CN112103534A - High-efficient membrane humidifier of fuel cell - Google Patents
High-efficient membrane humidifier of fuel cell Download PDFInfo
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- CN112103534A CN112103534A CN202011017752.0A CN202011017752A CN112103534A CN 112103534 A CN112103534 A CN 112103534A CN 202011017752 A CN202011017752 A CN 202011017752A CN 112103534 A CN112103534 A CN 112103534A
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- 239000012528 membrane Substances 0.000 title claims abstract description 165
- 239000000446 fuel Substances 0.000 title claims abstract description 28
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000007789 sealing Methods 0.000 claims description 10
- 239000012982 microporous membrane Substances 0.000 claims description 5
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
- H01M8/04126—Humidifying
- H01M8/04149—Humidifying by diffusion, e.g. making use of membranes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Fuel Cell (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
Abstract
The invention discloses a high-efficiency membrane humidifier for a fuel cell, which at least comprises a shell, wherein two sides of the shell are provided with opposite humidifying medium inlets and outlets; a membrane humidifying component is arranged between the flow cavities at two sides in the shell, and at least humidifying membrane tubes arranged in a square matrix are arranged on the membrane humidifying component; the two sides of the shell adjacent to the inlet and the outlet are respectively provided with a connecting flow guide end cover, and the two side flow guide end covers are respectively communicated with a gas guide port. The structure can effectively reduce the impact and separation action among the humidifying membrane tube bundles, reduce the disturbance in the flow field and improve the flow distribution uniformity of the humidifying medium measured outside the humidifying membrane tube; the air flow in the humidifying membrane tube is smoother, the membrane tube is prevented from vibrating, the resistance in the membrane tube is reduced, and the service life of the membrane tube is prolonged; the uniform gap of the humidifying membrane tube in the longitudinal direction is not increased in resistance while the filling rate of the membrane tube is increased, so that the mass and heat transfer efficiency of the whole humidifier is improved.
Description
Technical Field
The invention relates to the field of proton exchange membrane fuel cell systems, in particular to a high-efficiency membrane humidifier for a fuel cell.
Background
Proton Exchange Membrane Fuel Cells (PEMFC) have the advantages of environmental protection, high efficiency, high starting speed, high power density and the like, are one of the main competitors of future traffic power systems, and the fuel cells can obtain good working performance under the condition of proper humidity. Both fuel cell air and hydrogen feed gases need to be humidified to prevent dehydration of the proton exchange membrane from degrading cell performance and operating life, allowing efficient operation of the fuel cell. In many humidification technical routes, wet waste gas put by the membrane humidifier through the PEMFC is recycled for humidifying and heating reactants, and the membrane humidifier becomes a mainstream external humidification technical scheme at present due to the advantages of stable humidification, strong controllability, large humidification amount, no extra power consumption and the like. In particular, membrane humidifiers utilize the principle of membrane diffusion, with dry and wet gas streams flowing in parallel across the membrane, while water vapor and thermal energy are diffused from one side of the membrane to the other. Among them, the water diffusivity depends mainly on the water flow rate (humidity difference convection), membrane pressure difference (diffusion), membrane thickness, fluid temperature characteristics. Under the condition that the performance of the membrane material and the condition of the use environment are the same, the humidifying performance of the membrane humidifier also depends on a humidifying medium flow field structure formed by a membrane tube arrangement structure of a humidifying module, particularly a hollow fiber tubular membrane humidifier, no matter the structure is a cross flow type structure or a counter flow type structure, the arrangement structure of the humidifying membrane tubes has very important influence on the humidifying efficiency.
The humidifying membrane tubes of current humidifying modules are generally placed in several arrangements as shown in fig. 1-3:
wherein, fig. 1 is a random arrangement in the same direction, in this form, because the humidifying membrane tube 20 is soft, the state of the humidifying membrane tube 20 in the humidifying module is curved and in a loose state, the curve increases the flow resistance of the dry gas flow field, and the bending causes the vibration of the humidifying membrane tube 20 due to the coanda effect, thereby causing the increase of the flow resistance and affecting the service life of the humidifying membrane tube 20; the randomness of randomly placing the tube bundle distribution can lead the velocity distribution of the outer flow field of the tube bundle to be seriously deteriorated, the nonuniformity of the flow distribution can lead the randomly arranged tube bundle to cause the heat and mass transfer performance to be obviously reduced, the conjugate boundary of the membrane surface of the humidifying membrane tube 20 has larger deterioration effect, and the corresponding convection heat and mass transfer coefficient is lower than that under the ideal boundary condition; the comprehensive membrane tube filling rate of the whole humidifier is low, and the humidifying efficiency is influenced;
wherein, fig. 2 is a bundling and random arrangement form in the same direction, in which, even though the bundling is performed, the transverse bending is improved, the random arrangement is still a disadvantage because the humidifying membrane tubes 20 are soft; the humidifying membrane tubes 20 in the bundled tube bundle are still randomly placed, and the deterioration of the velocity distribution of the external flow field is still serious; the comprehensive membrane tube filling rate of the whole humidifier is low, and the humidifying efficiency is influenced;
in the form, the tube bundle states of the humidifying membrane tubes 20 in the integration cage 3 are equivalent to larger bundled tube bundles after being bundled more tightly, although the humidifying membrane tubes 20 are transversely placed straighter, the humidifying membrane tubes 20 in the integration cage 3 are closer to each other, and the anti-seismic performance of the humidifying membrane tubes is improved, but the problem that the humidifying membrane tubes 20 are randomly placed still exists; the tighter state of the humidifying membrane tubes 20 makes it difficult for the humidifying medium to enter the tube bundle, resulting in too low local speed or flow dead zone inside the assembly, and still having the deteriorating effect of flow distribution non-uniformity on the cooling efficiency and the humidifying efficiency of the assembly; in order to reduce the humidifying medium flow resistance, sufficient space must be left when the humidifying unit is placed in the housing, which affects the overall membrane tube fill rate.
Accordingly, those skilled in the art have been made in an effort to develop a fuel cell high efficiency membrane humidifier to solve the above problems.
Disclosure of Invention
In view of the above-mentioned defects in the prior art, the technical problem to be solved by the present invention is to provide a high efficiency membrane humidifier for fuel cell, which can improve the humidification efficiency and the service life of the membrane tube under the same humidification material and usage environment, so as to effectively reduce the volume of the humidifier and improve the service life of the whole fuel cell.
In order to solve the above problems, the invention provides a high-efficiency membrane humidifier for a fuel cell, which at least comprises a shell, wherein the shell is of a three-dimensional structure, two opposite humidifying medium inlets and outlets are arranged on two sides of the shell, a flow guide cavity is arranged in the shell, and the humidifying medium inlets and outlets are communicated with the flow guide cavity; a membrane humidifying component is arranged between the diversion cavities on two sides in the shell, and at least humidifying membrane tubes arranged in a square matrix are arranged on the membrane humidifying component; and the two sides of the shell adjacent to the inlet and the outlet are respectively provided with a connecting flow guide end cover, and the flow guide end covers at the two sides are respectively communicated with a gas guide port.
Furthermore, the two opposite end faces of the shell and the flow guide end cover are respectively provided with a mounting ring I and a mounting ring II, and the mounting rings I and the mounting rings II are fastened through bolts, so that the flow guide end cover is connected to the shell.
Furthermore, a sealing ring is arranged between the flow guide end cover and the mounting ring I and the mounting ring II at the two ends of the shell, anti-skid lines are arranged on the surface of the sealing ring, and the shell and the flow guide end cover are stably sealed.
Furthermore, the humidifying membrane tubes are fixed by a mesh grid structure and arranged in a square matrix, and shockproof cages are arranged outside the humidifying membrane tubes arranged in the square matrix and integrated with the mesh grid structure.
Furthermore, the two ends of the humidifying unit formed by the shockproof cage and the humidifying membrane tube matrix are sealed with the shell through glue filling.
Furthermore, the grid structure is provided with N rows (N is more than 2) of grid cage nets used for restraining the membrane tubes in the longitudinal direction, the membrane tubes are restrained to be vertically stacked and arranged, the membrane tubes are kept in a horizontal straight state, and gaps are formed between the vertically arranged membrane tubes and can be used as humidifying medium air channels.
Furthermore, a humidified medium cavity is formed by the air guide port, the flow guide end cover, the glue filling and the inner side of the humidifying membrane tube, the humidifying medium inlet and outlet, the flow guide cavity, the outer side of the membrane tube and the glue filling form a humidifying medium cavity, and the humidified medium cavity and the humidifying medium cavity are separated through the wall of the humidifying membrane tube, so that the humidified medium and the humidifying medium are effectively isolated.
Furthermore, the humidifying medium can be wet gas or liquid water, the humidifying medium can have higher temperature, the humidifying medium with higher temperature, such as water vapor or water, can increase the transfer speed of water in the membrane humidifying component with the special structure so as to increase the humidifying efficiency of the membrane humidifying component with the special structure, and the heat of the humidifying medium can be effectively transmitted to the medium to be humidified through the membrane humidifying component with the special structure so as to realize the warming of the medium to be humidified during humidifying.
Furthermore, the humidifying membrane tube may be a homogeneous membrane material with selective permeation made of a high polymer material, or a microporous membrane material with selective permeation made of a high polymer material.
The implementation of the fuel cell high-efficiency membrane humidifier provided by the invention has the following technical effects:
(1) in the technical scheme, the flow guide cavity arranged at the inlet and the outlet of the humidifying medium on the shell can improve the flow field structure of the humidifying cavity;
(2) in the technical scheme, the arrangement of the humidifying membrane tube structures arranged in a matrix can realize that uniform gaps are kept among the membrane tubes in the inlet and outlet directions of the humidifying medium; the film tubes are arranged in a square parallel matrix, and the humidifying film tubes are vertically kept in linear and compact arrangement; meanwhile, the transverse linear fixation of the membrane tube can be kept, the membrane tube vibration caused by the coanda effect due to the bending and loosening of the membrane tube is effectively reduced, the resistance is reduced, and the service life of the membrane tube is prolonged;
(3) in the technical scheme, the humidifying unit formed by the shockproof cage and the humidifying membrane tube matrix can assist in realizing higher comprehensive membrane tube filling rate;
(4) in the technical scheme, the design of the grid structure strengthens the vertical heat-moisture exchange of the membrane tube arrays and does not influence the heat-moisture exchange between the transverse membrane tube arrays;
(5) according to the technical scheme, the impact and separation action among tube bundles are effectively reduced, the disturbance in a flow field is reduced, the flow distribution uniformity is improved, especially the flow distribution uniformity of a humidification medium around a membrane tube can be still kept when the flow becomes large and the flow speed becomes fast when a fuel cell system runs at high power, the membrane surface is kept close to constant concentration, and the mass transfer coefficient and the resistance coefficient are optimized;
(6) in the technical scheme, the uniform gap of the humidifying membrane tube in the longitudinal direction enables the filling rate of the membrane tube to be increased without increasing resistance, so that the mass and heat transfer efficiency of the whole humidifier is improved.
Drawings
The conception, the specific structure and the technical effects of the present invention will be further described in conjunction with the accompanying drawings so as to fully understand the objects, the features and the effects of the present invention:
FIGS. 1 to 3 are schematic views showing the arrangement of humidifying membrane tubes in the background art of the present invention;
FIG. 4 is a schematic view of the membrane humidifier according to an embodiment of the present invention;
FIG. 5 is a schematic structural diagram of a humidifying unit in an embodiment of the present invention;
FIG. 6 is a schematic view of the glue filling structure of FIG. 5;
FIG. 7 is a schematic diagram of a mesh grid structure in an embodiment of the invention;
FIG. 8 is a schematic view of the structure of a constrained membrane tube of the grid structure of FIG. 7;
fig. 9 is a schematic top view of the humidifying unit.
In the figure:
1. a housing; 100. a humidifying medium inlet; 101. a humidifying medium outlet; 11. a flow guide cavity; 12. a flow guide end cover; 130. an air guide inlet; 131. an air outlet; 14. a seal ring; 15. a mounting ring I; 16. a mounting ring II; 17. bolt
20. Humidifying the membrane tube; 21. a mesh structure; 22. an air duct; 24. a shock-proof cage; 25. pouring glue;
3. an integrated cage.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The technical solution of the present invention is described in detail below using examples.
As shown in fig. 4 to 9, the embodiment provides a high-efficiency membrane humidifier for a fuel cell, which at least includes a housing 1, where the housing 1 is of a three-dimensional structure, two opposite humidifying medium inlets and outlets are disposed on two side surfaces of the housing 1 of the three-dimensional structure, flow guide cavities 11 are disposed on inner sides of two side cavities of the housing 1 where the humidifying medium inlets and outlets are disposed, the humidifying medium inlets and outlets are communicated with the flow guide cavities 11, a humidifying medium enters the flow guide cavities 11 through the humidifying medium inlets and outlets and then enters the housing 1, and the flow guide cavities 11 are disposed to improve a flow field structure of.
The humidifying medium inlet and outlet actually comprise two parts, namely a humidifying medium inlet 100 and a humidifying medium outlet 101, wherein the humidifying medium enters the inner cavity of the shell 1 from the humidifying medium inlet 100 and is discharged to the outside of the shell 1 from the humidifying medium outlet 101; as shown in the figure, a humidifying medium inlet 100 is arranged above the right side of the shell 1, and a humidifying medium outlet 101 is arranged below the left side of the shell 1; in actual operation, the position can be adjusted as required.
A membrane humidifying component is arranged between the side flow cavities 11 at two sides in the shell 1, and at least humidifying membrane tubes 20 arranged in a square matrix are arranged on the membrane humidifying component; the humidifying membrane tubes 20 are fixed by a grid structure 21 to be arranged in a square matrix, N rows (N is more than 2) of grid cage nets for restraining the membrane tubes are arranged on the grid structure 21 in the longitudinal direction, the membrane tubes are restrained to be arranged in a vertical stacked mode, the membrane tubes are kept in a horizontal straight state, and gaps are formed between the vertically arranged membrane tubes to serve as humidifying medium air channels 22.
Generally speaking, the grid structure 21 is a rectangular three-dimensional structure formed by longitudinally arranging a plurality of rows of rectangular grids, and the rectangular grids are the same as the conventional grids and are formed by sequentially arranging a plurality of grid bars.
The outsides of the humidifying membrane tubes 20 arranged in a square matrix are provided with shockproof cages 23 which are integrated with the mesh grid structure 21; the two ends of the humidifying unit formed by the shockproof cage 23 and the humidifying membrane tube 20 matrix form sealing with the shell 1 through potting adhesive 24.
Two sides of the shell 1 adjacent to the humidifying medium inlet and outlet 10 are respectively provided with a connecting flow guide end cover 12, and the flow guide end covers 12 on the two sides are respectively communicated with a gas guide port. The opposite end faces of the shell 1 and the diversion end cover 12 are respectively provided with a mounting ring I15 and a mounting ring II16, and the mounting ring I15 and the mounting ring II16 are fastened through bolts 17, so that the diversion end cover 12 is connected to the shell 1. Sealing rings 14 are arranged between the guide end cover 12 and the mounting rings I15 and II16 at the two ends of the shell 1, and anti-skid grains are arranged on the surfaces of the sealing rings 14 to ensure the stable sealing of the shell 1 and the guide end cover 12.
In practical operation, the connection between the casing 1 and the flow guide end cover 12 may take other forms as long as the connection and the sealing fastening of the casing and the flow guide end cover are ensured.
The air guide port is divided into an air guide inlet 130 and an air guide outlet 131, and the air guide inlet 13 is arranged above the left air guide end cover 12 as shown in the figure and is used for the entrance of the dry air; the air outlet 131 is arranged above the Oume's air guide end cover 12 as shown in the figure and is used for discharging the dry air, and the height of the air outlet 131 is slightly higher than that of the air inlet 130.
The air guide port, the guide end cover 12, the glue filling 24 and the inner side of the humidifying membrane tube 20 form a humidified medium cavity, the humidifying medium inlet and outlet 10, the guide cavity 11, the outer side of the humidifying membrane tube 20 and the glue filling 24 form a humidifying medium cavity, and the humidified medium cavity and the humidifying medium cavity are separated through the wall of the humidifying membrane tube 20, so that the humidified medium and the humidifying medium are effectively isolated.
The humidifying medium can be wet gas or liquid water, the humidifying medium can have higher temperature, the humidifying medium with higher temperature, such as water vapor or water, can increase the transfer speed of moisture in the membrane humidifying component with the special structure so as to increase the humidifying efficiency of the membrane humidifying component with the special structure, and the heat of the humidifying medium can be effectively transmitted to the medium to be humidified through the membrane humidifying component with the special structure so as to realize the temperature increase of the medium to be humidified during humidification.
The humidifying membrane tube 20 may be a homogeneous membrane material with selective permeation made of a polymer material, or a microporous membrane material with selective permeation made of a polymer material.
Based on the high-efficient membrane humidifier of above-mentioned fuel cell, its theory of operation does: when the humidifying device is used, a user adds a humidifying medium into the humidifying medium inlet/outlet 10, the humidifying medium enters the inner cavity of the flow guide cavity 11 and further enters the shell 1, so that the humidifying medium inlet/outlet 10, the flow guide cavity 11, the outer side of the membrane tube and the lower strand of glue filling 24 are matched to form a humidifying medium cavity, and the humidified medium is input into the membrane humidifying component in the shell 1; the air guide port 13, the guide end cover and the inner side of the humidifying membrane tube 20 form a humidified medium cavity, in the process, the humidifying membrane tube 20 can be a homogeneous membrane material with selective permeation made of high polymer material, the transmission of water inside and outside the humidifying membrane tube 20 is realized by utilizing the partial pressure difference between the inside and the outside of the membrane tube so as to realize high-efficiency humidifying performance, this humidification membrane pipe 20 also can be made by macromolecular material and has selectively permeable microporous membrane material, the micropore size is for can effectively stopping liquid water but allow vapor to pass through, utilize the concentration difference and the pressure differential on membrane both sides, realize the transmission of moisture in humidification membrane pipe 20 inside and outside and realize high-efficient humidification performance, homogeneous membrane material and selectively permeable microporous membrane material all possess the selective barrier effect, only the hydrone passes through in the membrane material for humidification medium in the humidification process and by effectively keeping apart between the humidification medium. In the process, as the mesh grid structures 21 longitudinally arranged in the membrane humidification assembly restrain the humidification membrane tubes 20 to form vertical stacked arrangement and keep the membrane tubes in a horizontal straight state, gaps can be formed between the vertically arranged membrane tubes to serve as humidification medium air channels 22, so that the heat and humidity exchange between the vertical membrane tube arrays is effectively guaranteed, and the heat and humidity exchange between the horizontal membrane tube arrays is not influenced; meanwhile, the grid structure 21 and the shockproof cage 23 are combined and fixed with the shell 1 through the potting adhesive 24, so that the membrane tube vibration caused by the coanda effect due to bending and loosening of the membrane tube is effectively reduced, the resistance is reduced, and the service life of the membrane tube is prolonged.
Based on the high-efficiency membrane humidifier for the fuel cell, the membrane humidification component with a special structure can effectively reduce impact and separation between tube bundles, reduce disturbance in a flow field, improve the uniformity of flow distribution, and particularly can still keep the uniformity of flow distribution of a humidification medium around a membrane tube when the flow becomes large and the flow rate becomes fast when a fuel cell system runs at high power, so that the surface of the membrane keeps close to constant concentration, and the mass transfer coefficient and the resistance coefficient of the membrane humidifier are optimized; the uniform gaps of the humidifying membrane tubes 20 which are longitudinally arranged do not increase resistance while increasing the filling rate of the membrane tubes, so that the mass and heat transfer efficiency of the whole humidifier is improved, the volume of the humidifier can be reduced, and the service life of the humidifier can be prolonged.
It should be added that, unless otherwise defined, technical or scientific terms used herein shall have the ordinary meaning as understood by those of ordinary skill in the art to which this invention belongs. The terms "connected" or "coupled" and the like as used in the description and claims of the present patent application are not restricted to physical or mechanical connections, but may include electrical connections, whether direct or indirect. "upper", "lower", "end", "side", and the like are used merely to indicate relative positional relationships, and when the absolute position of the object to be described is changed, the relative positional relationships are changed accordingly.
Other embodiments of the invention will be apparent to those skilled in the art from consideration of the specification and practice of the invention disclosed herein. This application is intended to cover any uses or adaptations of the invention following, in general, the principles of the invention and including such departures from the present disclosure as come within known or customary practice within the art to which the invention pertains. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the invention being indicated by the following claims.
It will be understood that the present invention is not limited to the structures that have been described above and shown in the drawings, and that various modifications and changes can be made without departing from the scope thereof. The scope of the invention is limited only by the appended claims.
Claims (9)
1. The high-efficiency membrane humidifier for the fuel cell is characterized by at least comprising a shell, wherein the shell is of a three-dimensional structure, two opposite humidifying medium inlets and outlets are formed in two sides of the shell, a flow guide cavity is formed in the shell, and the humidifying medium inlets and outlets are communicated with the flow guide cavity; a membrane humidifying component is arranged between the diversion cavities on two sides in the shell, and at least humidifying membrane tubes arranged in a square matrix are arranged on the membrane humidifying component; and the two sides of the shell adjacent to the inlet and the outlet are respectively provided with a connecting flow guide end cover, and the flow guide end covers at the two sides are respectively communicated with a gas guide port.
2. The fuel cell high efficiency membrane humidifier according to claim 1, wherein a mounting ring I and a mounting ring II are respectively disposed on two opposite end surfaces of the housing and the flow guide end cap, and the mounting ring I and the mounting ring II are fastened by bolts to connect the flow guide end cap to the housing.
3. The high-efficiency membrane humidifier for the fuel cell as claimed in claim 2, wherein sealing rings are arranged between the flow guide end cover and the mounting rings I and II at two ends of the casing, and the surfaces of the sealing rings are provided with anti-skid lines to ensure the stable sealing between the casing and the flow guide end cover.
4. The fuel cell high efficiency membrane humidifier according to claim 1, wherein said humidification membrane tubes are fixed in a square matrix arrangement by a mesh structure, and vibration-proof cages are provided outside said humidification membrane tubes in the square matrix arrangement and integrated with said mesh structure.
5. The fuel cell high efficiency membrane humidifier according to claim 4, wherein the two ends of the humidification unit formed by the vibration-proof cage and the humidification membrane tube matrix are sealed with the housing by potting.
6. The fuel cell high efficiency membrane humidifier according to claim 5, wherein the mesh structure is provided with N rows (N > 2) of mesh cage nets for restraining the membrane tubes in a longitudinal direction, the membrane tubes are restrained in a vertically stacked arrangement, and the membrane tubes are kept in a horizontal straight state, and gaps are formed between the vertically arranged membrane tubes to serve as humidifying medium air channels.
7. The efficient membrane humidifier for fuel cells as claimed in claim 6, wherein the air guide port, the flow guide end cap, the potting adhesive and the inner side of the humidification membrane tube form a humidified medium cavity, the humidification medium inlet/outlet, the flow guide cavity, the outer side of the membrane tube and the potting adhesive form a humidification medium cavity, and the humidified medium cavity and the humidification medium cavity are separated through the wall of the humidification membrane tube, so that the humidified medium and the humidification medium are effectively isolated.
8. The efficient membrane humidifier for fuel cell as claimed in claim 7, wherein the humidification medium can be wet gas or liquid water, the humidification medium can have a higher temperature, the higher temperature humidification medium can increase the transfer rate of water in the specially configured membrane humidification module to increase the humidification efficiency of the specially configured membrane humidification module, and the heat of the humidification medium can be effectively conducted to the medium to be humidified through the specially configured membrane humidification module to increase the temperature of the medium to be humidified while humidifying.
9. The high efficiency membrane humidifier for fuel cell as claimed in claim 8, wherein the humidifying membrane tube is made of a homogeneous membrane material with selective permeation, or a microporous membrane material with selective permeation.
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CN202011017752.0A CN112103534A (en) | 2020-09-24 | 2020-09-24 | High-efficient membrane humidifier of fuel cell |
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CN116387562A (en) * | 2023-06-02 | 2023-07-04 | 国家电投集团氢能科技发展有限公司 | Humidifier, fuel cell system, and humidity adjustment method |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016004850A1 (en) * | 2016-04-22 | 2017-10-26 | Daimler Ag | Humidifier for a fuel cell system. Fuel cell system and vehicle |
CN109378502A (en) * | 2018-10-30 | 2019-02-22 | 嘉兴德燃动力系统有限公司 | A kind of film humidifier of automotive fuel cell dynamical system |
CN208955117U (en) * | 2018-10-16 | 2019-06-07 | 深圳市南科动力科技有限公司 | A kind of fuel cell membranes humidifier |
CN110957511A (en) * | 2019-12-31 | 2020-04-03 | 大连宇科创新科技有限公司 | Integrated fuel cell test platform gas humidification heating device |
CN214672701U (en) * | 2020-09-24 | 2021-11-09 | 天朤(江苏)氢能源科技有限公司 | High-efficient membrane humidifier of fuel cell |
-
2020
- 2020-09-24 CN CN202011017752.0A patent/CN112103534A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016004850A1 (en) * | 2016-04-22 | 2017-10-26 | Daimler Ag | Humidifier for a fuel cell system. Fuel cell system and vehicle |
CN208955117U (en) * | 2018-10-16 | 2019-06-07 | 深圳市南科动力科技有限公司 | A kind of fuel cell membranes humidifier |
CN109378502A (en) * | 2018-10-30 | 2019-02-22 | 嘉兴德燃动力系统有限公司 | A kind of film humidifier of automotive fuel cell dynamical system |
CN110957511A (en) * | 2019-12-31 | 2020-04-03 | 大连宇科创新科技有限公司 | Integrated fuel cell test platform gas humidification heating device |
CN214672701U (en) * | 2020-09-24 | 2021-11-09 | 天朤(江苏)氢能源科技有限公司 | High-efficient membrane humidifier of fuel cell |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116387562A (en) * | 2023-06-02 | 2023-07-04 | 国家电投集团氢能科技发展有限公司 | Humidifier, fuel cell system, and humidity adjustment method |
CN116387562B (en) * | 2023-06-02 | 2023-08-18 | 国家电投集团氢能科技发展有限公司 | Humidifier, fuel cell system, and humidity adjustment method |
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