CN111925693A - Oil-resistant isolation primer, preparation method, application method and construction method thereof, and obtained colorful exposed composite waterproof coating layer - Google Patents

Oil-resistant isolation primer, preparation method, application method and construction method thereof, and obtained colorful exposed composite waterproof coating layer Download PDF

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CN111925693A
CN111925693A CN202010743850.6A CN202010743850A CN111925693A CN 111925693 A CN111925693 A CN 111925693A CN 202010743850 A CN202010743850 A CN 202010743850A CN 111925693 A CN111925693 A CN 111925693A
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oil
agent
resistant
primer
layer
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严从立
王荣博
辛海洋
于绪童
袁强
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Shandong North Chuangxin Waterproof Technology Group Co Ltd
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Shandong North Chuangxin Waterproof Technology Group Co Ltd
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    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D31/00Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
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    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
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    • E04BUILDING
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Abstract

The invention discloses an oil-resistant isolation primer, a preparation method, a use method and a construction method thereof, and an obtained colorful exposed composite waterproof coating layer. The oil-resistant isolation primer disclosed by the invention comprises the following components in parts by weight: 50-90 parts of high polymer latex, 1-10 parts of zinc oxide, 5-20 parts of filler, 1-12 parts of reinforcing auxiliary agent, 0.05-0.25 part of anti-settling agent, 0.1-0.75 part of dispersing agent, 0.01-0.25 part of wetting agent, 0.3-0.5 part of defoaming agent, 0.25-1.5 parts of antioxidant, 0.25-1.0 part of light stabilizer, 0.1-0.2 part of mildew-proof auxiliary agent, 0-0.2 part of pH value regulator, 0.1-0.3 part of thickening agent and 3-25 parts of deionized water; wherein the solid content of the polymer latex is 45-65%. The isolation primer disclosed by the invention can effectively prevent the oil component from returning upwards, and the color change time of the color elastic finish paint is prolonged.

Description

Oil-resistant isolation primer, preparation method, application method and construction method thereof, and obtained colorful exposed composite waterproof coating layer
Technical Field
The invention belongs to the technical field of environment-friendly materials, and particularly relates to an oil-resistant isolation primer, a preparation method, a use method and a construction method thereof, and an obtained colorful exposed composite waterproof coating layer.
Background
For areas cold in winter and hot in summer, the sprayed rapid-hardening rubber asphalt waterproof coating and the colored exposed elastic finish paint are used for preventing water on exposed occasions in a composite manner, and the waterproof paint is attractive, has good waterproof performance and also has high and low temperature resistance. However, at high temperature, oil in the asphalt component of the sprayed rapid-hardening rubber asphalt waterproof coating can be separated out and return to the surface layer, so that the surface layer is discolored, and the application of the sprayed rapid-hardening rubber asphalt waterproof material is limited. Research shows that the higher the temperature is, the more violent the molecular motion is, the shorter the time for the oil to analyze and penetrate through the color surface layer is, and the color change time of the surface layer is 20-45 days when the temperature is hotter in summer; in winter, the temperature is low, the molecular motion is slow, and the surface layer basically has no color change problem. In order to solve the problem that the color of a color surface layer is changed due to the fact that oil content returns upwards to penetrate through the color surface layer, the invention discloses an oil-resistant isolation primer.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides an oil-resistant isolation primer, a preparation method, a use method and a construction method thereof, and an obtained colorful exposed composite waterproof coating layer.
The technical scheme of the invention is as follows:
an oil-resistant isolation primer comprises the following components in parts by weight: 50-90 parts of high polymer latex, 1-10 parts of zinc oxide, 5-20 parts of filler, 1-12 parts of reinforcing auxiliary agent, 0.05-0.25 part of anti-settling agent, 0.10-0.75 part of dispersing agent, 0.01-0.25 part of wetting agent, 0.3-0.5 part of defoaming agent, 0.25-1.5 parts of antioxidant, 0.25-1.0 part of light stabilizer, 0.1-0.2 part of mildew-proof auxiliary agent, 0.1-0.2 part of pH value regulator, 0.1-0.3 part of thickening agent and 3-25 parts of deionized water; wherein the solid content of the polymer latex is 45-65%.
Preferably, the polymer latex comprises one or two of anionic neoprene latex, anionic butyronitrile latex and anionic carboxyl anionic butyronitrile latex. The polymer latex has good oil resistance, high elasticity and glass transition temperature lower than-25 ℃.
Preferably, the zinc oxide is coating-grade zinc oxide, the content of the zinc oxide is more than 99%, and the particle size of the zinc oxide is 2-45 micrometers;
preferably, the filler is a filler with a plate-shaped structure, and the particle size of the filler ranges from 600 meshes to 3000 meshes.
Preferably, the filler comprises one or two of talc powder, mica powder and graphene.
Preferably, the reinforcing aid comprises fumed silica, precipitated silica, or nanosilica colloids.
Preferably, the anti-settling agent is an inorganic anti-settling agent and comprises attapulgite and bentonite, wherein the bentonite comprises sodium bentonite and calcium bentonite, and the sodium bentonite is preferred. The sodium bentonite adopted in the application has the advantages of large expansion times and good anti-settling effect.
Preferably, the dispersant is an anionic dispersant, including a sodium salt dispersant and an ammonium salt dispersant, wherein the ammonium salt dispersant is preferred. The ammonium salt dispersant has good water resistance.
Preferably, the wetting agent is alkylphenol polyoxyethylene ether wetting agent.
Preferably, the defoaming agent is a silicone-based defoaming agent.
Preferably, the antioxidant is a hindered phenol antioxidant, and comprises one or two of an antioxidant 1010, an antioxidant 1076 and an antioxidant 1078.
Preferably, the light stabilizer is an ultraviolet absorber, and the ultraviolet absorber is UV-292 or UV-1130.
Preferably, the mildew-proof auxiliary agent is one of 2-n-octyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone (MIT) or 5-chloro-2-methyl-4-isothiazoline-3-ketone (CIT).
Preferably, the PH adjuster comprises one or more of sodium hydroxide, potassium hydroxide, ethanolamines, and 2-amino-2-methyl-1-propanol.
Preferably, the thickener is an alkali swelling thickener or an acrylic thickener.
The preparation method of the oil-resistant release primer comprises the following steps:
step 1): adding the dispersant, the wetting agent, the defoaming agent, the anti-settling agent, the reinforcing aid, the zinc oxide, the filler, the antioxidant, the light stabilizer and the mildew-proof aid into deionized water in percentage by mass, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the sizing agent, the pH regulator, the defoaming agent and the thickening agent into the polymer latex, and uniformly dispersing to obtain the oil-resistant isolation primer.
Preferably, in step 1), the addition amount of the defoaming agent is 2/3 of the total defoaming agent addition amount, and in step 2), the addition amount of the defoaming agent is 1/3 of the total defoaming agent addition amount.
A construction method for obtaining a barrier type colorful exposed composite waterproof coating layer by using an oil-resistant type isolation primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface, alternately atomizing the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, maintaining and airing to obtain a waterproof layer;
step 2): spraying an oil-resistant isolation primer on the waterproof layer, maintaining and airing to obtain an oil-resistant isolation primer layer;
step 3): and spraying the colorful exposed elastic finish paint on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, and bonding the three layers into a whole to form the isolating colorful exposed composite waterproof coating layer.
A barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
The invention has the beneficial effects that:
the invention discloses an oil-resistant isolation primer which is simple to prepare and can effectively block oil content in a bottom layer and delay the discoloration of a surface layer. Tests show that when a common isolation primer is adopted but the oil-proof isolation primer is not adopted, the color change time of the finish is shorter than 1 month in hotter summer, and after the oil-proof isolation primer is added, the color of the finish is not changed for 1-2 years. The oil-resistant isolation primer disclosed by the invention is prepared from rubber latex with good oil resistance, physical crosslinking is formed by adding a reinforcing auxiliary agent to improve the cohesive strength so as to improve the oil resistance, chemical crosslinking is formed by adding zinc oxide to further improve the cohesive strength so as to improve the oil resistance, and in addition, a flaky filler is matched to prolong an oil permeation path so as to further improve the oil barrier property. The rubber latex selected by the invention is oil-resistant rubber latex which has good oil resistance, is often used in oil-resistant products such as oil-resistant butyronitrile gloves, oil-resistant chloroprene gloves and the like, and can better isolate oil content and delay the time of color change of finish paint when being used as oil-resistant isolation primer; the oil resistance of the acrylate latex, the styrene-acrylic latex and the styrene-butadiene latex used in the conventional paint is inferior to that of the anionic neoprene latex and the anionic butyronitrile latex, and when the paint is used as an oil-resistant primer, the oil-barrier effect is poor, and the color change phenomenon of the finish paint occurs in a short time.
The oil-resistant isolation primer disclosed by the invention has the following advantages:
❶ has good low temperature resistance, no fracture and no crack at-25 deg.C;
❷ elongation at break is more than or equal to 500%, which ensures synchronous expansion with heat and contraction with cold of spraying rapid-setting rubber asphalt waterproof layer and color elastic surface layer, and no crack is generated even in severe cold and hot weather;
❸, the adhesion between layers is firm, the rubber latex selected by the oil-proof isolation priming paint is polar rubber latex, the latex in the spraying quick-setting rubber asphalt waterproof paint is anionic neoprene latex generally, the latex in the finishing paint is acrylate latex generally, which are both polar latex, the compatibility of the oil-proof isolation priming paint with the spraying quick-setting rubber asphalt waterproof paint and the colorful acrylate finishing paint is good, and the adhesion performance is good.
In addition, the oil-resistant isolation primer disclosed by the invention is simple in preparation process and is the same as a common waterproof coating; the construction process of the oil-resistant isolation primer is simple, the construction process of the oil-resistant isolation primer is the same as that of a common water-based paint, the oil-resistant isolation primer can be directly sprayed, the operation difficulty of construction workers is not increased, and the construction is simple and rapid.
Drawings
FIG. 1 is a schematic structural diagram of a barrier type color exposed composite waterproof coating layer according to the present invention.
In the figure: 1. a waterproof layer, 2, an oil-resistant isolation primer layer, 3 and a colorful exposed elastic finish.
Detailed Description
The first embodiment is as follows:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 70Kg of anion neoprene latex with solid content of 58 percent, 5Kg of zinc oxide, 10Kg of talcum powder, 5Kg of gas-phase silicon dioxide, 0.15Kg of sodium bentonite, 0.3Kg of ammonium salt dispersant, 0.1Kg of alkylphenol polyoxyethylene ether wetting agent, 0.4Kg of organosilicon antifoaming agent, 10100.5 Kg of antioxidant, 0.1Kg of UV-2920.5 Kg of 2-n-octyl-4-isothiazoline-3 ketone, 0.1Kg of 2-amino-2 methyl-1-propanol, 0.1Kg of alkali swelling thickener and 10Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding the ammonium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 organosilicon defoamer, sodium bentonite, fumed silica, zinc oxide, talcum powder, an antioxidant 1010, UV-292 and 2-n-octyl-4-isothiazoline-3 ketone into deionized water, and grinding at a high speed until the components are uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, 2-amino-2 methyl-1-propanol, 1/3 organic silicon defoaming agent and alkali swelling thickener into the anionic neoprene latex, and dispersing uniformly to obtain the oil-resistant type isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 1.5 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.5mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.3 mm;
step 3): spraying a colorful exposed elastic finish paint with the thickness of 0.5mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.3mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer, as shown in figure 1.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
In the application, a colored exposed composite waterproof coating layer obtained by directly compounding the sprayed quick-setting rubber asphalt waterproof coating and the colored exposed elastic finish paint is used as a comparative example.
Tests show that the color-exposed composite waterproof coating layer obtained by directly compounding the sprayed quick-setting rubber asphalt waterproof coating and the color-exposed elastic finish paint has the surface color change time of 20-45 days.
In the first embodiment, the oil-resistant isolation primer is used to obtain the blocking type color exposed composite waterproof coating layer, and the color change time of the surface layer is 14 months.
Example two:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 80 Kg of anion neoprene latex with solid content of 50 percent, 4Kg of zinc oxide, 5Kg of talcum powder, 4Kg of nano silicon dioxide colloid, 0.15Kg of sodium bentonite, 0.3Kg of ammonium salt dispersant, 0.1Kg of alkylphenol polyoxyethylene ether wetting agent, 0.4Kg of organosilicon defoamer, 10100.5 Kg of antioxidant, UV-2920.5 Kg, 0.1Kg of 2-n-octyl-4-isothiazoline-3 ketone, 0.1Kg of 2-amino-2 methyl-1-propanol, 0.1Kg of alkali swelling thickener and 8Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding the ammonium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 organosilicon defoamer, sodium bentonite, zinc oxide, nano silica colloid, talcum powder, an antioxidant 1010, UV-292 and 2-n-octyl-4-isothiazoline-3 ketone into deionized water, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, 2-amino-2 methyl-1-propanol, 1/3 organic silicon defoaming agent and alkali swelling thickener into the anionic neoprene latex, and dispersing uniformly to obtain the oil-resistant type isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3.3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.0 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.7mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.4 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.7mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.4mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
As can be seen from the test, in the second embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 18 months.
Example three:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 60 Kg of anion neoprene latex with solid content of 50 percent, 5Kg of zinc oxide, 5Kg of talcum powder, 5Kg of graphene, 5Kg of precipitated silica, 0.15Kg of sodium bentonite, 0.45Kg of ammonium salt dispersant, 0.15Kg of alkylphenol polyoxyethylene ether wetting agent, 0.5Kg of organosilicon antifoaming agent, 10760.5 Kg of antioxidant, 0.15Kg of UV-2920.5 Kg, 0.15Kg of 2-methyl-4-isothiazoline-3 ketone (MIT), 0.15Kg of 2-amino-2 methyl-1-propanol, 0.1Kg of alkali swelling thickener and 20Kg of deionized water.
2. Preparation method
Step 1): adding the ammonium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 silicone defoamer, sodium bentonite, precipitated silica, zinc oxide, talcum powder, graphene, an antioxidant 1076, UV-292 and 2-methyl-4-isothiazoline-3-ketone (MIT) into deionized water, and grinding at high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, 2-amino-2 methyl-1-propanol, 1/3 organic silicon defoaming agent and alkali swelling thickener into the anionic neoprene latex, and dispersing uniformly to obtain the oil-resistant type isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3.3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.0 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.7mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.4 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.7mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.4mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
Tests show that in the third embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 20 months.
Example four:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 80 Kg of anionic butyronitrile latex with solid content of 45 percent, 3Kg of zinc oxide, 3Kg of talcum powder, 5Kg of mica powder, 3Kg of nano silica colloid, 0.06Kg of sodium bentonite, 0.10Kg of sodium salt dispersant, 0.05Kg of alkylphenol polyoxyethylene ether wetting agent, 0.35Kg of organosilicon defoamer, 10760.8 Kg of antioxidant, 0.15Kg of UV-11300.8 Kg, 0.15Kg of 2-methyl-4-isothiazoline-3 ketone (MIT), 0.15Kg of dimethylethanolamine, 0.1Kg of acrylic thickener and 6Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding the sodium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 organic silicon defoamer, sodium bentonite, nano silica colloid, zinc oxide, talcum powder, mica powder, an antioxidant 1076, UV-1130 and 2-methyl-4-isothiazoline-3-ketone (MIT) into deionized water, and grinding at high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, dimethylethanolamine, 1/3 organosilicon antifoaming agent and acrylic thickener into the anionic butyronitrile latex, and uniformly dispersing to obtain the oil-resistant isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3.3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.0 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.7mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.4 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.7mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.4mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
Tests show that in the fourth embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 12 months.
Example five:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 70Kg of carboxyl anion butyronitrile latex with solid content of 45 percent, 3Kg of zinc oxide, 7Kg of talcum powder, 8Kg of mica powder, 2Kg of nano silica colloid, 0.20Kg of sodium bentonite, 0.6Kg of ammonium salt dispersant, 0.2Kg of alkylphenol polyoxyethylene ether wetting agent, 0.3Kg of organosilicon defoamer, 10780.5 Kg of antioxidant, UV-11300.5 Kg, 0.15Kg of 5-chloro-2-methyl 4-isothiazoline-3 ketone (CIT), 0.15Kg of sodium hydroxide, 0.1Kg of acrylic thickener and 20Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding an ammonium salt dispersant, an alkylphenol polyoxyethylene ether wetting agent, 2/3 organosilicon defoamer, nano silica colloid, sodium bentonite, zinc oxide, talcum powder, mica powder, an antioxidant 1078, UV-1130 and 5-chloro-2-methyl 4-isothiazoline-3-ketone into deionized water, and grinding at high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, adding the slurry, sodium hydroxide, 1/3 organosilicon defoaming agent and acrylic acid thickening agent into the anionic carboxyl butyronitrile latex in sequence, and dispersing uniformly to obtain the oil-resistant isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 4.2mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.4 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.8mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.5 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.8mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.5mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
As shown in the test, in the fifth embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 18 months.
Example six:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 75Kg of anionic butyronitrile latex with solid content of 45 percent, 5Kg of zinc oxide, 5Kg of graphene, 5Kg of fumed silica, 0.25Kg of calcium bentonite, 0.4Kg of ammonium salt dispersant, 0.15Kg of alkylphenol polyoxyethylene ether wetting agent, 0.3Kg of organosilicon defoamer, 10780.4 Kg of antioxidant, UV-11300.5 Kg, 0.15Kg of 5-chloro-2-methyl 4-isothiazoline-3-ketone (CIT), 0.15Kg of potassium hydroxide, 0.1Kg of acrylic thickener and 10Kg of deionized water.
2. Preparation method
Step 1): adding an ammonium salt dispersant, an alkylphenol polyoxyethylene ether wetting agent, 2/3 organosilicon defoamer, calcium bentonite, fumed silica, zinc oxide, graphene, an antioxidant 1078, UV-1130 and 5-chloro-2-methyl 4-isothiazoline-3-one (CIT) into deionized water, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, adding the slurry, potassium hydroxide, 1/3 organosilicon defoaming agent and acrylic acid thickening agent into the anionic butyronitrile latex in sequence, and dispersing uniformly to obtain the oil-resistant isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 4.2mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.4 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.8mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.5 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.8mm on the oil-resistant isolation primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.5mm, and the three layers are bonded into a whole to form the isolation type colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
Tests show that the oil-resistant isolation primer is utilized to obtain the barrier type colorful exposed composite waterproof coating layer, and the surface layer discoloration time is 2 years.
The rapid hardening rubber asphalt waterproof coating adopted in the first to sixth embodiments of the application is the spraying rapid hardening rubber asphalt waterproof coating disclosed in CN201210301863.3, and the spraying rapid hardening rubber asphalt waterproof coating is the prior art and is not described herein again.

Claims (10)

1. An oil-resistant isolation primer is characterized in that: the paint comprises the following components in parts by weight: 50-90 parts of high polymer latex, 1-10 parts of zinc oxide, 5-20 parts of filler, 1-12 parts of reinforcing auxiliary agent, 0.05-0.25 part of anti-settling agent, 0.10-0.75 part of dispersing agent, 0.01-0.25 part of wetting agent, 0.3-0.5 part of defoaming agent, 0.25-1.5 parts of antioxidant, 0.25-1.0 part of light stabilizer, 0.1-0.2 part of mildew-proof auxiliary agent, 0.1-0.2 part of pH value regulator, 0.1-0.3 part of thickening agent and 3-25 parts of deionized water; wherein the solid content of the polymer latex is 45-65%.
2. The oil resistant release primer according to claim 1, characterized in that: the polymer latex comprises one or two of anionic neoprene latex, anionic butyronitrile latex and anionic carboxyl anionic butyronitrile latex.
3. The oil resistant release primer according to claim 1, characterized in that: the zinc oxide is coating-grade zinc oxide, the content of the zinc oxide is more than 99%, and the particle size of the zinc oxide is 2-45 micrometers.
4. The oil resistant release primer according to claim 1, characterized in that: the filler is of a platy structure, and the particle size range of the filler is 600-3000 meshes.
5. The oil resistant release primer according to claim 1, characterized in that: the filler comprises one or two of talcum powder, mica powder and graphene.
6. The oil resistant release primer according to claim 1, characterized in that: the reinforcing auxiliary agent comprises fumed silica, precipitated silica or nano silica colloid.
7. A preparation method of the oil-resistant isolation primer is characterized by comprising the following steps: the method comprises the following steps:
step 1): adding the dispersant, the wetting agent, the defoaming agent, the anti-settling agent, the reinforcing aid, the zinc oxide, the filler, the antioxidant, the light stabilizer and the mildew-proof aid into deionized water in percentage by mass, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the sizing agent, the pH regulator, the defoaming agent and the thickening agent into the polymer latex, and uniformly dispersing to obtain the oil-resistant isolation primer.
8. The method for producing an oil resistant primer sealer according to claim 7, wherein: in the step 1), the addition amount of the defoaming agent is 2/3 of the total defoaming agent addition amount, and in the step 2), the addition amount of the defoaming agent is 1/3 of the total defoaming agent addition amount.
9. A construction method for obtaining a barrier type colorful exposed composite waterproof coating layer by using an oil-resistant type isolation primer is characterized by comprising the following steps: the method comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface, alternately atomizing the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, maintaining and airing to obtain a waterproof layer;
step 2): spraying an oil-resistant isolation primer on the waterproof layer, maintaining and airing to obtain an oil-resistant isolation primer layer;
step 3): and spraying the colorful exposed elastic finish paint on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, and bonding the three layers into a whole to form the isolating colorful exposed composite waterproof film layer.
10. A barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
CN202010743850.6A 2020-07-29 2020-07-29 Oil-resistant isolation primer, preparation method, application method and construction method thereof, and obtained colorful exposed composite waterproof coating layer Pending CN111925693A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101113260A (en) * 2006-07-28 2008-01-30 中宏(天津)实业有限公司 Production technique of single-component precipitation-proof aqueous waterproofing paint
CN102964929A (en) * 2012-11-30 2013-03-13 山东北方创信防水技术有限公司 Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond
CN108636741A (en) * 2018-04-11 2018-10-12 桂林市金谷新材料有限公司 The preparation method of nitrile rubber composite metal plate
CN110408274A (en) * 2019-08-23 2019-11-05 山东北方创信防水科技股份有限公司 A kind of single-component water-based rubber asphalt quick-drying water-repellent paint
CN110484074A (en) * 2019-07-19 2019-11-22 山东北方创信防水科技股份有限公司 A method of spraying rapid hardening coloured polymer coating and its formation composite water-proof film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101113260A (en) * 2006-07-28 2008-01-30 中宏(天津)实业有限公司 Production technique of single-component precipitation-proof aqueous waterproofing paint
CN102964929A (en) * 2012-11-30 2013-03-13 山东北方创信防水技术有限公司 Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond
CN108636741A (en) * 2018-04-11 2018-10-12 桂林市金谷新材料有限公司 The preparation method of nitrile rubber composite metal plate
CN110484074A (en) * 2019-07-19 2019-11-22 山东北方创信防水科技股份有限公司 A method of spraying rapid hardening coloured polymer coating and its formation composite water-proof film
CN110408274A (en) * 2019-08-23 2019-11-05 山东北方创信防水科技股份有限公司 A kind of single-component water-based rubber asphalt quick-drying water-repellent paint

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