CN111925693A - Oil-resistant isolation primer, preparation method, application method and construction method thereof, and obtained colorful exposed composite waterproof coating layer - Google Patents
Oil-resistant isolation primer, preparation method, application method and construction method thereof, and obtained colorful exposed composite waterproof coating layer Download PDFInfo
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- CN111925693A CN111925693A CN202010743850.6A CN202010743850A CN111925693A CN 111925693 A CN111925693 A CN 111925693A CN 202010743850 A CN202010743850 A CN 202010743850A CN 111925693 A CN111925693 A CN 111925693A
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- 238000002955 isolation Methods 0.000 title claims abstract description 81
- 239000002131 composite material Substances 0.000 title claims abstract description 39
- 239000011247 coating layer Substances 0.000 title claims abstract description 31
- 238000010276 construction Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000003921 oil Substances 0.000 claims abstract description 112
- 239000003973 paint Substances 0.000 claims abstract description 61
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229920000126 latex Polymers 0.000 claims abstract description 44
- 239000004816 latex Substances 0.000 claims abstract description 39
- 239000011787 zinc oxide Substances 0.000 claims abstract description 26
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 25
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000002562 thickening agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000080 wetting agent Substances 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 9
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 8
- 239000004611 light stabiliser Substances 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 claims description 84
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 238000005507 spraying Methods 0.000 claims description 29
- 239000010426 asphalt Substances 0.000 claims description 28
- 229920001971 elastomer Polymers 0.000 claims description 27
- 239000005060 rubber Substances 0.000 claims description 27
- 125000000129 anionic group Chemical group 0.000 claims description 20
- 230000004888 barrier function Effects 0.000 claims description 17
- 239000000701 coagulant Substances 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 12
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 10
- 239000000084 colloidal system Substances 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910021389 graphene Inorganic materials 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910021485 fumed silica Inorganic materials 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 238000004513 sizing Methods 0.000 claims description 2
- 241000276425 Xiphophorus maculatus Species 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000008859 change Effects 0.000 abstract description 8
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 description 15
- 150000003863 ammonium salts Chemical class 0.000 description 13
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 description 13
- 229910000280 sodium bentonite Inorganic materials 0.000 description 13
- 229940080314 sodium bentonite Drugs 0.000 description 13
- 239000013530 defoamer Substances 0.000 description 10
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 239000003513 alkali Substances 0.000 description 7
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 230000008961 swelling Effects 0.000 description 7
- 238000000889 atomisation Methods 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 6
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- YHEPZZFDBQOSSN-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate;1-o-methyl 10-o-(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical group COC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1.C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 YHEPZZFDBQOSSN-UHFFFAOYSA-N 0.000 description 4
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 229910000281 calcium bentonite Inorganic materials 0.000 description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- 229940092782 bentonite Drugs 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- XNINAOUGJUYOQX-UHFFFAOYSA-N 2-cyanobutanoic acid Chemical compound CCC(C#N)C(O)=O XNINAOUGJUYOQX-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Images
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-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D111/00—Coating compositions based on homopolymers or copolymers of chloroprene
- C09D111/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/02—Copolymers with acrylonitrile
- C09D109/04—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D113/00—Coating compositions based on rubbers containing carboxyl groups
- C09D113/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/02—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against ground humidity or ground water
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/66—Sealings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
- E04D13/16—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Paints Or Removers (AREA)
Abstract
The invention discloses an oil-resistant isolation primer, a preparation method, a use method and a construction method thereof, and an obtained colorful exposed composite waterproof coating layer. The oil-resistant isolation primer disclosed by the invention comprises the following components in parts by weight: 50-90 parts of high polymer latex, 1-10 parts of zinc oxide, 5-20 parts of filler, 1-12 parts of reinforcing auxiliary agent, 0.05-0.25 part of anti-settling agent, 0.1-0.75 part of dispersing agent, 0.01-0.25 part of wetting agent, 0.3-0.5 part of defoaming agent, 0.25-1.5 parts of antioxidant, 0.25-1.0 part of light stabilizer, 0.1-0.2 part of mildew-proof auxiliary agent, 0-0.2 part of pH value regulator, 0.1-0.3 part of thickening agent and 3-25 parts of deionized water; wherein the solid content of the polymer latex is 45-65%. The isolation primer disclosed by the invention can effectively prevent the oil component from returning upwards, and the color change time of the color elastic finish paint is prolonged.
Description
Technical Field
The invention belongs to the technical field of environment-friendly materials, and particularly relates to an oil-resistant isolation primer, a preparation method, a use method and a construction method thereof, and an obtained colorful exposed composite waterproof coating layer.
Background
For areas cold in winter and hot in summer, the sprayed rapid-hardening rubber asphalt waterproof coating and the colored exposed elastic finish paint are used for preventing water on exposed occasions in a composite manner, and the waterproof paint is attractive, has good waterproof performance and also has high and low temperature resistance. However, at high temperature, oil in the asphalt component of the sprayed rapid-hardening rubber asphalt waterproof coating can be separated out and return to the surface layer, so that the surface layer is discolored, and the application of the sprayed rapid-hardening rubber asphalt waterproof material is limited. Research shows that the higher the temperature is, the more violent the molecular motion is, the shorter the time for the oil to analyze and penetrate through the color surface layer is, and the color change time of the surface layer is 20-45 days when the temperature is hotter in summer; in winter, the temperature is low, the molecular motion is slow, and the surface layer basically has no color change problem. In order to solve the problem that the color of a color surface layer is changed due to the fact that oil content returns upwards to penetrate through the color surface layer, the invention discloses an oil-resistant isolation primer.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides an oil-resistant isolation primer, a preparation method, a use method and a construction method thereof, and an obtained colorful exposed composite waterproof coating layer.
The technical scheme of the invention is as follows:
an oil-resistant isolation primer comprises the following components in parts by weight: 50-90 parts of high polymer latex, 1-10 parts of zinc oxide, 5-20 parts of filler, 1-12 parts of reinforcing auxiliary agent, 0.05-0.25 part of anti-settling agent, 0.10-0.75 part of dispersing agent, 0.01-0.25 part of wetting agent, 0.3-0.5 part of defoaming agent, 0.25-1.5 parts of antioxidant, 0.25-1.0 part of light stabilizer, 0.1-0.2 part of mildew-proof auxiliary agent, 0.1-0.2 part of pH value regulator, 0.1-0.3 part of thickening agent and 3-25 parts of deionized water; wherein the solid content of the polymer latex is 45-65%.
Preferably, the polymer latex comprises one or two of anionic neoprene latex, anionic butyronitrile latex and anionic carboxyl anionic butyronitrile latex. The polymer latex has good oil resistance, high elasticity and glass transition temperature lower than-25 ℃.
Preferably, the zinc oxide is coating-grade zinc oxide, the content of the zinc oxide is more than 99%, and the particle size of the zinc oxide is 2-45 micrometers;
preferably, the filler is a filler with a plate-shaped structure, and the particle size of the filler ranges from 600 meshes to 3000 meshes.
Preferably, the filler comprises one or two of talc powder, mica powder and graphene.
Preferably, the reinforcing aid comprises fumed silica, precipitated silica, or nanosilica colloids.
Preferably, the anti-settling agent is an inorganic anti-settling agent and comprises attapulgite and bentonite, wherein the bentonite comprises sodium bentonite and calcium bentonite, and the sodium bentonite is preferred. The sodium bentonite adopted in the application has the advantages of large expansion times and good anti-settling effect.
Preferably, the dispersant is an anionic dispersant, including a sodium salt dispersant and an ammonium salt dispersant, wherein the ammonium salt dispersant is preferred. The ammonium salt dispersant has good water resistance.
Preferably, the wetting agent is alkylphenol polyoxyethylene ether wetting agent.
Preferably, the defoaming agent is a silicone-based defoaming agent.
Preferably, the antioxidant is a hindered phenol antioxidant, and comprises one or two of an antioxidant 1010, an antioxidant 1076 and an antioxidant 1078.
Preferably, the light stabilizer is an ultraviolet absorber, and the ultraviolet absorber is UV-292 or UV-1130.
Preferably, the mildew-proof auxiliary agent is one of 2-n-octyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone (MIT) or 5-chloro-2-methyl-4-isothiazoline-3-ketone (CIT).
Preferably, the PH adjuster comprises one or more of sodium hydroxide, potassium hydroxide, ethanolamines, and 2-amino-2-methyl-1-propanol.
Preferably, the thickener is an alkali swelling thickener or an acrylic thickener.
The preparation method of the oil-resistant release primer comprises the following steps:
step 1): adding the dispersant, the wetting agent, the defoaming agent, the anti-settling agent, the reinforcing aid, the zinc oxide, the filler, the antioxidant, the light stabilizer and the mildew-proof aid into deionized water in percentage by mass, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the sizing agent, the pH regulator, the defoaming agent and the thickening agent into the polymer latex, and uniformly dispersing to obtain the oil-resistant isolation primer.
Preferably, in step 1), the addition amount of the defoaming agent is 2/3 of the total defoaming agent addition amount, and in step 2), the addition amount of the defoaming agent is 1/3 of the total defoaming agent addition amount.
A construction method for obtaining a barrier type colorful exposed composite waterproof coating layer by using an oil-resistant type isolation primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface, alternately atomizing the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, maintaining and airing to obtain a waterproof layer;
step 2): spraying an oil-resistant isolation primer on the waterproof layer, maintaining and airing to obtain an oil-resistant isolation primer layer;
step 3): and spraying the colorful exposed elastic finish paint on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, and bonding the three layers into a whole to form the isolating colorful exposed composite waterproof coating layer.
A barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
The invention has the beneficial effects that:
the invention discloses an oil-resistant isolation primer which is simple to prepare and can effectively block oil content in a bottom layer and delay the discoloration of a surface layer. Tests show that when a common isolation primer is adopted but the oil-proof isolation primer is not adopted, the color change time of the finish is shorter than 1 month in hotter summer, and after the oil-proof isolation primer is added, the color of the finish is not changed for 1-2 years. The oil-resistant isolation primer disclosed by the invention is prepared from rubber latex with good oil resistance, physical crosslinking is formed by adding a reinforcing auxiliary agent to improve the cohesive strength so as to improve the oil resistance, chemical crosslinking is formed by adding zinc oxide to further improve the cohesive strength so as to improve the oil resistance, and in addition, a flaky filler is matched to prolong an oil permeation path so as to further improve the oil barrier property. The rubber latex selected by the invention is oil-resistant rubber latex which has good oil resistance, is often used in oil-resistant products such as oil-resistant butyronitrile gloves, oil-resistant chloroprene gloves and the like, and can better isolate oil content and delay the time of color change of finish paint when being used as oil-resistant isolation primer; the oil resistance of the acrylate latex, the styrene-acrylic latex and the styrene-butadiene latex used in the conventional paint is inferior to that of the anionic neoprene latex and the anionic butyronitrile latex, and when the paint is used as an oil-resistant primer, the oil-barrier effect is poor, and the color change phenomenon of the finish paint occurs in a short time.
The oil-resistant isolation primer disclosed by the invention has the following advantages:
❶ has good low temperature resistance, no fracture and no crack at-25 deg.C;
❷ elongation at break is more than or equal to 500%, which ensures synchronous expansion with heat and contraction with cold of spraying rapid-setting rubber asphalt waterproof layer and color elastic surface layer, and no crack is generated even in severe cold and hot weather;
❸, the adhesion between layers is firm, the rubber latex selected by the oil-proof isolation priming paint is polar rubber latex, the latex in the spraying quick-setting rubber asphalt waterproof paint is anionic neoprene latex generally, the latex in the finishing paint is acrylate latex generally, which are both polar latex, the compatibility of the oil-proof isolation priming paint with the spraying quick-setting rubber asphalt waterproof paint and the colorful acrylate finishing paint is good, and the adhesion performance is good.
In addition, the oil-resistant isolation primer disclosed by the invention is simple in preparation process and is the same as a common waterproof coating; the construction process of the oil-resistant isolation primer is simple, the construction process of the oil-resistant isolation primer is the same as that of a common water-based paint, the oil-resistant isolation primer can be directly sprayed, the operation difficulty of construction workers is not increased, and the construction is simple and rapid.
Drawings
FIG. 1 is a schematic structural diagram of a barrier type color exposed composite waterproof coating layer according to the present invention.
In the figure: 1. a waterproof layer, 2, an oil-resistant isolation primer layer, 3 and a colorful exposed elastic finish.
Detailed Description
The first embodiment is as follows:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 70Kg of anion neoprene latex with solid content of 58 percent, 5Kg of zinc oxide, 10Kg of talcum powder, 5Kg of gas-phase silicon dioxide, 0.15Kg of sodium bentonite, 0.3Kg of ammonium salt dispersant, 0.1Kg of alkylphenol polyoxyethylene ether wetting agent, 0.4Kg of organosilicon antifoaming agent, 10100.5 Kg of antioxidant, 0.1Kg of UV-2920.5 Kg of 2-n-octyl-4-isothiazoline-3 ketone, 0.1Kg of 2-amino-2 methyl-1-propanol, 0.1Kg of alkali swelling thickener and 10Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding the ammonium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 organosilicon defoamer, sodium bentonite, fumed silica, zinc oxide, talcum powder, an antioxidant 1010, UV-292 and 2-n-octyl-4-isothiazoline-3 ketone into deionized water, and grinding at a high speed until the components are uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, 2-amino-2 methyl-1-propanol, 1/3 organic silicon defoaming agent and alkali swelling thickener into the anionic neoprene latex, and dispersing uniformly to obtain the oil-resistant type isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 1.5 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.5mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.3 mm;
step 3): spraying a colorful exposed elastic finish paint with the thickness of 0.5mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.3mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer, as shown in figure 1.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
In the application, a colored exposed composite waterproof coating layer obtained by directly compounding the sprayed quick-setting rubber asphalt waterproof coating and the colored exposed elastic finish paint is used as a comparative example.
Tests show that the color-exposed composite waterproof coating layer obtained by directly compounding the sprayed quick-setting rubber asphalt waterproof coating and the color-exposed elastic finish paint has the surface color change time of 20-45 days.
In the first embodiment, the oil-resistant isolation primer is used to obtain the blocking type color exposed composite waterproof coating layer, and the color change time of the surface layer is 14 months.
Example two:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 80 Kg of anion neoprene latex with solid content of 50 percent, 4Kg of zinc oxide, 5Kg of talcum powder, 4Kg of nano silicon dioxide colloid, 0.15Kg of sodium bentonite, 0.3Kg of ammonium salt dispersant, 0.1Kg of alkylphenol polyoxyethylene ether wetting agent, 0.4Kg of organosilicon defoamer, 10100.5 Kg of antioxidant, UV-2920.5 Kg, 0.1Kg of 2-n-octyl-4-isothiazoline-3 ketone, 0.1Kg of 2-amino-2 methyl-1-propanol, 0.1Kg of alkali swelling thickener and 8Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding the ammonium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 organosilicon defoamer, sodium bentonite, zinc oxide, nano silica colloid, talcum powder, an antioxidant 1010, UV-292 and 2-n-octyl-4-isothiazoline-3 ketone into deionized water, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, 2-amino-2 methyl-1-propanol, 1/3 organic silicon defoaming agent and alkali swelling thickener into the anionic neoprene latex, and dispersing uniformly to obtain the oil-resistant type isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3.3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.0 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.7mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.4 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.7mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.4mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
As can be seen from the test, in the second embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 18 months.
Example three:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 60 Kg of anion neoprene latex with solid content of 50 percent, 5Kg of zinc oxide, 5Kg of talcum powder, 5Kg of graphene, 5Kg of precipitated silica, 0.15Kg of sodium bentonite, 0.45Kg of ammonium salt dispersant, 0.15Kg of alkylphenol polyoxyethylene ether wetting agent, 0.5Kg of organosilicon antifoaming agent, 10760.5 Kg of antioxidant, 0.15Kg of UV-2920.5 Kg, 0.15Kg of 2-methyl-4-isothiazoline-3 ketone (MIT), 0.15Kg of 2-amino-2 methyl-1-propanol, 0.1Kg of alkali swelling thickener and 20Kg of deionized water.
2. Preparation method
Step 1): adding the ammonium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 silicone defoamer, sodium bentonite, precipitated silica, zinc oxide, talcum powder, graphene, an antioxidant 1076, UV-292 and 2-methyl-4-isothiazoline-3-ketone (MIT) into deionized water, and grinding at high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, 2-amino-2 methyl-1-propanol, 1/3 organic silicon defoaming agent and alkali swelling thickener into the anionic neoprene latex, and dispersing uniformly to obtain the oil-resistant type isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3.3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.0 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.7mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.4 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.7mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.4mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
Tests show that in the third embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 20 months.
Example four:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 80 Kg of anionic butyronitrile latex with solid content of 45 percent, 3Kg of zinc oxide, 3Kg of talcum powder, 5Kg of mica powder, 3Kg of nano silica colloid, 0.06Kg of sodium bentonite, 0.10Kg of sodium salt dispersant, 0.05Kg of alkylphenol polyoxyethylene ether wetting agent, 0.35Kg of organosilicon defoamer, 10760.8 Kg of antioxidant, 0.15Kg of UV-11300.8 Kg, 0.15Kg of 2-methyl-4-isothiazoline-3 ketone (MIT), 0.15Kg of dimethylethanolamine, 0.1Kg of acrylic thickener and 6Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding the sodium salt dispersant, the alkylphenol polyoxyethylene ether wetting agent, the 2/3 organic silicon defoamer, sodium bentonite, nano silica colloid, zinc oxide, talcum powder, mica powder, an antioxidant 1076, UV-1130 and 2-methyl-4-isothiazoline-3-ketone (MIT) into deionized water, and grinding at high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the slurry, dimethylethanolamine, 1/3 organosilicon antifoaming agent and acrylic thickener into the anionic butyronitrile latex, and uniformly dispersing to obtain the oil-resistant isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 3.3mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.0 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.7mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.4 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.7mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.4mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
Tests show that in the fourth embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 12 months.
Example five:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 70Kg of carboxyl anion butyronitrile latex with solid content of 45 percent, 3Kg of zinc oxide, 7Kg of talcum powder, 8Kg of mica powder, 2Kg of nano silica colloid, 0.20Kg of sodium bentonite, 0.6Kg of ammonium salt dispersant, 0.2Kg of alkylphenol polyoxyethylene ether wetting agent, 0.3Kg of organosilicon defoamer, 10780.5 Kg of antioxidant, UV-11300.5 Kg, 0.15Kg of 5-chloro-2-methyl 4-isothiazoline-3 ketone (CIT), 0.15Kg of sodium hydroxide, 0.1Kg of acrylic thickener and 20Kg of deionized water.
2. The preparation method of the oil-resistant isolation primer comprises the following steps:
step 1): adding an ammonium salt dispersant, an alkylphenol polyoxyethylene ether wetting agent, 2/3 organosilicon defoamer, nano silica colloid, sodium bentonite, zinc oxide, talcum powder, mica powder, an antioxidant 1078, UV-1130 and 5-chloro-2-methyl 4-isothiazoline-3-ketone into deionized water, and grinding at high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, adding the slurry, sodium hydroxide, 1/3 organosilicon defoaming agent and acrylic acid thickening agent into the anionic carboxyl butyronitrile latex in sequence, and dispersing uniformly to obtain the oil-resistant isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 4.2mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.4 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.8mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.5 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.8mm on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.5mm, and the three layers are bonded into a whole to form an isolating colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
As shown in the test, in the fifth embodiment, the oil-resistant isolation primer is used to obtain the barrier type color exposed composite waterproof coating layer, and the surface layer discoloration time is 18 months.
Example six:
1. oil-resistant isolation primer:
the oil-resistant isolation primer consists of the following components: 75Kg of anionic butyronitrile latex with solid content of 45 percent, 5Kg of zinc oxide, 5Kg of graphene, 5Kg of fumed silica, 0.25Kg of calcium bentonite, 0.4Kg of ammonium salt dispersant, 0.15Kg of alkylphenol polyoxyethylene ether wetting agent, 0.3Kg of organosilicon defoamer, 10780.4 Kg of antioxidant, UV-11300.5 Kg, 0.15Kg of 5-chloro-2-methyl 4-isothiazoline-3-ketone (CIT), 0.15Kg of potassium hydroxide, 0.1Kg of acrylic thickener and 10Kg of deionized water.
2. Preparation method
Step 1): adding an ammonium salt dispersant, an alkylphenol polyoxyethylene ether wetting agent, 2/3 organosilicon defoamer, calcium bentonite, fumed silica, zinc oxide, graphene, an antioxidant 1078, UV-1130 and 5-chloro-2-methyl 4-isothiazoline-3-one (CIT) into deionized water, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, adding the slurry, potassium hydroxide, 1/3 organosilicon defoaming agent and acrylic acid thickening agent into the anionic butyronitrile latex in sequence, and dispersing uniformly to obtain the oil-resistant isolation primer.
3. The construction method for obtaining the obstructing type colorful exposed composite waterproof coating layer by utilizing the oil-resistant type isolating primer comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface at the same time, performing cross atomization and quick setting on the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, wherein the wet film thickness of the black waterproof film is 4.2mm, and maintaining and airing to obtain a waterproof layer, wherein the thickness of the waterproof layer is 2.4 mm;
step 2): spraying an oil-resistant isolation primer layer with the thickness of 0.8mm on the waterproof layer, maintaining and airing to obtain the oil-resistant isolation primer layer, wherein the thickness of the oil-resistant isolation primer layer is 0.5 mm;
step 3): and spraying a colorful exposed elastic finish paint with the thickness of 0.8mm on the oil-resistant isolation primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, wherein the thickness of the colorful exposed elastic finish paint layer is 0.5mm, and the three layers are bonded into a whole to form the isolation type colorful exposed composite waterproof paint layer.
4. The barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
Tests show that the oil-resistant isolation primer is utilized to obtain the barrier type colorful exposed composite waterproof coating layer, and the surface layer discoloration time is 2 years.
The rapid hardening rubber asphalt waterproof coating adopted in the first to sixth embodiments of the application is the spraying rapid hardening rubber asphalt waterproof coating disclosed in CN201210301863.3, and the spraying rapid hardening rubber asphalt waterproof coating is the prior art and is not described herein again.
Claims (10)
1. An oil-resistant isolation primer is characterized in that: the paint comprises the following components in parts by weight: 50-90 parts of high polymer latex, 1-10 parts of zinc oxide, 5-20 parts of filler, 1-12 parts of reinforcing auxiliary agent, 0.05-0.25 part of anti-settling agent, 0.10-0.75 part of dispersing agent, 0.01-0.25 part of wetting agent, 0.3-0.5 part of defoaming agent, 0.25-1.5 parts of antioxidant, 0.25-1.0 part of light stabilizer, 0.1-0.2 part of mildew-proof auxiliary agent, 0.1-0.2 part of pH value regulator, 0.1-0.3 part of thickening agent and 3-25 parts of deionized water; wherein the solid content of the polymer latex is 45-65%.
2. The oil resistant release primer according to claim 1, characterized in that: the polymer latex comprises one or two of anionic neoprene latex, anionic butyronitrile latex and anionic carboxyl anionic butyronitrile latex.
3. The oil resistant release primer according to claim 1, characterized in that: the zinc oxide is coating-grade zinc oxide, the content of the zinc oxide is more than 99%, and the particle size of the zinc oxide is 2-45 micrometers.
4. The oil resistant release primer according to claim 1, characterized in that: the filler is of a platy structure, and the particle size range of the filler is 600-3000 meshes.
5. The oil resistant release primer according to claim 1, characterized in that: the filler comprises one or two of talcum powder, mica powder and graphene.
6. The oil resistant release primer according to claim 1, characterized in that: the reinforcing auxiliary agent comprises fumed silica, precipitated silica or nano silica colloid.
7. A preparation method of the oil-resistant isolation primer is characterized by comprising the following steps: the method comprises the following steps:
step 1): adding the dispersant, the wetting agent, the defoaming agent, the anti-settling agent, the reinforcing aid, the zinc oxide, the filler, the antioxidant, the light stabilizer and the mildew-proof aid into deionized water in percentage by mass, and grinding at a high speed until the mixture is uniformly dispersed to obtain slurry;
step 2): under the condition of low-speed stirring, sequentially adding the sizing agent, the pH regulator, the defoaming agent and the thickening agent into the polymer latex, and uniformly dispersing to obtain the oil-resistant isolation primer.
8. The method for producing an oil resistant primer sealer according to claim 7, wherein: in the step 1), the addition amount of the defoaming agent is 2/3 of the total defoaming agent addition amount, and in the step 2), the addition amount of the defoaming agent is 1/3 of the total defoaming agent addition amount.
9. A construction method for obtaining a barrier type colorful exposed composite waterproof coating layer by using an oil-resistant type isolation primer is characterized by comprising the following steps: the method comprises the following steps:
step 1): spraying quick-setting rubber asphalt waterproof paint and coagulant on the treated base surface, alternately atomizing the quick-setting rubber asphalt waterproof paint and the coagulant to form a black waterproof film, maintaining and airing to obtain a waterproof layer;
step 2): spraying an oil-resistant isolation primer on the waterproof layer, maintaining and airing to obtain an oil-resistant isolation primer layer;
step 3): and spraying the colorful exposed elastic finish paint on the oil-resistant isolating primer layer, curing and airing to obtain a colorful exposed elastic finish paint layer, and bonding the three layers into a whole to form the isolating colorful exposed composite waterproof film layer.
10. A barrier type colorful exposed composite waterproof coating layer obtained by the construction method.
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CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
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