grey water footprint based on the dilution effect, directly quantifying the effect of the discharge of wastewater pollutants on the water environment in the form of a dilution water volume. The invention provides a dilution influence theory on the basis of the existing grey water footprint, so that the concept is simple, the understanding and the acceptance are easier, and the concrete accounting and evaluation application are convenient.
Preferably, the volume of the dilution water is: based on the existing environmental water quality standard and the natural water quality, the maximum water quantity required for diluting various potential water environment influences to the natural water quality is the grey water footprint based on dilution influence, and the influence category is a characteristic influence factor.
Preferably, said step (2) determines an accounting and evaluation boundary: according to the research purpose, selecting the life cycle stage of the product, determining the related investment of each production chain segment and the discharge of wastewater pollutants in the research boundary, classifying the wastewater pollutants according to the environmental influence categories, and determining the amount of the discharged wastewater pollutants, wherein the environmental influence categories comprise water eutrophication, water acidification and water ecotoxicity.
Preferably, before the quantitative calculation, the step (3) further includes a calculation method for different water environment influence types: for water eutrophication, water acidification and water ecotoxicity, the accounting method for three water environment influence categories is shown in table 1:
TABLE 1 accounting method for different environmental impact categories
According to the characteristic that the wastewater pollutants in the production wastewater of textile and clothing products are complex and various, the same type of environmental influence caused by different wastewater pollutants has an accumulation effect, so that the accounting method for different types of environmental influence is obtained.
Due to the adoption of the technical scheme, the method has the following beneficial effects:
the invention relates to a textile garment product gray water footprint accounting and evaluating method based on dilution influence, wherein the influence of the production activity of the textile garment product on the water environment deterioration can be more visually represented by directly analyzing the gray water footprint from the perspective of the water environment influence, so that the accounting result has more practical significance.
The textile and clothing production wastewater pollutants are complex in types, various potential environmental influences are caused on natural water bodies, and similar environmental influences caused by different pollutants have an accumulation effect. Based on the grey water footprint affected by dilution, neglecting the combination of contaminants in the water body due to only considering characteristic contaminants is avoided. Meanwhile, the sizes of various potential environmental influences caused by different production process chain segments of different types of textile clothing products and the same type of textile clothing products can be visually compared in a dilution water volume mode, so that the key problem that quantification index units of multi-dimensional environmental influences are not uniform is solved. And further, the process flow can be optimized in a targeted manner, the input of related materials and the output of pollutants are controlled, and reasonable and effective data support is provided for the prevention and treatment of water environment pollution.
Detailed Description
The textile and clothing product grey water footprint accounting and evaluating method based on dilution influence mainly comprises three parts. The first part is to define a grey water footprint based on dilution effects; the second part is to determine the accounting and evaluation boundary; and the third part is to construct a dilution-influenced grey water footprint accounting and evaluation model. The method comprises the following specific steps:
(1) defining a grey water footprint based on dilution effects
Redefining grey water footprints based on 'water environment influence', directly quantifying the influence of the discharge of wastewater pollutants on the water environment in the form of 'diluted water volume', and defining the basic concept as follows: based on the existing environmental water quality standard and the natural water quality, the maximum water quantity required for diluting various potential water environment influences to the natural water quality is the grey water footprint based on dilution influence, and the influence category is a characteristic influence factor.
(2) Determining accounting and evaluation boundaries
According to the research purpose, the life cycle stage of the product is selected, the input of raw materials of each production chain segment and the discharge of wastewater pollutants are determined within the research boundary, the wastewater pollutants are classified according to the influence categories, and the quantity of the discharged wastewater pollutants is determined. The environmental impact categories include water eutrophication, water acidification and water ecotoxicity.
(3) Constructing dilution-influenced gray water footprint accounting and evaluating model
3.1 accounting method for different environmental impact categories
According to the characteristics of complexity and diversity of wastewater pollutants in the production wastewater of textile and clothing products, the environmental influences of the same type caused by different wastewater pollutants have an additive effect. According to different environmental impact categories related to wastewater pollutants discharged in the production of textile and clothing products, the water environmental impact categories are divided into three indexes of water eutrophication, water acidification and water ecological toxicity, and the quantification method is shown in table 1.
TABLE 1 accounting method for different environmental impact categories
3.2 Grey water footprint accounting and evaluating method based on dilution influence
Based on the dilution theory, the water occupied by the potential influence of the water environment caused by the production of the textile and clothing products is diluted by adopting formula 1:
in the formula, GWFinFor grey water footprint based on dilution effects, m3(ii) a k is the environmental impact category, (k is water eutrophication, water acidification, water ecotoxicity);a characteristic factor of a pollutant i in a k-th influence category; miKg, mass of contaminant i; cmax,iThe maximum allowable concentration of the pollutant i in the existing environmental water quality standard is mg/L; cnat,iIs the natural background concentration of the pollutant i, mg/L.
And (3) diluting each caused environment influence type, wherein the environment influence occupying the most water resource amount is the characteristic environment influence, and the occupied water resource amount is the grey water footprint based on the dilution influence.
The invention is further illustrated by the following specific examples:
taking the water environment influence of the dyeing and finishing chain segment of the cotton textile as an example to carry out accounting and evaluation demonstration. The cotton textile dyeing and finishing chain segment mainly comprises three unit modules of pretreatment, dyeing and after-treatment. And collecting wastewater pollutant discharge data by taking 1000kg of cotton textiles as an accounting functional unit, and performing grey water footprint accounting and evaluation based on dilution influence on dyeing and finishing of the cotton textiles.
Step (1)
According to the discharge data of the pollutants in the cotton textile production wastewater in the dyeing and finishing chain segment boundary, a pollutant discharge list is formulated (see table 2), and the pollutants in the wastewater are classified according to the water environment influence types (see table 3).
Table 2 list of major pollutants in dyeing and finishing chain of cotton textiles
TABLE 3 Classification of wastewater contaminants
Step (2)
2.1 quantifying various classes of Water environmental impact
And (3) according to the wastewater pollutant discharge list and the environmental impact classification formulated in the step (1), accounting is carried out on each water environment impact type of the cotton textile dyeing and finishing chain segment, and the accounting result is shown in a table 4.
TABLE 4 Cotton textile dyeing and finishing Process Each environmental footprint accounting result
2.2 accounting for dilution-impact-based Grey Water footprints
According to the 2.1 accounting result of each environmental footprint, the formula (1) is adopted, the water resource amount occupied by each water environment influence is directly quantified in a 'dilution water volume' form (see table 5), and then the grey water footprint based on dilution influence is obtained (see table 6).
TABLE 5 Cotton textile dyeing and finishing Process Each environmental footprint accounting result
Table 6 cotton textile dyeing and finishing process multiple contaminant grey water footprint based on dilution impact
According to the calculation result, the influences of all processes and all types of water environments of the dyeing and finishing chain segments of the cotton textiles are expressed in the form of a unified unit 'diluted water volume', and the sizes of grey water footprints based on the dilution influences are as follows in sequence: dyeing > after finishing > pre-treatment. Wherein, the three production processes are characterized in that the environmental influence is water ecological toxicity, and the water ecological toxicity influence is far larger than the water eutrophication influence and the water acidification influence.
Through example calculation, it can be seen that the cotton textile dyeing and finishing segment gray water footprint accounting method based on dilution influence considers the water environment accumulation influence caused by different types of wastewater pollutants. The size of potential water environment influences of different types in waste water discharged by a dyeing and finishing process is visually reflected in a form of 'diluting water volume', so that the key problem that quantification index units of multi-dimensional environment influences are not uniform is solved. Further, the process flow can be optimized in a targeted manner, the input of related materials and the output of wastewater pollutants are controlled, and the problem of water environment pollution is effectively reduced and treated.
The above is only a specific embodiment of the present invention, but the technical features of the present invention are not limited thereto. Any simple changes, equivalent substitutions or modifications made on the basis of the present invention to solve the same technical problems and achieve the same technical effects are all covered in the protection scope of the present invention.
Claims (5)
1. The textile and clothing product grey water footprint accounting and evaluating method based on dilution influence is characterized by comprising the following steps of:
(1) defining a grey water footprint based on dilution effects;
(2) determining an accounting and evaluation boundary; classifying the wastewater pollutants according to environmental impact categories, and determining the amount of the wastewater pollutants to be discharged, wherein the environmental impact categories comprise water eutrophication, water acidification and water ecotoxicity;
(3) constructing a dilution-influenced grey water footprint accounting and evaluating model:
based on the dilution theory, the potential influence of the production of textile and clothing products on the water environment is quantified by adopting a formula 1:
in the formula, GWFinFor grey water footprint based on dilution effects, m3(ii) a k is the environmental impact category, (k is water eutrophication, water acidification, water ecotoxicity);a characteristic factor of a pollutant i in a k-th influence category; miKg, mass of contaminant i; cmax,iThe maximum allowable concentration of the pollutant i in the existing environmental water quality standard is mg/L; cnat,iIs the natural background concentration of the pollutant i, mg/L.
2. The dilution influence based textile garment product grey water footprint accounting and evaluation method of claim 1: the step (1) defines a grey water footprint based on dilution effects, and directly quantifies the effects of wastewater pollutant emissions on the water environment in the form of dilution water volumes.
3. The dilution influence based textile garment product grey water footprint accounting and evaluation method of claim 2: the volume of the dilution water is as follows: based on the existing environmental water quality standard and the natural water quality, the maximum water quantity required for diluting various potential water environment influences to the natural water quality is the grey water footprint based on dilution influence, and the influence category is a characteristic influence factor.
4. The dilution influence based textile garment product grey water footprint accounting and evaluation method of claim 1: the step (2) determines an accounting and evaluation boundary: according to the research purpose, selecting the life cycle stage of the product, determining the related investment of each production chain segment and the discharge of wastewater pollutants in the research boundary, classifying the wastewater pollutants according to the environmental influence categories, and determining the amount of the discharged wastewater pollutants, wherein the environmental influence categories comprise water eutrophication, water acidification and water ecotoxicity.
5. The dilution influence based textile garment product grey water footprint accounting and evaluation method of claim 4: before quantification, the step (3) further comprises accounting methods of different water environment influence types: the accounting method for three water environment influence categories of water eutrophication, water acidification and water ecotoxicity comprises the following steps:
water eutrophication:
wherein, NPi: trophic potential coefficient of contaminant i, Mi: mass of contaminant i, WFNHas the unit of kgPO4 3-eq;
Water acidification:
wherein,APiAcidification potential coefficient of contaminant i, Mi: mass of contaminant i, WFAHas the unit of kgSO2eq;
Water ecotoxicity:
wherein, AETPi: water body ecotoxicity potential coefficient, M, of pollutant ii: mass of contaminant i, WFAETIs in the unit of m3H2Oeq。
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