CN111944235A - Cup body material capable of releasing negative ions and preparation method thereof - Google Patents
Cup body material capable of releasing negative ions and preparation method thereof Download PDFInfo
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- 150000002500 ions Chemical class 0.000 title claims abstract description 53
- 239000000463 material Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 122
- 238000002156 mixing Methods 0.000 claims abstract description 119
- 239000002131 composite material Substances 0.000 claims abstract description 93
- 239000006185 dispersion Substances 0.000 claims abstract description 51
- 239000007788 liquid Substances 0.000 claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229940070527 tourmaline Drugs 0.000 claims abstract description 28
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 28
- 239000011032 tourmaline Substances 0.000 claims abstract description 28
- 239000012295 chemical reaction liquid Substances 0.000 claims abstract description 23
- -1 polypropylene Polymers 0.000 claims abstract description 19
- 239000004743 Polypropylene Substances 0.000 claims abstract description 18
- 229920001155 polypropylene Polymers 0.000 claims abstract description 18
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims abstract description 17
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000008347 soybean phospholipid Substances 0.000 claims abstract description 17
- 239000010457 zeolite Substances 0.000 claims abstract description 17
- 102000030523 Catechol oxidase Human genes 0.000 claims abstract description 16
- 108010031396 Catechol oxidase Proteins 0.000 claims abstract description 16
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 15
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 15
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 15
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 15
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 15
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 15
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 15
- 244000144730 Amygdalus persica Species 0.000 claims abstract description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- 235000006040 Prunus persica var persica Nutrition 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- 238000005245 sintering Methods 0.000 claims abstract description 14
- 238000011068 loading method Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 103
- 239000000203 mixture Substances 0.000 claims description 34
- 238000001914 filtration Methods 0.000 claims description 32
- 239000011812 mixed powder Substances 0.000 claims description 30
- 150000001450 anions Chemical class 0.000 claims description 29
- 238000001035 drying Methods 0.000 claims description 26
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- 239000012065 filter cake Substances 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 24
- 238000005303 weighing Methods 0.000 claims description 20
- 230000010355 oscillation Effects 0.000 claims description 18
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000001238 wet grinding Methods 0.000 claims description 10
- 239000011324 bead Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 238000004321 preservation Methods 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical group OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 5
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000006845 Michael addition reaction Methods 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920006113 non-polar polymer Polymers 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention relates to a cup body material capable of releasing negative ions and a preparation method thereof, belonging to the technical field of preparation of articles for daily use. The method comprises the steps of firstly preparing a dispersion liquid by taking tourmaline and magnesium oxide as raw materials and polyethylene glycol and carboxymethyl cellulose as auxiliary materials, then taking zeolite with high porosity as a carrier, loading the dispersion liquid, sintering to obtain porous composite powder, mixing polyvinyl alcohol and 3, 4-dihydroxybenzoic acid to obtain a reaction liquid, mixing the reaction liquid with the porous composite powder, adding catechol oxidase to react, compounding with soybean phospholipid to obtain a modified negative ion releasing agent, and finally mixing polypropylene, the modified negative ion releasing agent and peach gum for granulation to finally obtain the negative ion releasable cup body material, wherein the application prospect is wide.
Description
Technical Field
The invention relates to a cup body material capable of releasing negative ions and a preparation method thereof, belonging to the technical field of preparation of articles for daily use.
Background
The cup is an essential water container in daily life, and along with the improvement of living standard of people, the demand of people on the cup is not limited to be used as a water container, so that the cup which is beneficial to the health of people and can release negative ions is provided for a long time, but the research and the equipment of the organic modification technology of the negative ion powder are laggard at present, so that the dispersibility and the stability of the tourmaline powder in the high polymer cup matrix can not meet the requirements of practical application. In application, the difference between the surface properties of the tourmaline powder and the high molecular polymer is large, so that the tourmaline powder is not easy to uniformly disperse and stably exist in a non-polar polymer, and if the tourmaline powder is directly filled in an organic matter, certain properties of the material are easy to reduce, and the property of the cup body material for releasing negative ions is influenced.
In view of the above-mentioned drawbacks, the present designer is actively making research and innovation to create a cup material capable of releasing negative ions and a method for manufacturing the same, so that the cup material has industrial utility value.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide a cup body material capable of releasing negative ions and a preparation method thereof.
The invention relates to a cup body material capable of releasing negative ions, which comprises the following raw materials in parts by weight: 50-60 parts of polypropylene, 10-15 parts of modified anion releasing agent and 5-8 parts of peach gum;
the modified negative ion releasing agent is prepared by mixing and oscillating pre-modified composite powder and modified liquid for reaction;
the modified liquid is prepared by mixing soybean phospholipid and acetone;
the pre-modified composite powder is prepared from reaction liquid, porous composite powder and catechol oxidase;
the reaction solution is prepared by mixing a polyvinyl alcohol solution and a 3, 4-dihydroxy benzoic acid solution;
the porous composite powder is prepared from dispersion liquid and zeolite powder;
the dispersion liquid is prepared from polyethylene glycol, carboxymethyl cellulose, absolute ethyl alcohol and mixed powder;
the mixed powder is prepared by mixing nano magnesium oxide and nano tourmaline powder.
A cup body material capable of releasing negative ions is prepared by the following specific steps:
(1) preparation of mixed powder: mixing nano magnesium oxide and nano tourmaline powder, wet grinding, and drying to obtain mixed powder;
(2) preparation of the dispersion: weighing polyethylene glycol, carboxymethyl cellulose, absolute ethyl alcohol and mixed powder, mixing and dispersing to obtain a dispersion liquid;
(3) preparing porous composite powder: mixing and oscillating the dispersion liquid and the zeolite powder, and sintering to obtain porous composite powder;
(4) preparation of reaction solution: mixing and reacting polyvinyl alcohol solution and 3, 4-dihydroxy benzoic acid solution to obtain reaction solution;
(5) preparing pre-modified composite powder: mixing the reaction liquid with the porous composite powder, adding catechol oxidase, and reacting to obtain pre-modified composite powder;
(6) preparing a modified negative ion releasing agent: mixing soybean phospholipid and acetone to obtain a modified liquid, and carrying out oscillation reaction on the pre-modified composite powder and the modified liquid to obtain a modified negative ion releasing agent;
(7) preparing a material of the cup body capable of releasing negative ions: weighing polypropylene, a modified anion releasing agent and peach gum, mixing, and extruding and granulating to obtain the cup body material capable of releasing anions.
Further, the preparation method comprises the following specific steps:
(1) preparation of mixed powder: mixing nano magnesium oxide and nano tourmaline powder to obtain composite powder, mixing the composite powder with zirconia ball milling beads and deionized water, putting the mixture into a ball milling tank, wet milling, filtering and separating to obtain filter residue, and drying to obtain mixed powder;
(2) preparation of the dispersion: weighing polyethylene glycol, carboxymethyl cellulose, absolute ethyl alcohol and mixed powder, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment to obtain a dispersion liquid;
(3) preparing porous composite powder: mixing the obtained dispersion liquid and zeolite powder, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, and carrying out heat preservation sintering to obtain porous composite powder;
(4) preparation of reaction solution: mixing a polyvinyl alcohol solution and a 3, 4-dihydroxybenzoic acid solution, then putting the mixture into a reaction kettle, heating, raising the temperature, and stirring for reaction to obtain a reaction solution;
(5) preparing pre-modified composite powder: mixing the obtained reaction liquid and the porous composite powder, putting the mixture into a reaction kettle, stirring for pre-reaction, continuously adding catechol oxidase into the reaction kettle, continuously stirring for reaction, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder;
(6) preparing a modified negative ion releasing agent: mixing soybean phospholipid and acetone to obtain a modified solution, mixing the pre-modified composite powder and the modified solution, placing the mixture on a shaking table, carrying out oscillation reaction, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent;
(7) preparing a material of the cup body capable of releasing negative ions: weighing polypropylene, the modified negative ion releasing agent and peach gum, mixing, then loading into a mixing roll, heating, mixing, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the negative ion releasable cup body material.
Further, the preparation method comprises the following specific steps:
(1) preparation of mixed powder: mixing nano magnesium oxide and nano tourmaline powder according to a mass ratio of 1:5 to obtain composite powder, mixing the composite powder, zirconia ball grinding beads and deionized water according to a mass ratio of 1:2:1, putting the mixture into a ball milling tank, carrying out wet milling for 3-5 h, filtering and separating to obtain filter residues, and drying to obtain mixed powder;
(2) preparation of the dispersion: weighing 0.5-1.0 part by weight of polyethylene glycol, 2-3 parts by weight of carboxymethyl cellulose, 50-60 parts by weight of absolute ethyl alcohol and 10-15 parts by weight of the mixed powder, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment at a rotating speed of 2000-3000 r/min for 30-40 min to obtain a dispersion liquid;
(3) preparing porous composite powder: mixing the obtained dispersion liquid and zeolite powder according to a mass ratio of 10:1, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment for 3-5 h at a frequency of 35-45 kHz, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, carrying out temperature programming to 900-950 ℃ at a temperature rise rate of 10 ℃/min, and carrying out heat preservation sintering for 2-3 h to obtain porous composite powder;
(4) preparation of reaction solution: mixing 20 mass percent of polyvinyl alcohol solution and 30 mass percent of 3, 4-dihydroxybenzoic acid solution according to the mass ratio of 3:1, putting the mixture into a reaction kettle, heating to 70-80 ℃, and stirring at the rotating speed of 200-300 r/min for reaction for 3-5 hours to obtain reaction liquid;
(5) preparing pre-modified composite powder: and (3) mixing the obtained reaction solution and the porous composite powder according to the mass ratio of 8: 1, mixing, putting into a reaction kettle, stirring for pre-reaction for 15-20 min, continuously adding catechol oxidase with the mass of 5% of the reaction liquid into the reaction kettle, continuously stirring for reaction for 3-5 h at 30-40 ℃, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder;
(6) preparing a modified negative ion releasing agent: mixing soybean phospholipid and acetone according to the mass ratio of 1:5 to obtain a modified liquid, mixing the pre-modified composite powder and the modified liquid according to the mass ratio of 1:10, placing the mixture on a shaking table, carrying out oscillation reaction for 1-2 h, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent;
(7) preparing a material of the cup body capable of releasing negative ions: weighing 50-60 parts of polypropylene, 10-15 parts of the modified anion releasing agent and 5-8 parts of peach gum according to parts by weight, mixing, putting into a mixing roll, heating to 180-200 ℃, mixing for 15-20 min, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the cup body material capable of releasing anions.
By the scheme, the invention at least has the following advantages:
(1) the invention firstly uses tourmaline and magnesium oxide as raw materials, polyethylene glycol and carboxymethyl cellulose are used as auxiliary materials to prepare dispersion liquid, zeolite with high porosity is used as a carrier, porous composite powder is obtained by sintering after loading the dispersion liquid, then polyvinyl alcohol and 3, 4-dihydroxy benzoic acid are mixed to prepare reaction liquid, the reaction liquid is mixed with the porous composite powder, catechol oxidase is added for reaction, the reaction liquid is compounded with soybean phospholipid to prepare modified anion releasing agent, finally polypropylene, the modified anion releasing agent and peach gum are mixed and granulated to finally prepare the anion releasing cup body material, the invention uses tourmaline capable of releasing anions as a main material, magnesium oxide as a sintering aid and carboxymethyl cellulose as an adhesive to promote the dispersion liquid to be adhered to the surface of the zeolite and in the internal gaps thereof, the tourmaline is loaded on the surface of the porous zeolite by sintering, and the characteristic of large specific surface area of the zeolite is utilized, the contact area of the tourmaline and the air under the same volume is greatly increased, and the efficiency of the tourmaline for releasing negative ions is improved, so that porous composite powder capable of efficiently releasing negative ions is prepared, and the negative ion release performance of the cup body material prepared from the porous composite powder is improved;
(2) then, the invention uses polyvinyl alcohol solution and 3, 4-dihydroxy benzoic acid solution to carry out esterification reaction firstly, thereby introducing catechol functional group, then carries out secondary reaction with catechol oxidase, uses catechol oxidase to oxidize catechol group to form catechol structure, generates Michael addition reaction between the catechol to form covalent bond crosslinking point, finally forms a layer of hydrophilic high polymer network polymer with viscosity on the surface of the porous composite powder to prepare pre-modified composite powder, then mixes the pre-modified composite powder and soybean phospholipid solution for reaction, and the soybean phospholipid is amphiphilic substance, the hydrophilic end of the soybean phospholipid can attract the hydrophilic group on the surface of the pre-modified composite powder, thereby exposing the hydrophobic end, forming a micelle layer on the surface of the composite powder, and the micelle layer increases the steric hindrance on the surface of the composite powder, the Van der Waals force among the hydrophobic groups is reduced, so that the dispersibility of the composite powder is improved, the hydrophobic groups are nonpolar groups, the polypropylene matrix is nonpolar resin, the compatibility of the hydrophobic groups and the polypropylene matrix is improved according to the principle of polarity similarity, the improvement of the compatibility is beneficial to the maximum effect of active ingredients of the tourmaline, the performance of releasing negative ions of the cup body material is improved, and the application prospect is wide.
The foregoing is a summary of the present invention, and in order to provide a clear understanding of the technical means of the present invention and to be implemented in accordance with the present specification, the following is a detailed description of the preferred embodiments of the present invention.
Detailed Description
Mixing nano magnesium oxide and nano tourmaline powder according to a mass ratio of 1:5 to obtain composite powder, mixing the composite powder, zirconia ball grinding beads and deionized water according to a mass ratio of 1:2:1, putting the mixture into a ball milling tank, carrying out wet milling for 3-5 h, filtering and separating to obtain filter residues, and drying to obtain mixed powder; weighing 0.5-1.0 part by weight of polyethylene glycol, 2-3 parts by weight of carboxymethyl cellulose, 50-60 parts by weight of absolute ethyl alcohol and 10-15 parts by weight of the mixed powder, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment at a rotating speed of 2000-3000 r/min for 30-40 min to obtain a dispersion liquid; mixing the obtained dispersion liquid and zeolite powder according to a mass ratio of 10:1, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment for 3-5 h at a frequency of 35-45 kHz, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, carrying out temperature programming to 900-950 ℃ at a temperature rise rate of 10 ℃/min, and carrying out heat preservation sintering for 2-3 h to obtain porous composite powder; mixing 20 mass percent of polyvinyl alcohol solution and 30 mass percent of 3, 4-dihydroxybenzoic acid solution according to the mass ratio of 3:1, putting the mixture into a reaction kettle, heating to 70-80 ℃, and stirring at the rotating speed of 200-300 r/min for reaction for 3-5 hours to obtain reaction liquid; and (3) mixing the obtained reaction solution and the porous composite powder according to the mass ratio of 8: 1, mixing, putting into a reaction kettle, stirring for pre-reaction for 15-20 min, continuously adding catechol oxidase with the mass of 5% of the reaction liquid into the reaction kettle, continuously stirring for reaction for 3-5 h at 30-40 ℃, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder; mixing soybean phospholipid and acetone according to the mass ratio of 1:5 to obtain a modified liquid, mixing the pre-modified composite powder and the modified liquid according to the mass ratio of 1:10, placing the mixture on a shaking table, carrying out oscillation reaction for 1-2 h, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent; weighing 50-60 parts of polypropylene, 10-15 parts of the modified anion releasing agent and 5-8 parts of peach gum according to parts by weight, mixing, putting into a mixing roll, heating to 180-200 ℃, mixing for 15-20 min, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the cup body material capable of releasing anions.
Example 1
Mixing nano magnesium oxide and nano tourmaline powder according to a mass ratio of 1:5 to obtain composite powder, mixing the composite powder, zirconia ball milling beads and deionized water according to a mass ratio of 1:2:1, putting the mixture into a ball milling tank, carrying out wet milling for 3 hours, filtering and separating to obtain filter residue, and drying to obtain mixed powder; weighing 0.5 part of polyethylene glycol, 2 parts of carboxymethyl cellulose, 50 parts of absolute ethyl alcohol and 10 parts of the mixed powder according to parts by weight, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment at the rotating speed of 2000r/min for 30min to obtain a dispersion liquid; mixing the obtained dispersion liquid and zeolite powder according to a mass ratio of 10:1, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment for 3 hours at a frequency of 35kHz, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, carrying out temperature programming to 900 ℃ at a temperature rise rate of 10 ℃/min, and carrying out heat preservation sintering for 2 hours to obtain porous composite powder; mixing 20 mass percent of polyvinyl alcohol solution and 30 mass percent of 3, 4-dihydroxybenzoic acid solution according to the mass ratio of 3:1, then putting the mixture into a reaction kettle, heating to 70 ℃, and stirring at the rotating speed of 200r/min for reaction for 3 hours to obtain reaction liquid; and (3) mixing the obtained reaction solution and the porous composite powder according to the mass ratio of 8: 1, mixing, putting into a reaction kettle, stirring for pre-reaction for 15min, continuously adding catechol oxidase with the mass of 5% of the reaction liquid into the reaction kettle, continuously stirring for reaction for 3h at the temperature of 30 ℃, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder; mixing soybean phospholipid and acetone according to the mass ratio of 1:5 to obtain a modified liquid, mixing the pre-modified composite powder and the modified liquid according to the mass ratio of 1:10, placing the mixture on a shaking table, carrying out oscillation reaction for 1h, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent; weighing 50 parts of polypropylene, 10 parts of the modified anion releasing agent and 5 parts of peach gum according to the parts by weight, mixing, putting into a mixing roll, heating to 180 ℃, mixing for 15min, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the cup body material capable of releasing anions.
Example 2
Mixing nano magnesium oxide and nano tourmaline powder according to a mass ratio of 1:5 to obtain composite powder, mixing the composite powder, zirconia ball milling beads and deionized water according to a mass ratio of 1:2:1, putting the mixture into a ball milling tank, carrying out wet milling for 4 hours, filtering and separating to obtain filter residue, and drying to obtain mixed powder; weighing 0.8 part of polyethylene glycol, 2 parts of carboxymethyl cellulose, 55 parts of absolute ethyl alcohol and 13 parts of the mixed powder according to parts by weight, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment at the rotating speed of 2500r/min for 35min to obtain a dispersion liquid; mixing the obtained dispersion liquid and zeolite powder according to a mass ratio of 10:1, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment for 4 hours at a frequency of 40kHz, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, carrying out temperature programming to 930 ℃ at a temperature rise rate of 10 ℃/min, and carrying out heat preservation sintering for 2 hours to obtain porous composite powder; mixing 20 mass percent of polyvinyl alcohol solution and 30 mass percent of 3, 4-dihydroxybenzoic acid solution according to the mass ratio of 3:1, then putting the mixture into a reaction kettle, heating to 75 ℃, and stirring at the rotating speed of 250r/min for reaction for 4 hours to obtain reaction liquid; and (3) mixing the obtained reaction solution and the porous composite powder according to the mass ratio of 8: 1, mixing, putting into a reaction kettle, stirring for pre-reaction for 18min, continuously adding catechol oxidase with the mass of 5% of the reaction liquid into the reaction kettle, continuously stirring for reaction for 4h at 35 ℃, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder; mixing soybean phospholipid and acetone according to the mass ratio of 1:5 to obtain a modified liquid, mixing the pre-modified composite powder and the modified liquid according to the mass ratio of 1:10, placing the mixture on a shaking table, carrying out oscillation reaction for 1h, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent; weighing 55 parts of polypropylene, 13 parts of the modified anion releasing agent and 7 parts of peach gum according to the parts by weight, mixing, putting into a mixing roll, heating to 190 ℃, mixing for 18min, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the cup body material capable of releasing anions.
Example 3
Mixing nano magnesium oxide and nano tourmaline powder according to a mass ratio of 1:5 to obtain composite powder, mixing the composite powder, zirconia ball grinding beads and deionized water according to a mass ratio of 1:2:1, putting the mixture into a ball milling tank, carrying out wet milling for 5 hours, filtering and separating to obtain filter residues, and drying to obtain mixed powder; weighing 1.0 part of polyethylene glycol, 3 parts of carboxymethyl cellulose, 60 parts of absolute ethyl alcohol and 15 parts of the mixed powder according to parts by weight, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment at a rotating speed of 3000r/min for 40min to obtain a dispersion liquid; mixing the obtained dispersion liquid and zeolite powder according to a mass ratio of 10:1, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment for 5 hours at a frequency of 45kHz, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, carrying out temperature programming to 950 ℃ at a temperature rise rate of 10 ℃/min, and carrying out heat preservation sintering for 3 hours to obtain porous composite powder; mixing 20 mass percent of polyvinyl alcohol solution and 30 mass percent of 3, 4-dihydroxybenzoic acid solution according to the mass ratio of 3:1, then putting the mixture into a reaction kettle, heating to 80 ℃, and stirring at the rotating speed of 300r/min for 5 hours to obtain reaction liquid; and (3) mixing the obtained reaction solution and the porous composite powder according to the mass ratio of 8: 1, mixing, putting into a reaction kettle, stirring for pre-reaction for 20min, continuously adding catechol oxidase with the mass of 5% of the reaction liquid into the reaction kettle, continuously stirring for reaction for 5h at 40 ℃, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder; mixing soybean phospholipid and acetone according to the mass ratio of 1:5 to obtain a modified liquid, mixing the pre-modified composite powder and the modified liquid according to the mass ratio of 1:10, placing the mixture on a shaking table, carrying out oscillation reaction for 2 hours, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent; weighing 60 parts of polypropylene, 15 parts of the modified anion releasing agent and 8 parts of peach gum according to the parts by weight, mixing, putting into a mixing roll, heating to 200 ℃, mixing for 20min, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the cup body material capable of releasing anions.
Comparative example 1: the preparation method is substantially the same as that of example 1 of the present invention except that tourmaline is directly used instead of the modified anion releasing agent of the present invention;
comparative example 2: the preparation method is basically the same as that of the embodiment 1 of the invention, except that the porous composite powder is directly used for replacing the modified anion releasing agent of the invention;
comparative example 3: the preparation method was substantially the same as that of example 1 of the present invention except that tourmaline powder was directly used in place of the porous composite powder of the present invention;
the cup materials of examples 1 to 3 of the present invention and comparative examples 1 to 3 were subjected to performance tests, and the test results are shown in table 1;
detecting items: negative oxygen ion
The detection method comprises the following steps: method for referencing JC/T1016-2006
TABLE 1 Performance test results
As can be seen from the detection data in the table above, in the comparative example 1, because the modified anion releasing agent of the invention is not used, but tourmaline is directly used, the probability of contacting with air is low, and the compatibility with polypropylene is poor, the quantity of anions of the final material is seriously reduced, and the addition of the modified anion releasing agent of the invention can be seen to improve the performance of the cup body material for releasing anions;
in comparative example 2, since the porous composite powder is not modified to improve the compatibility, the compatibility with polypropylene is reduced, and the release amount of negative ions is reduced, so that the modification step of improving the compatibility of the invention can indeed improve the release amount of the negative ions in the product;
in the comparative example 3, because the step of modifying the tourmaline to enlarge the porosity is not carried out, the contact probability with the air is reduced, and the release amount of negative ions is reduced, so that the step of modifying the porosity to enlarge the porosity of the tourmaline can be seen, and the release amount of the negative ions of the product is indeed improved; has wide application prospect.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, it should be noted that, for those skilled in the art, many modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.
Claims (4)
1. A releasable anion cup material is characterized in that: the composite material comprises the following raw materials in parts by weight: 50-60 parts of polypropylene, 10-15 parts of modified anion releasing agent and 5-8 parts of peach gum;
the modified negative ion releasing agent is prepared by mixing and oscillating pre-modified composite powder and modified liquid for reaction;
the modified liquid is prepared by mixing soybean phospholipid and acetone;
the pre-modified composite powder is prepared from reaction liquid, porous composite powder and catechol oxidase;
the reaction solution is prepared by mixing a polyvinyl alcohol solution and a 3, 4-dihydroxy benzoic acid solution;
the porous composite powder is prepared from dispersion liquid and zeolite powder;
the dispersion liquid is prepared from polyethylene glycol, carboxymethyl cellulose, absolute ethyl alcohol and mixed powder;
the mixed powder is prepared by mixing nano magnesium oxide and nano tourmaline powder.
2. A cup body material capable of releasing negative ions is characterized by comprising the following specific preparation steps:
(1) preparation of mixed powder: mixing nano magnesium oxide and nano tourmaline powder, wet grinding, and drying to obtain mixed powder;
(2) preparation of the dispersion: weighing polyethylene glycol, carboxymethyl cellulose, absolute ethyl alcohol and mixed powder, mixing and dispersing to obtain a dispersion liquid;
(3) preparing porous composite powder: mixing and oscillating the dispersion liquid and the zeolite powder, and sintering to obtain porous composite powder;
(4) preparation of reaction solution: mixing and reacting polyvinyl alcohol solution and 3, 4-dihydroxy benzoic acid solution to obtain reaction solution;
(5) preparing pre-modified composite powder: mixing the reaction liquid with the porous composite powder, adding catechol oxidase, and reacting to obtain pre-modified composite powder;
(6) preparing a modified negative ion releasing agent: mixing soybean phospholipid and acetone to obtain a modified liquid, and carrying out oscillation reaction on the pre-modified composite powder and the modified liquid to obtain a modified negative ion releasing agent;
(7) preparing a material of the cup body capable of releasing negative ions: weighing polypropylene, a modified anion releasing agent and peach gum, mixing, and extruding and granulating to obtain the cup body material capable of releasing anions.
3. A cup body material capable of releasing negative ions is characterized by comprising the following specific preparation steps:
(1) preparation of mixed powder: mixing nano magnesium oxide and nano tourmaline powder to obtain composite powder, mixing the composite powder with zirconia ball milling beads and deionized water, putting the mixture into a ball milling tank, wet milling, filtering and separating to obtain filter residue, and drying to obtain mixed powder;
(2) preparation of the dispersion: weighing polyethylene glycol, carboxymethyl cellulose, absolute ethyl alcohol and mixed powder, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment to obtain a dispersion liquid;
(3) preparing porous composite powder: mixing the obtained dispersion liquid and zeolite powder, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, and carrying out heat preservation sintering to obtain porous composite powder;
(4) preparation of reaction solution: mixing a polyvinyl alcohol solution and a 3, 4-dihydroxybenzoic acid solution, then putting the mixture into a reaction kettle, heating, raising the temperature, and stirring for reaction to obtain a reaction solution;
(5) preparing pre-modified composite powder: mixing the obtained reaction liquid and the porous composite powder, putting the mixture into a reaction kettle, stirring for pre-reaction, continuously adding catechol oxidase into the reaction kettle, continuously stirring for reaction, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder;
(6) preparing a modified negative ion releasing agent: mixing soybean phospholipid and acetone to obtain a modified solution, mixing the pre-modified composite powder and the modified solution, placing the mixture on a shaking table, carrying out oscillation reaction, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent;
(7) preparing a material of the cup body capable of releasing negative ions: weighing polypropylene, the modified negative ion releasing agent and peach gum, mixing, then loading into a mixing roll, heating, mixing, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the negative ion releasable cup body material.
4. A releasable negative ion cup material and a preparation method thereof are characterized in that: the preparation method comprises the following specific steps:
(1) preparation of mixed powder: mixing nano magnesium oxide and nano tourmaline powder according to a mass ratio of 1:5 to obtain composite powder, mixing the composite powder, zirconia ball grinding beads and deionized water according to a mass ratio of 1:2:1, putting the mixture into a ball milling tank, carrying out wet milling for 3-5 h, filtering and separating to obtain filter residues, and drying to obtain mixed powder;
(2) preparation of the dispersion: weighing 0.5-1.0 part by weight of polyethylene glycol, 2-3 parts by weight of carboxymethyl cellulose, 50-60 parts by weight of absolute ethyl alcohol and 10-15 parts by weight of the mixed powder, mixing, putting into a high-speed dispersion machine, and performing dispersion treatment at a rotating speed of 2000-3000 r/min for 30-40 min to obtain a dispersion liquid;
(3) preparing porous composite powder: mixing the obtained dispersion liquid and zeolite powder according to a mass ratio of 10:1, putting the mixture into an ultrasonic oscillator, carrying out ultrasonic oscillation treatment for 3-5 h at a frequency of 35-45 kHz, filtering, separating to obtain a filter cake, putting the obtained filter cake into a muffle furnace, carrying out temperature programming to 900-950 ℃ at a temperature rise rate of 10 ℃/min, and carrying out heat preservation sintering for 2-3 h to obtain porous composite powder;
(4) preparation of reaction solution: mixing 20 mass percent of polyvinyl alcohol solution and 30 mass percent of 3, 4-dihydroxybenzoic acid solution according to the mass ratio of 3:1, putting the mixture into a reaction kettle, heating to 70-80 ℃, and stirring at the rotating speed of 200-300 r/min for reaction for 3-5 hours to obtain reaction liquid;
(5) preparing pre-modified composite powder: and (3) mixing the obtained reaction solution and the porous composite powder according to the mass ratio of 8: 1, mixing, putting into a reaction kettle, stirring for pre-reaction for 15-20 min, continuously adding catechol oxidase with the mass of 5% of the reaction liquid into the reaction kettle, continuously stirring for reaction for 3-5 h at 30-40 ℃, filtering after the reaction is finished, and separating to obtain a reaction filter cake, namely the pre-modified composite powder;
(6) preparing a modified negative ion releasing agent: mixing soybean phospholipid and acetone according to the mass ratio of 1:5 to obtain a modified liquid, mixing the pre-modified composite powder and the modified liquid according to the mass ratio of 1:10, placing the mixture on a shaking table, carrying out oscillation reaction for 1-2 h, filtering and separating to obtain reaction filter residues, and drying to obtain a modified negative ion releasing agent;
(7) preparing a material of the cup body capable of releasing negative ions: weighing 50-60 parts of polypropylene, 10-15 parts of the modified anion releasing agent and 5-8 parts of peach gum according to parts by weight, mixing, putting into a mixing roll, heating to 180-200 ℃, mixing for 15-20 min, transferring the mixed material into a double-screw extruder, extruding and granulating, discharging, naturally cooling and drying to obtain the cup body material capable of releasing anions.
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CN115650764A (en) * | 2022-11-16 | 2023-01-31 | 福建师范大学泉港石化研究院 | Low-temperature sintered negative ion porous ceramic and preparation method thereof |
CN116751422A (en) * | 2023-08-16 | 2023-09-15 | 广州海天塑胶有限公司 | Negative ion polypropylene composite polymer material for automobile and preparation method thereof |
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