CN112095361A

CN112095361A - Tea leaf residue paper box material and preparation method thereof

Info

Publication number: CN112095361A
Application number: CN202010862168.9A
Authority: CN
Inventors: 周秀妍
Original assignee: Cafa Technology Shanghai Co ltd
Current assignee: Cafa Technology Shanghai Co ltd
Priority date: 2020-08-25
Filing date: 2020-08-25
Publication date: 2020-12-18

Abstract

The invention discloses a tea leaf residue paper box material which comprises, by weight, 30-60 parts of tea leaf residue, 20-55 parts of plant fiber, 1-3 parts of mineral fiber, 1-3 parts of an antibacterial agent, 1-10 parts of an oxygen bleaching agent, 1-10 parts of a degrading enzyme, 1-15 parts of an adhesive and 5-10 parts of a waterproof agent. The tea leaf residues contain tea polyphenol, so that the natural bacteriostatic and deodorant functions are achieved, and the bacteriostatic performance of each component of the carton material can be improved by using the tea leaf residues as the raw materials of the carton material. Plant fiber in this scheme is the mixture of straw fibre and fibrilia, and the straw fibre has natural hydrophobicity and ageing resistance, and the fibrilia has better mechanical properties, and the carton material especially breeds the bacterium easily under the environment of humidity, mixes straw fibre and fibrilia and can improve whole carton material's hydrophobic property and mechanical strength, further can reduce breeding of bacterium and microorganism.

Description

Tea leaf residue paper box material and preparation method thereof

Technical Field

The application belongs to the technical field of paper materials, and particularly relates to a tea leaf residue paper box material and a preparation method thereof.

Background

With the improvement of economic level and the enhancement of environmental awareness, the use of disposable plastics by people is reduced, the use amount of the paper box as a substitute is gradually increased, the existing paper box has poor mechanical strength, bacteria are easy to breed after repeated use, and wood pulp is basically used as a raw material, so that a large number of trees are felled. Tea leaves are inherited by Chinese civilization for thousands of years, tea drinking is gradually becoming a part of global life style, the amount of tea leaves is also increasing year by year along with the further increase of the sales volume of the tea leaves, and the tea leaves can be used as raw materials of paper pulp to replace wood pulp and reduce the production cost of paper boxes by utilizing the waste of the tea leaves. However, the water resistance of the tea leaves is poor, and bacteria are easy to breed.

Disclosure of Invention

In order to solve the technical problem, the first aspect of the invention provides a tea leaf residue paper box material, which comprises, by weight, 30-60 parts of tea leaf residue, 20-55 parts of plant fiber, 1-3 parts of mineral fiber, 1-3 parts of an antibacterial agent, 1-10 parts of an oxygen bleaching agent, 1-10 parts of a degrading enzyme, 1-15 parts of an adhesive and 5-10 parts of a waterproof agent.

Preferably, the plant fiber is at least one selected from straw fiber, wood fiber, bamboo fiber, hemp fiber and cotton fiber.

Preferably, the plant fiber is a mixture of straw fiber and fibrilia, and the mass ratio of the straw fiber to the fibrilia is (3-5): 1.

preferably, the mineral fiber is selected from at least one of aluminum silicate fiber, glass fiber, gypsum fiber and carbon fiber.

Preferably, the antibacterial agent is a guanidine polymer, and the guanidine polymer is polyguanidine salt and/or polybiguanide salt.

Preferably, the oxygen bleaching agent is hydrogen peroxide.

Preferably, the degrading enzyme is selected from at least one of xylanase, hemicellulase, lignin degrading enzyme, cellulase and beta-glucanase.

Preferably, the binder is a mixture of a cellulose derivative containing methyl groups and starches, and the mass ratio of the cellulose derivative containing methyl groups to the starches is: 1: (3-5).

Preferably, the methyl group-containing cellulose derivative is at least one selected from the group consisting of methylcellulose, hydroxyethylmethylcellulose, and methylhydroxypropylcellulose.

Preferably, the water repellent is a methyl group-containing polysiloxane derivative.

Preferably, the methyl group-containing polysiloxane derivative is at least one selected from the group consisting of polydimethylsiloxane, cyclomethicone, polymethylphenylsiloxane and polymethylhydrosiloxane.

The second aspect of the invention provides a preparation method of a tea leaf residue paper box material, which at least comprises the following steps:

(1) crushing plant fiber and tea leaves to 0.1-1.5mm, and adding mineral fiber, degrading enzyme and water, wherein the weight ratio of the tea leaves to the water is 2: 5, standing for 8-12h at 50-70 ℃ to obtain a mixture A;

(2) adding white rot fungi into the mixture A at the temperature of 20-40 ℃, and standing for 24-73h, wherein the mass ratio of the white rot fungi to the mixture is 1: 50-80 to obtain a mixture B;

(3) adding an oxygen bleaching agent into the mixture B, and bleaching to obtain a mixture C;

(4) adding an antibacterial agent, an adhesive and a waterproof agent into the mixture C, and pulping to obtain a mixture D;

(5) and pressing and forming the mixture D in a mould to obtain the tea leaf residue paper box material.

Has the advantages that:

(1) the tea leaf residues contain tea polyphenol, so that the natural bacteriostatic and deodorizing functions are achieved, the bacteriostatic performance of each component of the carton material can be improved by using the tea leaf residues as the raw materials of the carton material, the tea leaf residues are recycled, and the production cost of the carton raw materials is reduced.

(2) Plant fiber in this scheme is the mixture of straw fibre and fibrilia, and the straw fibre has natural hydrophobicity and ageing resistance, and the fibrilia has better mechanical properties, and the carton material especially breeds the bacterium easily under the environment of humidity, mixes straw fibre and fibrilia and can improve whole carton material's hydrophobic property and mechanical strength, further can reduce breeding of bacterium.

(3) The antibacterial agent in the scheme is guanidine polymer, the guanidine polymer has good virus, bacteria and fungus resistance, and the guanidine polymer is non-toxic, non-irritant, oxidation-resistant, free of yellowing phenomenon of paper pulp and in line with the concept of green and environment protection.

(4) Mineral fiber is added in the scheme, so that the mechanical strength and the forming processability of the whole carton material are improved.

(5) In the scheme, the mixture of the cellulose derivative containing methyl and the starch is used as the adhesive, so that the better adhesive strength and mechanical strength of the carton are ensured.

(6) The waterproof agent in the scheme is the methyl-containing polysiloxane derivative, the methyl-containing polysiloxane derivative cannot achieve a good waterproof effect due to low addition content, the antibacterial performance of the guanidine polymer can be influenced due to high addition content, and when the methyl-containing polysiloxane derivative with a certain content is added, a waterproof film can be formed on the surface of the carton material, so that the waterproof performance of the carton material is improved, and the antibacterial performance of the guanidine polymer cannot be influenced.

Detailed Description

For purposes of the following detailed description, it is to be understood that the invention may assume various alternative variations and step sequences, except where expressly specified to the contrary. Moreover, other than in any operating examples, or where otherwise indicated, all numbers expressing, for example, quantities of ingredients used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.

Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements.

When a range of values is disclosed herein, the range is considered to be continuous and includes both the minimum and maximum values of the range, as well as each value between such minimum and maximum values. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range-describing features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to encompass any and all subranges subsumed therein. For example, a stated range from "1 to 10" should be considered to include any and all subranges between the minimum value of 1 and the maximum value of 10. Exemplary subranges of the range 1 to 10 include, but are not limited to, 1 to 6.1, 3.5 to 7.8, 5.5 to 10, and the like.

In order to solve the technical problem, the first aspect of the invention provides a tea leaf residue paper box material, which comprises, by weight, 30-60 parts of tea leaf residue, 20-55 parts of plant fiber, 1-3 parts of mineral fiber, 1-3 parts of an antibacterial agent, 1-10 parts of an oxygen bleaching agent, 1-10 parts of a degrading enzyme, 1-15 parts of an adhesive and 5-10 parts of a waterproof agent. The tea dregs of the invention can be any one or a mixture of several kinds of tea dregs, and the tea dregs are not limited at all.

As a preferable technical solution, the plant fiber is at least one selected from plant straw fiber, wood fiber, bamboo fiber, hemp fiber and cotton fiber.

As a preferable technical scheme, the fiber is a mixture of straw fiber and fibrilia, and the mass ratio of the straw fiber to the fibrilia is (3-5): 1.

the straw is a general term of the stem and leaf parts of mature crops. Generally refers to the remainder of wheat, rice, corn, potatoes, oilseed rape, cotton, sugar cane and other crops after harvesting the seeds. More than half of the products of crop photosynthesis exist in the straws, and the straws are also a coarse feed and are characterized by high content of coarse fibers and containing lignin, and the straw fibers are the fibers of the straws. The straw fiber has better hydrophobic property and ageing resistance.

As a preferred technical scheme, the straw fiber is wheat straw fiber.

As a preferable embodiment, the mineral fiber is at least one selected from the group consisting of an aluminum silicate fiber, a glass fiber, a gypsum fiber, and a carbon fiber.

Mineral fibers are increasingly used in the paper industry. Its excellent properties can make paper possess the functions which plant fibre does not have.

As a preferred technical solution, the mineral fiber is gypsum fiber.

The gypsum fiber is a mineral fiber with excellent performance and low price. The gypsum microfiber can be used as a reinforcing agent in paper making to improve the strength of paper, reduce the consumption of wood, protect the environment, reduce the wastewater discharge in a paper mill and reduce pollution, and the gypsum fiber has better dispersibility and can not agglomerate in paper pulp.

In a preferred embodiment, the antibacterial agent is a guanidine polymer, and the guanidine polymer is polyguanidine salt and/or polybiguanide salt.

As a preferred technical solution, the polyguanidine salt is polyhexamethylene guanidine hydrochloride.

The polyhexamethylene guanidine hydrochloride has the advantages of wide sterilization range, low effective concentration, high action speed, stable property, long-term bacteriostasis, no side effect, no corrosion, no color, no smell, no toxicity, no combustion, no explosion and safe use. The polyhexamethylene guanidine hydrochloride is a polyguanidine high-molecular polymer, the polarity of amino in the polyhexamethylene guanidine hydrochloride is strong, and the amino can interact with hydroxyl on fibers, so that the polyhexamethylene guanidine hydrochloride is adsorbed on the fibers to form a durable antibacterial effect, and ammonia in the polyhexamethylene guanidine hydrochloride is a secondary amino, so that the polyhexamethylene guanidine hydrochloride is high in steric hindrance and not easy to oxidize, and the phenomenon of yellowing of paper is avoided. However, polyhexamethylene guanidine hydrochloride has poor hydrophobicity and is easy to absorb moisture, and the hydrophilic group part of the polyhexamethylene guanidine hydrochloride has strong electropositivity, adsorbs various bacteria and viruses which are usually electronegative, enters a cell membrane, inhibits the synthesis of intramembrane liposome, causes the apoptosis of thalli and achieves the optimal sterilization effect.

As a preferable technical scheme, the oxygen bleaching agent is hydrogen peroxide.

In a preferred embodiment, the degrading enzyme is at least one selected from the group consisting of xylanase, hemicellulase, a lignin degrading enzyme, cellulase and β -glucanase.

Xylan is a heterogeneous polysaccharide present in plant cell walls, accounting for about 15% to 35% of the dry weight of plant cells, and is the main component of plant hemicellulose. Most xylans are structurally complex, highly branched heterogeneous polysaccharides containing many different substituents. Biodegradation of xylan also therefore requires a complex enzyme system to degrade xylan through the synergistic interaction of the various components therein. Thus, xylanases are a group of enzymes, being xylanase systems, not one enzyme. The xylanase system is an enzyme system for degrading xylan, comprises beta-1, 4-endoxylanase, beta-xylosidase, alpha-L-arabinosidase, alpha-D-glucuronidase, acetyl xylanase and phenolic acid esterase, and can degrade xylan hemicellulose which exists in the nature in a large amount. In the xylanase system, beta-1, 4-endoxylanase is the most critical hydrolase, which hydrolyzes xylan into xylooligosaccharides such as small oligosaccharides and xylobiose, and small amounts of xylose and arabinose by hydrolyzing the beta-1, 4-glycosidic bond of xylan molecule. Beta-xylosidase catalyzes the release of xylose residues by hydrolyzing the terminal end of xylo-oligosaccharides. In addition, side chain hydrolases such as alpha-L-arabinofuranosidase, alpha-glucuronidase, acetylxylan esterase, and phenolic acid esterase capable of degrading the ester bond formed by arabinose side chain residue and phenolic acid in xylan are involved in the complete degradation of xylan, and they act on the glycosidic bond between xylose and side chain substituent, in cooperation with the action of backbone hydrolase, to convert xylan into its constituent monosaccharides.

In a preferred embodiment, the binder is a mixture of a cellulose derivative containing methyl groups and starches, and the mass ratio of the cellulose derivative containing methyl groups to the starches is: 1: (3-5).

In a preferred embodiment, the methyl group-containing cellulose derivative is at least one selected from the group consisting of methylcellulose, hydroxyethylmethylcellulose, and methylhydroxypropylcellulose.

In a preferred embodiment, the methyl group-containing cellulose derivative is methyl cellulose.

Methylcellulose is a nonionic cellulose ether made by the introduction of methyl groups into cellulose by etherification. The important functions of methylcellulose are thickening, surface activity, film forming and thermal gel forming. The methylcellulose solutions are stable over a wide range of pH (3.0-11.0) and have unique thermal gelling properties.

As a preferable technical scheme, the waterproof agent is polysiloxane derivative containing methyl.

In a preferred embodiment, the methyl group-containing polysiloxane derivative is at least one selected from polydimethylsiloxane, cyclomethicone, polymethylphenylsiloxane and polymethylhydrosiloxane.

The polysiloxane derivative containing methyl has better hydrophobicity, can form a better waterproof film on the surface of the fiber, and obviously improves the hydrophobic performance of the carton material. However, when the content of the methyl group-containing polysiloxane derivative in the carton material is high, the antibacterial property of polyhexamethylene guanidine hydrochloride is affected. The methyl-containing polysiloxane derivative can improve the compatibility among all components, reduce the friction among all components, improve the smoothness of the carton material, reduce the roughness of the carton material and further improve the mechanical property of the carton material.

(2) adding white rot fungi into the mixture A at the temperature of 20-40 ℃, and standing for 24-73h, wherein the mass ratio of the white rot fungi to the mixture A is 1: 50-80 to obtain a mixture B;

In addition, the starting materials used are all commercially available, unless otherwise specified.

Examples

Example 1

The first aspect of the embodiment provides a tea leaf residue carton material, which comprises, by weight, 30 parts of tea leaf residue, 20 parts of plant fiber, 1 part of mineral fiber, 1 part of antibacterial agent, 1 part of oxygen bleaching agent, 1 part of degrading enzyme, 1 part of adhesive and 5 parts of waterproof agent.

The tea leaves are collected from catering places and dried in the sun.

The plant fiber is a mixture of straw fiber and fibrilia, and the mass ratio of the straw fiber to the fibrilia is 3: 1. the straw fiber is wheat straw fiber, and the fibrilia is flax fiber. The wheat straw fiber and the flax fiber are obtained by harvesting wheat and flax planted by self and drying in the sun after the wheat and the flax are mature.

The mineral fiber is gypsum fiber, the gypsum fiber is purchased from Jinan Qingyuyuan new material Co., Ltd, and the product number is as follows: 202004.

the antibacterial agent is guanidine polymer, the guanidine polymer is polyguanidine salt, the polyguanidine salt is polyhexamethylene guanidine hydrochloride, and the polyhexamethylene guanidine hydrochloride is purchased from Shanghai high-polymer biological technology Co., Ltd, with the product number: p3000.

The oxygen bleaching agent is hydrogen peroxide, and the hydrogen peroxide is purchased from Shanghai Lixin chemical Co., Ltd, CAS No.: 7722-84-1.

The degrading enzyme is a mixture of xylanase and hemicellulase, and the mass ratio of the xylanase to the hemicellulase is 2: 1. the xylanase is purchased from Shandong Kangli Biotech limited, cat #: 322. the hemicellulase is purchased from Zhengzhou Wangbu chemical products Co., Ltd, and the product number is as follows: 1734.

the adhesive is a mixture of a cellulose derivative containing methyl and starch, and the mass ratio of the cellulose derivative containing methyl to the starch is as follows: 1: 3. the methyl group-containing cellulose derivative is methyl cellulose, which is available from risti reagent under the trade name R464324.

The starch is corn starch which is purchased from a chemical industry strength store of Changli in Jiaxing city, and the CAS number is as follows: 1423-9-7.

The waterproof agent is a methyl-containing polysiloxane derivative, the methyl-containing polysiloxane derivative is polymethylhydrosiloxane, and the polymethylhydrosiloxane is purchased from Shanghai Michelle chemical technology Co., Ltd and has the mark: and M37992.

A second aspect of this embodiment provides a method for preparing a tea leaf carton material, including the following steps:

(1) crushing wheat straw fiber, flax fiber and tea leaf residue to 0.1mm, and adding gypsum fiber, xylanase, hemicellulase and water, wherein the weight ratio of the tea leaf residue to the water is 2: 5, standing for 8 hours at the temperature of 50 ℃ to obtain a mixture A;

(2) adding white rot fungi into the mixture A at 35 ℃, and standing for 70h, wherein the mass ratio of the white rot fungi to the mixture A is 1: 50 to obtain a mixture B;

(3) adding hydrogen peroxide into the mixture B, and bleaching to obtain a mixture C;

(4) adding polyhexamethylene guanidine hydrochloride, methyl cellulose, corn starch and polymethylhydrosiloxane into the mixture C at 50 ℃, and pulping to obtain a mixture D;

The white rot fungi are purchased from Ruichu Biotechnology limited, Cathaka: BKM-F-1767.

Example 2

The first aspect of the embodiment provides a tea leaf residue carton material, which comprises the raw materials of, by weight, 45 parts of tea leaf residue, 40 parts of plant fiber, 2 parts of mineral fiber, 2 parts of an antibacterial agent, 5 parts of an oxygen bleaching agent, 5 parts of a degrading enzyme, 7 parts of an adhesive and 7 parts of a waterproof agent.

The tea leaves are collected from catering places and dried in the sun.

The plant fiber is a mixture of straw fiber and fibrilia, and the mass ratio of the straw fiber to the fibrilia is 4: 1. the straw fiber is wheat straw fiber, and the fibrilia is flax fiber. The wheat straw fiber and the flax fiber are obtained by harvesting wheat and flax planted by self and drying in the sun after the wheat and the flax are mature.

the adhesive is a mixture of a cellulose derivative containing methyl and starch, and the mass ratio of the cellulose derivative containing methyl to the starch is as follows: 1: 4. the methyl group-containing cellulose derivative is methyl cellulose, which is available from risti reagent under the trade name R464324.

(1) crushing wheat straw fiber, flax fiber and tea leaf residue to 1mm, and adding xylanase, gypsum fiber, hemicellulase and water, wherein the weight ratio of the tea leaf residue to the water is 2: 5, standing for 10 hours at the temperature of 60 ℃ to obtain a mixture A;

(2) adding white rot fungi into the mixture A at 35 ℃, and standing for 70h, wherein the mass ratio of the white rot fungi to the mixture A is 1: 70 to obtain a mixture B;

Example 3

The first aspect of the embodiment provides a tea leaf residue carton material, which comprises, by weight, 60 parts of tea leaf residue, 55 parts of plant fiber, 3 parts of mineral fiber, 3 parts of antibacterial agent, 10 parts of oxygen bleaching agent, 10 parts of degrading enzyme, 15 parts of adhesive and 10 parts of waterproof agent.

The tea leaves are collected from catering places and dried in the sun.

The plant fiber is a mixture of straw fiber and fibrilia, and the mass ratio of the straw fiber to the fibrilia is 5: 1. the straw fiber is wheat straw fiber, and the fibrilia is flax fiber. The wheat straw fiber and the flax fiber are obtained by harvesting wheat and flax planted by self and drying in the sun after the wheat and the flax are mature.

the adhesive is a mixture of a cellulose derivative containing methyl and starch, and the mass ratio of the cellulose derivative containing methyl to the starch is as follows: 1: 5. the methyl group-containing cellulose derivative is methyl cellulose, which is available from risti reagent under the trade name R464324. The starch is corn starch which is purchased from a chemical industry strength store of Changli in Jiaxing city, and the CAS number is as follows: 1423-9-7.

(1) crushing wheat straw fiber, flax fiber and tea leaf residue to 1.5mm, and adding xylanase, gypsum fiber, hemicellulase and water, wherein the weight ratio of the tea leaf residue to the water is 2: 5, standing for 12 hours at the temperature of 70 ℃ to obtain a mixture A;

(2) adding white rot fungi into the mixture A at 35 ℃, and standing for 70h, wherein the mass ratio of the white rot fungi to the mixture A is 1: 80 to obtain a mixture B;

Comparative example 1

The difference from example 1 is that: this comparative example contained no polyguanidine salt.

Comparative example 2

The difference from example 1 is that: the antibacterial agent in the comparative example is a quaternary ammonium salt antibacterial agent, the quaternary ammonium salt antibacterial agent is hydroxypropyl trimethyl ammonium chloride chitosan, the hydroxypropyl trimethyl ammonium chloride chitosan is purchased from Wuhan La Na pharmaceutical chemical Co., Ltd, and the product number is as follows: FD 23243.

Comparative example 3

The difference from example 1 is that: the example does not contain a water repellent.

Comparative example 4

The difference from example 1 is that: the water-proofing agent in this example was calcium stearate, which was purchased from Henan Turkey industries, Inc., under the following product number: 037.

comparative example 5

The difference from example 1 is that: the antibacterial agent is 1 part, and the waterproofing agent is 11 parts. The antibacterial agent is guanidine polymer, the guanidine polymer is polyguanidine salt, the polyguanidine salt is polyhexamethylene guanidine hydrochloride, and the polyhexamethylene guanidine hydrochloride is purchased from Shanghai high-polymer biological technology Co., Ltd, with the product number: p3000. The waterproof agent is a methyl-containing polysiloxane derivative, the methyl-containing polysiloxane derivative is polymethylhydrosiloxane, and the polymethylhydrosiloxane is purchased from Shanghai Michelle chemical technology Co., Ltd and has the mark: and M37992.

Comparative example 6

The difference from example 3 is that: the antibacterial agent is 4 parts, and the waterproof agent is 5 parts. The antibacterial agent is guanidine polymer, the guanidine polymer is polyguanidine salt, the polyguanidine salt is polyhexamethylene guanidine hydrochloride, and the polyhexamethylene guanidine hydrochloride is purchased from Shanghai high-polymer biological technology Co., Ltd, with the product number: p3000. The waterproof agent is a methyl-containing polysiloxane derivative, the methyl-containing polysiloxane derivative is polymethylhydrosiloxane, and the polymethylhydrosiloxane is purchased from Shanghai Michelle chemical technology Co., Ltd and has the mark: and M37992.

Performance testing

Testing one: the tea leaf residue paper box materials obtained in examples 1 to 3 and comparative examples 1 to 6 were divided into 9 groups, each group of 50 paper sheets of the same size were stored in an incubator at 35 ℃ and 50% humidity for 30 days, after 30 days, the antibacterial performance of the samples was judged by the presence or absence of mold spots, 0 to 2 samples were excellent in the antibacterial performance, 3 to 10 samples were good in the antibacterial performance, and 11 to 50 samples were poor in the antibacterial performance.

And (2) testing: the water absorption capacity of the tea leaf residue paper box materials obtained in examples 1-3 and comparative examples 1-6 was tested with reference to GB/1540-2002, and the waterproof effect was evaluated.

	Antibacterial property	Water absorption capacity (g/m)²)
			Example 1	Superior food	1.78
Example 2	Superior food	1.76
			Example 3	Superior food	1.74
Comparative example 1	Difference (D)	2.67
			Comparative example 2	Good wine	2.8
Comparative example 3	Good wine	10.57
			Comparative example 4	Good wine	5.24
Comparative example 5	Difference (D)	1.78
			Comparative example 6	Difference (D)	1.77

The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in other forms, and any person skilled in the art may modify or change the technical content of the above disclosure into equivalent embodiments with equivalent changes, but all those simple modifications, equivalent changes and modifications made to the above embodiments according to the technical spirit of the present invention still belong to the protection scope of the present invention.

Claims

1. The tea residue paper box material is characterized by comprising, by weight, 30-60 parts of tea residue, 20-55 parts of plant fiber, 1-3 parts of mineral fiber, 1-3 parts of an antibacterial agent, 1-10 parts of an oxygen bleaching agent, 1-10 parts of a degrading enzyme, 1-15 parts of an adhesive and 5-10 parts of a waterproof agent.

2. The tea grounds carton material of claim 1, wherein the plant fiber is selected from at least one of straw fiber, wood fiber, bamboo fiber, hemp fiber and cotton fiber.

3. The tea grounds carton material as claimed in claim 1 or 2, wherein the plant fiber is a mixture of straw fiber and hemp fiber, and the mass ratio of the straw fiber to the hemp fiber is (3-5): 1.

4. the tea grounds carton material of claim 1, wherein the mineral fibers are selected from at least one of aluminum silicate fibers, glass fibers, gypsum fibers, and carbon fibers.

5. The tea grounds carton material of claim 1, wherein the antimicrobial agent is a guanidine polymer, the guanidine polymer being a polyguanidine salt and/or a polybiguanide salt.

6. The tea grounds carton material of claim 1, wherein the oxygen bleach is hydrogen peroxide.

7. Tea leaf carton material according to claim 1, characterized in that the degrading enzyme is selected from at least one of xylanase, hemicellulase, lignin degrading enzyme, cellulase and β -glucanase.

8. The tea leaf carton material according to claim 1, wherein the binder is a mixture of a cellulose derivative containing methyl groups and starches, and the mass ratio of the cellulose derivative containing methyl groups to the starches is: 1: (3-5).

9. A tea grounds carton material according to claim 1, wherein the water repellent agent is a methyl group containing polysiloxane derivative.

10. A method of making a tea grounds carton material according to any one of claims 1-9 comprising at least the steps of: