CN112143411A - Cloth brushing aqueous adhesive cement for folding grass-color heel strip cloth of rubber shoes and preparation method thereof - Google Patents
Cloth brushing aqueous adhesive cement for folding grass-color heel strip cloth of rubber shoes and preparation method thereof Download PDFInfo
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- CN112143411A CN112143411A CN202011053326.2A CN202011053326A CN112143411A CN 112143411 A CN112143411 A CN 112143411A CN 202011053326 A CN202011053326 A CN 202011053326A CN 112143411 A CN112143411 A CN 112143411A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J107/00—Adhesives based on natural rubber
- C09J107/02—Latex
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a brushing water-based adhesive cement for folding edges of grass-color heel strips of rubber shoes and a preparation method thereof, wherein the brushing water-based adhesive cement comprises, by weight, 95-105 parts of natural latex, 1.5-1.9 parts of a water-based vulcanization system, 0.8-1.2 parts of ammonia water, 0.8-1.2 parts of peregal O, 0.25-0.35 part of grass green ball milling liquid, 1.5-2.5 parts of sodium carboxymethyl cellulose, 55-59 parts of soft water, 0.4-0.6 part of potassium hydroxide and 0.08-0.12 part of mildew preventive BCM. The invention researches the formula and the preparation method of the brushing water-based adhesive for folding the grass color heel strip cloth of the rubber shoes to obtain the water-based adhesive with safety, environmental protection and good adhesive property, and the brushing water-based adhesive has the advantages of wide material source, low cost, high safety and simple preparation process and is suitable for industrial production. The invention is simple and easy to implement, low in cost and good in using effect of the product.
Description
Technical Field
The invention relates to the field of rubber processing, in particular to a brushing cloth aqueous adhesive cement for folding edges of grass-colored heel strips and cloth of rubber shoes and a preparation method thereof.
Background
In the manufacturing process of the upper of the rubber shoe, the reinforcing strip of the heel of the upper is usually formed by sewing folded edges of upper surface cloth, the adhesive required to be used for fixing the folded edges is usually a solvent adhesive, and the conventionally used shoe adhesive is rubber cement made of natural rubber compound and using toluene, benzene or gasoline and esters as solvents. The adhesive has toxicity and can harm human health, and meanwhile, the safety of production environment is low due to the inflammability of the rubber paste. With the development of the shoe manufacturing industry, the water-based adhesive cement for edge folding, which is nontoxic, safe and environment-friendly and has a simple manufacturing method, is a new inevitable demand.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the brushing water-based adhesive cement for folding the grass color heel strip cloth of the rubber shoe and the preparation method thereof are safe, environment-friendly and good in adhesive property, and overcome the defects of the prior art.
The invention is realized by the following steps: the cloth brushing aqueous adhesive cement for folding the grass-color heel stripe cloth of the rubber shoes comprises, by weight, 95-105 parts of natural latex, 1.5-1.9 parts of a water-based vulcanization system, 0.8-1.2 parts of ammonia water, 0.8-1.2 parts of peregal O, 0.25-0.35 part of grass green ball milling liquid, 1.5-2.5 parts of sodium carboxymethyl cellulose, 55-59 parts of soft water, 0.4-0.6 part of potassium hydroxide and 0.08-0.12 part of a mildew preventive BCM.
The environment-friendly and environment-friendly anti-mildew agent comprises, by weight, 100 parts of natural latex, 1.7 parts of a water-based vulcanization system ball-milling liquid, 1.0 part of ammonia water, 1.0 part of peregal O, 0.3 part of a grass green ball-milling liquid, 2.0 parts of sodium carboxymethyl cellulose, 57 parts of soft water, 0.5 part of potassium hydroxide and 0.10 part of a mildew preventive BCM.
Wherein, 1.7 parts of water-based vulcanization system ball-milling liquid consists of 0.1 part of sulfur, 0.05 part of accelerator M, 0.10 part of accelerator TMTD, 0.15 part of nano zinc oxide, 0.10 part of anti-aging agent KY-405L, 0.10 part of potassium hydroxide, 0.05 part of powdery diffusant NNO, 0.05 part of powdery casein anhydride and 1.0 part of soft water.
The used 0.3 part of the grass green ball milling liquid comprises, per 20 parts of the grass green ball milling liquid, 1.0 part of potassium hydroxide, 0.2 part of powdery diffusant NNO, 0.2 part of powdery casein anhydride, 0.05 part of borax, 0.35 part of black coating slurry, 1.0 part of green coating slurry, 8.5 parts of medium chrome yellow and 8.7 parts of soft water.
The preparation method of the brushing water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes comprises the following steps of:
step A, preparing an aqueous thick viscous body: gradually adding soft water to the sodium carboxymethylcellulose under stirring until the total amount of the soft water is 57 parts, potassium hydroxide is 0.5 part and mildew preventive BCM is 0.10 part, and stirring until the sodium carboxymethylcellulose is fully dissolved into a uniform viscous body;
step B, preparing a mixture: sequentially adding peregal O, a water-based vulcanization system ball-milling liquid and ammonia water into the prepared aqueous viscous mass while stirring, and uniformly stirring for later use;
and C: preparing brushing water-based adhesive cement for folding grass color heel strips and cloth of rubber shoes: and adding 5-8 parts of natural latex and the grass green ball milling liquid into the mixture, uniformly stirring, adding the rest natural latex, and fully and uniformly stirring to obtain a finished product.
The preparation method of the water-based vulcanization system ball-milling liquid and the grass green ball-milling liquid system comprises the steps of adding each component in the water-based vulcanization system or the compounding agent component of the grass green ball-milling liquid system into a rotary ball mill with a rotating shaft parallel to the ground for rotary ball-milling for 6-10 hours; stopping the ball mill after the ball milling time meets the requirement, thus obtaining the ball mill.
In order to verify the technical effect of the present invention, the following tests were performed:
firstly, research on a water-based vulcanization system ball-milling liquid: the results are shown in Table 1.
1.7 parts of water-based vulcanization system ball-milling liquid consists of 0.1 part of sulfur, 0.05 part of accelerator M, 0.10 part of accelerator TMTD, 0.15 part of nano zinc oxide, 0.10 part of anti-aging agent KY-405L, 0.10 part of potassium hydroxide, 0.05 part of powdery diffusant NNO, 0.05 part of powdery casein anhydride and 1.0 part of soft water, wherein the amplification is 100 times: 170 parts of water-based vulcanization system ball-milling liquid, namely 10 parts of sulfur, 5 parts of accelerator M, 10 parts of accelerator TMTD, 15 parts of nano zinc oxide, 10 parts of anti-aging agent KY-405L, 10 parts of potassium hydroxide, 5 parts of powdery diffusant NNO, 5 parts of powdery casein anhydride and 100 parts of soft water
TABLE 1 ball milling study of water-based vulcanization system (100-fold expansion test, unit: parts)
According to the table 1, the optimal formula of the water-based vulcanization system ball milling liquid is as follows: 1.7 parts of water-based vulcanization system ball-milling liquid consists of 0.1 part of sulfur, 0.05 part of accelerator M, 0.10 part of accelerator TMTD, 0.15 part of nano zinc oxide, 0.10 part of anti-aging agent KY-405L, 0.10 part of potassium hydroxide, 0.05 part of powdery diffusant NNO, 0.05 part of powdery casein anhydride and 1.0 part of soft water,
secondly, researching the proportion of the aqueous viscous material: the results are shown in Table 2.
TABLE 2 study of aqueous viscous compositions (unit: parts):
as can be seen from table 2, the optimal ratio for preparing the aqueous viscous paste is soft water: sodium carboxymethylcellulose: potassium hydroxide soft water 2: 0.5: 57.
by adopting the technical scheme, compared with the prior art, the invention researches the formula and the preparation method of the brushing water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes to obtain the brushing water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes, which is safe, environment-friendly and good in adhesive property, and has the advantages of wide material source, low cost, high safety, simple preparation process and suitability for industrial production. The invention is simple and easy to implement, low in cost and good in using effect of the product.
Detailed Description
Example 1 of the invention: the cloth brushing aqueous adhesive cement for folding the grass color heel stripe cloth of the rubber shoes, 100 parts of natural latex, 1.7 parts of water-based vulcanization system ball-milling liquid, 1.0 part of ammonia water, 1.0 part of peregal O, 0.3 part of grass green ball-milling liquid, 2.0 parts of sodium carboxymethyl cellulose, 57 parts of soft water, 0.5 part of potassium hydroxide and 0.10 part of mildew preventive BCM.
The preparation method of the brushing water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes comprises the following steps of:
step B, preparing a mixture: sequentially adding peregal O, a water-based vulcanization system ball-milling liquid and ammonia water into the prepared aqueous viscous mass while stirring, and uniformly stirring for later use;
and C: preparing brushing water-based adhesive cement for folding grass color heel strips and cloth of rubber shoes: and adding 5-8 parts of natural latex and the grass green ball milling liquid into the mixture, uniformly stirring, adding the rest natural latex, and fully and uniformly stirring to obtain a finished product.
Example 2 of the invention: the cloth brushing aqueous adhesive cement for folding the grass color heel stripe cloth of the rubber shoes comprises 100 parts of natural latex, 1.6 parts of water-based vulcanization system ball-milling liquid, 1.0 part of ammonia water, 1.0 part of peregal O, 0.3 part of grass green ball-milling liquid, 2.1 parts of sodium carboxymethyl cellulose, 58 parts of soft water, 0.4 part of potassium hydroxide and 0.10 part of mildew preventive BCM.
The preparation method is the same as example 1.
Example 3 of the invention: the cloth brushing aqueous adhesive cement for folding the grass color heel stripe cloth of the rubber shoes comprises 100 parts of natural latex, 1.8 parts of water-based vulcanization system ball-milling liquid, 1.1 parts of ammonia water, 0.90 part of peregal O, 0.32 part of grass green ball-milling liquid, 2.0 parts of sodium carboxymethyl cellulose, 56 parts of soft water, 0.35 part of potassium hydroxide and 0.10 part of mildew preventive BCM.
The preparation method is the same as example 1.
Claims (6)
1. The utility model provides a rubber overshoes grass colour is with strip cloth for hem brush cloth water-based adhesive cement which characterized in that: the environment-friendly and environment-friendly anti-mildew agent comprises, by weight, 95-105 parts of natural latex, 1.5-1.9 parts of a water-based vulcanization system, 0.8-1.2 parts of ammonia water, 0.8-1.2 parts of peregal O, 0.25-0.35 part of grass green ball milling liquid, 1.5-2.5 parts of sodium carboxymethyl cellulose, 55-59 parts of soft water, 0.4-0.6 part of potassium hydroxide and 0.08-0.12 part of a mildew preventive BCM.
2. The cloth brushing aqueous cement for folding the grass color heel strip cloth of the rubber shoes according to claim 1, which is characterized in that: the environment-friendly and environment-friendly anti-mildew agent comprises, by weight, 100 parts of natural latex, 1.7 parts of a water-based vulcanization system ball-milling liquid, 1.0 part of ammonia water, 1.0 part of peregal O, 0.3 part of a grass green ball-milling liquid, 2.0 parts of sodium carboxymethyl cellulose, 57 parts of soft water, 0.5 part of potassium hydroxide and 0.10 part of a mildew-proof agent BCM.
3. The shoe brush cloth water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes according to claim 1 or 2, which is characterized in that: every 1.7 parts of water-based vulcanization system ball-milling liquid consists of 0.1 part of sulfur, 0.05 part of accelerator M, 0.10 part of accelerator TMTD, 0.15 part of nano zinc oxide, 0.10 part of anti-aging agent KY-405L, 0.10 part of potassium hydroxide, 0.05 part of powdery diffusant NNO, 0.05 part of powdery casein anhydride and 1.0 part of soft water.
4. The shoe brush cloth water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes according to claim 1 or 2, which is characterized in that: the used 0.3 part of the grass green ball milling liquid comprises, per 20 parts of the grass green ball milling liquid, 1.0 part of potassium hydroxide, 0.2 part of powdery diffusant NNO, 0.2 part of powdery casein anhydride, 0.05 part of borax, 0.35 part of black coating slurry, 1.0 part of green coating slurry, 8.5 parts of medium chrome yellow and 8.7 parts of soft water.
5. A method for preparing the brushing cloth aqueous adhesive cement for folding the grass color heel stripe cloth of the rubber shoe as claimed in claim 1, which is characterized in that: the preparation method comprises the following steps of:
step A, preparing an aqueous thick viscous body: gradually adding soft water to sodium carboxymethylcellulose under stirring until the total amount of the soft water is 57 parts, potassium hydroxide is 0.5 part and mildew preventive BCM is 0.10 part, and stirring until the sodium carboxymethylcellulose is fully dissolved into a uniform viscous body;
step B, preparing a mixture: sequentially adding peregal O, a water-based vulcanization system ball-milling liquid and ammonia water into the prepared aqueous viscous mass while stirring, and uniformly stirring for later use;
and C: preparing brushing water-based adhesive cement for folding grass color heel strips and cloth of rubber shoes: and adding 5-8 parts of natural latex and the grass green ball milling liquid into the mixture, uniformly stirring, adding the rest natural latex, and fully and uniformly stirring to obtain a finished product.
6. The method for preparing the brushing water-based adhesive cement for folding the grass color heel stripe cloth of the rubber shoes according to the claim 5, which is characterized in that: the preparation method of the water-based vulcanization system ball-milling liquid and the grass green ball-milling liquid system comprises the steps of adding each component in the water-based vulcanization system or the compounding agent component of the grass green ball-milling liquid system into a rotary ball mill with a rotating shaft parallel to the ground for rotary ball-milling for 6-10 hours; stopping the ball mill after the ball milling time meets the requirement, thus obtaining the ball mill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011053326.2A CN112143411A (en) | 2020-09-29 | 2020-09-29 | Cloth brushing aqueous adhesive cement for folding grass-color heel strip cloth of rubber shoes and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011053326.2A CN112143411A (en) | 2020-09-29 | 2020-09-29 | Cloth brushing aqueous adhesive cement for folding grass-color heel strip cloth of rubber shoes and preparation method thereof |
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| CN112143411A true CN112143411A (en) | 2020-12-29 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486882A (en) * | 2009-03-04 | 2009-07-22 | 际华三五三七制鞋有限责任公司 | Water soluble adhesive and preparation method thereof |
| CN103265910A (en) * | 2013-06-18 | 2013-08-28 | 际华三五三七制鞋有限责任公司 | Water-based anti-static bonding agent for shoes and preparation method thereof |
| CN106220909A (en) * | 2016-08-24 | 2016-12-14 | 际华三五三七制鞋有限责任公司 | Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry |
| CN106318271A (en) * | 2016-08-24 | 2017-01-11 | 际华三五三七制鞋有限责任公司 | Green bonding glue of grass green ponchos protective boots and preparing method and application thereof |
-
2020
- 2020-09-29 CN CN202011053326.2A patent/CN112143411A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486882A (en) * | 2009-03-04 | 2009-07-22 | 际华三五三七制鞋有限责任公司 | Water soluble adhesive and preparation method thereof |
| CN103265910A (en) * | 2013-06-18 | 2013-08-28 | 际华三五三七制鞋有限责任公司 | Water-based anti-static bonding agent for shoes and preparation method thereof |
| CN106220909A (en) * | 2016-08-24 | 2016-12-14 | 际华三五三七制鞋有限责任公司 | Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry |
| CN106318271A (en) * | 2016-08-24 | 2017-01-11 | 际华三五三七制鞋有限责任公司 | Green bonding glue of grass green ponchos protective boots and preparing method and application thereof |
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Application publication date: 20201229 |
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