CN112185475A - Aiming at SCR denitration system distortion NOxHigh-precision intelligent concentration prediction method - Google Patents
Aiming at SCR denitration system distortion NOxHigh-precision intelligent concentration prediction method Download PDFInfo
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Abstract
The invention relates to the technical field of thermal power engineering, and particularly discloses a method for generating distorted NO of an SCR (selective catalytic reduction) denitration systemxThe high-precision intelligent concentration predicting method comprises the following steps: establishing and SCR system inlet and outlet NOxNO matched with working state of concentration analyzerxA concentration measurement data switching control framework; training to obtain distorted inlet NO under the input of parametersxIntelligent concentration prediction model and distorted state outlet NOxA concentration intelligent prediction model; by individually targeted adjustment of inlet or outlet NOxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are used for realizing NO in a distorted state and a non-distorted statexThe concentration is switched to finally obtain NO with high precision in the whole timexConcentration measurement data. The invention can realize the NO in the distorted state aiming at the SCR denitration systemxThe high-precision intelligent prediction of the concentration,and an accurate data base is provided for the operation optimization adjustment of a subsequent system.
Description
Technical Field
The invention relates to the technical field of thermal energy power engineering, in particular to a method for generating distorted NO of an SCR (selective catalytic reduction) denitration systemxA high-precision intelligent concentration prediction method.
Background
Selective Catalytic Reduction (SCR) denitration system is flue gas Nitric Oxide (NO) mainly applied to current coal-fired equipmentx) The removal system obtains the accurate running state of the unit in real time, and has great significance for guiding the running optimization of the unit. The operating state of the SCR denitration system can be comprehensively described by a plurality of operating parameters, and the inlet NO isxConcentration and outlet NOxThe two concentration measurement parameters are two very key operation parameters of the SCR denitration system; wherein: inlet NOxConcentration characterization of NO entering SCR denitration systemxThe amount of the ammonia can be used for guiding the operator to inject the amount of the ammonia to participate in the denitration oxidation-reduction reaction without causing insufficient ammonia or excessive ammonia; outlet NOxConcentration characterization of NO flowing out of SCR denitration systemxThe amount of the NO can be reflected whether the NO is satisfied by the nationxThe emission control requirement is met, and meanwhile, the method has stronger guiding significance on ammonia injection characteristic evaluation and the like.
However, at present, the inlet or outlet NO of the SCR denitration system of coal burning equipmentxConcentration measurement mode is NO of extraction typexThe concentration measurement method is influenced by the high-dust arrangement mode of the SCR denitration system, the extracted flue gas contains a large amount of fly ash, and continuous long-time online analysis is easy to carry out on NOxThe operation of the concentration analyzer is adversely affected and may even cause clogging of the analyzer, damage to the core analytical unit (optical engine, etc.), and the like. Therefore, in industrial application environment, coal burning equipment SCR denitration system inlet or outlet NOxThe concentration analyzer adopts a working mode of regular maintenance, namely openStopping the sampling of the flue gas at regular intervals, and then using compressed air and other back-blowing sampling pipelines, thereby achieving the purpose of avoiding damaging the core measuring equipment, wherein the NO isxThe duration of single maintenance of the concentration analyzer is as long as about 5-10 minutes. From the above, it is easy to find that NOxThe regular maintenance mode of operation of the concentration analyzer necessarily results in NO during maintenance operationsxInaccuracy, unrepresentative of concentration measurements, and many occurrences of NO after each maintenance runxAbnormal jump in the actual measured value of the concentration, NO in such a distorted statexThe concentration measurement value is very unfavorable for guiding the normal operation of the unit.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides the SCR denitration system distortion state NO with full time, high precision and accurate measurement resultxA high-precision intelligent concentration prediction method.
The invention is realized by the following technical scheme:
aims at SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps of: (1) establishing and SCR system inlet and outlet NOxNO matched with working state of concentration analyzerxA concentration measurement data switching control framework; (2) under the input of the combustion parameters in the furnace, the unit load and the coal mill operation parameters, the distorted state inlet NO is obtained by trainingxA concentration intelligent prediction model; (3) at the inlet of the ammonia injection amount NOxTraining to obtain distorted state outlet NO under the input of concentration and combustion parameters in the furnacexA concentration intelligent prediction model; (4) based on the above 3 steps, the inlet or outlet NO is adjusted individually and specificallyxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are used for realizing NO in a distorted state and a non-distorted statexThe concentration is switched to finally obtain the NO with full time and high precisionxConcentration measurement data.
Firstly, establishing NO at inlet and outlet of SCR systemxFull-time high-precision NO matched with working state of concentration analyzerxConcentration measurement data switching control framework(ii) a Then under the input of the combustion parameters in the furnace, the unit load and the coal mill operation parameters, training is carried out to obtain the NO of the distorted inletxA concentration intelligent prediction model; further, NO is injected into the ammonia injection amount and the inletxTraining to obtain distorted state outlet NO under the input of concentration and combustion parameters in the furnacexA concentration intelligent prediction model; finally by individually targeted adjustment of inlet or outlet NOxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are used for realizing NO in a distorted state and a non-distorted statexThe concentration is switched to finally obtain NO with high precision in the whole timexConcentration measurement data.
The method can realize the NO in the distorted state aiming at the SCR denitration systemxAnd the high-precision intelligent prediction of the concentration provides an accurate data basis for the operation optimization and adjustment of a subsequent system.
The more preferable technical scheme of the invention is as follows:
in step (1), inlet and outlet NOxThe working states of the concentration analyzer are respectively 0 and 1, wherein the state 0 represents NOxNO output from normal operation of concentration analyzerxThe concentration measurement is correct and state 1 indicates NOxThe concentration analyzer is in maintenance operation state, and NO is outputxThe concentration measurement value is in a distorted state, and the actual measurement result is inaccurate.
NOxConcentration measurement data switching control framework pair NOxOperating period T with concentration analysis state of 01Taking NOxNO normally output from concentration analyzerxA concentration measurement; and for NOxOperating time period T with concentration analyzer state of 12Taking in NO through inlet or outletxNO output by intelligent concentration prediction modelxAnd (5) predicting the concentration.
In step (2), the distorted state is entered as NOxIn the concentration intelligent prediction model, the combustion parameters in the furnace comprise total components, total coal quantity, upper layer over-fire air door opening and upper layer secondary small air door opening, the unit load is the real power of the unit, and the coal mill operation parameters comprise the start-stop working state and the instantaneous coal feeding quantity of each coal mill.
Step (ii) of(3) Medium, distorted state outlet NOxIn the intelligent concentration prediction model, the ammonia injection amount is the instantaneous ammonia injection flow of a reactor on the corresponding side of the SCR denitration system, and NO is introduced into an inletxConcentration of corresponding side inlet NOxNO output from concentration analyzerxThe actual measurement value of the concentration, and the combustion parameters in the furnace comprise total component, total amount, opening degree of an upper layer burn-out air door, opening degree of an upper layer secondary small air door and flue gas flow.
The distorted state inlet NOxThe intelligent concentration prediction model is characterized in that the model inputs are furnace combustion parameters, unit load and coal mill operation parameters; model output as Inlet NOxPredicting the concentration value; NO is carried out by jointly applying fuzzy tree model and support vector machine modelxAnd (4) predicting the concentration.
The distorted state outlet NOxThe intelligent concentration prediction model is characterized in that the model inputs comprise ammonia injection amount and inlet NOxConcentration, furnace combustion parameters; model output as Outlet NOxPredicting the concentration value; NO is carried out by jointly applying fuzzy tree model and support vector machine modelxAnd (4) predicting the concentration.
Preferably, NOxThe concentration prediction is mainly based on the prediction output of a fuzzy tree model, and the prediction output of a support vector machine model is paid, and the specific combined application rule is as follows:
calculating the variation trend of the prediction result of the fuzzy tree model at the adjacent timeAnd the variation trend of the prediction result of the fuzzy tree model at the adjacent time;
Wherein:is composed oftInlet or outlet NO at moment +1xThe output value of the intelligent concentration prediction model is predicted;is composed oftInlet or outlet NO based on fuzzy tree model at +1 momentxPredicting the concentration value;is composed oftInlet or outlet NO based on support vector machine model at time +1xAnd (5) predicting the concentration.
In the step (4), the NOxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are embodied as preset delay time tau, and the setting rule is as follows:
wherein tau is the delay time of the delay module to be set,is corresponding to inlet or outlet NOxThe total duration of the single maintenance operation state of the concentration analyzer, wherein kappa is an empirically set coefficient and takes any value between 1/8 and 1/4 according to the operation condition.
Said full time, high precision NOxIn the concentration measurement data, the total time is determined by NOxNormal running time period of concentration analyzer, NOxThe maintenance operation time of the concentration analyzer is short; wherein NO is due to the setting of the delay time τxIn a short time after the maintenance of the concentration analyzer is finished, NO is still takenxNO output by intelligent concentration prediction modelxAnd (5) predicting the concentration.
Compared with the prior art, the invention has the advantages that: provides a method for SCR denitration system distortion NOxThe high-precision intelligent concentration predicting method establishes NO at the inlet and outlet of SCR systemxFull-time high-precision NO matched with working state of concentration analyzerxThe concentration measurement data switching control frame establishes a distorted inlet or outlet NO by combining the fuzzy tree and the support vector machine modelxThe concentration intelligent prediction model realizes the NO in a distorted state and a non-distorted state by utilizing a delay modulexThe concentration is switched to obtain NO with high precision in the whole timexConcentration measurement data. The application of the invention can compensate NOxThe concentration analyzer has the defect of distorted concentration measurement values during maintenance and operation, realizes accurate description of the key operation state of SCR denitration in the whole period, and can provide an accurate data base for operation optimization and adjustment of a subsequent system.
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The invention will be further described with reference to the accompanying drawings.
FIG. 1 is a schematic process flow diagram of the present invention;
FIG. 2 shows inlet NO in an embodiment of the present inventionxIntelligent concentration prediction characteristics;
FIG. 3 shows the outlet NO in the example of the present inventionxThe concentration intelligent prediction characteristic.
Detailed Description
The present invention is described in detail below with reference to the accompanying drawings, which are used for implementing the present invention on the premise of the technical solution, and it should be understood that the implementation case is for illustrating the present invention, but the protection scope of the present invention is not limited to the implementation case.
The implementation case is based on the specific implementation of a SCR system of a front-wall and rear-wall opposed firing boiler of a certain 600MW coal-fired thermal power generating unit, and the provided SCR denitration system distortion state NO is developedxAnd (3) carrying out engineering application research on a high-precision intelligent concentration prediction method. The specific implementation process is as follows:
step 1: establishing and SCR system inlet and outlet NOxFull time interval matched with working state of concentration analyzerHigh precision NOxA concentration measurement data switching control framework;
inlet and outlet NO of the unitxThe concentration analyzer adopts the working modes of extraction type measurement and regular maintenance back flushing; inlet and outlet NOxThe concentration analyzer does not perform 1-time maintenance back flushing every 2 hours, and the total time of single maintenance is 255 seconds; inlet NOxMaintenance time and outlet NO of concentration analyzerxThe maintenance time of the concentration analyzer is not overlapped and is carried out independently. Inlet and outlet NO of the unitxThe working state of the concentration analyzer is 0 and 1, and the state 0 represents NOxThe concentration analyzer is working normally, and state 1 shows NOxThe concentration analyzer is in a maintenance operation state.
For this setting, for NOxOperating time period T with state of concentration analyzer being 01Taking NOxNO normally output from concentration analyzerxA concentration measurement; and for NOxOperating time period T with state of concentration analyzer being 02Taking in NO through inlet or outletxNO output by intelligent concentration prediction modelxAnd (5) predicting the concentration.
Step 2: under the input of the combustion parameters in the furnace, the unit load and the coal mill operation parameters, the distorted state inlet NO is obtained by trainingxA concentration intelligent prediction model;
the used furnace combustion parameters, unit load and coal mill operation parameters are shown in (part of) tables 1 and 2, and continuous operation data are used to respectively train and obtain inlet NO based on fuzzy treexConcentration prediction model, support vector machine-based inlet NOxA concentration prediction model.
Based on the prediction output of fuzzy tree model, support vector machineEstablishing inlet NO by jointly applying fuzzy tree model and support vector machine model based on principle that model prediction output is auxiliaryxAnd (3) a concentration intelligent prediction model.
FIG. 2 shows the inlet NO of the present method in an embodiment of the present inventionxConcentration intelligent prediction characteristic, and NO at inlet can be seenxEnabling inlet NO in distorted state during maintenance of concentration analyzerxMore accurate prediction of concentration, and in NOxNO does not appear after the maintenance of the concentration analyzer is finishedxA significant jump in concentration.
And step 3: at the inlet of the ammonia injection amount NOxTraining to obtain distorted state outlet NO under the input of concentration and combustion parameters in the furnacexA concentration intelligent prediction model;
amount of injected ammonia used, inlet NOxThe concentrations and the combustion parameters in the furnace are shown in tables 1, 2 and 3 (part), and outlet NO based on the fuzzy tree is obtained by using continuous operation data through training respectivelyxConcentration prediction model and support vector machine-based outlet NOxA concentration prediction model.
Establishing the export NO by jointly applying the fuzzy tree model and the support vector machine model according to the principle that the prediction output of the fuzzy tree model is taken as the main part and the prediction output of the support vector machine model is taken as the auxiliary partxAnd (3) a concentration intelligent prediction model.
FIG. 3 shows the export NO of the method according to an embodiment of the present inventionxThe intelligent concentration prediction characteristic can show that NO is at the outletxEnabling distorted state NO to be exported during maintenance of the concentration analyzerxMore accurate prediction of concentration, and in NOxNO does not appear after the maintenance of the concentration analyzer is finishedxA significant jump in concentration.
And 4, step 4: based on the aforementioned 3 steps, by individually and specifically adjusting the inlet or outlet NOxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are used for realizing NO in a distorted state and a non-distorted statexThe switching of the concentration is carried out,finally obtain NO with high precision in the whole timexConcentration measurement data.
In this embodiment, the inlet and outlet NO's are empirically setxThe characteristic parameter of the delay module downstream of the concentration intelligent prediction model is tau =50 seconds, and the empirical setting coefficient is about 0.196 at this time.
The embodiment can show that the invention discloses a method for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method can realize the purpose of predicting the NO in the SCR denitration system in a distorted statexThe high-precision intelligent prediction of the concentration can provide an accurate data base for the operation optimization and adjustment of a subsequent system.
As described above, although the embodiments of the present invention have been described in connection with the embodiments and the accompanying drawings, they should not be construed as limiting the present invention itself. On the basis of the technical scheme of the invention, various modifications or changes which can be made by any unit or person without creative labor are still within the protection scope of the invention.
Claims (9)
1. Aims at SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps of: (1) establishing and SCR system inlet and outlet NOxNO matched with working state of concentration analyzerxA concentration measurement data switching control framework; (2) under the input of the combustion parameters in the furnace, the unit load and the coal mill operation parameters, the distorted state inlet NO is obtained by trainingxA concentration intelligent prediction model; (3) at the inlet of the ammonia injection amount NOxTraining to obtain distorted state outlet NO under the input of concentration and combustion parameters in the furnacexA concentration intelligent prediction model; (4) based on the above 3 steps, the inlet or outlet NO is adjusted individually and specificallyxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are used for realizing NO in a distorted state and a non-distorted statexThe concentration is switched to finally obtain the NO with full time and high precisionxConcentration measurement data.
2. The method as claimed in claim 1 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: in step (1), inlet and outlet NOxThe working states of the concentration analyzer are respectively 0 and 1, wherein the state 0 represents NOxNO output from normal operation of concentration analyzerxThe concentration measurement is correct and state 1 indicates NOxThe concentration analyzer is in maintenance operation state, and NO is outputxThe concentration measurement value is in a distorted state, and the actual measurement result is inaccurate.
3. The method as claimed in claim 2 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: in step (1), NOxConcentration measurement data switching control framework pair NOxOperating period T with concentration analysis state of 01Taking NOxNO normally output from concentration analyzerxA concentration measurement; and for NOxOperating time period T with concentration analyzer state of 12Taking in NO through inlet or outletxNO output by intelligent concentration prediction modelxAnd (5) predicting the concentration.
4. The method as claimed in claim 1 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: in step (2), the distorted state is entered as NOxIn the concentration intelligent prediction model, the combustion parameters in the furnace comprise total components, total coal quantity, upper layer over-fire air door opening and upper layer secondary small air door opening, the unit load is the real power of the unit, and the coal mill operation parameters comprise the start-stop working state and the instantaneous coal feeding quantity of each coal mill.
5. The method as claimed in claim 1 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: in step (3), the outlet NO is distortedxIn the intelligent concentration prediction model, the ammonia injection amount is the instantaneous ammonia injection flow of a reactor on the corresponding side of the SCR denitration system, and NO is introduced into an inletxConcentration ofIs a corresponding side inlet NOxNO output from concentration analyzerxThe actual measurement value of the concentration, and the combustion parameters in the furnace comprise total component, total amount, opening degree of an upper layer burn-out air door, opening degree of an upper layer secondary small air door and flue gas flow.
6. The method as claimed in claim 1 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: in the steps (2) and (3), the inlet NO of the distorted statexIntelligent concentration prediction model and distorted state outlet NOxThe intelligent concentration prediction model jointly applies a fuzzy tree model and a support vector machine model to carry out NOxAnd (4) predicting the concentration.
7. The method as claimed in claim 6 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: NOxThe concentration prediction is mainly based on the prediction output of a fuzzy tree model, and the prediction output of a support vector machine model is paid, and the specific combined application rule is as follows:,(ii) a Calculating the variation trend of the prediction result of the fuzzy tree model at the adjacent timeAnd the variation trend of the prediction result of the fuzzy tree model at the adjacent time;Wherein:is composed oftEntry at time +1Or outlet NOxThe output value of the intelligent concentration prediction model is predicted;is composed oftInlet or outlet NO based on fuzzy tree model at +1 momentxPredicting the concentration value;is composed oftInlet or outlet NO based on support vector machine model at time +1xAnd (5) predicting the concentration.
8. The method as claimed in claim 1 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: in the step (4), the NOxThe characteristic parameters of a delay module system at the downstream of the concentration intelligent prediction model are embodied as preset delay time tau, and the setting rule is as follows:(ii) a Wherein tau is the delay time of the delay module to be set,is corresponding to inlet or outlet NOxThe total duration of the single maintenance operation state of the concentration analyzer, wherein kappa is an empirically set coefficient and takes any value between 1/8 and 1/4 according to the operation condition.
9. The method as claimed in claim 8 for SCR denitration system distortion state NOxThe high-precision intelligent concentration prediction method is characterized by comprising the following steps: said full time, high precision NOxIn the concentration measurement data, the total time is determined by NOxNormal running time period of concentration analyzer, NOxThe maintenance operation time of the concentration analyzer is short; wherein NO is due to the setting of the delay time τxIn a short time after the maintenance of the concentration analyzer is finished, NO is still takenxNO output by intelligent concentration prediction modelxAnd (5) predicting the concentration.
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