CN111956896A - Ozone water therapeutic apparatus and method for preparing high-purity ozone water by using same - Google Patents

Ozone water therapeutic apparatus and method for preparing high-purity ozone water by using same Download PDF

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CN111956896A
CN111956896A CN202010935290.4A CN202010935290A CN111956896A CN 111956896 A CN111956896 A CN 111956896A CN 202010935290 A CN202010935290 A CN 202010935290A CN 111956896 A CN111956896 A CN 111956896A
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water
ozone
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water tank
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胡松
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M5/00Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
    • A61M5/14Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
    • A61M5/1414Hanging-up devices
    • A61M5/1415Stands, brackets or the like for supporting infusion accessories
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M5/00Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
    • A61M5/14Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
    • A61M5/1414Hanging-up devices
    • A61M5/1417Holders or handles for hanging up infusion containers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M5/00Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
    • A61M5/14Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
    • A61M5/168Means for controlling media flow to the body or for metering media to the body, e.g. drip meters, counters ; Monitoring media flow to the body
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/2319Methods of introducing gases into liquid media
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2376Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
    • B01F23/23761Aerating, i.e. introducing oxygen containing gas in liquids
    • B01F23/237613Ozone
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/13Ozone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M2202/00Special media to be introduced, removed or treated
    • A61M2202/02Gases
    • A61M2202/0216Ozone

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Anesthesiology (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Hematology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Vascular Medicine (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
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  • Water Treatment By Electricity Or Magnetism (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention provides an ozone water therapeutic apparatus and a method for preparing high-purity ozone water, which is characterized in that: the ozone water therapeutic apparatus comprises an ion exchange membrane electrode ozone generating device, an injection water storage and conveying device and a high-purity ozone water generation and storage device. Pure ozone gas is obtained by taking deionized water as a raw material, and the ozone gas and injection water are mixed to form high-purity ozone water. The ozone generation amount is indirectly controlled by controlling the input current of the ion exchange membrane electrode ozone generation device, so that the concentration of ozone water is accurately adjusted. The outlet of the ozone water is connected with a medical transfusion titration device, and the prepared high-purity ozone water can be directly input into the veins of human bodies by a conventional transfusion method, so that the defects of impure ozone and inaccurate ozone amount metering in a 'multi-amount autohemotherapy' are overcome. The concentration of the high-purity ozone water and the dropping amount of the infusion are selected so as to treat various diseases. Has the advantages of scientific and reasonable structure, convenient operation and safe use.

Description

Ozone water therapeutic apparatus and method for preparing high-purity ozone water by using same
Technical Field
The invention belongs to the technical field of medical instruments, and particularly relates to an ozone water therapeutic apparatus and a method for preparing high-purity ozone water by using the same.
Background
Ozone has been known and used for over a hundred years, and decades have been spent using ozone for the treatment of various diseases, with many examples of successful treatments in europe. Much of the ozone treatment experience is documented in the work of ozone therapeutics (Beijing university medical Press) by Velio Bocci, Italy.
A typical method of ozone therapy is "multiple Autohemotherapy" (Major Autohemotherapy MAH), and the specific treatment method is as follows: taking 10-50ml of venous blood into a sealed container, injecting a proper amount of ozone gas into the container, shaking to mix the ozone gas with the blood, and then infusing the mixture back into the human vein.
The 'multiple autohemotherapy' is introduced into China from the end of eighty to the beginning of ninety years in the 20 th century, and is in a quite wide field in China for decades, and is commonly accepted by a plurality of disease patients: firstly, the method is effective; secondly, the treatment cost is low. "multiple self-blood therapy" has proven to be of life and promising future, but the deficiencies in "multiple self-blood therapy" have clearly limited its development.
The following drawbacks of "macroautohemotherapy" are now analyzed:
(1) the working principle and process of the device used for "macroautohemotherapy" are as follows: a high voltage power supply generates high voltage electricity, and a discharge phenomenon (corona) occurs between the electrodes and the dielectric. When air passes between the electrode and the dielectric, nitrogen in the air is ionized into carcinogenic nitrogen oxide, so that the ozone ionized by using air as a raw material is eliminated. When medical oxygen is used as a raw material, the purity of the medical oxygen is also problematic. Although an oil-free air compressor is used for manufacturing the medical oxygen to avoid oil wax pollution, micro particles of various substances in a PM2.5 large class in the air are not filtered, namely, the ozone ionized by the medical oxygen contains a large number of micro particles of various substances, and the ozone prepared by the micro particles has important defects when entering the blood of a human body. Meanwhile, in the process of preparing ozone by medical oxygen ionization, the ozone amount generated by oxygen is interfered by many factors such as ambient temperature, humidity, oxygen purity, oxygen pressure, oxygen gas flow and the like. As a result, the amount of ozone generated is extremely unstable, and volatile matters lost in the discharge of the electrodes contaminate the ozone.
(2) "macroautohemotherapy" is a method in which 10 to 50ml of blood is transferred from the body to a container, ozone gas is injected into the container, and the ozone gas is mixed with the blood by shaking, and it is unknown how much ozone is contained in the blood.
(3) 10-50ml of blood is taken into the container, and the blood can become sticky due to the self-coagulation property of the blood and can not be returned to the vein, so that an anticoagulant is required to be added, even if the whole operation process is difficult to control, even a medical accident can occur.
Human blood contains 83% of water, and "macroautohemotherapy" extracts blood and mixes it with ozone, and actually ozone is dissolved in the water in blood. Practice proves that: the incorporation of a certain amount of ozone into the water content of human blood is effective in a variety of diseases, which is an important outcome of ozone application for humans.
The invention discloses an ozone therapeutic apparatus, which is used for preparing high-purity ozone water which can be directly infused into human blood, and is a technical problem to be solved urgently in the field and also a responsibility which is required to be coursed and born by a majority of technical workers on human health.
The basic condition for realizing the invention is that 100 percent of pure ozone can be prepared, and the amount of the ozone can be accurately controlled. The electrolytic ozone generator can electrolyze deionized water to prepare 100% pure ozone, and the ozone generation amount can be controlled by current.
The invention patent of China 'electrolytic ozone generating device' (patent number ZL97122126. X) makes specific invention and improvement on the ion exchange membrane electrolysis principle and the membrane electrode basic structure of an electrolytic ozone generator, and converts the laboratory technology into the electrolytic ozone generator product which can be industrially produced for the first time. Since then, electrolytic ozone generators have been developed in practice for production applications. The Chinese utility model patent of 'a membrane electrode electrolysis ozone generator' with patent application number 201821701404.3 makes further improvement to the membrane electrode technology and effectively solves the problem of uniform current distribution of the membrane electrode.
Under the action of an external electric field, hydrogen ions in water molecules are transferred to form H+Hydrogen is formed after the hydrogen is transferred to the cathode, and the transfer quantity of the hydrogen ions corresponds to the number of electrons provided by external current. Therefore, adjusting the working current of the external power supply is equivalent to controlling the migration amount of hydrogen ions, namely controlling the ozone generation amount. Deionized water is subjected to hydrogen ion migration, hydrogen is generated at the cathode, oxygen and ozone are generated at the anode, and the generated ozone is pure and does not contain any impurity.
Disclosure of Invention
The invention aims to solve the problems in the prior art and provides an ozone water therapeutic apparatus and an ozone water therapeutic apparatus
The method for preparing the high-purity ozone water can mix the prepared pure ozone and the water for injection into the high-purity ozone water, is used for treating diseases by infusing into human veins by a conventional infusion method, can accurately control the concentration and output quantity of the high-purity ozone water, and has convenient operation and safe use.
The purpose of the invention is realized by the following technical scheme:
an ozone water therapeutic apparatus comprises an electrolytic ozone generator, and is characterized by also comprising an injection water storage and conveying device and a high-purity ozone water generation and storage device; the electrolytic ozone generator is an ion exchange membrane electrode ozone generating device, an ozone outlet of the ion exchange membrane electrode ozone generating device is communicated with the high-purity ozone water generating and storing device through a gas output pipeline, and the high-purity ozone water generating and storing device is used for dissolving input ozone gas and injection water in the ozone gas to generate high-purity ozone water; the injection water storage and conveying device is used for storing and conveying injection water and is communicated with the high-purity ozone water generation and storage device through a liquid communicating pipe; the high-purity ozone water generation and storage device is provided with a high-purity ozone water outlet.
The improvement of the technical scheme is as follows: the ion exchange membrane electrode ozone generating device comprises a deionized water storage tank, an ion exchange membrane electrode ozone generator, an electric cabinet and an electrolytic water tank; the deionized water storage tank is connected to the electrolytic water tank through a deionized water replenishing pipeline, a first water pump and a first one-way valve are arranged on the deionized water replenishing pipeline, and the control end of the first water pump is connected to the electric cabinet; the ion exchange membrane electrode ozone generator is connected with the electrolytic water tank through a circulating water pipe, and the ion exchange membrane electrode ozone generator is also provided with a hydrogen and migration water discharge port; the ion exchange membrane electrode ozone generator is connected with an electric control box, and the electric control box comprises an electric current regulator and an electric quantity display and is powered by a direct current working power supply.
The technical scheme is further improved as follows: the injection water storage and conveying device comprises an injection water storage tank and an ozone water concentration stabilizing water tank; the water outlet of the injection water storage tank is connected to the ozone water concentration stabilizing water tank through an injection water replenishing pipe, a second water pump and a second one-way valve are arranged on the injection water replenishing pipe, and the control end of the second water pump is connected to the electric cabinet; the ozone water concentration stabilizing water tank is also provided with an exhaust one-way valve; the high-purity ozone water generation and storage device comprises a high-purity ozone water tank and an ozone reducer; the high-purity ozone water tank and the ozone water concentration stabilizing water tank are arranged at the same height, the bottom of the high-purity ozone water tank is communicated with the bottom of the ozone water concentration stabilizing water tank through the liquid communicating pipe, and the liquid communicating pipe is used for keeping the water level of the injection water in the ozone water concentration stabilizing water tank and the ozone water in the high-purity ozone water tank consistent; the gas output pipeline is led out of the top of the electrolytic water tank, and the other end of the gas output pipeline is communicated with the bottom of the high-purity ozone water tank; an ozone and oxygen discharge pipeline is arranged at the top of the high-purity ozone water tank, the other end of the ozone and oxygen discharge pipeline is communicated with the ozone reducer, and activated carbon particles are arranged in the ozone reducer; the high-purity ozone water outlet is arranged at the bottom of the high-purity ozone water tank, and the ozone water outlet is connected with a medical infusion titration device.
The technical scheme is further improved as follows: and the electrolytic water tank and the ozone water concentration stabilizing water tank are respectively provided with an electrolytic water tank water level detector and an ozone water concentration stabilizing water tank water level detector, and the electrolytic water tank water level detector and the ozone water concentration stabilizing water tank water level detector are both connected to the electric cabinet.
The technical scheme is further improved as follows: the deionized water storage tank, the electrolytic water tank, the injection water storage tank, the ozone water concentration stabilizing water tank, the high-purity ozone water tank and the ozone reducer are all made of medical borosilicate glass, and water volume scales are arranged on the side wall of the high-purity ozone water tank; the first water pump and the second water pump are both polytetrafluoroethylene diaphragm micro pumps; the first check valve, the second check valve and the exhaust check valve are all made of polytetrafluoroethylene materials; the deionized water replenishing pipeline, the circulating water pipe, the gas output pipeline, the water replenishing pipe for injection, the ozone and oxygen discharge pipe and the liquid communicating pipe are all polytetrafluoroethylene hoses.
The improvement of the technical scheme is as follows: the ozone water therapeutic apparatus is further provided with a telescopic support, the telescopic support comprises an upper box body, a telescopic inner pipe, a telescopic outer pipe, a lower box body and a base, the telescopic inner pipe is inserted into the telescopic outer pipe and is fixed through a fastening bolt, the lower end of the telescopic outer pipe is fixed on the base, the upper box body is fixed on the telescopic inner pipe, the lower box body is fixed on the base, a deionized water storage tank, a first water pump and a first one-way valve are arranged in the lower box body, and a water storage tank for injection, a second water pump and a second one-way valve are arranged in the ozone water therapeutic apparatus.
Another improvement to the above technical solution: the ozone water therapeutic instrument is further provided with a telescopic support, the telescopic support comprises a top cross beam, a telescopic inner tube, a telescopic outer tube and a base, the telescopic inner tube is inserted into the telescopic outer tube and stretches out and draws back, the telescopic inner tube is fixed to the upper end of the telescopic inner tube through a fastening bolt, the top cross beam is connected to the upper end of the telescopic inner tube, the lower end of the telescopic outer tube is fixed to the base, the deionized water storage tank, the first water pump, the first check valve, the injection water storage tank, the second water pump and the second check valve are all arranged on the telescopic outer tube or the base, and other components in the ozone water therapeutic instrument are all arranged on the top cross.
The invention also provides a method for preparing high-purity ozone water by adopting the ozone water therapeutic apparatus, which is characterized by comprising the following steps of:
s1, adding deionized water into the deionized water storage tank, and adding injection water into the injection water storage tank;
s2, the electric cabinet controls the first water pump and the first one-way valve to make the deionized water in the deionized water storage tank supplement the deionized water into the electrolytic water tank, and the water level in the electrolytic water tank is kept stable by the water level detector of the electrolytic water tank; the electric cabinet controls the second water pump and the second one-way valve to supplement the injection water in the injection water storage tank into the ozone water concentration stabilizing water tank, and the water level in the injection water storage tank is kept stable through the ozone water concentration stabilizing water tank water level detector;
s3, an ion exchange membrane electrode ozone generator in the ion exchange membrane electrode ozone generating device works under the control of an electric cabinet, and ozone gas is prepared in an electrolytic water tank; during the electrolysis process of the electrolysis water tank, the generated hydrogen is discharged from a hydrogen gas exhaust port-migration water discharge port; undissolved ozone and oxygen enter the ozone reducer from an outlet at the top of the high-purity ozone water tank through an ozone and oxygen discharge pipeline and are discharged from the bottom;
s4, conveying oxygen and ozone gas generated by the electrolysis of the deionized water in the electrolytic water tank into the high-purity ozone water tank through a gas output pipeline to be dissolved in the water for injection to form ozone water, wherein the water level in the high-purity ozone water tank is consistent with the water level in the ozone water concentration stabilizing water tank due to the action of the liquid communicating pipe;
and S5, outputting the high-purity ozone water through an ozone water outlet arranged on the high-purity ozone water tank.
The improvement of the technical scheme is as follows: in the step S3, the input current of the ion exchange membrane electrode ozone generator is controlled by the electric cabinet to indirectly control the ozone generation amount, so that the concentration of the high-purity ozone water is accurately adjusted; in the step S5, a medical infusion titration device is connected to an outlet of the ozone water provided on the high-purity ozone water tank, and the medical infusion titration device is used to directly deliver the high-purity ozone water to a patient needing treatment for intravenous infusion.
The invention has the following advantages and positive effects:
1. the invention adopts an ion exchange membrane electrode electrolysis ozone generator to electrolyze deionized water to prepare 100% pure ozone, and dissolves the ozone into water for injection to form high-purity ozone water.
2. The method for preparing the high-purity ozone water by the ozone water therapeutic apparatus can efficiently prepare the high-purity ozone water, can accurately control the concentration and the output quantity of the high-purity ozone water, is convenient to input into blood vessels of a human body timely and accurately, and is convenient to operate and safe to use.
Drawings
FIG. 1 is a schematic structural view of an embodiment of an ozonated water treatment apparatus according to the present invention;
fig. 2 is a schematic view of a telescopic bracket with a box body in an ozone water treatment apparatus of the present invention.
The numbering in the figure is: 1-ion exchange membrane electrode ozone generating device, 1.1-deionized water storage tank, 1.2-first water pump, 1.3-first check valve, 1.4-deionized water supply pipeline, 1.5-hydrogen gas exhaust port-migration water discharge port, 1.6-ion exchange membrane electrode ozone generator, 1.7-circulating water pipe, 1.8-electric cabinet (comprising current regulator and electric quantity display), 1.9-direct current working power supply, 1.10-electrolytic water tank, 1.11-ozone gas, 1.12-electrolytic water tank water level detector and 1.13-gas output pipeline;
2-injection water storage and conveying device, 2.1-injection water storage tank, 2.2-second water pump, 2.3-second one-way valve, 2.4-injection water replenishing pipe, 2.5-ozone water concentration stabilizing water tank, 2.6-exhaust one-way valve and 2.7-ozone water concentration stabilizing water tank water level detector;
3-ozone water generating and storing device, 3.1-high-purity ozone water tank, 3.2-ozone reducer, 3.3-ozone and oxygen discharging pipeline; 4-a liquid communicating pipe, 5-a gas output pipeline and 6-a medical transfusion titration device;
7-telescopic bracket, 7.1-upper box body, 7.2-telescopic inner tube, 7.3-telescopic outer tube, 7.4-lower box body and 7.5-base.
Detailed Description
The invention is described in further detail below with reference to the accompanying drawings:
referring to fig. 1, an embodiment of an ozonated water treatment apparatus according to the present invention includes an electrolytic ozonator, an injection water storage and delivery means 2, and a high purity ozonated water generation and storage means 3. The electrolytic ozone generator is an ion exchange membrane electrode ozone generating device 1, an ozone outlet of the ion exchange membrane electrode ozone generating device 1 is communicated with the high-purity ozone water generating and storing device 3 through a gas output pipeline 5, the gas output pipeline 5 is used for conveying ozone gas generated by the ion exchange membrane electrode ozone generating device 1 to the high-purity ozone water generating and storing device 3, and the high-purity ozone water generating and storing device 3 is used for dissolving input ozone gas and injection water therein to generate high-purity ozone water; the injection water storage and conveying device 2 is used for storing and conveying injection water, and the injection water storage and conveying device 2 is communicated with the high-purity ozone water generation and storage device 3 through a liquid communication pipe 4; the bottom of the high-purity ozone water generation and storage device 3 is provided with a high-purity ozone water outlet.
Specifically, the method comprises the following steps: the ion exchange membrane electrode ozone generating device 1 comprises a deionized water storage tank 1.1, an ion exchange membrane electrode ozone generator 1.6, an electric cabinet 1.8 and an electrolytic water tank 1.10; the deionized water storage tank 1.1 is connected to the electrolytic water tank 1.10 through a deionized water replenishing pipeline 1.4, a first water pump 1.2 and a first one-way valve 1.3 are arranged on the deionized water replenishing pipeline 1.4, and the control end of the first water pump 1.2 is connected to the electric cabinet 1.8; the ion exchange membrane electrode ozone generator 1.6 is connected with the electrolytic water tank 1.10 by a circulating water pipe 1.7, and the ion exchange membrane electrode ozone generator 1.6 is also provided with a hydrogen and migration water discharge port 1.5; the ion exchange membrane electrode ozone generator 1.6 is connected with the electric cabinet 1.8, and the electric cabinet 1.8 comprises a current regulator and an electric quantity display and is powered by a direct current working power supply 1.9.
Further, the injection water storage and conveying device 2 comprises an injection water storage tank 2.1 and an ozone water concentration stabilizing water tank 2.5; the water outlet of the injection water storage tank 2.1 is connected to the ozone water concentration stabilizing water tank 2.5 through an injection water replenishing pipe 2.4, a second water pump 2.2 and a second one-way valve 2.3 are arranged on the injection water replenishing pipe 2.4, and the control end of the second water pump 2.2 is connected to the electric cabinet 1.8; the ozone water concentration stabilizing water tank 2.5 is also provided with an exhaust one-way valve 2.6.
Still further, the above-mentioned high-purity ozone water generation storage means 3 includes a high-purity ozone water tank 3.1 and an ozone reducer 3.2. The high-purity ozone water tank 3.1 is arranged at the same height as the ozone water concentration stabilizing water tank 2.5. The bottom of the high-purity ozone water tank 3.1 is communicated with the bottom of the ozone water concentration stabilizing water tank 2.5 through a liquid communicating pipe 4, and the liquid communicating pipe 4 is used for keeping the water level of the injection water in the ozone water concentration stabilizing water tank 2.5 consistent with the water level of the ozone water in the high-purity ozone water tank 3.1. The gas output pipeline 5 is led out from the top of the electrolytic water tank 1.10, and the other end of the gas output pipeline 5 is communicated with the bottom of the high-purity ozone water tank 3.1. An ozone and oxygen discharge pipeline 3.3 is arranged at the top of the high-purity ozone water tank 3.1, the other end of the ozone and oxygen discharge pipeline 3.3 is communicated with the ozone reducer 3.2, and activated carbon particles are arranged in the ozone reducer 3.2.
In order to facilitate intravenous infusion, the high-purity ozone water outlet is arranged at the bottom of the high-purity ozone water tank 3.1, and the ozone water outlet is connected with a medical infusion titration device 6.
Still further, an electrolytic water tank water level detector 1.12 and an ozone water concentration stabilizing water tank water level detector 2.7 are respectively arranged on the electrolytic water tank 1.10 and the ozone water concentration stabilizing water tank 2.5, and the electrolytic water tank water level detector 1.12 and the ozone water concentration stabilizing water tank water level detector 2.7 are both connected to the electric cabinet 1.8, so that the water levels in the electrolytic water tank 1.10 and the ozone water concentration stabilizing water tank 2.5 can be conveniently controlled.
Preferably, the deionized water storage tank 1.1, the electrolytic water tank 1.10, the water storage tank for injection water 2.1, the ozone water concentration stabilizing water tank 2.5, the high-purity ozone water tank 3.1 and the ozone reducer 3.2 are all made of medical borosilicate glass, and a water volume scale is arranged on the side wall of the high-purity ozone water tank 3.1.
The first water pump 1.2 and the second water pump 2.2 are both polytetrafluoroethylene diaphragm micro pumps; the first one-way valve 1.3, the second one-way valve 2.3 and the exhaust one-way valve 2.6 are all made of polytetrafluoroethylene materials; the deionized water replenishing pipeline 1.4, the circulating water pipe 1.7, the gas output pipeline 5, the injection water replenishing pipe 2.4, the ozone and oxygen discharge pipe 3.3 and the liquid communicating pipe 4 are all polytetrafluoroethylene hoses.
As shown in fig. 1, in order to meet the pressure requirement of intravenous infusion, the invention provides a telescopic bracket 7, which comprises a top beam, a telescopic inner tube, a telescopic outer tube and a base, wherein the telescopic inner tube is inserted into the telescopic outer tube for stretching and is fixed by a fastening bolt, the upper end of the telescopic inner tube is connected with the top beam, and the lower end of the telescopic outer tube is fixed on the base. The deionized water storage tank 1.1, the first water pump 1.2, the first one-way valve 1.3, the injection water storage tank 2.1, the second water pump 2.2 and the second one-way valve 2.3 are all arranged on the telescopic outer pipe or the base, and other parts in the ozone water therapeutic apparatus are all arranged on the top cross beam or the telescopic inner pipe.
As shown in fig. 2, in order to meet the requirement of intravenous infusion pressure, and to make the appearance neat and safer to use, the invention provides a telescopic bracket 7 with a box body, the telescopic bracket 7 with the box body comprises an upper box body 7.1, a telescopic inner tube 7.2, a telescopic outer tube 7.3, a lower box body 7.4 and a base 7.5, the upper box body 7.1 is fixed on the telescopic inner tube 7.2, the lower box body 7.4 is fixed on the base 7.5, the deionized water storage tank 1.1, the first water pump 1.2, the first one-way valve 1.3, the injection water storage tank 2.1, the second water pump 2.2 and the second one-way valve 2.3 are all arranged in the lower box body 7.4, and the rest parts in the ozone water therapeutic apparatus are all arranged in the upper box body 5.1.
A door body is arranged on the upper box body 7.1, and deionized water and water for injection can be added when the door body is opened. The transparent window is arranged on the door body, so that the observation of an operator is facilitated. The bottom surface of the upper box body 7.1 is provided with an infusion tube leading-out hole, which is convenient for leading out an infusion tube in the medical infusion titration device 6. The lower box body 7.4 is provided with a door body, and the door body is opened, so that the observation, the operation and the maintenance are convenient. Two through holes are arranged on the bottom surface of the upper box body 7.1, and two through holes are correspondingly arranged on the top surface of the lower box body 7.4, so that the injection water replenishing pipe 2.4 and the deionized water replenishing pipeline 1.4 can be conveniently led out.
The following are parameters of main components of one embodiment of the ozone water treatment apparatus of the present invention:
1.1-deionized water storage tank, which is made of medical borosilicate glass. The volume is 5L, wherein the deionized water RO is subjected to reverse osmosis secondary preparation, and the conductivity is less than 3 mu s;
1.2-a first water pump, which adopts a polytetrafluoroethylene membrane removing pump;
1.3-a first one-way valve made of polytetrafluoroethylene;
1.4-a deionized water replenishing pipeline, which adopts a polytetrafluoroethylene hose with the outer diameter of 6mm and the wall thickness of 0.5 mm;
1.6-ion exchange membrane electrode assembly ozone generator, ozone generation amount 700mg/h, deionized water consumption 5g/h, working current 0.5-12A, working voltage 2.9-3.3V, attenuation 10%/1000h, continuous working, anode gas ozone: 22% of oxygen: 78 percent;
1.7-a circulating water pipe, which adopts a polytetrafluoroethylene hose and has an outer diameter of 6mm and a wall thickness of 0.5 mm;
1.8-electric control box (including current regulator, electric quantity display);
1.9-DC working power supply, DC 0-15A, can be continuously adjusted, and the working voltage is 2.9-3.3V.
1.10-electrolytic water tank. Medical borosilicate glass, cylindrical. Phi 70mm (inner diameter) x 230mm (height).
2.1-water tank for injection, made of quartz glass, volume 5L.
2.2-a second water pump, which adopts a polytetrafluoroethylene membrane removing pump;
2.3-a second one-way valve made of polytetrafluoroethylene;
2.4-a water replenishing pipe for injection, which adopts a polytetrafluoroethylene hose with the outer diameter of 6mm and the wall thickness of 0.5 mm;
2.5-high purity ozone water concentration stabilizing water tank. Quartz glass, phi 50mm (inner diameter). times.300 mm (height).
2.6-exhaust one-way valve, polytetrafluoroethylene material;
3.1-high purity ozone water tank, made of quartz glass, phi 50mm (inner diameter) x 300mm (height).
3.2-ozone reducer, made of medical borosilicate glass, with an outer diameter of 4mm and a wall thickness of 1 mm;
3.3-ozone and oxygen discharge pipeline, adopting polytetrafluoroethylene hose, with outer diameter of 4mm and wall thickness of 1 mm;
4-a liquid communicating pipe which is a polytetrafluoroethylene hose and has an outer diameter of 6mm and a wall thickness of 0.5 mm;
5-ozone and oxygen output pipelines, which are made of polytetrafluoroethylene hoses, and have the outer diameter of 4mm and the wall thickness of 1 mm;
6-medical infusion titration device, adopting a common disposable medical infusion titration device;
7-the telescopic bracket shown in fig. 1 and 2 is made of stainless steel, and the height can be adjusted within the range of 1800 + 2200 mm.
Referring to fig. 1 and 2, the present invention also provides an embodiment of a method for preparing high purity ozonated water using the ozonated water treatment apparatus described above, comprising the steps of:
s1, adding deionized water into a deionized water storage tank 1.1, and adding injection water into an injection water storage tank 2.1;
s2, the electric cabinet 1.8 controls the first water pump 1.2 and the first one-way valve 1.3 to make the deionized water in the deionized water storage tank 1.1 supplement the deionized water to the electrolytic water tank 1.10, and the water level in the electrolytic water tank is kept stable by the electrolytic water tank water level detector 1.12; the electric cabinet 1.8 controls the second water pump 2.2 and the second one-way valve 2.3 to supplement the injection water in the injection water storage tank 2.1 to the ozone water concentration stabilizing water tank 2.5, and the water level in the ozone water concentration stabilizing water tank is kept stable through the ozone water concentration stabilizing water tank water level detector 2.7;
s3, the ion exchange membrane electrode ozone generator 1.6 in the ion exchange membrane electrode ozone generator 1 works under the control of the electric cabinet 1.8, and ozone gas 1.11 is prepared in the electrolytic water tank 1.10; during the electrolysis process of the electrolysis water tank 1.10, the generated hydrogen is discharged from a hydrogen gas exhaust port-migration water discharge port 1.5; undissolved ozone and oxygen enter the ozone reducer 3.2 from an outlet at the top of the high-purity ozone water tank 3.1 through an ozone and oxygen discharge pipeline 3.3 and then are discharged from the bottom;
s4, conveying oxygen and ozone generated by the electrolysis of the deionized water in the electrolytic water tank 1.10 into the high-purity ozone water tank 3.1 through the gas output pipeline 5 to be dissolved in the water for injection to form ozone water, wherein the water level in the high-purity ozone water tank 3.1 is kept consistent with the water level in the ozone water concentration stabilizing water tank 2.5 due to the action of the liquid communicating pipe 4;
s5, high-purity ozone water is output through an ozone water outlet arranged on the high-purity ozone water tank 3.1.
Further, in the step S3, the input current of the ion exchange membrane electrode assembly ozone generator 1.6 is controlled by the electric cabinet 1.8 to indirectly control the ozone generation amount, so as to accurately adjust the concentration of the high-purity ozone water; in the step S5, the ozone water outlet of the high-purity ozone water tank 3.1 is connected to a medical infusion titration apparatus 6, and the medical infusion titration apparatus 6 is used to directly deliver the high-purity ozone water to a patient needing treatment for intravenous infusion.
The specific operation method of the ozone water therapeutic apparatus application of the invention comprises the following steps:
1. cleaning process before use:
(1) all quartz glassware needs to be cleaned completely, and finally all quartz glassware is washed by secondary RO water;
(2) cleaning all catheters, and finally washing all catheters with secondary RO water;
(3) all outsourced components, one-way valves, membranes, etc. need to be flushed with secondary RO water.
2. Preparing ozone water therapeutic equipment before starting:
(1) filling deionized water into the electrolytic water tank 1.10 and the deionized water storage tank 1.1;
(2) filling the ozone water concentration stabilizing water tank 2.5 and the high-purity ozone water tank 3.1 with water for injection;
(3) the current is adjusted through a current regulator in the electric cabinet 1.8, the working current of the direct current working power supply 1.9 is adjusted to 10A, and the working current is displayed on the electric quantity display to be 10A.
3. Adjusting the concentration of the high-purity ozone water:
(1) in the electrolytic water tank 1.10
After the ion exchange membrane electrode electrolytic generator 1.6 inputs current from an external power supply, the anode gas ozone and oxygen pass through deionized water in the electrolytic water tank 1.10 in a bubble form and are input into the bottom of the high-purity ozone water through the gas output pipeline 5, and then pass through the injection water in the electrolytic water tank 1.10 in a bubble form (ozone is dissolved in the injection water to form the high-purity ozone water). Then, the ozone and oxygen which are not dissolved in the water enter the ozone reducer 3.22 through the ozone and oxygen discharge pipeline 3.3, and are released together with the oxygen after reduction.
(2) After the ion exchange membrane electrode electrolysis ozone generator is started for 1.6 hours, the ozone water therapeutic apparatus enters a stable state to be operated.
(3) 100ml of ozone water is taken from a high-purity ozone water tank 3.1, the concentration (mg/L) of the high-purity ozone water is measured by a potassium iodide titration method, then the working current is adjusted by a current regulator in an electric cabinet 1.8, the concentration of the ozone water is taken after 10 minutes, and the potassium iodide is used for calibrating the concentration of the ozone water until the concentration of the ozone of the high-concentration ozone water reaches the required range. For example, 20mg/L, at which time the therapeutic treatment with ozone water of the present invention is completed.
4. Treatment using operation:
(1) the basic parameters of the ozone water therapeutic apparatus of the invention are as follows:
a. ion exchange membrane electrode assembly ozone generator 1.6 ozone generation amount: 700 mg/h;
b. ozone concentration of high-purity ozone water: 20 mg/L;
c. the infusion speed is 40-60 drops/minute;
d. titration pressure: the outlet of the high-purity ozone water is about 100cm higher than the head of a human body.
(2) Examples of therapeutic applications:
doctors give the therapeutic amount of ozone according to different diseases, for example, 2mg of ozone in blood water needs to be injected into a patient for ozone treatment.
a. Adjusting the titration speed of the high-concentration ozone water to 50 drops/minute;
b. the concentration of the high-purity ozone water is 20 mg/L;
c, 100ml of ozone water and 2mg of ozone;
d. namely, 100ml of ozone water is dripped into the blood;
e, calculating the time consumption of 100ml of high-purity ozone water by the formula: 100mg/1.1ml =91 minutes;
f. the infusion vein treatment time is 91 minutes;
g. the treatment cost is within 100 yuan.
The water for injection used in the present application is usually distilled water or deionized water, and is also called double distilled water, which is the water for injection according to the pharmacopoeia. The high purity ozone water in this patent application is: deionized water is used as a raw material, pure ozone gas is prepared by adopting an ion exchange membrane electrode ozone generator 1, and then the pure ozone gas is dissolved in the water for injection to form high-purity ozone water.
The embodiment of the ozone water therapeutic apparatus provided by the invention is more scientific, safer and more convenient, and a proper amount of high-purity ozone water is input into the blood of a human body to achieve the purpose of treating diseases.
It is to be understood that the above description is not intended to limit the present invention, and the present invention is not limited to the above examples, and those skilled in the art may make modifications, alterations, additions or substitutions within the spirit and scope of the present invention.

Claims (10)

1. An ozone water therapeutic apparatus comprises an electrolytic ozone generator, and is characterized by also comprising an injection water storage and conveying device and a high-purity ozone water generation and storage device; the electrolytic ozone generator is an ion exchange membrane electrode ozone generating device, an ozone outlet of the ion exchange membrane electrode ozone generating device is communicated with the high-purity ozone water generating and storing device through a gas output pipeline, and the high-purity ozone water generating and storing device is used for dissolving input ozone gas and injection water in the ozone gas to generate high-purity ozone water; the injection water storage and conveying device is used for storing and conveying injection water and is communicated with the high-purity ozone water generation and storage device through a liquid communicating pipe; the high-purity ozone water generation and storage device is provided with a high-purity ozone water outlet.
2. The ozonated water treatment instrument of claim 1, wherein the ion exchange membrane electrode ozone generation device comprises a deionized water storage tank, an ion exchange membrane electrode ozone generator, an electric cabinet and an electrolytic water tank; the deionized water storage tank is connected to the electrolytic water tank through a deionized water replenishing pipeline, a first water pump and a first one-way valve are arranged on the deionized water replenishing pipeline, and the control end of the first water pump is connected to the electric cabinet; the ion exchange membrane electrode ozone generator is connected with the electrolytic water tank through a circulating water pipe, and the ion exchange membrane electrode ozone generator is also provided with a hydrogen and migration water discharge port; the ion exchange membrane electrode ozone generator is connected with an electric control box, and the electric control box comprises an electric current regulator and an electric quantity display and is powered by a direct current working power supply.
3. The ozonated water treatment apparatus according to claim 2, wherein the storage and transportation means for injection water comprises an injection water storage tank and an ozonated water concentration stabilizing tank; the water outlet of the injection water storage tank is connected to the ozone water concentration stabilizing water tank through an injection water replenishing pipe, a second water pump and a second one-way valve are arranged on the injection water replenishing pipe, and the control end of the second water pump is connected to the electric cabinet; the ozone water concentration stabilizing water tank is also provided with an exhaust one-way valve; the high-purity ozone water generation and storage device comprises a high-purity ozone water tank and an ozone reducer; the high-purity ozone water tank and the ozone water concentration stabilizing water tank are arranged at the same height, the bottom of the high-purity ozone water tank is communicated with the bottom of the ozone water concentration stabilizing water tank through the liquid communicating pipe, and the liquid communicating pipe is used for keeping the water level of the injection water in the ozone water concentration stabilizing water tank and the ozone water in the high-purity ozone water tank consistent; the gas output pipeline is led out of the top of the electrolytic water tank, and the other end of the gas output pipeline is communicated with the bottom of the high-purity ozone water tank; an ozone and oxygen discharge pipeline is arranged at the top of the high-purity ozone water tank, the other end of the ozone and oxygen discharge pipeline is communicated with the ozone reducer, and activated carbon particles are arranged in the ozone reducer; the high-purity ozone water outlet is arranged at the bottom of the high-purity ozone water tank, and the ozone water outlet is connected with a medical infusion titration device.
4. The ozonated water treatment apparatus according to claim 3, wherein an electrolyzed water tank level detector and an ozonated water concentration stabilizing water tank level detector are provided on the electrolyzed water tank and the ozonated water concentration stabilizing water tank, respectively, and both of the electrolyzed water tank level detector and the ozonated water concentration stabilizing water tank level detector are connected to the electric cabinet.
5. The ozonated water treatment apparatus according to claim 3 or 4, wherein the deionized water storage tank, the electrolytic water tank, the injection water storage tank, the ozonated water concentration stabilizing water tank, the high-purity ozonated water tank, and the ozone reducer are made of medical borosilicate glass, and water volume scales are provided on a side wall of the high-purity ozonated water tank; the first water pump and the second water pump are both polytetrafluoroethylene diaphragm micro pumps; the first check valve, the second check valve and the exhaust check valve are all made of polytetrafluoroethylene materials; the deionized water replenishing pipeline, the circulating water pipe, the gas output pipeline, the water replenishing pipe for injection, the ozone and oxygen discharge pipe and the liquid communicating pipe are all polytetrafluoroethylene hoses.
6. The ozonation water treatment instrument of claim 3 or 4, further comprising a telescopic bracket, wherein the telescopic bracket comprises an upper box body, a telescopic inner tube, a telescopic outer tube, a lower box body and a base, the telescopic inner tube is inserted into the telescopic outer tube to be telescopic and fixed by a fastening bolt, the lower end of the telescopic outer tube is fixed on the base, the upper box body is fixed on the telescopic inner tube, the lower box body is fixed on the base, the deionized water storage tank, the first water pump, the first one-way valve, the injection water storage tank, the second water pump and the second one-way valve are all arranged in the lower box body, and the rest components in the ozonation water treatment instrument are all arranged in the upper box body.
7. The ozonation water treatment instrument of claim 5, further comprising a telescopic bracket, wherein the telescopic bracket comprises an upper box body, a telescopic inner tube, a telescopic outer tube, a lower box body and a base, the telescopic inner tube is inserted into the telescopic outer tube to be telescopic and fixed by a fastening bolt, the lower end of the telescopic outer tube is fixed on the base, the upper box body is fixed on the telescopic inner tube, the lower box body is fixed on the base, the deionized water storage tank, the first water pump, the first one-way valve, the injection water storage tank, the second water pump and the second one-way valve are all arranged in the lower box body, and the rest components in the ozonation water treatment instrument are all arranged in the upper box body.
8. The ozonated water treatment instrument of claim 3 or 4, further comprising a telescopic bracket, wherein the telescopic bracket comprises a top beam, a telescopic inner tube, a telescopic outer tube and a base, the telescopic inner tube is inserted into the telescopic outer tube to be telescopic and fixed by a fastening bolt, the top beam is connected to the upper end of the telescopic inner tube, the lower end of the telescopic outer tube is fixed on the base, the deionized water storage tank, the first water pump, the first check valve, the injection water storage tank, the second water pump and the second check valve are all arranged on the telescopic outer tube or the base, and the rest components in the ozonated water treatment instrument are all arranged on the top beam or the telescopic inner tube.
9. A method for producing high purity ozone water using the ozone water treatment apparatus of any one of claims 1 to 8, comprising the steps of:
s1, adding deionized water into the deionized water storage tank, and adding injection water into the injection water storage tank;
s2, the electric cabinet controls the first water pump and the first one-way valve to make the deionized water in the deionized water storage tank supplement the deionized water into the electrolytic water tank, and the water level in the electrolytic water tank is kept stable by the water level detector of the electrolytic water tank; the electric cabinet controls the second water pump and the second one-way valve to supplement the injection water in the injection water storage tank into the ozone water concentration stabilizing water tank, and the water level in the injection water storage tank is kept stable through the ozone water concentration stabilizing water tank water level detector;
s3, an ion exchange membrane electrode ozone generator in the ion exchange membrane electrode ozone generating device works under the control of an electric cabinet, and ozone gas is prepared in an electrolytic water tank; during the electrolysis process of the electrolysis water tank, the generated hydrogen is discharged from a hydrogen gas exhaust port-migration water discharge port; undissolved ozone and oxygen enter the ozone reducer from an outlet at the top of the high-purity ozone water tank through an ozone and oxygen discharge pipeline and are discharged from the bottom;
s4, conveying oxygen and ozone gas generated by the electrolysis of the deionized water in the electrolytic water tank into the high-purity ozone water tank through a gas output pipeline to be dissolved in the water for injection to form ozone water, wherein the water level in the high-purity ozone water tank is consistent with the water level in the ozone water concentration stabilizing water tank due to the action of the liquid communicating pipe;
and S5, outputting the high-purity ozone water through an ozone water outlet arranged on the high-purity ozone water tank.
10. The ozonation apparatus according to claim 9, wherein the ozone generation amount is indirectly controlled by controlling the input current of the ion exchange membrane electrode and membrane electrode ozonator through an electric cabinet, thereby precisely adjusting the concentration of the high-purity ozonated water in step S3; in the step S5, a medical infusion titration device is connected to an outlet of the ozone water provided on the high-purity ozone water tank, and the medical infusion titration device is used to directly deliver the high-purity ozone water to a patient needing treatment for intravenous infusion.
CN202010935290.4A 2020-09-08 2020-09-08 Ozone water therapeutic apparatus and method for preparing high-purity ozone water by using same Pending CN111956896A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114016056A (en) * 2021-11-25 2022-02-08 珠海格力电器股份有限公司 Ozone water disinfectant manufacturing machine and high-pressure prevention control method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114016056A (en) * 2021-11-25 2022-02-08 珠海格力电器股份有限公司 Ozone water disinfectant manufacturing machine and high-pressure prevention control method thereof

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