CN111938137A - Starch gel rich in active polysaccharide and preparation method and application thereof - Google Patents

Starch gel rich in active polysaccharide and preparation method and application thereof Download PDF

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CN111938137A
CN111938137A CN202010800652.9A CN202010800652A CN111938137A CN 111938137 A CN111938137 A CN 111938137A CN 202010800652 A CN202010800652 A CN 202010800652A CN 111938137 A CN111938137 A CN 111938137A
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starch
active polysaccharide
polysaccharide
parts
active
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CN111938137B (en
Inventor
于滨
崔波
陶海腾
赵海波
刘鹏飞
袁超
吴正宗
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Qilu University of Technology
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Qilu University of Technology
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/125Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives containing carbohydrate syrups; containing sugars; containing sugar alcohols; containing starch hydrolysates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/075Macromolecular gels
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2403/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2403/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00

Abstract

The invention belongs to the technical field of health product processing, and particularly relates to starch gel rich in active polysaccharide, and a preparation method and application thereof. The starch gel rich in active polysaccharide comprises the following raw materials in parts by weight: 20-30 parts of starch, 1-3 parts of glucosamine, 10-15 parts of active polysaccharide and 10-15 parts of waxy potato starch. The glucosamine can be added to generate electrostatic interaction with the active polysaccharide, and a glucose coating layer is formed on the surface of the active polysaccharide, so that the starch molecules and the active polysaccharide molecules are prevented from being separated; the method is characterized in that the waxy potato starch paste and the glucosamine-active polysaccharide electrostatic compound are mixed to be tangled, so that the quality of the product is improved. Simple process, easy operation, and is beneficial to industrial production, and diversified products such as vermicelli, sheet jelly or rice flour can be obtained.

Description

Starch gel rich in active polysaccharide and preparation method and application thereof
Technical Field
The invention belongs to the technical field of health product processing, and particularly relates to starch gel rich in active polysaccharide, and a preparation method and application thereof.
Background
Starch is an important energy substance in food and also an important raw material for food processing. After being gelatinized, the starch can form a translucent gel with certain elasticity and strength, and the starch gel is a multidimensional net structure formed by mutually connecting starch molecules, is a special existing form of colloid and has the property between solid and liquid. The starch gel is widely applied to food, for example, the food such as vermicelli, sheet jelly, rice flour and the like are all traditional food produced by utilizing the property of the starch gel, and the food is popular with consumers. However, these products contain only starch, all of which are relatively single in nutritional ingredients and are liable to cause significant increases in blood glucose levels in humans, and thus are not suitable for people with diabetes and the like.
The active polysaccharide is polysaccharide compound with physiological activities of resisting tumor, reducing blood lipid, improving immunity, etc. Active polysaccharides are important raw materials for developing functional foods. The addition of active polysaccharide is an important means for solving the problems of nutrition and functionality of the starch gel product. However, since most of the active polysaccharide molecules have surface charges and phase separation occurs when the active polysaccharide molecules are added into a starch gel system, the addition amount of the polysaccharide is less than 5% because the simple addition of the active polysaccharide affects the texture characteristics of the starch gel product, and thus, the innovative active polysaccharide addition method is the key to solve the problems.
Disclosure of Invention
The invention provides a starch gel rich in active polysaccharide and a preparation method and application thereof in order to make up for the defects of the existing products and technologies.
The invention is realized by the following technical scheme:
the starch gel rich in active polysaccharide comprises the following raw materials in parts by weight: 20-30 parts of starch, 1-3 parts of glucosamine, 10-15 parts of active polysaccharide and 10-15 parts of waxy potato starch.
The starch comprises: mung bean starch, pea starch, potato starch or sweet potato starch.
The active polysaccharide is acidic polysaccharide.
The active polysaccharide is lycium barbarum polysaccharide, lentinan or tea polysaccharide.
The preparation method of the starch gel rich in the active polysaccharide comprises the following steps:
(1) dissolving: mixing glucosamine and active polysaccharide, adding 100 parts of water, controlling the pH value at 6-6.5, and heating at 50 ℃ for 1-2 hours to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing waxy potato starch into 100 parts of water, and heating at 90-95 deg.C for 30-40 min to obtain waxy potato starch paste;
(3) mixing: mixing the glucosamine-active polysaccharide electrostatic compound solution with the waxy potato starch paste according to the ratio of 1:1, and then stirring for 2-3 hours at the temperature of 50-60 ℃ and the speed of 300-500 rpm;
(4) adding: adding starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at the temperature of 90-95 ℃ for 30-40 minutes, and cooling and forming to obtain the starch gel rich in the active polysaccharide.
The starch gel rich in active polysaccharide prepared by the preparation method is applied to preparing vermicelli, sheet jelly or rice flour.
The invention has the beneficial effects that:
(1) in order to reduce the occurrence of phase separation between the active polysaccharide and the starch, the glucosamine is added to enable the glucosamine to generate electrostatic interaction with the active polysaccharide, and a glucose coating layer is formed on the surface of the active polysaccharide, so that the starch molecules and the active polysaccharide molecules are prevented from being separated, and the texture characteristics of the product are improved;
(2) the addition of the glucosamine can not only effectively avoid the separation of starch molecules and active polysaccharide molecules, but also enable the product to have the functions of the glucosamine such as immunoregulation, osteoarthritis treatment, oxidation resistance, aging resistance and the like, and also has the function of synergistic interaction with the active polysaccharide;
(3) in the step (3), the waxy potato starch paste and the glucosamine-active polysaccharide electrostatic compound are mixed, and the glucosamine-active polysaccharide electrostatic compound and the potato amylopectin form molecular entanglement by using proper shearing force under the condition of controlling the rotating speed, so that the quality characteristics of the product are improved.
(4) And (3) controlling the viscosity of the mixed solution in the step (3) to be in a proper range by controlling the concentration and stirring and shearing treatment, so that after the starch is added in the step (4), the starch particles are suspended in the mixed solution, and a firmer network structure can be formed when the mixed solution is heated again.
(5) Simple process, easy operation, and is beneficial to industrial production, and diversified products such as vermicelli, sheet jelly or rice flour can be obtained.
Detailed Description
Example 1
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: mixing 10g of glucosamine and 150g of tea polysaccharide, adding 1000g of water, controlling the pH value to be 6-6.5, and heating at 50 ℃ for 1 hour to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing 100g of waxy potato starch into 1000g of water, and heating at 90-95 ℃ for 30 minutes to obtain a waxy potato starch paste;
(3) mixing: mixing 1100g of glucosamine-active polysaccharide electrostatic compound with 1100g of waxy potato starch paste, and stirring for 3 hours at 50 ℃ and 300 rpm;
(4) adding: adding 200g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 40 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Example 2
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: mixing 30g of glucosamine and 100g of lentinan, adding into 1000g of water, controlling the pH value to be 6-6.5, and heating at 50 ℃ for 2 hours to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing 150g of waxy potato starch into 1000g of water, and heating at 90-95 ℃ for 40 minutes to obtain waxy potato starch paste;
(3) mixing: mixing 1130g of glucosamine-active polysaccharide electrostatic compound with 1130g of waxy potato starch paste, and then stirring for 2 hours at the temperature of 60 ℃ and the speed of 500 rpm;
(4) adding: adding 300g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 30 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Example 3
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: mixing 20 g of glucosamine and 130g of lentinan, adding into 1000g of water, controlling the pH value to be 6-6.5, and heating at 50 ℃ for 1.5 hours to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing 130g of waxy potato starch into 1000g of water, and heating at 90-95 ℃ for 35 minutes to obtain waxy potato starch paste;
(3) mixing: mixing 1130g of glucosamine-active polysaccharide electrostatic compound with 1130g of waxy potato starch paste, and then stirring for 2.5 hours at the temperature of 55 ℃ and the speed of 400 rpm;
(4) adding: adding 250g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 35 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Example 4
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: mixing 30g of glucosamine and 150g of lycium barbarum polysaccharide, adding 1000g of water, controlling the pH value to be 6-6.5, and heating at 50 ℃ for 1.5 hours to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing 150g of waxy potato starch into 1000g of water, and heating at 90-95 ℃ for 35 minutes to obtain waxy potato starch paste;
(3) mixing: mixing 1150g of glucosamine-active polysaccharide electrostatic compound with 1150g of waxy potato starch paste, and then stirring for 2.5 hours at the temperature of 55 ℃ and the speed of 400 rpm;
(4) adding: adding 250g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 35 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Comparative example 1
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: adding 130g lentinan into 1000g water, controlling pH at 6-6.5, heating at 50 deg.C for 1.5 hr to form glucosamine-active polysaccharide electrostatic complex;
(2) pasting: dispersing 130g of waxy potato starch into 1000g of water, and heating at 90-95 ℃ for 35 minutes to obtain waxy potato starch paste;
(3) mixing: mixing 1130g of glucosamine-active polysaccharide electrostatic compound with 1130g of waxy potato starch paste, and then stirring for 2.5 hours at the temperature of 55 ℃ and the speed of 400 rpm;
(4) adding: adding 250g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 35 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Comparative example 2
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: mixing 20 g of glucosamine and 130g of lentinan, adding into 1000g of water, controlling the pH value to be 6-6.5, and heating at 50 ℃ for 1.5 hours to form a glucosamine-active polysaccharide electrostatic compound; then stirring for 2.5 hours at the conditions of 55 ℃ and 400 rpm;
(2) adding: adding 250g of starch into the mixed liquor obtained in the step (1), and fully stirring to suspend the starch in the mixed liquor;
(3) heating: and (3) heating the mixed solution obtained in the step (2) at 90-95 ℃ for 35 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Comparative example 3
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: mixing 20 g of glucosamine and 130g of lentinan, adding into 1000g of water, controlling the pH value to be 6-6.5, and heating at 50 ℃ for 1.5 hours to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing 130g of waxy potato starch into 1000g of water;
(3) mixing: mixing 1130g of glucosamine-active polysaccharide electrostatic compound with 1130g of waxy potato starch, and then stirring for 2.5 hours at the temperature of 55 ℃ and the speed of 400 rpm;
(4) adding: adding 250g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 35 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Comparative example 4
A method for preparing starch gel rich in active polysaccharide comprises the following steps:
(1) dissolving: adding 30g of glucosamine into 1000g of water, controlling the pH value to be 6-6.5, and heating for 1.5 hours at the temperature of 50 ℃ to form a glucosamine-active polysaccharide electrostatic complex;
(2) pasting: dispersing 150g of waxy potato starch into 1000g of water, and heating at 90-95 ℃ for 35 minutes to obtain waxy potato starch paste;
(3) mixing: mixing 1030g of glucosamine-active polysaccharide electrostatic compound with 1030g of waxy potato starch paste, and stirring for 2.5 hours at 55 ℃ and 400 rpm;
(4) adding: adding 250g of starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at 90-95 ℃ for 35 minutes, and cooling and forming to obtain the starch gel rich in active polysaccharide.
Examples of the effects of the invention
The starch gel products prepared in examples 1 to 4 and comparative examples 1 to 4 were analyzed for their properties as shown in Table 1.
TABLE 1 Properties of starch gels of active polysaccharides prepared in examples 1-4 and comparative examples 1-4
Figure DEST_PATH_IMAGE001

Claims (6)

1. The starch gel rich in active polysaccharide is characterized by comprising the following raw materials in parts by weight: 20-30 parts of starch, 1-3 parts of glucosamine, 10-15 parts of active polysaccharide and 10-15 parts of waxy potato starch.
2. The reactive polysaccharide-rich starch gel of claim 1, wherein said starch comprises: mung bean starch, pea starch, potato starch or sweet potato starch.
3. The active polysaccharide-rich starch gel of claim 1, wherein the active polysaccharide is an acidic polysaccharide.
4. The starch gel rich in active polysaccharide of claim 1 or 3, wherein the active polysaccharide is lycium barbarum polysaccharide, lentinan polysaccharide or tea polysaccharide.
5. A process for the preparation of a starch gel enriched in active polysaccharides as claimed in claim 1, characterized in that it comprises the following steps:
(1) dissolving: mixing glucosamine and active polysaccharide, adding 100 parts of water, controlling the pH value at 6-6.5, and heating at 50 ℃ for 1-2 hours to form a glucosamine-active polysaccharide electrostatic compound;
(2) pasting: dispersing waxy potato starch into 100 parts of water, and heating at 90-95 deg.C for 30-40 min to obtain waxy potato starch paste;
(3) mixing: mixing the glucosamine-active polysaccharide electrostatic compound solution with the waxy potato starch paste according to the ratio of 1:1, and then stirring for 2-3 hours at the temperature of 50-60 ℃ and the speed of 300-500 rpm;
(4) adding: adding starch into the mixed solution obtained after mixing in the step (3), and fully stirring to suspend the starch in the mixed solution;
(5) heating: and (4) heating the mixed solution obtained in the step (4) at the temperature of 90-95 ℃ for 30-40 minutes, and cooling and forming to obtain the starch gel rich in the active polysaccharide.
6. Use of the starch gel rich in active polysaccharides prepared by the process of claim 5 for the preparation of a therapeutic vermicelli, bean vermicelli, sheet jelly or rice flour.
CN202010800652.9A 2020-08-11 2020-08-11 Starch gel rich in active polysaccharide and preparation method and application thereof Active CN111938137B (en)

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Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101433302A (en) * 2008-12-17 2009-05-20 合肥工业大学 Vermicelli or bean vermicelli produced from non-alum arrow root/potato powder and method of processing the same
CN102960655A (en) * 2012-11-20 2013-03-13 成冠辉 Cooking-resistant vanadium-free vermicelli and preparation technology thereof
CN108201119A (en) * 2016-12-19 2018-06-26 吉林农业大学 A kind of composite modified edible starch film of functional polysaccharide matter

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101433302A (en) * 2008-12-17 2009-05-20 合肥工业大学 Vermicelli or bean vermicelli produced from non-alum arrow root/potato powder and method of processing the same
CN102960655A (en) * 2012-11-20 2013-03-13 成冠辉 Cooking-resistant vanadium-free vermicelli and preparation technology thereof
CN108201119A (en) * 2016-12-19 2018-06-26 吉林农业大学 A kind of composite modified edible starch film of functional polysaccharide matter

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* Cited by examiner, † Cited by third party
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