CN112103410B - flexible battery - Google Patents

flexible battery Download PDF

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Publication number
CN112103410B
CN112103410B CN201910527729.7A CN201910527729A CN112103410B CN 112103410 B CN112103410 B CN 112103410B CN 201910527729 A CN201910527729 A CN 201910527729A CN 112103410 B CN112103410 B CN 112103410B
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China
Prior art keywords
layer
rubber
battery
flexible battery
barrier layer
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Application number
CN201910527729.7A
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Chinese (zh)
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CN112103410A (en
Inventor
韩玲莉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Xiaomi Mobile Software Co Ltd
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Beijing Xiaomi Mobile Software Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Beijing Xiaomi Mobile Software Co Ltd filed Critical Beijing Xiaomi Mobile Software Co Ltd
Priority to CN202311321944.4A priority Critical patent/CN117276770A/en
Priority to CN201910527729.7A priority patent/CN112103410B/en
Publication of CN112103410A publication Critical patent/CN112103410A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/131Primary casings, jackets or wrappings of a single cell or a single battery characterised by physical properties, e.g. gas-permeability or size
    • H01M50/136Flexibility or foldability
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/102Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
    • H01M50/105Pouches or flexible bags
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/124Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
    • H01M50/126Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
    • H01M50/129Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers with two or more layers of only organic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The disclosure relates to a flexible battery, and belongs to the technical field of batteries. The flexible battery provided by the disclosure has better flexibility, better deformability and difficult damage in the deformation process. The flexible battery includes: electrode assembly and package case. Wherein, the packaging shell wraps the electrode assembly and comprises a rubber layer, a barrier layer and a bonding layer which are arranged in a stacked manner; the barrier layer is located between the rubber layer and the adhesive layer.

Description

Flexible battery
Technical Field
The disclosure relates to the field of battery technology, and in particular relates to a flexible battery.
Background
In recent years, flexible batteries that can be bent and deformed have become a new trend in the development of batteries. The flexible battery can be widely applied to wearable electronic products and electronic products with folding screens or curved screens. When in use, the flexible battery adapts to different use forms of the electronic product through bending. It will be appreciated that the flexibility of the flexible battery is a key property to ensure the quality of the flexible battery.
Disclosure of Invention
The present disclosure provides a flexible battery having better flexibility and deformation stability.
According to the flexible battery provided by the embodiment of the disclosure, the flexible battery comprises: an electrode assembly; the packaging shell is used for coating the electrode assembly and comprises a rubber layer, a barrier layer and a bonding layer which are arranged in a stacked manner; the barrier layer is located between the rubber layer and the adhesive layer.
In one embodiment, the adhesive layer is located on a side of the barrier layer facing the electrode assembly; the rubber layer is located on a side of the barrier layer facing away from the electrode assembly.
In one embodiment, the rubber layer is in conforming connection with the barrier layer.
In one embodiment, a glue layer is provided between the rubber layer and the barrier layer, through which glue layer the rubber layer is connected to the barrier layer.
In one embodiment, the material of the tie layer comprises a rubber component.
In one embodiment, the material of the rubber layer and the rubber component include at least one of: nitrile rubber, styrene butadiene rubber, isoprene rubber, neoprene rubber.
In one embodiment, the tie layer is a composite layer, the material of the tie layer further comprising a resin component.
In one embodiment, the resin component in the tie layer comprises at least one of: polypropylene and polyethylene.
In one embodiment, the barrier layer is a metal foil, and the material of the barrier layer is selected from aluminum, copper, phosphor bronze, aluminum bronze, and copper alloy.
In one embodiment, the electrode assembly includes: a battery anode, a separator, and a battery cathode, which are stacked; the flexible battery further includes: one end of the anode terminal is connected with the battery anode, and the other end of the anode terminal is positioned outside the packaging shell; and a cathode terminal having one end connected to the cathode of the battery and the other end located outside the package case.
In one embodiment, the electrode assembly further comprises: an inner casing that encapsulates the battery anode, the separator, and the battery cathode.
The flexible battery provided by the disclosure has at least the following beneficial effects:
according to the flexible battery provided by the embodiment of the disclosure, the flexibility of the whole flexible battery is improved by arranging the rubber layer in the packaging shell, and the deformation matching degree of the flexible battery and the external component is improved. And in the use process, the packaging shell is not easy to damage, so that the use stability and the safety of the flexible battery are improved.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the disclosure and together with the description, serve to explain the principles of the disclosure.
Fig. 1 is a schematic structural view of a flexible battery according to an exemplary embodiment;
fig. 2 is a schematic structural view of a flexible battery according to another exemplary embodiment;
fig. 3 is a schematic structural view of a flexible battery according to another exemplary embodiment;
fig. 4 is a schematic structural view showing a cross section of a package case in a flexible battery according to an exemplary embodiment;
fig. 5 is a sectional view showing a combined structure of a package case and an electrode assembly in a flexible battery according to an exemplary embodiment.
Detailed Description
Reference will now be made in detail to exemplary embodiments, examples of which are illustrated in the accompanying drawings. When the following description refers to the accompanying drawings, the same numbers in different drawings refer to the same or similar elements, unless otherwise indicated. The implementations described in the following exemplary examples do not represent all implementations consistent with the application. Rather, they are merely examples of apparatus and methods consistent with aspects of the application as detailed in the accompanying claims.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the application. Unless defined otherwise, technical or scientific terms used herein should be given the ordinary meaning as understood by one of ordinary skill in the art to which this application belongs. The use of the terms "a" or "an" and the like in the description and in the claims do not denote a limitation of quantity, but rather denote the presence of at least one. Unless otherwise indicated, the terms "comprises," "comprising," and the like are intended to cover the presence of elements or articles recited as being "comprising" or "including," and equivalents thereof, without excluding other elements or articles. The terms "connected" or "connected," and the like, are not limited to physical or mechanical connections, but may include electrical connections, whether direct or indirect.
As used in this specification and the appended claims, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise. It should also be understood that the term "and/or" as used herein refers to and encompasses any or all possible combinations of one or more of the associated listed items.
The flexible battery has a flexible packaging shell to ensure that the flexible battery can be bent or folded during use. In the related art, an aluminum plastic film is used to form the package housing. The inventors have found that the flexibility of the package case in the related art has room for further improvement to optimize the flexibility of the flexible battery.
Based on the foregoing, embodiments of the present disclosure provide a flexible battery. Fig. 1 to 5 are schematic structural views of a flexible battery provided according to various embodiments.
As shown in fig. 1, the flexible battery includes an electrode assembly 10, a package case 20 covering the electrode assembly 10, and an electrode terminal 30 (not shown in the connection part) provided on the package case 20 and connected to the electrode assembly 10.
The package case 20 encapsulates the electrode assembly 10, the electrode terminal 30, and the electrolyte as one body. Wherein the package case 20 forms a package cavity 25, and the electrode assembly 10 and the electrolyte are positioned inside the package cavity 25. The electrode terminal 30 has one end connected to the electrode assembly 10 and the other end located outside the package cavity 25 for cooperation with a power interface of an external assembly.
In one embodiment, as shown in fig. 2, the electrode assembly 10 includes a battery anode 11, a separator 12, and a battery cathode 13, which are stacked.
The battery anode 11 includes an anode current collector and an anode active material layer. Wherein the anode active material layer is provided on at least one face of the anode current collector. Illustratively, an anode active material layer is coated on at least one side of the anode current collector. The battery cathode 13 includes a cathode current collector and a cathode active material. Wherein the cathode active material is disposed on at least one side of the cathode current collector. Illustratively, a cathode active material layer is coated on at least one side of the cathode current collector. Separator 12 is disposed between cell anode 11 and cell cathode 13, separating cell anode 11 from cell cathode 13.
Wherein, the battery anode 11, the battery cathode 13 and the diaphragm 12 are made of flexible materials which can be bent and deformed. Illustratively, the battery anode 11 and the battery cathode 13 are prepared using metal foils, such as copper foil, aluminum foil, cobalt foil, zinc foil, nickel foil, manganese foil, titanium foil, iron foil, silver foil, and the like. The separator 12 is made of a resin film, such as a polypropylene film, a polyethylene film, or the like.
The electrode terminal 30 includes an anode terminal 31 and a cathode terminal 32. Wherein one end of the anode terminal 31 is connected to the battery anode 11 and the other end is exposed to the outside of the package case 20. One end of the cathode terminal 32 is connected to the battery cathode 13, and the other end is exposed to the outside of the package case 20. The portions of the anode terminal 31 and the cathode terminal 32 exposed to the outside of the package case 20 are for cooperation with a power interface of an external device such that the flexible battery supplies power to the external device.
In one embodiment, as shown in fig. 3, electrode assembly 10 further includes an inner casing 14 that encloses battery anode 11, battery cathode 13, separator 12, and electrolyte. The sealability of the flexible battery is further enhanced by the encapsulation of the inner case 14, and the stable use of the flexible battery is ensured. The inner can 14 is made of flexible material and is folded synchronously with the electrode assembly 10 and the outer can 20 when in use.
Optionally, inner housing 14 has a smooth surface that is curved to provide a smooth curve. Or, alternatively, inner housing 14 includes a toughening structure. For example, the toughening structure includes associated recesses and protrusions disposed on the surface of inner housing 14. The toughening structure is wavy for improving the toughness of the inner shell 14.
In one embodiment, as shown in fig. 4, the package housing 20 includes a rubber layer 21, a barrier layer 22, and an adhesive layer 23, which are stacked.
The barrier layer 22 is used to prevent impurities (e.g., moisture, etc.) outside the package case 20 from entering the package cavity 25, and secure the use of the electrode assembly 10. Optionally, the barrier layer 22 is made of a metal foil, which combines both barrier properties and bending properties of the barrier layer 22. Wherein the metal foil is made of aluminum, copper, phosphor bronze, aluminum bronze, copper alloy, etc.
The rubber layer 21 is provided on one side of the barrier layer 22. As an example, the rubber layer 21 is directly attached to the barrier layer 22. For example, the rubber layer 21 is directly formed on the barrier layer 22 by a process of spraying, coating, curtain coating, or the like. As another example, a glue layer 24 is provided between the rubber layer 21 and the barrier layer 22, and the rubber layer 21 is connected to the barrier layer 22 through the glue layer 24.
Alternatively, the thickness of the rubber layer 21 is 20 to 30 micrometers (μm), for example 23 μm, 25 μm, 27 μm, etc.
Illustratively, the rubber layer 21 includes at least one of the following rubber components: nitrile rubber, styrene butadiene rubber, isoprene rubber, neoprene rubber and fluororubber. Of course, the rubber layer 21 may also include other rubber components. Here, when the rubber layer 21 includes a plurality of rubber components, the rubber layer 21 further includes a modifier. The modifier is used for regulating and controlling the combination stability of different rubber components so as to optimize the mechanical properties of the rubber layer 21.
The rubber layer 21 is excellent in flexibility and deformation ability. In the embodiment of the present disclosure, by providing the rubber layer 21 on the barrier layer 22, the flexibility of the entire package housing 20 is optimized, so that the package housing 20 is more easily bent. Accordingly, the flexible battery and the external component are kept synchronously bent, so that the flexible battery is fitted with the external component as much as possible. For example, the degree of deformation of the flexible battery is consistent with the degree of deformation of the flexible display screen, or the degree of deformation of the flexible battery is consistent with the degree of deformation of the wristband.
The rubber layer 21 has elasticity and is not easily broken after being bent a plurality of times. Therefore, when the flexible battery provided by the embodiment of the disclosure is used, the package shell 20 is not easy to damage due to bending, the occurrence of battery fire and other conditions is reduced, and the stable and safe use of the flexible battery is ensured.
The adhesive layer 23 is provided on the opposite side of the barrier layer 22 from the rubber layer 21. The adhesive layer 23 has a barrier effect to prevent corrosive substances from damaging the barrier layer 22. The adhesive layer 23 also has an adhesive connection function, and the package housing 20 is bonded by the adhesive layer 23 to form a package cavity 25.
As for the connection mode of the adhesive layer 23 and the barrier layer 22, as shown in fig. 4, an adhesive layer 24 is provided between the adhesive layer 23 and the barrier layer 22, and the adhesive layer 23 is connected to the barrier layer 22 through the adhesive layer 24.
As for the material of the adhesive layer 23, as an example, the material of the adhesive layer 23 is a resin such as polyethylene, polypropylene, cast polypropylene (cast polypropylene, CPP), or the like.
As another example, the material of the adhesive layer 23 includes a rubber component. For example, the material of the adhesive layer 23 is a rubber/resin composite material. The rubber/resin composite material is prepared by taking rubber and resin as main components through a physical blending or graft blending process. Optionally, the rubber/resin composite further comprises components such as a coupling agent. The coupling agent is used for improving the interfacial properties of the rubber component and the resin component, and ensuring that the adhesive layer 23 has good mechanical properties and processability.
Optionally, the rubber component in the tie layer 23 includes at least one of: nitrile rubber, styrene butadiene rubber, isoprene rubber, neoprene rubber and fluororubber. The resin component in the adhesive layer 23 includes at least one of: polyethylene, polypropylene (including cast polypropylene). Of course, other resin components and rubber components may be used, and the embodiments of the present disclosure are not particularly limited.
In this way, the adhesive layer 23 of the rubber/resin composite material has better flexibility and deformability than the simple resin adhesive layer 23. Accordingly, the flexibility of the package housing 20 is further optimized, so that the deformability of the flexible battery is improved, and the stable and safe use of the flexible battery is ensured.
In one embodiment, as shown in fig. 5, the rubber layer 21 is located on the side of the barrier layer 22 facing away from the electrode assembly 10, i.e., the rubber layer 21 faces the outside of the encapsulation cavity 25. In this way, the rubber layer 21 plays an external protective role, so that the barrier layer 22 is protected from mechanical damage. In addition, the rubber layer 21 is also decorative, so that the appearance performance of the flexible battery is improved.
The adhesive layer 23 is located on the side of the barrier layer 22 facing the electrode assembly 10, i.e., the rubber layer 21 is located inside the encapsulation cavity 25. In this way, the barrier layer 22 and the electrolyte solution or other corrosive liquid within the package cavity 25 are isolated by the adhesive layer 23. Particularly in the case of flexible batteries that do not include an inner housing 14, corrosion of barrier layer 22 by the electrolyte is effectively avoided by adhesive layer 23.
The flexible battery provided by the embodiment of the disclosure improves the flexibility of the whole flexible battery and improves the deformation matching degree of the flexible battery and an external component by arranging the rubber layer 21 in the packaging shell 20. And the package case 20 is not easily broken during use, improving the stability and safety of the use of the flexible battery.
It should be noted that, in the embodiment of the present disclosure, the flexible battery may be applied to a wearable device (e.g., a bracelet, a watch, glasses, etc.), a mobile terminal (e.g., a mobile phone, a tablet computer, etc.) having a flexible screen or a curved screen, a vehicle-mounted device, or a medical device.
Other embodiments of the disclosure will be apparent to those skilled in the art from consideration of the specification and practice of the disclosure disclosed herein. This application is intended to cover any adaptations, uses, or adaptations of the disclosure following, in general, the principles of the disclosure and including such departures from the present disclosure as come within known or customary practice within the art to which the disclosure pertains. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the disclosure being indicated by the following claims.

Claims (9)

1. A flexible battery, the flexible battery comprising:
an electrode assembly including a battery anode, a separator, and a battery cathode, which are stacked; the electrode assembly further includes: an inner packaging shell for packaging the battery anode, the diaphragm and the battery cathode, wherein the inner packaging shell is made of flexible materials; and
the packaging shell is used for coating the electrode assembly and comprises a rubber layer, a barrier layer and a bonding layer which are arranged in a stacked manner; the barrier layer is located between the rubber layer and the adhesive layer, the material of the adhesive layer including a rubber component.
2. The flexible battery of claim 1, wherein the adhesive layer is located on a side of the barrier layer facing the electrode assembly; the rubber layer is located on a side of the barrier layer facing away from the electrode assembly.
3. The flexible battery of claim 1, wherein the rubber layer is in conforming connection with the barrier layer.
4. The flexible battery of claim 1, wherein a glue layer is disposed between the rubber layer and the barrier layer, the rubber layer being connected to the barrier layer by the glue layer.
5. The flexible battery of claim 1, wherein the rubber layer material and the rubber component comprise at least one of: nitrile rubber, styrene butadiene rubber, isoprene rubber, neoprene rubber and fluororubber.
6. The flexible battery of claim 1, wherein the adhesive layer is a composite layer, the material of the adhesive layer further comprising a resin component.
7. The flexible battery of claim 6, wherein the resin component in the tie layer comprises at least one of: polypropylene and polyethylene.
8. The flexible battery according to claim 1, wherein the barrier layer is a metal foil, and the material of the barrier layer is selected from the group consisting of aluminum, copper, phosphor bronze, aluminum bronze, and copper alloy.
9. The flexible battery of claim 1, wherein the flexible battery further comprises: one end of the anode terminal is connected with the battery anode, and the other end of the anode terminal is positioned outside the packaging shell; and a cathode terminal having one end connected to the battery cathode and the other end exposed to the outside of the package case.
CN201910527729.7A 2019-06-18 2019-06-18 flexible battery Active CN112103410B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202311321944.4A CN117276770A (en) 2019-06-18 2019-06-18 Flexible battery and electronic product
CN201910527729.7A CN112103410B (en) 2019-06-18 2019-06-18 flexible battery

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Application Number Priority Date Filing Date Title
CN201910527729.7A CN112103410B (en) 2019-06-18 2019-06-18 flexible battery

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CN112103410B true CN112103410B (en) 2023-09-05

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112909404A (en) * 2021-02-05 2021-06-04 盐城师范学院 Flexible battery and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004199994A (en) * 2002-12-18 2004-07-15 Toshiba Corp Battery
CN104282848A (en) * 2013-07-07 2015-01-14 许振宇 Flexible battery structure
CN106605313A (en) * 2014-09-04 2017-04-26 阿莫绿色技术有限公司 Flexible battery, manufacturing method therefor, and auxiliary battery comprising flexible battery
CN106663757A (en) * 2014-09-05 2017-05-10 阿莫绿色技术有限公司 Flexible battery, manufacturing method therefor, and auxiliary battery comprising flexible battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004199994A (en) * 2002-12-18 2004-07-15 Toshiba Corp Battery
CN104282848A (en) * 2013-07-07 2015-01-14 许振宇 Flexible battery structure
CN106605313A (en) * 2014-09-04 2017-04-26 阿莫绿色技术有限公司 Flexible battery, manufacturing method therefor, and auxiliary battery comprising flexible battery
CN106663757A (en) * 2014-09-05 2017-05-10 阿莫绿色技术有限公司 Flexible battery, manufacturing method therefor, and auxiliary battery comprising flexible battery

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CN117276770A (en) 2023-12-22

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