Disclosure of Invention
The invention provides high-strength high-volume stability concrete, a preparation method thereof and application thereof as a cushion block for a protective layer, aiming at the problems of low compressive strength and poor volume stability of a steel bar protective layer used in the existing engineering, and the cushion blocks with various specifications and shapes are formulated by designing a high-strength high-volume stability concrete proportion and combining with the actual situation on site, so that the protective function of the steel bar protective layer is effectively guaranteed, the maintenance is carried out for 28 days, and the compressive strength can reach 50-90 Mpa.
The high-strength high-volume stability concrete comprises the following raw materials in parts by weight:
4-12 parts of an expanding agent,
40-60 parts of yellow sand,
2-6 parts of silica fume,
0.1 to 0.6 portion of water reducing agent,
0.01 to 0.08 portion of defoaming agent,
35 to 50 parts of ordinary Portland cement,
15-30 parts of matrix asphalt,
10-20 parts of petroleum resin.
The expanding agent is a mixture of any one or more of anhydrite, shell powder, vermiculite hydrate or graphene, and the using amount of the anhydrite is not less than 50% of the total amount of the expanding agent.
The yellow sand is sand in zone II, and has mud content of less than or equal to 2.0% and mud block content of less than or equal to 0.5%
The defoaming agent is a polyether modified organic silicon defoaming agent, the defoaming time is less than 20 seconds, and the foam inhibition time is not less than 30 min.
The matrix asphalt and the petroleum resin are conventional products which are purchased commercially.
The water reducing agent is a mixture of any one or more than two of an aliphatic water reducing agent and a naphthalene water reducing agent, an amino water reducing agent or a polycarboxylic acid water reducing agent in any proportion, and the using amount of the aliphatic water reducing agent is not less than 50% of the total amount of the water reducing agent.
Further, the raw materials of the high-strength high-volume-stability concrete also comprise 5-10 parts of polyethylene wax. Polyethylene wax is added into the ingredients of the cushion block, so that the later-stage forming of the cushion block is facilitated on one hand, and the compressive strength of the cushion block is improved by utilizing the cohesive force of the polyethylene wax on the other hand.
Further, the raw materials of the high-strength high-volume stability concrete also comprise 5-10 parts of glass fiber. The polyethylene wax and the glass fiber are used in a composite mode, the polyethylene wax is attached to the surface of the glass fiber, and meanwhile, a space net structure with the glass fiber as a framework is formed in the cushion block, so that the portland cement particles are captured, and the compression strength of the cushion block is further improved.
The preparation method of the high-strength high-volume stability concrete comprises the following operation steps:
s1, mixing the raw materials according to a ratio, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the molded product in molds of different shapes, and curing and molding for 24 hours;
s4, after the form is removed, placing the concrete in a curing room with the humidity not lower than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the high-strength high-volume stability concrete.
The high-strength high-volume-stability concrete disclosed by the invention is applied as a cushion block for a reinforced concrete protective layer.
The invention has the following beneficial effects:
the high-strength high-volume-stability concrete disclosed by the invention can be used for making cushion blocks with various specifications and shapes by combining with the actual conditions on site, so that the protection function of a reinforcing steel bar protection layer can be effectively guaranteed. According to the invention, the aliphatic water reducing agent and the anhydrite are compounded, and the water absorption of the anhydrite and the aliphatic water reducing agent form a synergistic effect, so that the curing rate of the cushion block is further improved; because the anhydrite can generate calcium ions after being dissolved in water, the calcium ions and the aliphatic water reducing agent generate calcification reaction to form water-insoluble compounds such as fatty acid calcium and the like, the tensile strength and the shock resistance of the cushion block are improved, and the cushion block can be attached to the surface of the reinforcing steel bar to improve the corrosion resistance of the reinforcing steel bar.
Detailed Description
Example 1: a concrete protection cushion block with impermeability, high strength and high volume stability is shown in figure 1, and a strip cushion block is mainly used for plate, beam and column members and comprises the following components in parts by weight: 4 parts of expanding agent, 40 parts of yellow sand, 2 parts of silica fume, 0.1 part of water reducing agent, 0.01 part of defoaming agent, 35 parts of ordinary portland cement, 15 parts of matrix asphalt and 10 parts of petroleum resin.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The water reducing agent consists of 60 percent of aliphatic series and 40 percent of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
S3, placing the mixture in a mold, and curing and molding for 24 hours;
s4, after the mold is removed, placing the steel bar in a curing room with the humidity not lower than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the steel bar protective layer thickness control block.
Example 2: a impervious high-strength high-volume-stability concrete protection cushion block is a wheel type cushion block and is mainly used for components in the vertical direction of a side wall and the like as shown in figure 2, and comprises 12 parts of an expanding agent, 60 parts of yellow sand, 6 parts of silica fume, 0.6 part of a water reducing agent, 0.08 part of an antifoaming agent, 50 parts of ordinary portland cement, 30 parts of matrix asphalt and 20 parts of petroleum resin.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The water reducing agent consists of 60 percent of aliphatic series and 40 percent of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
S3, placing the mixture in a mold for curing and forming for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Example 3: a concrete protection cushion block with impermeability, high strength and high volume stability, a quincunx cushion block, as shown in figure 3, comprises 8 parts of an expanding agent, 50 parts of yellow sand, 4 parts of silica fume, 0.3 part of a water reducing agent, 0.04 part of an antifoaming agent, 42 parts of ordinary portland cement, 22 parts of matrix asphalt and 15 parts of petroleum resin.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The water reducing agent consists of 60 percent of aliphatic series and 40 percent of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold, and curing and molding for 24 hours;
And S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Example 4: a concrete protection cushion block with impermeability, high strength and high volume stability is used for an axillary corner of a beam body, and is shown in figure 4, and comprises 6 parts of an expanding agent, 55 parts of yellow sand, 5 parts of silica fume, 0.4 part of a water reducing agent, 0.07 part of a defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt and 16 parts of petroleum resin.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The water reducing agent consists of 60 percent of aliphatic series and 40 percent of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold and curing for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Example 5: a concrete protection cushion block with impermeability, high strength and high volume stability is used for an axillary corner of a beam body, and is shown in figure 4, and comprises 6 parts of an expanding agent, 55 parts of yellow sand, 5 parts of silica fume, 0.4 part of a water reducing agent, 0.07 part of a defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt and 16 parts of petroleum resin.
The expanding agent is composed of 70% anhydrite and 30% vermiculite hydrate.
The water reducing agent consists of 60 percent of aliphatic series, 20 percent of naphthalene series water reducing agent and 20 percent of amino water reducing agent.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold and curing for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Example 6: a concrete protection cushion block with impermeability, high strength and high volume stability is used for an axillary corner of a beam body, and is shown in figure 4, and comprises 6 parts of an expanding agent, 55 parts of yellow sand, 5 parts of silica fume, 0.4 part of a water reducing agent, 0.07 part of a defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt and 16 parts of petroleum resin.
The expanding agent is composed of 75% of anhydrite and 25% of graphene.
The water reducing agent consists of 55% of aliphatic series, 20% of polycarboxylic acid and 25% of amino water reducing agent.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold and curing for 24 hours;
and S4, after removing the formwork, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the impervious high-strength high-volume-stability concrete protective cushion block.
Example 7: the concrete protective cushion block with the characteristics of permeability resistance, high strength and high volume stability comprises 6 parts of an expanding agent, 55 parts of yellow sand, 5 parts of silica fume, 0.4 part of a water reducing agent, 0.07 part of a defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt, 16 parts of petroleum resin and 8 parts of polyethylene wax.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The water reducing agent consists of 60 percent of aliphatic series and 40 percent of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt, petroleum resin and polyethylene wax, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold, and curing and molding for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Example 8: the concrete protecting cushion block with high impermeability, high strength and high volume stability comprises 6 parts of an expanding agent, 55 parts of yellow sand, 5 parts of silica fume, 0.4 part of a water reducing agent, 0.07 part of a defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt, 16 parts of petroleum resin, 8 parts of polyethylene wax and 10 parts of glass fiber.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The water reducing agent consists of 60 percent of aliphatic series and 40 percent of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps of:
s1, mixing an expanding agent, yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt, petroleum resin, polyethylene wax and glass fiber, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold, and curing and molding for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Comparative example 1: the concrete protective cushion block comprises 55 parts of yellow sand, 5 parts of silica fume, 0.4 part of water reducing agent, 0.07 part of defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt and 16 parts of petroleum resin.
The water reducing agent consists of 60% of aliphatic series and 40% of polycarboxylic acid.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing yellow sand, silica fume, a water reducing agent, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold, and curing and molding for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Comparative example 2: the concrete protective cushion block with the impermeability, high strength and high volume stability comprises 6 parts of an expanding agent, 55 parts of yellow sand, 5 parts of silica fume, 0.07 part of a defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt and 16 parts of petroleum resin.
The expanding agent consists of 60 percent of anhydrite and 40 percent of shell powder.
The defoaming agent is composed of polyether modified organic silicon.
The preparation method of the comparative test comprises the following operation steps:
s1, mixing an expanding agent, yellow sand, silica fume, a defoaming agent, ordinary portland cement, matrix asphalt, petroleum resin, polyethylene wax and glass fiber, and uniformly stirring by using a stirrer;
S2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold, and curing and molding for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
Comparative example 3: the concrete protective cushion block with impermeability, high strength and high volume stability comprises 55 parts of yellow sand, 5 parts of silica fume, 0.07 part of defoaming agent, 45 parts of ordinary portland cement, 20 parts of matrix asphalt and 16 parts of petroleum resin.
The preparation method of the impervious high-strength high-volume-stability concrete protection cushion block comprises the following operation steps:
s1, mixing yellow sand, silica fume, a defoaming agent, ordinary portland cement, matrix asphalt and petroleum resin, and uniformly stirring by using a stirrer;
s2, adding water according to the weight part ratio of 0.13-0.20, and uniformly stirring by using a mortar stirrer;
s3, placing the mixture in a mold, and curing and molding for 24 hours;
and S4, after the mold is removed, placing the concrete in a curing room with the humidity of not less than 95% and the temperature of 20 +/-2 ℃ for curing for 28 days to obtain the anti-permeability high-strength high-volume-stability concrete protection cushion block.
The compression strength of the cushion blocks in the examples 1-8 and the comparative examples 1-3 of the invention is tested according to the regulation of GB50107 'concrete strength test evaluation standard';
testing the permeability resistance of the cushion blocks in the examples 1-8 and the comparative examples 1-3 of the invention according to the regulations of the standard GB/T50082-2019 for testing the long-term performance and durability of common concrete
And (3) performance testing:
table 1 results of performance testing
Comparing the above case data, it can be seen from examples 1, 2, 3 and 4 that when the mixing amount of the expanding agent and the water reducing agent reaches the optimum value, the synergistic effect of the gypsum and the aliphatic water reducing agent enables the strength of the concrete protection cushion block to reach the optimum value; comparing examples 5, 6 and 7, it can be seen that the polyethylene wax and the glass fiber both contribute to the strength and structural compactness of the protective mat, and when both are blended in a certain proportion, the strength and impermeability of the mat are optimized. Example 4 and comparative examples 1, 2 and 3 show that gypsum and aliphatic water reducing agent both have an effect of promoting the strength of the concrete protective cushion block, and the addition of the gypsum and the aliphatic water reducing agent simultaneously can generate calcium fatty acid to promote the strength and the impermeability of the cushion block.
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.