CN112011396A - Antirust grinding fluid and application thereof in bonding neodymium iron boron magnet - Google Patents

Antirust grinding fluid and application thereof in bonding neodymium iron boron magnet Download PDF

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Publication number
CN112011396A
CN112011396A CN202011011076.6A CN202011011076A CN112011396A CN 112011396 A CN112011396 A CN 112011396A CN 202011011076 A CN202011011076 A CN 202011011076A CN 112011396 A CN112011396 A CN 112011396A
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China
Prior art keywords
grinding fluid
iron boron
neodymium iron
antirust
triethanolamine
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Pending
Application number
CN202011011076.6A
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Chinese (zh)
Inventor
关世昊
韩谋智
高洁
潘勤
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Anhui Hengci Magnetoelectric Co ltd
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Anhui Hengci Magnetoelectric Co ltd
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Priority to CN202011011076.6A priority Critical patent/CN112011396A/en
Publication of CN112011396A publication Critical patent/CN112011396A/en
Priority to CN202111025548.8A priority patent/CN113583746B/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B1/00Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • H01F41/0266Moulding; Pressing
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing Cores, Coils, And Magnets (AREA)
  • Hard Magnetic Materials (AREA)

Abstract

The invention discloses an antirust grinding fluid and application thereof in bonding neodymium iron boron magnets, wherein the antirust grinding fluid comprises the following components in percentage by mass: 4-6% of triethanolamine borate oleate, 0.6-1.2% of triethanolamine, 640.6-1.2% of polyether L, 0.6-0.8% of trisodium phosphate, 0.1-0.3% of an antifoaming agent, 0.05-0.1% of a preservative and the balance of pure water. The raw materials adopted by the invention are all environment-friendly aqueous media, can be naturally degraded in natural environment and have no pollution to the environment.

Description

Antirust grinding fluid and application thereof in bonding neodymium iron boron magnet
Technical Field
The invention belongs to the technical field of antirust grinding fluid, and particularly relates to antirust grinding fluid and application thereof in bonding neodymium iron boron magnets.
Background
After the bonded neodymium iron boron magnet is subjected to compression molding and curing, sharp edges can be generated at the corner edges, and due to the existence of the sharp edges, the corrosion resistance of the magnet is greatly reduced after electrophoresis and roll spraying coating, and the subsequent installation of the magnet and the application after installation are also seriously influenced. In order to avoid the adverse effects, the magnet after being pressed and formed needs to be polished, chamfered and chamfered by brown corundum abrasive, the chamfering process comprises a dry grinding method and a wet grinding method, the dry grinding method is to directly grind the magnet by the brown corundum abrasive without adding grinding fluid, the method can prevent the magnet from rusting, but the chamfering force is not easy to control, the edge and corner of the magnet are easily removed, and the wet grinding method is to add proper aqueous grinding fluid into the brown corundum abrasive, so that the edge and corner of a workpiece can be prevented from being lost in the grinding process, and the workpiece can be prevented from rusting in the grinding process. The traditional method is to add sodium nitrite into the formula of the aqueous grinding fluid for rust prevention, and the sodium nitrite as an aqueous rust inhibitor has good effect, but is carcinogenic and not beneficial to environmental protection.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to provide the antirust grinding fluid for the bonded neodymium iron boron magnet and the application thereof aiming at the defects of the prior art.
The technical scheme is as follows: the invention relates to an antirust grinding fluid for a bonded neodymium iron boron magnet, which comprises the following components in percentage by mass: 4-6% of triethanolamine borate oleate, 0.6-1.2% of triethanolamine, 640.6-1.2% of polyether L, 0.6-0.8% of trisodium phosphate, 0.1-0.3% of an antifoaming agent, 0.05-0.1% of a preservative and the balance of pure water.
Further perfecting the technical scheme, the paint comprises the following components in percentage by mass: 5% of triethanolamine borate oleate, 1% of triethanolamine, 641% of polyether L, 0.7% of trisodium phosphate, 0.2% of defoaming agent, 0.1% of preservative and 92% of pure water.
Further, the conductivity of the pure water is less than or equal to 10 mu S/cm.
The invention also provides application of the antirust grinding fluid in bonding neodymium iron boron magnets.
Further, the application of the antirust grinding fluid in the bonded neodymium iron boron magnet comprises the following steps: after the bonded neodymium iron boron magnet is pressed, molded and solidified, the rust-proof grinding fluid is added into the brown corundum abrasive, and the corners and edges of the bonded neodymium iron boron magnet are ground by a wet grinding method.
Has the advantages that: compared with the prior art, the invention has the advantages that: the invention does not adopt sodium nitrite as an antirust component, but adopts other various environment-friendly water-based antirust agents to replace sodium nitrite, can be naturally degraded in natural environment, and has no pollution to the environment, thereby achieving the effect of both antirust and environment protection. The rust-proof grinding fluid provided by the invention is used for grinding the corners and edges of the bonded neodymium iron boron magnet, and after multiple uses, the chamfered workpiece corners and edges are verified to be round and smooth, and the rust-proof performance is excellent.
Detailed Description
The technical solution of the present invention is described in detail below, but the scope of the present invention is not limited to the embodiments.
Example 1: the invention provides an antirust grinding fluid for a bonded neodymium iron boron magnet, which is prepared according to the following formula:
Figure BDA0002697582190000021
mixing the above materials according to a certain proportion, stirring thoroughly, and packaging.
Figure BDA0002697582190000022
Figure BDA0002697582190000031
All the raw materials adopted in the formula are environment-friendly aqueous media, can be naturally degraded in a natural environment, and have no pollution to the environment.
Example 2: the invention provides an antirust grinding fluid for a bonded neodymium iron boron magnet, which is prepared according to the following formula:
Figure BDA0002697582190000032
mixing the above materials according to a certain proportion, stirring thoroughly, and packaging.
Figure BDA0002697582190000033
All the raw materials adopted in the formula are environment-friendly aqueous media, can be naturally degraded in a natural environment, and have no pollution to the environment.
As noted above, while the present invention has been shown and described with reference to certain preferred embodiments, it is not to be construed as limited thereto. Various changes in form and detail may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (5)

1. The antirust grinding fluid is characterized by comprising the following components in percentage by mass: 4-6% of triethanolamine borate oleate, 0.6-1.2% of triethanolamine, 640.6-1.2% of polyether L, 0.6-0.8% of trisodium phosphate, 0.1-0.3% of an antifoaming agent, 0.05-0.1% of a preservative and the balance of pure water.
2. The rust-preventive grinding fluid according to claim 1, characterized in that: the composite material comprises the following components in percentage by mass: 5% of triethanolamine borate oleate, 1% of triethanolamine, 641% of polyether L, 0.7% of trisodium phosphate, 0.2% of defoaming agent, 0.1% of preservative and 92% of pure water.
3. The rust-preventive grinding fluid according to claim 1, characterized in that: the conductivity of the pure water is less than or equal to 10 mu S/cm.
4. Use of the rust-preventive grinding fluid according to any one of claims 1 to 3 for bonding neodymium-iron-boron magnets.
5. The application of the antirust grinding fluid in bonding neodymium iron boron magnets is characterized by comprising the following steps: after the bonded neodymium iron boron magnet is pressed, molded and solidified, the rust-proof grinding fluid is added into the brown corundum abrasive, and the corners and edges of the bonded neodymium iron boron magnet are ground by a wet grinding method.
CN202011011076.6A 2020-09-23 2020-09-23 Antirust grinding fluid and application thereof in bonding neodymium iron boron magnet Pending CN112011396A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202011011076.6A CN112011396A (en) 2020-09-23 2020-09-23 Antirust grinding fluid and application thereof in bonding neodymium iron boron magnet
CN202111025548.8A CN113583746B (en) 2020-09-23 2021-09-02 Antirust grinding fluid for bonded neodymium-iron-boron magnet and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011011076.6A CN112011396A (en) 2020-09-23 2020-09-23 Antirust grinding fluid and application thereof in bonding neodymium iron boron magnet

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CN202111025548.8A Active CN113583746B (en) 2020-09-23 2021-09-02 Antirust grinding fluid for bonded neodymium-iron-boron magnet and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102311860B (en) * 2011-04-26 2013-07-24 东莞市安美润滑科技有限公司 Water-based cutting fluid used for processing neodymium-iron-boron material slices and application method thereof
CN103725387B (en) * 2012-10-11 2015-10-14 沈阳工业大学 A kind of Nd-Fe-Bo permanent magnet material wire cutting liquid

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CN113583746B (en) 2023-03-17

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Application publication date: 20201201