CN111907931A - Low-temperature fresh-keeping device based on hydrogen - Google Patents

Low-temperature fresh-keeping device based on hydrogen Download PDF

Info

Publication number
CN111907931A
CN111907931A CN202010860546.XA CN202010860546A CN111907931A CN 111907931 A CN111907931 A CN 111907931A CN 202010860546 A CN202010860546 A CN 202010860546A CN 111907931 A CN111907931 A CN 111907931A
Authority
CN
China
Prior art keywords
hydrogen
storage
low
temperature
keeping
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010860546.XA
Other languages
Chinese (zh)
Inventor
沈文飚
程鹏飞
王曰桥
刘宇昊
王曙
赵干
黄丽琴
李龙娜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Agricultural University
Original Assignee
Nanjing Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Agricultural University filed Critical Nanjing Agricultural University
Priority to CN202010860546.XA priority Critical patent/CN111907931A/en
Publication of CN111907931A publication Critical patent/CN111907931A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)

Abstract

The invention provides a low-temperature preservation device based on hydrogen, and belongs to the technical field of low-temperature preservation. The invention mainly comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device, other optional device modules and the like. Aiming at different fresh-keeping objects and the opening of the cabin, the device adjusts hydrogen with certain concentration and time generated by a hydrogen storage or generation device in the closed cabin under the low temperature condition through an automatic control device, and realizes the uniform distribution of the hydrogen in the closed cabin by utilizing a gas circulation device; through mutually supporting with hydrogen concentration detection device, avoided local hydrogen concentration too high potential risk that leads to.

Description

Low-temperature fresh-keeping device based on hydrogen
Technical Field
The invention belongs to the technical field of low-temperature preservation, and particularly relates to a low-temperature preservation device based on hydrogen
Background
With the continuous improvement of life quality, the consumer demand for food materials, foods and the like for preservation is higher and higher, and particularly, the demand for the color, taste and nutritional ingredients of the food materials and the foods is continuously improved. The raw materials, processed foods or semi-finished products of the foods are easy to rot and deteriorate in the processes of storage, transportation, distribution, retail sale and eating, so that the sale and edible nutritional values of the foods are reduced. Therefore, the food is required to be in a low-temperature environment generated by special equipment required by food in each link, so that the loss is reduced, the pollution and the deterioration are prevented, and the food safety and the biological safety of the product are ensured.
The low-temperature fresh-keeping device commonly used in industry is generally called a cold chain, such as a low-temperature refrigerator, a shade store, a low-temperature refrigerator, a refrigerator car, a freezer and a refrigerated container, and is used for reducing the loss of food raw materials, semi-finished products and finished products in the storage, transportation and sale links. At the consumer level, a common freezer or refrigerator is mainly used for preserving fruits and vegetables, meat and eggs, dairy products, aquatic products and the like. The effectiveness of these methods also depends on such factors as time, temperature and product shelf-life.
The hydrogen is a diatomic gas molecule, is colorless and transparent, odorless and tasteless, and has great industrial and energy values. Recent researches show that the phenomenon of reduction of endogenous hydrogen is generated during the preservation of fruits and vegetables, and the storage period of fruits and vegetables can be prolonged by adding hydrogen or hydrogen-rich water, and the patent CN 107372779A provides a method for mixing hydrogen with carbon monoxide, carbon dioxide and oxygen so as to preserve fresh meat, and provides a configuration device of the preservation gas; patent CN 107373279 a provides a method for keeping rhizoma Gastrodiae fresh by mixing hydrogen with carbon dioxide, water vapor and oxygen, and provides a device for preparing the fresh keeping gas. However, it does not combine a single preservative gas containing hydrogen with low temperatures to prolong the freshness of fresh meat and gastrodia elata; because the mixed gas is adopted, the method is complex and the cost is high. Although patent CN 111406789 a has proposed a method of mixing hydrogen with carbon dioxide and the like as a fresh-keeping gas, and combining low temperature for keeping eggs fresh. However, at present, a broad-spectrum device which can prolong the storage period of fruits and vegetables, meat products, rice and other grains, dairy products, aquatic products and the like by only utilizing hydrogen and low temperature is not available. The method is mainly characterized in that hydrogen has low density, easy escape, flammability and explosiveness, and the like, and meanwhile, the fresh-keeping effect of the hydrogen on fruits, vegetables, meat, eggs, rice and other grains, dairy products, aquatic products and the like depends on different hydrogen concentration ranges and treatment time, and the hydrogen does not completely have the dependence on concentration and time. Therefore, the low-temperature preservation device based on hydrogen gas modified atmosphere is designed, and aiming at a specific preservation object, the concentration and the processing time of hydrogen gas are automatically controlled through the automatic control device, so that the reduction of the hydrogen gas content of the preservation object in the storage period is delayed, the metabolism is inhibited, the respiratory strength and the expression of relevant aging genes and the proliferation speed of microorganisms are reduced, the low-temperature preservation device is further used for prolonging the storage period of raw materials, semi-finished products, finished products and the like such as fruits, vegetables, meat, eggs, rice and the like, milk products, aquatic products and the like, simultaneously reducing the transportation loss, and controlling the hydrogen gas concentration in an openable closed cabin below an explosion limit (4%).
Disclosure of Invention
The invention aims to provide a low-temperature preservation device based on hydrogen, which can further improve the storage resistance of grains such as fruits and vegetables, meat and eggs, rice and the like, dairy products, aquatic products and the like under the low-temperature condition by fully playing the biological function of the hydrogen, thereby prolonging the preservation time and reducing the transportation loss.
The purpose of the invention is realized by the following technologies:
the invention firstly provides a low-temperature fresh-keeping device based on hydrogen. Specifically, the method comprises the following steps: the device comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device and the like.
Further, the hydrogen gas can be supplied from various sources, such as hydrogen cylinders or pipelines, or can be obtained by electrolysis or other physical, chemical and biological preparation, wherein the chemical hydrogen production material includes, but is not limited to, magnesium hydride, ammonia borane, sodium borohydride and the like.
Further, the fresh keeping device includes, but is not limited to, common cold chain equipment and common household refrigeration and freezing devices, such as refrigerators, freezers, cryocoolers, refrigerated containers, and the like.
Drawings
For a more complete description of the embodiments of the present invention or solutions in the prior art, the accompanying drawings illustrate by way of example specific details and embodiments in which the invention may be practiced.
FIG. 1 is a schematic diagram of the structure of the apparatus of the present invention;
FIG. 2 is a schematic diagram of the module structure of the device of the present invention.
Detailed Description
The following detailed description refers to the accompanying drawings. It is to be expressly understood that the drawings in the following description are of exemplary embodiments of the invention only and are not intended as preferred or advantageous over other embodiments or designs.
It should be noted that different features (e.g., elements, structures, modules, steps, operations, characteristics, etc.) included in the embodiments mentioned in the present specification are to be understood as meaning that these features can be included in one or more embodiments of the present invention and also can be or are not necessarily combined in the embodiments.
It is to be noted that "a plurality" mentioned in the present specification may refer to one or more.
In the embodiment of the invention, the low-temperature fresh-keeping device comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a temperature monitoring device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device, an alarm device and an interaction device.
As shown in the schematic diagram of the device structure in FIG. 1, the low-temperature fresh-keeping device comprises a shell, a closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device and an automatic control device. The sealed cabin accommodates food materials and food such as fruits and vegetables, meat and eggs, grains such as rice, dairy products, aquatic products and the like which need to be stored, the refrigerating device is arranged outside the sealed cabin, and the gas circulating device, the hydrogen concentration real-time detection device and the automatic control device are arranged in the sealed cabin. When the hydrogen concentration detection device detects that the hydrogen concentration in the closed cabin is too low, the automatic control device continuously inputs hydrogen into the cabin by adjusting the hydrogen storage device and the gas circulation device until the hydrogen in the closed cabin uniformly reaches the set concentration.
As shown in the schematic diagram of the module structure of the device in fig. 2, the low-temperature fresh-keeping device comprises a closed cabin, a hydrogen storage (storage) or generating device, a refrigerating device, a temperature monitoring device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device, an alarm device and an interaction device. After the temperature and the hydrogen concentration required by the closed cabin are set through the interaction device, the automatic control device starts or closes the refrigerating device and the gas circulating device which is linked with the hydrogen storage (storage) or generating device according to the data measured by the temperature and hydrogen concentration detection device until the temperature and the hydrogen in the closed cabin reach the set values. When the hydrogen concentration continuously exceeds the set range for a certain time, the alarm device is started, and meanwhile, the gas circulation device starts an external circulation mode to quickly reduce the hydrogen concentration.
In the low-temperature fresh-keeping device provided by the invention, the hydrogen storage (storage) or generating device can be a hydrogen cylinder for storing compressed hydrogen, an electrolytic hydrogen production device, a chemical material (magnesium hydride, ammonia borane, sodium borohydride and the like) reaction hydrogen production device or a biological reaction hydrogen production device.
Specifically, if hydrogen is stored (is stored) or generating device is for storing the hydrogen steel bottle of compressed hydrogen, automatic control device feeds back the signal of changing the steel bottle to mutual device when the steel bottle internal pressure is low excessively, reminds in time to change the steel bottle, guarantees device normal operating.
Specifically, if the hydrogen storage (storage) or generation device is an electrolytic hydrogen production device, the purified water/alkali liquor is electrolyzed into hydrogen and oxygen respectively at two electrodes through an electrolytic bath, the hydrogen is input into the gas circulation device and then enters the closed cabin, and the oxygen is directly released into the environment.
Specifically, if the hydrogen storage (storage) or generation device is a chemical material reaction hydrogen production device, hydrogen production (storage) materials and reaction liquid can be added into the reaction tank to prepare hydrogen through chemical reaction.
Specifically, if the hydrogen storage (storage) or generation device is a biological reaction hydrogen production device, nutrient solution is periodically supplemented in the reaction tank to maintain the biological hydrogen production activity, and hydrogen is prepared through biochemical reaction.
The above-mentioned schematic diagrams of the device and the device module are only provided for the patent of the present invention, and are not intended to limit the patent of the present invention, and any modifications, equivalent substitutions and improvements made within the spirit and principle of the patent of the present invention should be included in the protection scope of the patent of the present invention.

Claims (8)

1. A low-temperature fresh-keeping device based on hydrogen. It is characterized by comprising: the device comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device and the like.
2. The cryogenic preservation device of claim 1, wherein the cryogenic preservation device is used in a range including but not limited to a cryocooler, a shady cold store, a drink storage bin, a refrigerator car, a refrigerator, a cold box, and a cold chain device such as a refrigerated container.
3. The cryogenic preservation device of claim 1, wherein the hydrogen storage or generation device includes but is not limited to hydrogen cylinders or pipelines, and also includes devices for electrolysis and other physical, chemical or biological methods to produce hydrogen.
4. The apparatus of claim 1, wherein the apparatus is a fixed apparatus or a mobile transportation apparatus.
5. The low-temperature fresh-keeping device according to claim 1, wherein the enclosed compartment contains 0.000001% -4% by volume of hydrogen.
6. The apparatus according to claim 1, wherein the hydrogen concentration and the storage time of the sealed compartment are adjusted according to the type of the stored goods and the opening of the compartment.
7. The low-temperature fresh-keeping device according to claim 1, wherein the temperature of the closed chamber is-80 ℃ to 20 ℃.
8. The low-temperature fresh-keeping device according to claim 1, wherein the automatic control device is electrically connected with the hydrogen storage (storage) or generation device, the refrigerating device, the hydrogen concentration real-time detection device and the gas circulation device, and can automatically monitor and adjust the temperature and the hydrogen concentration of the closed cabin.
CN202010860546.XA 2020-08-24 2020-08-24 Low-temperature fresh-keeping device based on hydrogen Pending CN111907931A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010860546.XA CN111907931A (en) 2020-08-24 2020-08-24 Low-temperature fresh-keeping device based on hydrogen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010860546.XA CN111907931A (en) 2020-08-24 2020-08-24 Low-temperature fresh-keeping device based on hydrogen

Publications (1)

Publication Number Publication Date
CN111907931A true CN111907931A (en) 2020-11-10

Family

ID=73279857

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010860546.XA Pending CN111907931A (en) 2020-08-24 2020-08-24 Low-temperature fresh-keeping device based on hydrogen

Country Status (1)

Country Link
CN (1) CN111907931A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113264501A (en) * 2021-05-18 2021-08-17 北京瑞奎德工业技术有限公司 Hydrogen concentration control method and system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202119183U (en) * 2010-12-10 2012-01-18 上海理工大学 A foodstuff fresh-keeping and pre-cooling device
CN107509909A (en) * 2016-06-17 2017-12-26 元智大学 Food fresh-keeping system
WO2018099456A1 (en) * 2016-12-02 2018-06-07 青岛海尔股份有限公司 Refrigeration device and preservation control method therefor
CN111011488A (en) * 2019-12-27 2020-04-17 北京蓝玖新能源科技有限公司 Controlled atmosphere preservation system and application
CN212767706U (en) * 2020-08-24 2021-03-23 南京农业大学 Low-temperature fresh-keeping device based on hydrogen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202119183U (en) * 2010-12-10 2012-01-18 上海理工大学 A foodstuff fresh-keeping and pre-cooling device
CN107509909A (en) * 2016-06-17 2017-12-26 元智大学 Food fresh-keeping system
WO2018099456A1 (en) * 2016-12-02 2018-06-07 青岛海尔股份有限公司 Refrigeration device and preservation control method therefor
CN111011488A (en) * 2019-12-27 2020-04-17 北京蓝玖新能源科技有限公司 Controlled atmosphere preservation system and application
CN212767706U (en) * 2020-08-24 2021-03-23 南京农业大学 Low-temperature fresh-keeping device based on hydrogen

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113264501A (en) * 2021-05-18 2021-08-17 北京瑞奎德工业技术有限公司 Hydrogen concentration control method and system
CN113264501B (en) * 2021-05-18 2022-08-23 北京瑞奎德工业技术有限公司 Hydrogen concentration control method and system

Similar Documents

Publication Publication Date Title
US3102777A (en) Apparatus and method of preserving animal and plant materials
CN212767706U (en) Low-temperature fresh-keeping device based on hydrogen
CN103851863B (en) Refrigerator and the method for refrigerator food fresh-keeping
Goswami Role of cryogenics in food processing and preservation
CN110226621A (en) A kind of refrigerated storage method of preservation of fishery
EP3037003A1 (en) Food preservation process combining cryogenic freezing and modified atmosphere packaging
US20130189402A1 (en) Systems and methods for maintaining red meat
CN107811030A (en) A kind of blueberry green precisely anti-rot and fresh-keeping method and its application
CN111907931A (en) Low-temperature fresh-keeping device based on hydrogen
CN203740350U (en) Air conditioning temperature control device
Alwazeer Reducing atmosphere packaging technique for extending the shelf-life of food products
JP2006275441A (en) Hydrogen gas-containing ice and its making method, and fresh food preserving method
CN102840734A (en) Refrigerator
Thakur et al. Isochoric freezing of foods: A review of instrumentation, mechanism, physicochemical influence, and applications
CN103734261A (en) Comprehensive method for refrigerating and refreshing waxberries
CN103766473B (en) A kind of control release type ethanol antistaling agent and its preparation method and application
US3102779A (en) Apparatus and method of preserving animal and plant materials
CN104757096A (en) Multiple-factor fence preservation technology of cooked beef
CN107455443A (en) A kind of quick-frozen liquid of food fresh keeping and preparation method thereof and application method
NO802787L (en) PROCEDURE AND APPARATUS FOR STORAGE AND CONSERVATION OF PRODUCTS THAT CAN BE SPECIAL, SPECIAL FOODSTUFFS
Dhanya et al. Comprehensive Review on Isochoric Freezing: A Recent Technology for Preservation of Food and Non-food Items
CN101213986B (en) Three-segment composite processing method for prolonging sea water vegetable fresh-keeping time
CN118111162A (en) Refrigerating and freezing device and control method thereof
JP2019115308A (en) Sterilization method of food product
CN105270763B (en) Cold Chain Logistics cold insulated cabinet storage structures

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
DD01 Delivery of document by public notice
DD01 Delivery of document by public notice

Addressee: Shen Wenbiao

Document name: Notice on publication of patent application for invention and entry into substantive examination