CN112028158A - A solar powered water treatment device - Google Patents

A solar powered water treatment device Download PDF

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Publication number
CN112028158A
CN112028158A CN202010767665.0A CN202010767665A CN112028158A CN 112028158 A CN112028158 A CN 112028158A CN 202010767665 A CN202010767665 A CN 202010767665A CN 112028158 A CN112028158 A CN 112028158A
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water
pipe
evaporation chamber
treatment device
glass cover
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周建华
魏安涢
孙志强
苗蕾
田永芝
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Guilin University of Electronic Technology
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Guilin University of Electronic Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention discloses a solar-driven water treatment device, which separates a water source from a photothermal conversion material through a flow-limiting valve, prevents heat from being conducted to a water body so as to reduce heat loss, simultaneously utilizes an air suction pump or an exhaust fan to quickly guide water vapor in an evaporation chamber into a condensation pipe, reduces the humidity of the evaporation chamber, is beneficial to water evaporation, and utilizes the condensation pipe to efficiently and quickly collect condensed water to exchange heat with cold water to be treated conveyed by gravity, the cold water absorbs latent heat in steam and then flows into a photothermal evaporator, and system energy is fully utilized.

Description

一种太阳能驱动水处理装置A solar powered water treatment device

技术领域:Technical field:

本发明涉及太阳能光热转换技术领域,具体涉及一种太阳能驱动水处理装置。The invention relates to the technical field of solar photothermal conversion, in particular to a solar energy-driven water treatment device.

背景技术:Background technique:

目前,随着世界人口的增长以及世界经济的快速发展,水污染和水资源短缺问题已成为人类面临的最大挑战之一。在过去的几十年中,已经开发了包括基于膜的技术和基于热在内的各种技术,以从盐水和污水中制备纯净水。但是,尽管这些技术发展成熟,但始终不可避免的高能耗和先进基础设施的要求,导致许多发展中国家和偏远地区无法使用。太阳能是一种无污染且可再生的能源,可持续且完全取之不尽。如今,人们以几种不同方式利用太阳能,由于其节能环保和可持续性,在海水淡化和污水净化有巨大的潜力。At present, with the growth of the world population and the rapid development of the world economy, water pollution and water shortages have become one of the greatest challenges facing mankind. Over the past few decades, various technologies, including membrane-based and thermal-based, have been developed to produce purified water from brine and sewage. However, despite the maturity of these technologies, the unavoidable high energy consumption and advanced infrastructure requirements have made them unavailable in many developing countries and remote areas. Solar energy is a non-polluting and renewable energy source that is sustainable and completely inexhaustible. Today, solar energy is harnessed in several different ways, and due to its energy saving and sustainability, it has huge potential in desalination and sewage purification.

传统的光热转换系统中,太阳光照射到整个水体上,导致蒸发速率低。新型界面太阳能蒸气发生系统将吸收的太阳能限制在水-空气界面,减少了能量损失和增加了水蒸发,但是,由于光热材料与水源直接接触,存在较大的热传导损失,由于水蒸气的回收是在封闭环境下进行,环境湿度较大,严重减少了水的蒸发,此外,只是获得了冷凝水,浪费了大量的蒸汽相变潜热,能量没有得到充分的利用。In traditional light-to-heat conversion systems, sunlight shines on the entire water body, resulting in low evaporation rates. The novel interfacial solar vapor generation system confines the absorbed solar energy to the water-air interface, reducing energy loss and increasing water evaporation, however, due to the direct contact between the photothermal material and the water source, there is a large heat conduction loss, due to the recovery of water vapor It is carried out in a closed environment with high ambient humidity, which seriously reduces the evaporation of water. In addition, only condensed water is obtained, a large amount of latent heat of vapor phase transition is wasted, and the energy is not fully utilized.

发明内容:Invention content:

本发明的目的是提供一种太阳能驱动水处理装置,该太阳能驱动水处理装置将水源与光热材料分离,并能控制光热转换材料的进水量,利用冷凝管收集冷凝水和水蒸气相变潜热,减少光热转换材料与水源的直接接触,高效收集冷凝水和回收水蒸气相变潜热,解决了现有技术能量没有得到充分利用的问题。The purpose of the present invention is to provide a solar-powered water treatment device, which separates the water source from the photothermal material, can control the water inflow of the photothermal conversion material, and uses a condenser tube to collect condensed water and water vapor phase change The latent heat reduces the direct contact between the photothermal conversion material and the water source, efficiently collects the condensed water and recovers the latent heat of the water vapor phase transition, and solves the problem that the energy of the existing technology is not fully utilized.

本发明是通过以下技术方案予以实现的:The present invention is achieved through the following technical solutions:

一种太阳能驱动水处理装置,该装置包括依次连接的光热蒸发室、冷凝及潜热收集器、集水系统和盛水容器;所述的光热蒸发室包括有机玻璃罩和有机玻璃罩内的光热转换材料,所述有机玻璃罩靠近冷凝及潜热收集器一侧设有上下两个开口,上端开口为蒸汽出口,下端开口是有一个限流阀门的进水口,有机玻璃罩底部设隔热珍珠棉泡沫,光热转换材料位于隔热珍珠棉泡沫上;所述集水系统由一个抽气泵或排气扇和锥形瓶构成;所述盛水容器安装在支架上装有待处理的水;有机玻璃罩靠近冷凝管一侧上端的蒸汽出口直接跟冷凝管内管一端连通,冷凝管内管另一端经真空尾接管分别跟锥形瓶和抽气泵连通;或有机玻璃罩靠近冷凝管一侧上端的开口通过排风扇跟冷凝管内管一端连通,冷凝管内管另一端经真空尾接管跟锥形瓶连通;冷凝管进水口经输水管和阀门跟盛水容器连通,冷凝管出水口跟有机玻璃罩下端进水口连通;待处理的水经输水管和阀门在重力作用下进入冷凝管,然后进入光热蒸发室产生热蒸汽,通过抽气泵或排风扇将光热蒸发室产生的热蒸汽导入冷凝管,与经输水管和阀门在重力作用下进入冷凝管的待处理的冷水进行热交换,热蒸汽冷却为水经真空尾接管流到锥形瓶得到净化的水,同时进入冷凝管的待处理的冷水吸收蒸汽中的潜热后流入光热蒸发室内,提高输入蒸发室内待处理液体的温度,从而回收利用蒸发过程中汽化潜热,降低水处理的能耗,同时促进了水的大通量蒸发,实现在能量密度较低的普通太阳光驱动下将海水、苦咸水、工业污水、生活废水等水体快速高效地净化。A solar-powered water treatment device, the device comprises a photothermal evaporation chamber, a condensation and latent heat collector, a water collection system and a water container connected in sequence; the photothermal evaporation chamber comprises a plexiglass cover and a plexiglass cover. Light-to-heat conversion material, the plexiglass cover is provided with two upper and lower openings on one side near the condensation and latent heat collector, the upper opening is a steam outlet, the lower opening is a water inlet with a restrictor valve, and the bottom of the plexiglass cover is provided with heat insulation EPE foam, the light-to-heat conversion material is located on the heat-insulating EPE foam; the water collection system consists of an air pump or an exhaust fan and a conical flask; the water container is installed on the bracket and contains water to be treated; organic The steam outlet of the glass cover near the upper end of the condenser tube is directly connected to one end of the inner tube of the condenser tube, and the other end of the inner tube of the condenser tube is connected to the conical flask and the suction pump respectively through the vacuum tail pipe; or the opening of the plexiglass cover near the upper end of the side of the condenser tube The exhaust fan is connected to one end of the inner tube of the condensation tube, and the other end of the inner tube of the condensation tube is connected to the conical flask through the vacuum tailpiece; the water inlet of the condensation tube is connected to the water container through the water delivery pipe and the valve, and the water outlet of the condensation tube is connected to the water inlet at the lower end of the plexiglass cover Connected; the water to be treated enters the condenser pipe under the action of gravity through the water pipe and valve, and then enters the photothermal evaporation chamber to generate hot steam. Under the action of gravity, the water pipe and valve enter the cold water to be treated in the condenser for heat exchange, and the hot steam is cooled into water that flows through the vacuum tail pipe to the conical flask to get purified water, and at the same time enters the cold water to be treated in the condenser to absorb the steam. The latent heat flows into the photothermal evaporation chamber to increase the temperature of the liquid to be treated in the input evaporation chamber, thereby recycling the latent heat of vaporization in the evaporation process, reducing the energy consumption of water treatment, and promoting the large flux of water evaporation, achieving higher energy density. Driven by low ordinary sunlight, it can quickly and efficiently purify water bodies such as seawater, brackish water, industrial sewage, and domestic wastewater.

特别地,所述光热转换材料为海绵基复合材料,其制备方法包括以下步骤:In particular, the light-to-heat conversion material is a sponge-based composite material, and its preparation method includes the following steps:

把切割后的海绵用酒精和去离子水超声清洗并烘干;Ultrasonic cleaning and drying of the cut sponge with alcohol and deionized water;

将碳材料(例如石墨粉、碳粉)、等离激元金属纳米粒子、半导体材料中的任一种吸光材料)加入0.5~3wt%壳聚糖溶液中搅拌得到混合溶液,然后把海绵放入混合溶液中,浸渍1h之后冷冻干燥,即得到海绵基复合材料。Add carbon materials (such as graphite powder, carbon powder), plasmonic metal nanoparticles, and light-absorbing materials in semiconductor materials) into 0.5-3wt% chitosan solution and stir to obtain a mixed solution, and then put the sponge into the solution. In the mixed solution, the sponge-based composite material was obtained after immersion for 1 h and then freeze-drying.

本发明与现有的技术相比,具有以下优点:Compared with the prior art, the present invention has the following advantages:

本发明设计的太阳能驱动水处理装置,通过限流阀门将水源和光热转换材料分离,阻止热量传导至水体从而减少热损失,同时利用抽气泵或排气扇将蒸发室内的水蒸气快速导入冷凝管,减少蒸发室的湿度,利于水蒸发,此外利用冷凝管高效、快速收集冷凝水,与由于重力输送过来的待处理冷水进行热交换,冷水吸收蒸汽中的潜热后流入光热蒸发器中,充分利用系统能量。The solar-driven water treatment device designed by the present invention separates the water source and the light-to-heat conversion material through a flow-limiting valve, prevents the heat from being conducted to the water body and reduces heat loss, and at the same time utilizes an air pump or an exhaust fan to quickly guide the water vapor in the evaporation chamber into condensation In addition, the condensation tube is used to efficiently and quickly collect the condensed water and exchange heat with the cold water to be treated due to gravity. The cold water absorbs the latent heat in the steam and flows into the photothermal evaporator. Make full use of system energy.

附图说明:Description of drawings:

图1是本发明实施例一的太阳能驱动水处理装置的结构示意图;1 is a schematic structural diagram of a solar-powered water treatment device according to Embodiment 1 of the present invention;

其中,1、有机玻璃罩,2、光热转换材料,3、蒸汽流,4、限流阀门,5、冷凝管,6、锥形瓶,7、抽气泵,8、真空尾接管,9、阀门,10、支架、11、盛水容器、12、输水管。Among them, 1, plexiglass cover, 2, photothermal conversion material, 3, steam flow, 4, restrictor valve, 5, condenser tube, 6, conical flask, 7, air pump, 8, vacuum tail pipe, 9, Valve, 10, bracket, 11, water container, 12, water pipe.

图2是本发明实施例二的太阳能驱动水处理装置的结构示意图;2 is a schematic structural diagram of a solar-powered water treatment device according to Embodiment 2 of the present invention;

其中,1、有机玻璃罩,2、光热转换材料,3、蒸汽流,4、限流阀门,5、冷凝管,6、锥形瓶,7、排风扇,8、真空尾接管,9、阀门,10、支架、11、盛水容器、12、输水管,13、异型管。Among them, 1. plexiglass cover, 2. light-to-heat conversion material, 3. steam flow, 4. restrictor valve, 5. condenser pipe, 6. conical flask, 7. exhaust fan, 8. vacuum tail pipe, 9. valve , 10, bracket, 11, water container, 12, water pipe, 13, special-shaped pipe.

图3是本发明实施例一的太阳能驱动水处理装置的蒸发室和冷凝管出水口的温度变化图。3 is a temperature change diagram of the evaporation chamber and the water outlet of the condenser tube of the solar-powered water treatment device according to the first embodiment of the present invention.

具体实施方式:Detailed ways:

以下是对本发明的进一步说明,而不是对本发明的限制。The following is a further description of the present invention, rather than a limitation of the present invention.

实施例一:Example 1:

如图1所示的一种太阳能驱动水处理装置,该装置包括依次连接的光热蒸发室、冷凝及潜热收集器、集水系统和盛水容器;所述的光热蒸发室包括有机玻璃罩1和有机玻璃罩1内的光热转换材料2,所述有机玻璃罩1靠近冷凝及潜热收集器一侧设有上下两个开口,上端开口为蒸汽出口,下端开口是有一个限流阀门4的进水口,有机玻璃罩1底部设隔热珍珠棉泡沫,光热转换材料2位于隔热珍珠棉泡沫上,隔热珍珠棉泡沫起到隔绝光热转换材料2向下传导热量的作用,加强光热转换材料的局域加热效应所述集水系统由一个抽气泵7和锥形瓶构成;所述盛水容器11安装在20cm高支架10上装有待处理的水;有机玻璃罩1靠近冷凝管5一侧上端的蒸汽出口直接跟冷凝管5内管一端连通,冷凝管5内管另一端经真空尾接管8分别跟锥形瓶6和抽气泵7连通;冷凝管5进水口经输水管12和阀门9跟盛水容器11连通,冷凝管5出水口跟有机玻璃罩1下端进水口连通;待处理的水经输水管12和阀门9在重力作用下进入冷凝管5,然后进入光热蒸发室产生热蒸汽,通过抽气泵7将光热蒸发室产生的热蒸汽导入冷凝管5,与经输水管12和阀门9在重力作用下进入冷凝管5的待处理的冷水进行热交换,热蒸汽冷却为水经真空尾接管8流到锥形瓶6得到净化的水,同时进入冷凝管的待处理的冷水吸收蒸汽中的潜热后流入光热蒸发室内,提高输入蒸发室内待处理液体的温度,蒸发室和冷凝管出水口的温差为7℃(如图3所示),从而回收利用蒸发过程中汽化潜热,降低水处理的能耗,同时抽气泵加快了蒸发室内热蒸汽的逃逸,降低蒸发室内的湿度,促进光热转换材料的水蒸发,促进了水的大通量蒸发,实现在能量密度较低的普通太阳光驱动下将海水、苦咸水、工业污水、生活废水等水体快速高效地净化。As shown in Figure 1, a solar-powered water treatment device includes a photothermal evaporation chamber, a condensation and latent heat collector, a water collection system and a water container connected in sequence; the photothermal evaporation chamber includes a plexiglass cover 1 and the light-to-heat conversion material 2 in the plexiglass cover 1, the plexiglass cover 1 is provided with two upper and lower openings on one side close to the condensation and latent heat collector, the upper opening is a steam outlet, and the lower opening is a restrictor valve 4 The bottom of the plexiglass cover 1 is provided with heat-insulating pearl cotton foam, and the light-heat conversion material 2 is located on the heat-insulating pearl cotton foam. Local heating effect of light-to-heat conversion material The water collection system is composed of an air pump 7 and a conical flask; the water container 11 is installed on a 20cm high bracket 10 and contains water to be treated; the plexiglass cover 1 is close to the condenser tube The steam outlet on the upper end of one side is directly connected with one end of the inner pipe of the condenser pipe 5, and the other end of the inner pipe of the condenser pipe 5 is communicated with the conical flask 6 and the air pump 7 respectively through the vacuum tail pipe 8; It is communicated with the water container 11 with the valve 9, and the water outlet of the condenser pipe 5 is communicated with the water inlet at the lower end of the plexiglass cover 1; the water to be treated enters the condenser pipe 5 through the water pipe 12 and the valve 9 under the action of gravity, and then enters the photothermal evaporation. The hot steam generated in the chamber generates hot steam, and the hot steam generated by the photothermal evaporation chamber is introduced into the condensing pipe 5 through the air pump 7, and exchanges heat with the cold water to be treated that enters the condensing pipe 5 through the water pipe 12 and the valve 9 under the action of gravity, and the hot steam The cooling is water that flows through the vacuum tail pipe 8 to the conical flask 6 to obtain purified water, and the cold water to be treated that enters the condenser pipe absorbs the latent heat in the steam and flows into the photothermal evaporation chamber, increasing the temperature of the liquid to be treated in the input evaporation chamber, The temperature difference between the evaporation chamber and the water outlet of the condenser tube is 7°C (as shown in Figure 3), so that the latent heat of vaporization in the evaporation process can be recycled and the energy consumption of water treatment can be reduced. The indoor humidity promotes the water evaporation of the photothermal conversion material, promotes the large flux evaporation of water, and realizes the rapid and efficient operation of seawater, brackish water, industrial sewage, domestic wastewater and other water bodies driven by ordinary sunlight with low energy density. to purify.

其中,光热材料与水源分离式设计,杜绝了热量从光热转换材料2传导至水源中,通过限流阀门4可以控制进水量,从而控制光热转换材料的含水量,提高光热转换材料的水蒸发速率。Among them, the separate design of the photothermal material and the water source prevents the heat from being transferred from the photothermal conversion material 2 to the water source, and the water intake can be controlled through the current limiting valve 4, thereby controlling the water content of the photothermal conversion material and improving the photothermal conversion material. the water evaporation rate.

所述光热转换材料为海绵基复合材料,其制备方法包括以下步骤:The light-to-heat conversion material is a sponge-based composite material, and its preparation method includes the following steps:

把切割后的海绵用酒精和去离子水超声清洗并烘干;Ultrasonic cleaning and drying of the cut sponge with alcohol and deionized water;

将碳材料(例如石墨粉、碳粉)、等离激元金属纳米粒子、半导体材料中的任一种吸光材料)加入0.5~3wt%壳聚糖溶液中搅拌得到混合溶液,然后把海绵放入混合溶液中,浸渍1h之后冷冻干燥,即得到海绵基复合材料。Add carbon materials (such as graphite powder, carbon powder), plasmonic metal nanoparticles, and light-absorbing materials in semiconductor materials) into 0.5-3wt% chitosan solution and stir to obtain a mixed solution, and then put the sponge into the solution. In the mixed solution, the sponge-based composite material was obtained after immersion for 1 h and then freeze-drying.

实施例二:Embodiment 2:

图2为本发明实施例二的太阳能驱动水处理装置的结构示意图,与实施例一不同的是将与尾接管8相连的抽气泵去掉,在有机玻璃罩靠近冷凝管一侧上端的蒸汽出口与冷凝管5之间增加排气扇7和异型管13,将蒸发室内的热蒸汽快速输送至冷凝管。该太阳能驱动水处理装置通过光热材料与水源分离式设计,减少热量的传导,并对蒸发过程中汽化潜热进行回收再利用,降低水处理的能耗,同时促进了水的大通量蒸发,实现在能量密度较低的普通太阳光驱动下将海水、苦咸水、工业污水、生活废水等水体快速高效地净化。Fig. 2 is a schematic structural diagram of the solar-driven water treatment device according to the second embodiment of the present invention. The difference from the first embodiment is that the suction pump connected to the tail pipe 8 is removed, and the steam outlet at the upper end of the plexiglass cover close to the side of the condensation pipe is connected to the An exhaust fan 7 and a special-shaped pipe 13 are added between the condensing pipes 5 to quickly transport the hot steam in the evaporation chamber to the condensing pipes. The solar-driven water treatment device is designed to separate the photothermal material from the water source to reduce heat conduction, and to recover and reuse the latent heat of vaporization during the evaporation process, reducing the energy consumption of water treatment, and at the same time promoting the large flux of water evaporation. Realize the rapid and efficient purification of seawater, brackish water, industrial sewage, domestic wastewater and other water bodies driven by ordinary sunlight with low energy density.

以上所述仅为本发明的部分实施例而已,并不限制本发明,凡在本发明的基础和设想之内,所作的任何修改,都应包含在本发明的保护范围之内。The above descriptions are only some embodiments of the present invention, and do not limit the present invention. Any modifications made within the basis and assumption of the present invention should be included within the protection scope of the present invention.

Claims (4)

1. A solar energy driven water treatment device is characterized by comprising a photo-thermal evaporation chamber, a condensation and latent heat collector, a water collecting system and a water container which are connected in sequence; the photothermal evaporation chamber comprises an organic glass cover and photothermal conversion materials in the organic glass cover, one side of the organic glass cover, which is close to the condensation and latent heat collector, is provided with an upper opening and a lower opening, the upper opening is a steam outlet, the lower opening is a water inlet provided with a flow-limiting valve, the bottom of the organic glass cover is provided with heat-insulating pearl wool foam, and the photothermal conversion materials are positioned on the heat-insulating pearl wool foam; the water collecting system consists of an air suction pump or an exhaust fan and a conical flask; the water container is arranged on the bracket and is filled with water to be treated; a steam outlet at the upper end of one side of the organic glass cover, which is close to the condenser pipe, is directly communicated with one end of an inner pipe of the condenser pipe, and the other end of the inner pipe of the condenser pipe is respectively communicated with the conical flask and the air pump through a vacuum tail pipe; or the opening of the organic glass cover close to the upper end of one side of the condensation pipe is communicated with one end of the inner pipe of the condensation pipe through an exhaust fan, and the other end of the inner pipe of the condensation pipe is communicated with the conical flask through a vacuum tail pipe; the water inlet of the condenser pipe is communicated with the water container through a water delivery pipe and a valve, and the water outlet of the condenser pipe is communicated with the water inlet at the lower end of the organic glass cover; water to be treated enters the condenser pipe through the water conveying pipe and the valve under the action of gravity, then enters the photo-thermal evaporation chamber to generate hot steam, the hot steam generated by the photo-thermal evaporation chamber is guided into the condenser pipe through the air suction pump or the exhaust fan, the hot steam and cold water to be treated entering the condenser pipe through the water conveying pipe and the valve under the action of gravity are subjected to heat exchange, the hot steam is cooled to be water, the water flows to the conical flask through the vacuum tail pipe to obtain purified water, and meanwhile, the cold water to be treated entering the condenser pipe flows into the photo-thermal evaporation chamber after absorbing latent heat in the steam.
2. The solar driven water treatment device of claim 1, wherein the photothermal conversion material is a sponge-based composite material prepared by a method comprising the steps of: ultrasonically cleaning the cut sponge by using alcohol and deionized water and drying; adding the light absorption material into 0.5-3 wt% of chitosan solution, stirring to obtain a mixed solution, then putting the sponge into the mixed solution, soaking for 1h, and freeze-drying to obtain the sponge-based composite material.
3. The solar driven water treatment device of claim 2, wherein the light absorbing material is any one of a carbon material, plasmonic metal nanoparticles, a semiconductor material.
4. The solar driven water treatment device as recited in claim 2, wherein the light absorbing material is selected from any one of graphite powder and carbon powder.
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