CN111977608A - Driving-adhesion integrated composite structure and preparation method thereof - Google Patents

Driving-adhesion integrated composite structure and preparation method thereof Download PDF

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Publication number
CN111977608A
CN111977608A CN202010903326.0A CN202010903326A CN111977608A CN 111977608 A CN111977608 A CN 111977608A CN 202010903326 A CN202010903326 A CN 202010903326A CN 111977608 A CN111977608 A CN 111977608A
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adhesion
driving
integrated composite
drive
dry adhesion
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刘志刚
孙俊
张晓龙
宋婷
宁雷
王金海
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Shanghai Aerospace Control Technology Institute
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Shanghai Aerospace Control Technology Institute
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B1/00Devices without movable or flexible elements, e.g. microcapillary devices
    • B81B1/006Microdevices formed as a single homogeneous piece, i.e. wherein the mechanical function is obtained by the use of the device, e.g. cutters
    • B81B1/008Microtips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00023Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems without movable or flexible elements
    • B81C1/00111Tips, pillars, i.e. raised structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00206Processes for functionalising a surface, e.g. provide the surface with specific mechanical, chemical or biological properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00214Processes for the simultaneaous manufacturing of a network or an array of similar microstructural devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/01Manufacture or treatment
    • H10N30/09Forming piezoelectric or electrostrictive materials
    • H10N30/092Forming composite materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/01Manufacture or treatment
    • H10N30/09Forming piezoelectric or electrostrictive materials
    • H10N30/098Forming organic materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/80Constructional details
    • H10N30/85Piezoelectric or electrostrictive active materials
    • H10N30/852Composite materials, e.g. having 1-3 or 2-2 type connectivity
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/80Constructional details
    • H10N30/85Piezoelectric or electrostrictive active materials
    • H10N30/857Macromolecular compositions

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
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  • Life Sciences & Earth Sciences (AREA)
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  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a driving-adhesion integrated composite structure and a preparation method thereof, wherein the driving-adhesion integrated composite structure comprises an electric driving structure and a dry adhesion structure; the electric driving structure is made of an ionic polymer metal composite material and can be deformed under the driving of voltage; the dry adhesion structure is an array consisting of a plurality of wedge-shaped structures; the dry adhesion structure is adhered to one end of the electric drive structure. The characteristic that the IPMC can deform under the control of voltage is utilized to connect a dry adhesion structure, so that the controllable adhesion and desorption of the adhesion material under the driving action are realized. The design of the wedge-shaped array structure reduces the force requirement in the desorption process and realizes the organic unification of driving and controllable adhesion.

Description

Driving-adhesion integrated composite structure and preparation method thereof
Technical Field
The invention relates to the field of functional materials, in particular to a driving-adhesion integrated composite structure and a preparation method thereof.
Background
Compared with wet adhesion, vacuum adsorption, magnetic adsorption, electrostatic adsorption and other technologies, the dry adhesion technology has the characteristics of strong adaptability to the appearance of a target surface, no damage and pollution caused by contact, no influence of a vacuum environment and the like, and in addition, the dry adhesion technology can be repeatedly used because the adhesion effect is generated by Van der Waals force. At present, researchers widely apply the dry adhesion technology to the foot end design of the wall-climbing robot, the pick-up and transportation in a vacuum environment, the medical diagnosis by attaching to the skin of a human body, and the like. In the application process of the dry adhesion material, how to realize controllable adhesion and desorption on a target surface is an important aspect of dry adhesion research. The isotropic vertical array structure researched by researchers at home and abroad shows isotropic adhesive strength, and controllable desorption cannot be realized; anisotropic structures with tilted arrays enable controlled desorption, but require a mechanical structure to exert a guiding force that deforms the tilted array in the direction of increasing adhesion.
Disclosure of Invention
The invention aims to solve the technical problem of how to realize controllable desorption by dry adhesion, and provides a driving-adhesion integrated composite structure and a preparation method.
In order to achieve the above object, the present invention provides a driving-adhesion integrated composite structure, including an electric driving structure and a dry adhesion structure; the electric driving structure is made of an ionic polymer metal composite material and can be deformed under the driving of voltage; the dry adhesion structure is an array consisting of a plurality of wedge-shaped structures; the dry adhesion structure is adhered to one end of the electric drive structure.
Preferably, the wedge-shaped structures are uniformly arranged.
Preferably, the wedge-shaped structures are of micron-scale.
Preferably, the dry-adhered structure is made of polydimethylsiloxane material.
Preferably, the dry adhesion structure is adhered to one end of the electric driving structure by a double-sided adhesive tape.
Preferably, one side of the double-sided adhesive tape is acrylic adhesive and is connected with the electric driving structure; the other side is special silicon rubber which is connected with the dry adhesion structure.
The invention also provides a preparation method of the driving-adhesion integrated composite structure, which comprises the following steps:
step 1, preparing an electric driving structure;
step 2, preparing a dry adhesion structure;
and 3, connecting the electric driving structure prepared in the step 1 with the dry adhesion structure prepared in the step 2 to prepare the driving-adhesion integrated composite structure.
Preferably, step 1 comprises:
step 1.1, mixing a Nafion solution and N, N-dimethylformamide according to a volume ratio of 4:1 to obtain a membrane casting solution, preparing a base membrane by adopting a solution casting method, and roughening the surface of the base membrane;
step 1.2, soaking the roughened basement membrane in platinum ammonia solution for more than 12 hours;
and step 1.3, plating metal Pt electrodes on two sides of the base film by adopting a chemical reduction plating method to obtain the electric drive structure.
Preferably, step 2 comprises:
step 2.1, processing by adopting a photoetching process to obtain an array reverse structure die consisting of the wedge-shaped structures;
step 2.2, coating a layer of micrometer-sized polydimethylsiloxane in thickness on the reverse structure die by adopting a spin coating method;
and 2.3, curing and demolding the polydimethylsiloxane coated in the step 2.2 to obtain the dry adhesion structure.
Preferably, step 3 comprises:
step 3.1, connecting one side of the dry adhesion structure prepared in the step 2 to the double-sided silicone rubber;
step 3.2, coating acrylic glue on the other side of the silicon rubber double-sided adhesive tape in the step 3.1;
and 3.3, connecting the dry adhesion structure coated with the super glue prepared in the step 3.2 to one end of the electric drive structure prepared in the step 1 to obtain the drive-adhesion integrated composite structure.
The beneficial effects of the invention include:
(1) the characteristic that the IPMC can deform under the control of voltage is utilized to connect the dry adhesion material, so that the controllable adhesion and desorption of the adhesion material under the driving action are realized.
(2) The design of the wedge-shaped array structure reduces the force requirement in the desorption process and realizes the organic unification of driving and controllable adhesion.
Drawings
Fig. 1 is a schematic view of a driving-adhesion integrated composite structure according to the present invention.
FIG. 2 is a schematic diagram of a dry adhesion structure with micro-scale slanted arrays according to the present invention.
Fig. 3 is a schematic diagram of the electrical drive configuration of the present invention.
FIG. 4-1 is a schematic diagram of the inverse structure of the micron-scale slanted array prepared by the present invention.
FIG. 4-2 is a schematic view of spin coating a PDMS layer on an inverse structure according to the present invention.
FIG. 4-3 is a schematic view of PDMS array obtained after curing and demolding.
Fig. 5-1 is a schematic view of the driving-adhesion integrated composite structure of the present invention when no driving voltage is applied.
Fig. 5-2 is a schematic diagram of the deformation of the driving-adhesion integrated composite structure of the present invention when the driving-adhesion integrated composite structure is driven by a dc voltage to adhere to a target surface.
Fig. 5-3 are schematic deformation diagrams of the driving-adhering integrated composite structure of the present invention for desorbing the target surface under the driving of the reverse dc voltage.
Description of the drawings: 1-electric drive structure, 2-dry adhesion structure, 3-double faced adhesive tape, 4-base film, 5-Pt electrode, 6-inverse structure mold, 7-electrode plate and 8-target surface.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings, and it should be understood that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
An Ionic Polymer Metal Composite (IPMC) is an Ionic electroactive driving material, a noble metal electrode is deposited on the surface of an ion exchange membrane (used as a basement membrane), and deformation and bending are generated by voltage driving. Therefore, the invention combines the dry adhesion material and the ionic polymer metal composite material, and the prepared driving-adhesion integrated composite structure can overcome the defect of the anisotropic structure with the inclined array and has wide application prospect.
As shown in fig. 1, the present invention provides a drive-adhesion integrated composite structure including an electrically driven structure 1 and a dry adhesion structure 2. The electric driving structure 1 is made of an ionic polymer metal composite material, namely IPMC, and the material can generate displacement deformation under the control of voltage. The dry adhesion structure 2 is made of Polydimethylsiloxane (PDMS), which has high adhesion and easy desorption characteristics and low surface energy. The dry adhesion structure 2 is connected to one end of the electric drive structure 1 through a double-sided adhesive tape 3. The two sides of the double-sided adhesive 3 are different in adhesive, and one side of the double-sided adhesive is acrylic adhesive and is connected with the electric driving structure 1; the other side is special silicon rubber which is connected with the dry adhesion structure 2 with low surface energy.
As shown in fig. 2, the dry adhesion structures 2 are an array formed by uniformly arranging wedge-shaped structures, and the wedge-shaped structures are in a micron-scale.
A method of making a drive-attach integrated composite structure, comprising:
step 1: the electrically driven structure 1 was prepared. Mixing Nafion (perfluorosulfonic acid) solution and N, N-dimethylformamide according to the volume ratio of 4:1 to obtain membrane casting solution, preparing a base membrane 4 by adopting a solution casting method, and roughening the surface of the base membrane 4 so as to better plate a metal platinum electrode; soaking the roughened basement membrane 4 in platinum ammonia solution for more than 12 hours; and plating Pt electrodes 5 on two sides of the base film by adopting an electroless reduction plating method to obtain the electrically driven structure 1 shown in figure 3.
Step 2: a dry adhesive structure 2 is prepared. As shown in fig. 4-1, a reverse structure mold 6 of an array composed of wedge-shaped structures is obtained by adopting a photoetching process; as shown in fig. 4-2, a micrometer-sized layer of polydimethylsiloxane is coated on the inverse structure mold 6 by a spin coating method; the coated polydimethylsiloxane was cured and demolded to yield the dry-adhered structure 2, as shown in fig. 4-3.
And step 3: preparing the driving-adhesion integrated composite structure. Connecting one side of the dry adhesion structure 2 prepared in the step 2 to the double-sided silicone rubber; the other side of the silicone rubber double faced adhesive tape is coated with acrylic adhesive tape and then connected to one end of the electric drive structure 1, so that the drive-adhesion integrated composite structure shown in fig. 1 can be obtained.
The use method of the driving-adhesion integrated composite structure prepared by the invention comprises the following steps: as shown in fig. 5-1, the end of the electrically driven structure 1 is clamped by the electrode sheet 7, and when the voltage is 0, the electrically driven structure 1 is not deformed, and the dry adhesion structure 2 has no adhesion to the target surface 8. As shown in fig. 5-2, when a direct current is applied, the electric driving structure 1 is driven by a voltage to deform and bend, so as to generate a driving force, and drive the dry adhesion structure 2 to contact the target surface 8, so that the contact manner between the wedge-shaped structure and the target surface is changed from the original point contact to the surface contact, thereby generating an adhesion effect and realizing controllable adhesion. As shown in fig. 5-3, when a reverse direct current is applied, the electric driving structure 1 is bent in the opposite direction to drive the dry adhesion structure 2 to peel off the target surface 8, the contact mode of the wedge-shaped structure and the target surface is changed from the original surface contact into point contact, and finally the target surface is peeled off, so that the controllable desorption is realized. This process is similar to the process of peeling off an adhesive tape, which is not easily removed in the normal direction when the tape is stuck flat on an object, but is easily removed by tearing in the tangential direction in the opposite direction.
In summary, the invention provides a driving-adhesion integrated composite structure and a preparation method thereof, the driving-adhesion integrated composite structure utilizes the characteristic that an IPMC (ionic polymer metal composite) can deform under the control of voltage to connect a dry adhesion structure, so that the controllable adhesion and desorption of an adhesion material under the driving action are realized, and meanwhile, the design of a wedge-shaped array structure reduces the force requirement of the desorption process, and the organic unification of driving and controllable adhesion is realized. The preparation method provided by the invention has the advantages of simple process, easy operation and wide application prospect.
While the present invention has been described in detail with reference to the preferred embodiments, it should be understood that the above description should not be taken as limiting the invention. Various modifications and alterations to this invention will become apparent to those skilled in the art upon reading the foregoing description. Accordingly, the scope of the invention should be determined from the following claims.

Claims (10)

1. A drive-adhesion integrated composite structure is characterized by comprising an electric drive structure and a dry adhesion structure; the electric driving structure is made of an ionic polymer metal composite material and can be deformed under the driving of voltage; the dry adhesion structure is an array consisting of a plurality of wedge-shaped structures; the dry adhesion structure is adhered to one end of the electric drive structure.
2. The drive-adhesion integrated composite structure of claim 1, wherein the wedge structures are uniformly arranged.
3. The driver-adhesive integrated composite structure of claim 1, wherein the wedge-shaped structures are micro-scale.
4. The integrated drive-adhesion composite structure of claim 1, wherein the dry adhesion structure is a polydimethylsiloxane material.
5. The drive-adhesion integrated composite structure of claim 1, wherein the dry adhesion structure is bonded to one end of the electrically driven structure by double sided adhesive.
6. The drive-adhere integrated composite structure of claim 5, wherein one side of the double-sided adhesive tape is acrylic adhesive, which is connected to the electric drive structure; the other side is special silicon rubber which is connected with the dry adhesion structure.
7. A method for preparing a driver-adhesive integrated composite structure according to claim 1, comprising:
step 1, preparing an electric driving structure;
step 2, preparing a dry adhesion structure;
and 3, connecting the electric driving structure prepared in the step 1 with the dry adhesion structure prepared in the step 2 to prepare the driving-adhesion integrated composite structure.
8. The method of manufacturing a drive-adhere integrated composite structure according to claim 7, wherein the step 1 comprises:
step 1.1, mixing a Nafion solution and N, N-dimethylformamide according to a volume ratio of 4:1 to obtain a membrane casting solution, preparing a base membrane by adopting a solution casting method, and roughening the surface of the base membrane;
step 1.2, soaking the roughened basement membrane in platinum ammonia solution for more than 12 hours;
and step 1.3, plating metal Pt electrodes on two sides of the base film by adopting a chemical reduction plating method to obtain the electric drive structure.
9. The method of manufacturing a drive-adhere integrated composite structure according to claim 7, wherein the step 2 comprises:
step 2.1, processing by adopting a photoetching process to obtain an array reverse structure die consisting of the wedge-shaped structures;
step 2.2, coating a layer of micrometer-sized polydimethylsiloxane in thickness on the reverse structure die by adopting a spin coating method;
and 2.3, curing and demolding the polydimethylsiloxane coated in the step 2.2 to obtain the dry adhesion structure.
10. The method of manufacturing a drive-adhere integrated composite structure according to claim 7, wherein the step 3 comprises:
step 3.1, connecting one side of the dry adhesion structure prepared in the step 2 to the double-sided silicone rubber;
step 3.2, coating acrylic glue on the other side of the silicon rubber double-sided adhesive tape in the step 3.1;
and 3.3, connecting the dry adhesion structure coated with the super glue prepared in the step 3.2 to one end of the electric drive structure prepared in the step 1 to obtain the drive-adhesion integrated composite structure.
CN202010903326.0A 2020-09-01 2020-09-01 Driving-adhesion integrated composite structure and preparation method thereof Pending CN111977608A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112727876A (en) * 2020-12-23 2021-04-30 南京航空航天大学 Controllable-strength adhesion device and control method thereof

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CN102372041A (en) * 2011-10-21 2012-03-14 南京航空航天大学 IPMC (Ion-exchange polymer-metal composites) based gecko-simulating active driving sole and driving mode
CN106784295A (en) * 2016-11-18 2017-05-31 南京航空航天大学 A kind of multi-pore channel IPMC electro-active materials based on foam metal and preparation method thereof
CN110801063A (en) * 2019-10-31 2020-02-18 上海航天控制技术研究所 Multifunctional spacesuit glove based on dry adhesion material

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Publication number Priority date Publication date Assignee Title
KR20100124170A (en) * 2009-05-18 2010-11-26 서울대학교산학협력단 Non-metallic all-organic actuator and process of preparing the same
CN102372041A (en) * 2011-10-21 2012-03-14 南京航空航天大学 IPMC (Ion-exchange polymer-metal composites) based gecko-simulating active driving sole and driving mode
CN106784295A (en) * 2016-11-18 2017-05-31 南京航空航天大学 A kind of multi-pore channel IPMC electro-active materials based on foam metal and preparation method thereof
CN110801063A (en) * 2019-10-31 2020-02-18 上海航天控制技术研究所 Multifunctional spacesuit glove based on dry adhesion material

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112727876A (en) * 2020-12-23 2021-04-30 南京航空航天大学 Controllable-strength adhesion device and control method thereof
CN112727876B (en) * 2020-12-23 2022-03-11 南京航空航天大学 Controllable-strength adhesion device and control method thereof

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