CN1120032A - Tap-hole clayplug for blast furnace iron notch - Google Patents

Tap-hole clayplug for blast furnace iron notch Download PDF

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Publication number
CN1120032A
CN1120032A CN95106751A CN95106751A CN1120032A CN 1120032 A CN1120032 A CN 1120032A CN 95106751 A CN95106751 A CN 95106751A CN 95106751 A CN95106751 A CN 95106751A CN 1120032 A CN1120032 A CN 1120032A
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account
tap
blast furnace
clay
hole
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CN1061962C (en
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陈炳庆
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Baoshan Iron and Steel Co Ltd
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Baoshan Iron and Steel Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632—Organic additives
    • C04B35/634—Polymers
    • C04B35/63496—Bituminous materials, e.g. tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0087—Uses not provided for elsewhere in C04B2111/00 for metallurgical applications
    • C04B2111/00887—Ferrous metallurgy
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3817—Carbides
    • C04B2235/3826—Silicon carbides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3873—Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422—Carbon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
    • C04B2235/9676—Resistance against chemicals, e.g. against molten glass or molten salts against molten metals such as steel or aluminium

Abstract

The tap-hole clay for blast furnace contains such raw materials (Wt.%) in different granularities as high-alumina corundum (40-60), Si3N4+SiC (15-30), coke powder (7-12), soft clay (7-12), kyanite (3-7), roasted alumina powder (3-6) and tar as binder, and features high alumina content up to 55-65% and high high-temp. strength and stability for elongating tapping time.

Description

Tap-hole clayplug for blast furnace iron notch
The present invention relates to the unshape refractory of a kind of aluminum oxide, can be used for the blast furnace ironmaking iron mouth clay gun stemming of blocking up for base.
Along with blast furnace to maximization, automation, high smelting intensity future development, adopt operation with high pressure, blast furnace is not established cinder notch, molten iron in the stove and slag are together by the discharging of iron mouth, the iron mouth block up with the performance of mud about to a certain extent the operation index of blast furnace, existing iron mouth tap-hole clay is main material with brown corundum, carborundum and coke powder, take mild-clay, sericite as bond, and SiO 2The content height, the host crystal of goods is relative with matrix strength relatively poor, and corrosion resistance and erosion resistibility are undesirable, and the blast furnace casting time is short, and every day, the number of casts was many.For reducing the clay consumption, the flat 1-13108 of Japanese patent application discloses a kind of " blast furnace iron notch pug ", be with the ferro-silicon nitride below 20%, 30% roasting aluminium vanadine, 5～25% carbon, 5～15% kaolin clay and other refractory materialss are that binding agent obtains with tar, this stemming is owing to contain iron in the ferro-silicon nitride, can influence the corrosion resistance of stemming, foreign matter content height, purity are hanged down and also can be influenced to some extent performance in the aluminium of the roasting simultaneously vanadine.
For achieving the above object, the present invention is achieved in that
A kind of blast furnace iron notch taphole clay, its composition (wt) is: high alumina corundum 40～60%, Si 3N4 is in conjunction with SiC 15～30%, coke powder 7～12%, soft clay 7～10%, kyanite 3～7%, roasting oxidation aluminium micro mist 3～6%, above-mentioned total raw material granularity consists of: the coarse fodder of 5～1mm accounts for 35～45%, and the granularity material accounts for 8～12% in 1mm～120 purposes,-120 purpose fine powders account for 45～55%, and 15～20wt% tar-bitumen of above-mentioned siccative total amount is a binding agent.
The granularmetric composition of this tap-hole clay raw material is: the high alumina corundum: 5～1mm accounts for 45～55wt%, and 1mm～120 orders account for 5～10wt%, and-120 orders account for 45～55wt%, Si 3N 4Account for 45～55wt% in conjunction with SiC:3～1mm, 1mm～120 orders account for 5～10wt%, and-120 purposes account for 45～55wt%.
Below the present invention is described in detail.
The present invention adopts high alumina corundum, Si 3N 4Be primary raw material in conjunction with SiC and coke powder, be bond with mild-clay, kyanite and roasting oxidation aluminium micro mist, by strengthening aggregate, improve material purity, making the host crystal that consists of the article construction main body is the high-melting-point crystalline phase, thermal structure intensity and the high volume stability of goods are improved, and bulk density increases, the porosity reduces, to improve its anti-mechanical erosion, resistance to chemical attack ability.Introduce the effect of each component below respectively:
High alumina corundum: 40～60wt%, granularmetric composition is: 5～1mm accounts for 45～55wt%, and 1mm～120 purposes account for 5～10wt%, and-120 orders account for 45～55wt%, and its production technology and brown corundum are basic identical, Al 2O 3Content height, its chemical analysis and physical property be near white fused alumina, and the characteristics such as utilize its hardness height, severe is big, fine and close, the porosity is low, have stable high-temperature performance, and resistance to slag corrosion is good are along with Al 2O 3The increase of content, amount of liquid phase reduces, and anti-slag action performance significantly improves.
Si 3N 4In conjunction with SiC:15～30wt%, granularmetric composition is: 3～1mm accounts for 35～45wt%, and 1mm～120 orders account for 5～10wt%, and-120 orders account for 45～55wt%, and this material is to add metallic silicon by carborundum to carry out nitrogen treatment and obtain, wherein Si 3N 4: SiC is about 1: 2, has very high hardness, good antiacid, alkali erosiveness, wearability and anti-thermal shock stability; Compare with adding ferro-silicon nitride in the prior art, because Si 3N 4In conjunction with the existence of SiC, and SiC is at high temperature very stable, Si 3N 4In N can be better and the clay reaction, be conducive to improve compactness and the erosion resisting of tap-hole clay.
Coke powder: 7～12wt%, granularity≤1mm, this is a kind of material of difficult infiltration, also is difficult for being etched and washing away.
The ability of anti-oxidant (erosion of slag, iron, soak into and infiltration) of iron mouth taphole clay is relevant with void content and volume density, and the air passing hole erosion of slag Tie Tong makes structure deteriorate.The porosity is low, bulk density is big, and then oxidation resistance is strong.The present invention adopts soft clay to add alumina powder, kyanite as wedding agent, can reduce void content, wherein:
Kyanite: 3～7wt%, granularity 120～200 orders, when taphole clay when temperature rises to 1300～1450 ℃ in the iron mouth, the kyanite volumetric expansion can reach 16～18%, and settles out, and temperature descends and does not also shrink, just the contraction of filling pug generation itself.
Roasting oxidation aluminium micro mist: 3～6wt%, granularity accounts for 80% less than 5 μ m, and adding this component can fill up because the soft clay pore that at high temperature volumetric shrinkage occurred improves density with the thermal expansion of kyanite.
Simultaneously, 5～1mm coarse grain: 1mm in this composition～120 purpose medium sizes :-120 purpose fine powders consist of 35～45: 8～12: 45～55, simultaneously maximum particle size is brought up to 5mm by 3mm, can improve the compactness of raw material, reduce void content.
Binding agent is the tar-bitumen of 15～20wt% of above-mentioned siccative total amount.
Compared with prior art, the present invention adopts high alumina corundum and the Si of function admirable 3N 4Be primary raw material in conjunction with SiC, and the bond that uses mild-clay, kyanite and roasting oxidation aluminium micro mist to form, alumina content improves, reach 55～65%, impurity reduces, and has removed iron in the raw material, make the physical property such as bulk density, apparent porosity, rupture strength of iron mouth tap-hole clay, anti-slag chemical erosion and mechanical erosion ability improve a lot, and do not generate low melting point when tapping a blast furnace, and tapping hole is difficult for enlarging.After using taphole clay operation of the present invention on the blast furnace, the time lengthening of tapping a blast furnace, the per day number of casts goes on foot 9 times by subtracting more than 15 times, and the stemming consumption of iron per ton measures 0.8kg and is reduced to 0.4kg, and the stokehold operating condition obviously improves.
Introduce embodiments of the invention below.
Prepare burden concrete composition such as table 1 of the required composition of this blast furnace iron notch tap-hole clay shown, earlier with coarse fodder, after add fines 40～60 fens kinds of in pug mill, mixing, tar asphalt adds at twice, discharges into cylindric mud post through the pug mill extruding, becomes large blast furnace tapping hole tap-hole clay.Table 1 has provided the contrast of the present invention and Comparative Examples composition and performance.
Table 1
The present invention Comparative Examples
????1 ????2 ????3 ????4 ????1 ????2
Proportioning raw materials (weight %) The high alumina corundum ????40 ????45 ????55 ????60
The palm fibre corundum ????42 ????40
Silicon carbide ????18 ????15
Silicon nitride ????5
Silicon nitride combined silicon carbide ????30 ????25 ????20 ????15
Coke powder ????7 ????10 ????8 ????12 ????11 ????11
Clay ????10 ????10 ????9 ????7 ????13 ????13
Alumina powder ????6 ????5 ????4 ????3
Kyanite ????7 ????5 ????4 ????3
Sericite ????16 ????16
Tar-bitumen ????20 ????18 ????17 ????15 ????20 ????20
Physics value Volume density (g/m 3) ????2.26 ????2.30 ????2.33 ????2.40 ????1.98 ????2.01
Apparent porosity (%) ????25.5 ????26.0 ????26.0 ????25.6 ????30.3 ????30.0
Folding strength (MPa) ????3.01 ????2.93 ????2.23 ????2.10 ????0.41 ????1.05
Ultimate compression strength (MPa) ????7.56 ????7.82 ????6.87 ????6.85 ????6.20 ????5.15
Slag resistance (%) ????52 ????55 ????60 ????65 ????100 ????70

Claims (2)

1. tap-hole clayplug for blast furnace iron notch, it is characterized in that: its raw material proportioning is: high alumina corundum 40～60wt%, Si 3N 4In conjunction with SiC 15～30wt%, coke powder 7～12wt%, mild-clay 7～10wt%, kyanite 3～7wt%, roasting oxidation aluminium micro mist 3～6wt%, above-mentioned total raw material granularity consists of: the coarse fodder of 5～1mm accounts for expects in 35～45,1mm～120 purposes to account for 8～12,-120 purpose fine powders account for 45～55wt%, and 15～20wt% tar of above-mentioned siccative total amount.
2. tap-hole clay according to claim 1, it is characterized in that: the granularmetric composition of described composition is: the high alumina corundum: 5～1mm accounts for 45～55wt%, and 1mm～120 orders account for 5～10wt%, and-120 orders account for 45～55wt%, Si 3N 4Account for 35～45wt% in conjunction with SiC:3～1mm, 1mm～120 orders account for 5～10wt%, and-120 orders account for 45～55wt%.
CN95106751A 1995-06-23 1995-06-23 Tap-hole clayplug for blast furnace iron notch Expired - Fee Related CN1061962C (en)

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CN95106751A CN1061962C (en) 1995-06-23 1995-06-23 Tap-hole clayplug for blast furnace iron notch

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Application Number Priority Date Filing Date Title
CN95106751A CN1061962C (en) 1995-06-23 1995-06-23 Tap-hole clayplug for blast furnace iron notch

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CN1120032A true CN1120032A (en) 1996-04-10
CN1061962C CN1061962C (en) 2001-02-14

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075475C (en) * 1996-11-29 2001-11-28 王明贤 Production process of water-less fire-resistant blasting slime
CN100398486C (en) * 2006-12-15 2008-07-02 郑州真金耐火材料有限责任公司 Composite wearing-resistant silica brick
CN100410209C (en) * 2005-11-25 2008-08-13 首钢总公司 Pouring material for torpedo tank liner repairing
CN101736107B (en) * 2010-01-14 2011-06-01 山西太钢不锈钢股份有限公司 Method for poking air inlet of blast furnace
CN102775155A (en) * 2011-05-10 2012-11-14 三和耐火工业股份有限公司 Plugging clay for iron tapping hole
CN108794030A (en) * 2018-08-06 2018-11-13 邵珠航 A kind of smelting iron and steel tap-hole clay and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1013108A (en) * 1996-06-21 1998-01-16 Nec Eng Ltd Resistance attenuator

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075475C (en) * 1996-11-29 2001-11-28 王明贤 Production process of water-less fire-resistant blasting slime
CN100410209C (en) * 2005-11-25 2008-08-13 首钢总公司 Pouring material for torpedo tank liner repairing
CN100398486C (en) * 2006-12-15 2008-07-02 郑州真金耐火材料有限责任公司 Composite wearing-resistant silica brick
CN101736107B (en) * 2010-01-14 2011-06-01 山西太钢不锈钢股份有限公司 Method for poking air inlet of blast furnace
CN102775155A (en) * 2011-05-10 2012-11-14 三和耐火工业股份有限公司 Plugging clay for iron tapping hole
CN108794030A (en) * 2018-08-06 2018-11-13 邵珠航 A kind of smelting iron and steel tap-hole clay and preparation method thereof

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