CN111907931A - Low-temperature fresh-keeping device based on hydrogen - Google Patents
Low-temperature fresh-keeping device based on hydrogen Download PDFInfo
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- CN111907931A CN111907931A CN202010860546.XA CN202010860546A CN111907931A CN 111907931 A CN111907931 A CN 111907931A CN 202010860546 A CN202010860546 A CN 202010860546A CN 111907931 A CN111907931 A CN 111907931A
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- hydrogen
- storage
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- temperature
- keeping
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 239000001257 hydrogen Substances 0.000 title claims abstract description 81
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 81
- 238000003860 storage Methods 0.000 claims abstract description 37
- 239000007789 gas Substances 0.000 claims abstract description 19
- 238000004321 preservation Methods 0.000 claims abstract description 16
- 238000011897 real-time detection Methods 0.000 claims abstract description 8
- 238000005057 refrigeration Methods 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 2
- 238000010170 biological method Methods 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 abstract description 5
- 238000001514 detection method Methods 0.000 abstract description 3
- 238000009827 uniform distribution Methods 0.000 abstract 1
- 235000013305 food Nutrition 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 235000013372 meat Nutrition 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 235000013601 eggs Nutrition 0.000 description 6
- 235000012055 fruits and vegetables Nutrition 0.000 description 6
- 241000209094 Oryza Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- 235000013365 dairy product Nutrition 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011265 semifinished product Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910012375 magnesium hydride Inorganic materials 0.000 description 2
- 238000012806 monitoring device Methods 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000305491 Gastrodia elata Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 230000008827 biological function Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000013622 meat product Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 201000009240 nasopharyngitis Diseases 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)
Abstract
The invention provides a low-temperature preservation device based on hydrogen, and belongs to the technical field of low-temperature preservation. The invention mainly comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device, other optional device modules and the like. Aiming at different fresh-keeping objects and the opening of the cabin, the device adjusts hydrogen with certain concentration and time generated by a hydrogen storage or generation device in the closed cabin under the low temperature condition through an automatic control device, and realizes the uniform distribution of the hydrogen in the closed cabin by utilizing a gas circulation device; through mutually supporting with hydrogen concentration detection device, avoided local hydrogen concentration too high potential risk that leads to.
Description
Technical Field
The invention belongs to the technical field of low-temperature preservation, and particularly relates to a low-temperature preservation device based on hydrogen
Background
With the continuous improvement of life quality, the consumer demand for food materials, foods and the like for preservation is higher and higher, and particularly, the demand for the color, taste and nutritional ingredients of the food materials and the foods is continuously improved. The raw materials, processed foods or semi-finished products of the foods are easy to rot and deteriorate in the processes of storage, transportation, distribution, retail sale and eating, so that the sale and edible nutritional values of the foods are reduced. Therefore, the food is required to be in a low-temperature environment generated by special equipment required by food in each link, so that the loss is reduced, the pollution and the deterioration are prevented, and the food safety and the biological safety of the product are ensured.
The low-temperature fresh-keeping device commonly used in industry is generally called a cold chain, such as a low-temperature refrigerator, a shade store, a low-temperature refrigerator, a refrigerator car, a freezer and a refrigerated container, and is used for reducing the loss of food raw materials, semi-finished products and finished products in the storage, transportation and sale links. At the consumer level, a common freezer or refrigerator is mainly used for preserving fruits and vegetables, meat and eggs, dairy products, aquatic products and the like. The effectiveness of these methods also depends on such factors as time, temperature and product shelf-life.
The hydrogen is a diatomic gas molecule, is colorless and transparent, odorless and tasteless, and has great industrial and energy values. Recent researches show that the phenomenon of reduction of endogenous hydrogen is generated during the preservation of fruits and vegetables, and the storage period of fruits and vegetables can be prolonged by adding hydrogen or hydrogen-rich water, and the patent CN 107372779A provides a method for mixing hydrogen with carbon monoxide, carbon dioxide and oxygen so as to preserve fresh meat, and provides a configuration device of the preservation gas; patent CN 107373279 a provides a method for keeping rhizoma Gastrodiae fresh by mixing hydrogen with carbon dioxide, water vapor and oxygen, and provides a device for preparing the fresh keeping gas. However, it does not combine a single preservative gas containing hydrogen with low temperatures to prolong the freshness of fresh meat and gastrodia elata; because the mixed gas is adopted, the method is complex and the cost is high. Although patent CN 111406789 a has proposed a method of mixing hydrogen with carbon dioxide and the like as a fresh-keeping gas, and combining low temperature for keeping eggs fresh. However, at present, a broad-spectrum device which can prolong the storage period of fruits and vegetables, meat products, rice and other grains, dairy products, aquatic products and the like by only utilizing hydrogen and low temperature is not available. The method is mainly characterized in that hydrogen has low density, easy escape, flammability and explosiveness, and the like, and meanwhile, the fresh-keeping effect of the hydrogen on fruits, vegetables, meat, eggs, rice and other grains, dairy products, aquatic products and the like depends on different hydrogen concentration ranges and treatment time, and the hydrogen does not completely have the dependence on concentration and time. Therefore, the low-temperature preservation device based on hydrogen gas modified atmosphere is designed, and aiming at a specific preservation object, the concentration and the processing time of hydrogen gas are automatically controlled through the automatic control device, so that the reduction of the hydrogen gas content of the preservation object in the storage period is delayed, the metabolism is inhibited, the respiratory strength and the expression of relevant aging genes and the proliferation speed of microorganisms are reduced, the low-temperature preservation device is further used for prolonging the storage period of raw materials, semi-finished products, finished products and the like such as fruits, vegetables, meat, eggs, rice and the like, milk products, aquatic products and the like, simultaneously reducing the transportation loss, and controlling the hydrogen gas concentration in an openable closed cabin below an explosion limit (4%).
Disclosure of Invention
The invention aims to provide a low-temperature preservation device based on hydrogen, which can further improve the storage resistance of grains such as fruits and vegetables, meat and eggs, rice and the like, dairy products, aquatic products and the like under the low-temperature condition by fully playing the biological function of the hydrogen, thereby prolonging the preservation time and reducing the transportation loss.
The purpose of the invention is realized by the following technologies:
the invention firstly provides a low-temperature fresh-keeping device based on hydrogen. Specifically, the method comprises the following steps: the device comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device and the like.
Further, the hydrogen gas can be supplied from various sources, such as hydrogen cylinders or pipelines, or can be obtained by electrolysis or other physical, chemical and biological preparation, wherein the chemical hydrogen production material includes, but is not limited to, magnesium hydride, ammonia borane, sodium borohydride and the like.
Further, the fresh keeping device includes, but is not limited to, common cold chain equipment and common household refrigeration and freezing devices, such as refrigerators, freezers, cryocoolers, refrigerated containers, and the like.
Drawings
For a more complete description of the embodiments of the present invention or solutions in the prior art, the accompanying drawings illustrate by way of example specific details and embodiments in which the invention may be practiced.
FIG. 1 is a schematic diagram of the structure of the apparatus of the present invention;
FIG. 2 is a schematic diagram of the module structure of the device of the present invention.
Detailed Description
The following detailed description refers to the accompanying drawings. It is to be expressly understood that the drawings in the following description are of exemplary embodiments of the invention only and are not intended as preferred or advantageous over other embodiments or designs.
It should be noted that different features (e.g., elements, structures, modules, steps, operations, characteristics, etc.) included in the embodiments mentioned in the present specification are to be understood as meaning that these features can be included in one or more embodiments of the present invention and also can be or are not necessarily combined in the embodiments.
It is to be noted that "a plurality" mentioned in the present specification may refer to one or more.
In the embodiment of the invention, the low-temperature fresh-keeping device comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a temperature monitoring device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device, an alarm device and an interaction device.
As shown in the schematic diagram of the device structure in FIG. 1, the low-temperature fresh-keeping device comprises a shell, a closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device and an automatic control device. The sealed cabin accommodates food materials and food such as fruits and vegetables, meat and eggs, grains such as rice, dairy products, aquatic products and the like which need to be stored, the refrigerating device is arranged outside the sealed cabin, and the gas circulating device, the hydrogen concentration real-time detection device and the automatic control device are arranged in the sealed cabin. When the hydrogen concentration detection device detects that the hydrogen concentration in the closed cabin is too low, the automatic control device continuously inputs hydrogen into the cabin by adjusting the hydrogen storage device and the gas circulation device until the hydrogen in the closed cabin uniformly reaches the set concentration.
As shown in the schematic diagram of the module structure of the device in fig. 2, the low-temperature fresh-keeping device comprises a closed cabin, a hydrogen storage (storage) or generating device, a refrigerating device, a temperature monitoring device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device, an alarm device and an interaction device. After the temperature and the hydrogen concentration required by the closed cabin are set through the interaction device, the automatic control device starts or closes the refrigerating device and the gas circulating device which is linked with the hydrogen storage (storage) or generating device according to the data measured by the temperature and hydrogen concentration detection device until the temperature and the hydrogen in the closed cabin reach the set values. When the hydrogen concentration continuously exceeds the set range for a certain time, the alarm device is started, and meanwhile, the gas circulation device starts an external circulation mode to quickly reduce the hydrogen concentration.
In the low-temperature fresh-keeping device provided by the invention, the hydrogen storage (storage) or generating device can be a hydrogen cylinder for storing compressed hydrogen, an electrolytic hydrogen production device, a chemical material (magnesium hydride, ammonia borane, sodium borohydride and the like) reaction hydrogen production device or a biological reaction hydrogen production device.
Specifically, if hydrogen is stored (is stored) or generating device is for storing the hydrogen steel bottle of compressed hydrogen, automatic control device feeds back the signal of changing the steel bottle to mutual device when the steel bottle internal pressure is low excessively, reminds in time to change the steel bottle, guarantees device normal operating.
Specifically, if the hydrogen storage (storage) or generation device is an electrolytic hydrogen production device, the purified water/alkali liquor is electrolyzed into hydrogen and oxygen respectively at two electrodes through an electrolytic bath, the hydrogen is input into the gas circulation device and then enters the closed cabin, and the oxygen is directly released into the environment.
Specifically, if the hydrogen storage (storage) or generation device is a chemical material reaction hydrogen production device, hydrogen production (storage) materials and reaction liquid can be added into the reaction tank to prepare hydrogen through chemical reaction.
Specifically, if the hydrogen storage (storage) or generation device is a biological reaction hydrogen production device, nutrient solution is periodically supplemented in the reaction tank to maintain the biological hydrogen production activity, and hydrogen is prepared through biochemical reaction.
The above-mentioned schematic diagrams of the device and the device module are only provided for the patent of the present invention, and are not intended to limit the patent of the present invention, and any modifications, equivalent substitutions and improvements made within the spirit and principle of the patent of the present invention should be included in the protection scope of the patent of the present invention.
Claims (8)
1. A low-temperature fresh-keeping device based on hydrogen. It is characterized by comprising: the device comprises a shell, an openable closed cabin, a hydrogen storage (storage) or generation device, a refrigeration device, a hydrogen concentration real-time detection device, a gas circulation device, an automatic control device and the like.
2. The cryogenic preservation device of claim 1, wherein the cryogenic preservation device is used in a range including but not limited to a cryocooler, a shady cold store, a drink storage bin, a refrigerator car, a refrigerator, a cold box, and a cold chain device such as a refrigerated container.
3. The cryogenic preservation device of claim 1, wherein the hydrogen storage or generation device includes but is not limited to hydrogen cylinders or pipelines, and also includes devices for electrolysis and other physical, chemical or biological methods to produce hydrogen.
4. The apparatus of claim 1, wherein the apparatus is a fixed apparatus or a mobile transportation apparatus.
5. The low-temperature fresh-keeping device according to claim 1, wherein the enclosed compartment contains 0.000001% -4% by volume of hydrogen.
6. The apparatus according to claim 1, wherein the hydrogen concentration and the storage time of the sealed compartment are adjusted according to the type of the stored goods and the opening of the compartment.
7. The low-temperature fresh-keeping device according to claim 1, wherein the temperature of the closed chamber is-80 ℃ to 20 ℃.
8. The low-temperature fresh-keeping device according to claim 1, wherein the automatic control device is electrically connected with the hydrogen storage (storage) or generation device, the refrigerating device, the hydrogen concentration real-time detection device and the gas circulation device, and can automatically monitor and adjust the temperature and the hydrogen concentration of the closed cabin.
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CN202010860546.XA CN111907931A (en) | 2020-08-24 | 2020-08-24 | Low-temperature fresh-keeping device based on hydrogen |
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CN202010860546.XA CN111907931A (en) | 2020-08-24 | 2020-08-24 | Low-temperature fresh-keeping device based on hydrogen |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113264501A (en) * | 2021-05-18 | 2021-08-17 | 北京瑞奎德工业技术有限公司 | Hydrogen concentration control method and system |
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CN202119183U (en) * | 2010-12-10 | 2012-01-18 | 上海理工大学 | A foodstuff fresh-keeping and pre-cooling device |
CN107509909A (en) * | 2016-06-17 | 2017-12-26 | 元智大学 | Food fresh-keeping system |
WO2018099456A1 (en) * | 2016-12-02 | 2018-06-07 | 青岛海尔股份有限公司 | Refrigeration device and preservation control method therefor |
CN111011488A (en) * | 2019-12-27 | 2020-04-17 | 北京蓝玖新能源科技有限公司 | Controlled atmosphere preservation system and application |
CN212767706U (en) * | 2020-08-24 | 2021-03-23 | 南京农业大学 | Low-temperature fresh-keeping device based on hydrogen |
-
2020
- 2020-08-24 CN CN202010860546.XA patent/CN111907931A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN202119183U (en) * | 2010-12-10 | 2012-01-18 | 上海理工大学 | A foodstuff fresh-keeping and pre-cooling device |
CN107509909A (en) * | 2016-06-17 | 2017-12-26 | 元智大学 | Food fresh-keeping system |
WO2018099456A1 (en) * | 2016-12-02 | 2018-06-07 | 青岛海尔股份有限公司 | Refrigeration device and preservation control method therefor |
CN111011488A (en) * | 2019-12-27 | 2020-04-17 | 北京蓝玖新能源科技有限公司 | Controlled atmosphere preservation system and application |
CN212767706U (en) * | 2020-08-24 | 2021-03-23 | 南京农业大学 | Low-temperature fresh-keeping device based on hydrogen |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113264501A (en) * | 2021-05-18 | 2021-08-17 | 北京瑞奎德工业技术有限公司 | Hydrogen concentration control method and system |
CN113264501B (en) * | 2021-05-18 | 2022-08-23 | 北京瑞奎德工业技术有限公司 | Hydrogen concentration control method and system |
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