CN111961396A - Polyurea waterproof coating and preparation method thereof - Google Patents
Polyurea waterproof coating and preparation method thereof Download PDFInfo
- Publication number
- CN111961396A CN111961396A CN202010932556.XA CN202010932556A CN111961396A CN 111961396 A CN111961396 A CN 111961396A CN 202010932556 A CN202010932556 A CN 202010932556A CN 111961396 A CN111961396 A CN 111961396A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- mixture
- waterproof coating
- polyurea waterproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/02—Polyureas
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to a polyurea waterproof coating and a preparation method thereof, wherein the polyurea waterproof coating comprises a component A and a component B, and the components in parts by weight are as follows: the component A comprises: 60-70 parts of aromatic isocyanate; 35-50 parts of polyether polyol; 10-15 parts of a rubber plasticizer; 5-10 parts of a solvent; and B component: 40-50 parts of amino-terminated resin; 30-40 parts of an amino-terminated chain extender; 10-15 parts of a rubber plasticizer; 2-3 parts of a flame retardant; 1-2 parts of a dispersant; 1-2 parts of a defoaming agent, wherein the weight ratio of the component A to the component B is 1: 1. the polyurea waterproof coating prepared by the invention has good waterproof and flame retardant properties and a simple preparation method.
Description
Technical Field
The invention relates to the technical field of waterproof coatings, in particular to a polyurea waterproof coating and a preparation method thereof.
Background
With the development of the building industry, the development and application of various waterproof coatings are rapidly developed, higher requirements are put on the quality and performance of the building waterproof coatings, and the building can be ensured not to leak or the leaking part can be blocked by coating the waterproof coatings after the building leaks. Most of waterproof coatings on the market at present are prepared by simply stirring emulsion with water, and after the waterproof coatings are coated on a substrate, a formed film is thin, so that the waterproof coatings are not beneficial to playing a role of water seepage prevention, and the waterproof coatings have general corrosion resistance and fire resistance.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provides a polyurea waterproof coating and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
the polyurea waterproof coating is characterized by comprising a component A and a component B, wherein the components in parts by weight are as follows:
the component A comprises:
60-70 parts of aromatic isocyanate;
35-50 parts of polyether polyol;
10-15 parts of a rubber plasticizer;
5-10 parts of a solvent;
and B component:
40-50 parts of amino-terminated resin;
30-40 parts of an amino-terminated chain extender;
10-15 parts of a rubber plasticizer;
2-3 parts of a flame retardant;
1-2 parts of a dispersant;
1-2 parts of a defoaming agent;
wherein the weight ratio of the component A to the component B is 1: 1.
particularly, the rubber plasticizer is one or more of naphthenic oil, aromatic oil, phthalate and dipropylene glycol dibenzoate.
Particularly, the flame retardant is one of triphenyl phosphate, ammonium polyphosphate and decabromodiphenyl ether.
In particular, the dispersant is vinyl bis stearamide.
In particular, the defoaming agent is polyether modified silicon.
A preparation method of polyurea waterproof paint is characterized by comprising the following steps:
(1) adding the components in the component A into a first reaction kettle according to parts by weight, heating to 80-100 ℃, starting stirring, and dehydrating for 1-2 hours under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture A;
(2) adding the components in the component B into a second reaction kettle according to the parts by weight, heating to 80-100 ℃, starting stirring, and dehydrating for 1-2 hours under a vacuum condition until the water content is below 0.05 percent to obtain a mixture B;
(3) mixing the mixture A and the mixture B according to a weight ratio of 1: 1, adding the mixture into a third reaction kettle, and stirring the mixture for 1 to 2 hours at room temperature to obtain a finished product.
Particularly, the stirring speed in the step (1), the step (2) and the step (3) is all 500-.
The invention has the beneficial effects that: by adopting the scheme, the polyurea waterproof coating prepared by the invention has excellent waterproof performance, flame retardant performance and corrosion resistance, and the preparation method is simple.
Detailed Description
The invention is further illustrated by the following examples:
example 1
The polyurea waterproof coating comprises a component A and a component B, wherein the components in parts by weight are as follows:
the component A comprises:
60 parts of aromatic isocyanate; 35 parts of polyether polyol; 10 parts of a rubber plasticizer; 5 parts of a solvent;
and B component:
40 parts of amino-terminated resin; 30 parts of an amino-terminated chain extender; 10 parts of a rubber plasticizer; 2 parts of a flame retardant; 1 part of a dispersant; 1 part of a defoaming agent;
wherein the weight ratio of the component A to the component B is 1: 1.
in particular, the rubber plasticizer is naphthenic oil.
In particular, the flame retardant is triphenyl phosphate.
In particular, the dispersant is vinyl bis stearamide.
In particular, the defoaming agent is polyether modified silicon.
A preparation method of polyurea waterproof paint is characterized by comprising the following steps:
(1) adding the components in the component A into a first reaction kettle according to parts by weight, heating to 80 ℃, starting stirring, and dehydrating for 1 hour under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture A;
(2) adding the components in the component B into a second reaction kettle according to the parts by weight, heating to 80 ℃, starting stirring, and dehydrating for 1 hour under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture B;
(3) mixing the mixture A and the mixture B according to a weight ratio of 1: 1, adding the mixture into a third reaction kettle, and stirring for 1 hour at room temperature to obtain a finished product, wherein the stirring speed is 500 r/min.
Particularly, the stirring speed in the step (1), the step (2) and the step (3) is 500 r/min.
Example 2
The polyurea waterproof coating is characterized by comprising a component A and a component B, wherein the components in parts by weight are as follows:
the component A comprises:
70 parts of aromatic isocyanate; 50 parts of polyether polyol; 15 parts of a rubber plasticizer; 10 parts of a solvent;
and B component:
50 parts of amino-terminated resin; 40 parts of an amino-terminated chain extender; 15 parts of a rubber plasticizer; 3 parts of a flame retardant; 2 parts of a dispersing agent; 2 parts of a defoaming agent;
wherein the weight ratio of the component A to the component B is 1: 1.
in particular, the rubber plasticizer is a phthalate.
In particular, the flame retardant is ammonium polyphosphate.
In particular, the dispersant is vinyl bis stearamide.
In particular, the defoaming agent is polyether modified silicon.
A preparation method of polyurea waterproof paint is characterized by comprising the following steps:
(1) adding the components in the component A into a first reaction kettle according to parts by weight, heating to 100 ℃, starting stirring, and dehydrating for 2 hours under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture A;
(2) adding the components in the component B into a second reaction kettle according to the parts by weight, heating to 100 ℃, starting stirring, and dehydrating for 2 hours under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture B;
(3) mixing the mixture A and the mixture B according to a weight ratio of 1: 1, adding the mixture into a third reaction kettle, and stirring for 2 hours at room temperature to obtain a finished product, wherein the stirring speed is 800 r/min.
Example 3
The polyurea waterproof coating is characterized by comprising a component A and a component B, wherein the components in parts by weight are as follows:
the component A comprises:
65 parts of aromatic isocyanate; 42 parts of polyether polyol; 12 parts of a rubber plasticizer; 8 parts of a solvent;
and B component:
45 parts of amino-terminated resin; 35 parts of an amino-terminated chain extender; 13 parts of a rubber plasticizer; 2.5 parts of a flame retardant; 1.5 parts of a dispersing agent; 1.5 parts of a defoaming agent;
wherein the weight ratio of the component A to the component B is 1: 1.
in particular, the rubber plasticizer is dipropylene glycol dibenzoate.
In particular, the flame retardant is decabromodiphenyl ether.
In particular, the dispersant is vinyl bis stearamide.
In particular, the defoaming agent is polyether modified silicon.
A preparation method of polyurea waterproof paint is characterized by comprising the following steps:
(1) adding the components in the component A into a first reaction kettle according to parts by weight, heating to 90 ℃, starting stirring, and dehydrating for 1.5 hours under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture A;
(2) adding the components in the component B into a second reaction kettle according to the parts by weight, heating to 90 ℃, starting stirring, and dehydrating for 1.5 hours under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture B;
(3) mixing the mixture A and the mixture B according to a weight ratio of 1: 1, adding the mixture into a third reaction kettle, and stirring the mixture for 1.5 hours at room temperature to obtain a finished product, wherein the stirring speed is 650 r/min.
The invention has been described in an illustrative manner, and it is to be understood that the invention is not limited to the specific embodiments described above, but is intended to cover various modifications, which may be made by the methods and technical solutions of the invention, or may be applied to other applications without modification.
Claims (7)
1. The polyurea waterproof coating is characterized by comprising a component A and a component B, wherein the components in parts by weight are as follows:
the component A comprises:
60-70 parts of aromatic isocyanate;
35-50 parts of polyether polyol;
10-15 parts of a rubber plasticizer;
5-10 parts of a solvent;
and B component:
40-50 parts of amino-terminated resin;
30-40 parts of an amino-terminated chain extender;
10-15 parts of a rubber plasticizer;
2-3 parts of a flame retardant;
1-2 parts of a dispersant;
1-2 parts of a defoaming agent;
wherein the weight ratio of the component A to the component B is 1: 1.
2. the polyurea waterproof coating according to claim 1, wherein the rubber plasticizer is one or more of naphthenic oil, aromatic oil, phthalate, and dipropylene glycol dibenzoate.
3. The polyurea waterproof coating according to claim 1, wherein the flame retardant is one of triphenyl phosphate, ammonium polyphosphate and decabromodiphenyl ether.
4. The polyurea waterproof coating material of claim 1, wherein the dispersant is vinyl bis stearamide.
5. The polyurea waterproof coating material of claim 1, wherein the defoaming agent is polyether modified silicon.
6. A preparation method of polyurea waterproof paint is characterized by comprising the following steps:
(1) adding the components in the component A into a first reaction kettle according to parts by weight, heating to 80-100 ℃, starting stirring, and dehydrating for 1-2 hours under a vacuum condition until the moisture content is below 0.05 percent to obtain a mixture A;
(2) adding the components in the component B into a second reaction kettle according to the parts by weight, heating to 80-100 ℃, starting stirring, and dehydrating for 1-2 hours under a vacuum condition until the water content is below 0.05 percent to obtain a mixture B;
(3) mixing the mixture A and the mixture B according to a weight ratio of 1: 1, adding the mixture into a third reaction kettle, and stirring the mixture for 1 to 2 hours at room temperature to obtain a finished product.
7. The method for preparing polyurea waterproof coating material as claimed in claim 6, wherein the stirring speed in the step (1), the step (2) and the step (3) is 500-800 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010932556.XA CN111961396A (en) | 2020-09-08 | 2020-09-08 | Polyurea waterproof coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010932556.XA CN111961396A (en) | 2020-09-08 | 2020-09-08 | Polyurea waterproof coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111961396A true CN111961396A (en) | 2020-11-20 |
Family
ID=73392550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010932556.XA Pending CN111961396A (en) | 2020-09-08 | 2020-09-08 | Polyurea waterproof coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111961396A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113201113A (en) * | 2021-05-11 | 2021-08-03 | 东营海瑞宝新材料有限公司 | Preparation method of anticorrosive material based on SPUA |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322786A (en) * | 2001-05-30 | 2001-11-21 | 海洋化工研究院 | Fireproof elastic painted polyurea material |
| CN101368062A (en) * | 2008-10-10 | 2009-02-18 | 海洋化工研究院 | High-temperature resistant water spray coating polyurea flexible composition, preparation, construction method and uses thereof |
| CN101818019A (en) * | 2009-02-26 | 2010-09-01 | 北京东方雨虹防水技术股份有限公司 | Spray polyurea high-performance waterproof paint and preparation method thereof |
| CN103214921A (en) * | 2013-04-17 | 2013-07-24 | 北京东方雨虹防水技术股份有限公司 | Reflective heat insulation spray-polyurea elastic coating and preparation method thereof |
| CN104497823A (en) * | 2014-10-20 | 2015-04-08 | 上海东方雨虹防水技术有限责任公司 | Explosion-proof energy-absorbing polyurea elastic coating and preparation method thereof |
| CN106118431A (en) * | 2016-07-29 | 2016-11-16 | 上海基典防水科技有限公司 | High intensity high ferro waterproof material and preparation method thereof |
| CN106243971A (en) * | 2016-07-29 | 2016-12-21 | 上海基典防水科技有限公司 | NEW TYPE OF COMPOSITE high ferro waterproof material and preparation method thereof |
| CN110105853A (en) * | 2019-04-23 | 2019-08-09 | 广东优美仕新材料科技有限公司 | A kind of reservoir dam special-purpose water-proof abrasion-proof polyurea coating and its processing technology |
-
2020
- 2020-09-08 CN CN202010932556.XA patent/CN111961396A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322786A (en) * | 2001-05-30 | 2001-11-21 | 海洋化工研究院 | Fireproof elastic painted polyurea material |
| CN101368062A (en) * | 2008-10-10 | 2009-02-18 | 海洋化工研究院 | High-temperature resistant water spray coating polyurea flexible composition, preparation, construction method and uses thereof |
| CN101818019A (en) * | 2009-02-26 | 2010-09-01 | 北京东方雨虹防水技术股份有限公司 | Spray polyurea high-performance waterproof paint and preparation method thereof |
| CN103214921A (en) * | 2013-04-17 | 2013-07-24 | 北京东方雨虹防水技术股份有限公司 | Reflective heat insulation spray-polyurea elastic coating and preparation method thereof |
| CN104497823A (en) * | 2014-10-20 | 2015-04-08 | 上海东方雨虹防水技术有限责任公司 | Explosion-proof energy-absorbing polyurea elastic coating and preparation method thereof |
| CN106118431A (en) * | 2016-07-29 | 2016-11-16 | 上海基典防水科技有限公司 | High intensity high ferro waterproof material and preparation method thereof |
| CN106243971A (en) * | 2016-07-29 | 2016-12-21 | 上海基典防水科技有限公司 | NEW TYPE OF COMPOSITE high ferro waterproof material and preparation method thereof |
| CN110105853A (en) * | 2019-04-23 | 2019-08-09 | 广东优美仕新材料科技有限公司 | A kind of reservoir dam special-purpose water-proof abrasion-proof polyurea coating and its processing technology |
Non-Patent Citations (2)
| Title |
|---|
| 沈春林: "《建筑防水工程施工技术》", 31 May 2019, 中国建筑工业出版社 * |
| 王荣等: "《管道的腐蚀与控制》", 31 March 2013, 西北工业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113201113A (en) * | 2021-05-11 | 2021-08-03 | 东营海瑞宝新材料有限公司 | Preparation method of anticorrosive material based on SPUA |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110655858A (en) | Single-component polyurethane waterproof coating and preparation method thereof | |
| CN112778886B (en) | Photo-curing two-component polyurea waterproof coating and preparation method thereof | |
| CN108276895B (en) | Polyurethane non-cured waterproof coating and production process thereof | |
| CN109722204B (en) | Single-component polyurethane adhesive and preparation method thereof | |
| CN101429418A (en) | Method for producing organic silica gel adhesive agent | |
| CN111040613A (en) | Solvent-free single-component polyurethane waterproof coating and preparation method thereof | |
| CN111574952A (en) | Special two-component solvent-free polyurethane adhesive for compounding aluminum-plated film | |
| CN113549391B (en) | Single-component polyurethane waterproof coating and preparation method thereof | |
| CN111961396A (en) | Polyurea waterproof coating and preparation method thereof | |
| CN113308186B (en) | Flame-retardant silane modified waterproof coating and preparation method thereof | |
| CN110724246A (en) | Free foaming sealing material composite material and preparation method thereof | |
| CN114574089B (en) | Single-component polyurethane waterproof coating capable of being formed by one-step construction and application thereof | |
| CN114410201B (en) | Waterproof coating and preparation method thereof | |
| CN113278396A (en) | Modified epoxy polyurethane sealant and preparation method thereof | |
| CN112143357B (en) | Bi-component heavy-duty anticorrosive paint based on modified chlorinated rubber | |
| KR102035319B1 (en) | Method of manufacturing putty composition and putty composition manufactured thereby | |
| CN115975461B (en) | Heat-insulating anti-condensation coating, and preparation method and application thereof | |
| CN106047131B (en) | A kind of self-closing's polyurethane water-proof paint and preparation method thereof | |
| CN113088237B (en) | Environment-friendly high-performance polyurethane pouring sealant and preparation method thereof | |
| CN112500551B (en) | PU curing agent and preparation method thereof | |
| CN117511242B (en) | Acid and alkali resistant polymer modified asphalt waterproof coiled material and preparation method thereof | |
| CN113480918A (en) | Preparation process of epoxy corrosion-resistant waterproof coating | |
| CN114686072A (en) | Preparation method of epoxy resin composition for high-temperature-resistant anticorrosive coating | |
| CN111704846A (en) | Tasteless wear-resistant water-based epoxy finish paint and preparation method thereof | |
| CN114891412A (en) | Breakdown-resistant electrophoretic paint and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20201120 |