CN112063923B - 1300MPa级含RE硫系易切削钢60mm棒材及其制备方法 - Google Patents
1300MPa级含RE硫系易切削钢60mm棒材及其制备方法 Download PDFInfo
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- CN112063923B CN112063923B CN202010930399.9A CN202010930399A CN112063923B CN 112063923 B CN112063923 B CN 112063923B CN 202010930399 A CN202010930399 A CN 202010930399A CN 112063923 B CN112063923 B CN 112063923B
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- 229910000915 Free machining steel Inorganic materials 0.000 title claims abstract description 109
- 150000004770 chalcogenides Chemical class 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 44
- 238000005520 cutting process Methods 0.000 claims abstract description 42
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 29
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 12
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 80
- 239000010959 steel Substances 0.000 claims description 80
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 55
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 51
- 239000011593 sulfur Substances 0.000 claims description 33
- 238000005242 forging Methods 0.000 claims description 26
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 26
- 238000012360 testing method Methods 0.000 claims description 24
- 229910052742 iron Inorganic materials 0.000 claims description 22
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- 238000010438 heat treatment Methods 0.000 claims description 20
- 239000000956 alloy Substances 0.000 claims description 17
- 239000011572 manganese Substances 0.000 claims description 17
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
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- 238000003723 Smelting Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 10
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 9
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- 239000000203 mixture Substances 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
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- 239000002184 metal Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
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- 229910021383 artificial graphite Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000571 coke Substances 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- 229910021382 natural graphite Inorganic materials 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 18
- 238000009826 distribution Methods 0.000 abstract description 9
- 238000005272 metallurgy Methods 0.000 abstract description 2
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 16
- 239000011651 chromium Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
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- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 150000004763 sulfides Chemical class 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000012876 topography Methods 0.000 description 4
- 229910000640 Fe alloy Inorganic materials 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 150000003463 sulfur Chemical class 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- IWTGVMOPIDDPGF-UHFFFAOYSA-N [Mn][Si][Fe] Chemical compound [Mn][Si][Fe] IWTGVMOPIDDPGF-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
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- 230000005496 eutectics Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- VCTOKJRTAUILIH-UHFFFAOYSA-N manganese(2+);sulfide Chemical class [S-2].[Mn+2] VCTOKJRTAUILIH-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- -1 rare earth oxysulfides Chemical class 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- OSMSIOKMMFKNIL-UHFFFAOYSA-N calcium;silicon Chemical compound [Ca]=[Si] OSMSIOKMMFKNIL-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
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- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
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- 238000005070 sampling Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J1/00—Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
- B21J1/06—Heating or cooling methods or arrangements specially adapted for performing forging or pressing operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J5/00—Methods for forging, hammering, or pressing; Special equipment or accessories therefor
- B21J5/002—Hybrid process, e.g. forging following casting
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0006—Adding metallic additives
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0025—Adding carbon material
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
- C22C33/06—Making ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Forging (AREA)
Abstract
Description
Mn | Si | Ni | C | S | P | Cr | O | Ce | La | |
高硫生铁 | 0.04 | 0.012 | 0 | 0.003 | 48 | 0.004 | 0 | 0.01 | 0 | 0 |
电解锰 | 99.58 | 0.015 | 0 | 0 | 0.100 | 0.010 | 0 | 0 | 0 | 0 |
硅铁合金 | 0 | 72.10 | 0 | 0.100 | 0.016 | 0.034 | 0 | 0.01 | 0 | 0 |
镍板 | 0 | 0 | 99.98 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
增碳剂 | 0 | 0 | 0 | 97.50 | 0 | 0 | 0 | 0 | 0 | 0 |
铬铁 | 0 | 1.32 | 0 | 0.06 | 0.03 | 0.04 | 58.2 | 0.008 | 0 | 0 |
稀土 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 63.5 | 33.5 |
高纯铁 | 0.04 | 0 | 0 | 0.002 | 0.001 | 0.004 | 0.01 | 0.008 | 0 | 0 |
物料 | 电解锰 | 硅铁合金 | 镍板 | 增碳剂 | 铬铁 | 稀土 | 高硫生铁 | 高纯铁 |
重量/Kg | 1.9 | 0.09 | 0.024 | 0.18 | 28.64 | 0.012 | 0.78 | 88.37 |
物料 | 电解锰 | 硅铁合金 | 镍板 | 增碳剂 | 铬铁 | 稀土 | 高硫生铁 | 高纯铁 |
重量/Kg | 1.52 | 0.15 | 0.06 | 0.15 | 29.3 | 0.009 | 0.66 | 88.15 |
长宽比 | 实施例1/% | 实施例2/% |
X≤3 | 85.8 | 87.5 |
3<X≤5 | 8.5 | 8.1 |
5<X≤10 | 4.2 | 3.9 |
10<X≤30 | 1.3 | 0.2 |
X>30 | 0.2 | 0.3 |
Claims (4)
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CN202010930399.9A CN112063923B (zh) | 2020-09-07 | 2020-09-07 | 1300MPa级含RE硫系易切削钢60mm棒材及其制备方法 |
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CN202010930399.9A CN112063923B (zh) | 2020-09-07 | 2020-09-07 | 1300MPa级含RE硫系易切削钢60mm棒材及其制备方法 |
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CN112063923A CN112063923A (zh) | 2020-12-11 |
CN112063923B true CN112063923B (zh) | 2022-03-22 |
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CN113073266A (zh) * | 2021-03-26 | 2021-07-06 | 成都先进金属材料产业技术研究院股份有限公司 | 1150MPa级高强度易切削不锈钢及其制备方法 |
CN113278894A (zh) * | 2021-05-20 | 2021-08-20 | 成都先进金属材料产业技术研究院股份有限公司 | Fe-Mn-Al-S系低密度易切削钢及其制备方法 |
CN113235019A (zh) * | 2021-05-20 | 2021-08-10 | 成都先进金属材料产业技术研究院股份有限公司 | Fe-Mn-Al-N-S系高氮低密度易切削钢棒材及其制备方法 |
CN115502610A (zh) * | 2022-10-14 | 2022-12-23 | 成都先进金属材料产业技术研究院股份有限公司 | 一种含钒钛的高强钢用焊丝钢水和高强钢用焊丝及其生产方法 |
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TW567233B (en) * | 2001-03-05 | 2003-12-21 | Kiyohito Ishida | Free-cutting tool steel |
JP3929035B2 (ja) * | 2002-07-03 | 2007-06-13 | 三菱製鋼株式会社 | 硫黄含有快削性機械構造用鋼 |
CN1184342C (zh) * | 2002-11-29 | 2005-01-12 | 莱芜钢铁集团有限公司 | 一种稀土系易切削钢及其生产方法 |
CN101397633B (zh) * | 2007-09-30 | 2010-08-11 | 宝山钢铁股份有限公司 | 一种含硫含铜的易切削不锈钢及其制备方法 |
CN101413091B (zh) * | 2008-11-28 | 2010-11-17 | 江苏大学 | 新型易切削不锈钢303b及其制造方法 |
CN102330040A (zh) * | 2011-10-09 | 2012-01-25 | 内蒙古包钢钢联股份有限公司 | 一种易切削钢铁材料 |
CN102363869B (zh) * | 2011-10-14 | 2013-06-19 | 攀钢集团江油长城特殊钢有限公司 | 一种易切削铁素体不锈钢430fm的制造方法 |
KR101326800B1 (ko) * | 2011-12-20 | 2013-11-11 | 지영준 | 고강도 쾌삭 스테인레스강 |
CN102634735B (zh) * | 2012-04-09 | 2013-11-27 | 广州市奥赛钢线科技有限公司 | 一种汽车悬架用弹簧钢及其制备方法和应用 |
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CN103911550A (zh) * | 2014-03-24 | 2014-07-09 | 北京科技大学 | 一种热塑性优良的环保型低碳高硫铋易切削钢 |
CN104152798B (zh) * | 2014-08-26 | 2016-08-24 | 武汉钢铁(集团)公司 | 抗拉强度≥1200MPa的汽车连杆用易切削钢及生产方法 |
CN104178692B (zh) * | 2014-08-26 | 2017-02-15 | 武汉钢铁(集团)公司 | 抗拉强度≥1200MPa的工程机械用易切削钢及生产方法 |
CN104388815A (zh) * | 2014-12-16 | 2015-03-04 | 内蒙古包钢钢联股份有限公司 | 一种铈变性夹杂物的新型易切削钢铁材料 |
CN105861955B (zh) * | 2016-05-31 | 2018-01-19 | 上海大学兴化特种不锈钢研究院 | 一种经济型含硫易切削奥氏体不锈钢合金材料 |
CN106591730B (zh) * | 2016-11-25 | 2019-02-19 | 邢台钢铁有限责任公司 | 低碳马氏体易切削不锈钢及其生产方法 |
CN109295384B (zh) * | 2018-08-31 | 2020-11-24 | 上海大学 | 含硫锡碲的易切削钢及其制备方法 |
CN109023104B (zh) * | 2018-09-25 | 2021-01-26 | 成都先进金属材料产业技术研究院有限公司 | 4Cr13塑料模具钢及其制备方法 |
CN110607483A (zh) * | 2019-10-23 | 2019-12-24 | 成都先进金属材料产业技术研究院有限公司 | 易切削不锈钢及其冶炼控制方法 |
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Application publication date: 20201211 Assignee: PANGANG GROUP JIANGYOU CHANGCHENG SPECIAL STEEL Co.,Ltd. Assignor: Chengdu advanced metal material industry technology Research Institute Co.,Ltd. Contract record no.: X2024980003064 Denomination of invention: 1300 MPa grade RE sulfur free cutting steel 60mm rod and its preparation method Granted publication date: 20220322 License type: Exclusive License Record date: 20240322 |