CN111889478B - Harmless utilization method of waste residues generated by resource utilization of hazardous waste inorganic salts - Google Patents
Harmless utilization method of waste residues generated by resource utilization of hazardous waste inorganic salts Download PDFInfo
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- CN111889478B CN111889478B CN201910530047.1A CN201910530047A CN111889478B CN 111889478 B CN111889478 B CN 111889478B CN 201910530047 A CN201910530047 A CN 201910530047A CN 111889478 B CN111889478 B CN 111889478B
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- parts
- waste
- waste residues
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- 239000002699 waste material Substances 0.000 title claims abstract description 88
- 238000000034 method Methods 0.000 title claims abstract description 62
- 150000003839 salts Chemical class 0.000 title claims abstract description 35
- 239000002920 hazardous waste Substances 0.000 title claims abstract description 29
- 239000004568 cement Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 238000004064 recycling Methods 0.000 claims abstract description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 9
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- CHLCPTJLUJHDBO-UHFFFAOYSA-M sodium;benzenesulfinate Chemical compound [Na+].[O-]S(=O)C1=CC=CC=C1 CHLCPTJLUJHDBO-UHFFFAOYSA-M 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 238000004898 kneading Methods 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 14
- 240000008042 Zea mays Species 0.000 claims description 14
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 14
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 14
- 235000005822 corn Nutrition 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000010902 straw Substances 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 9
- QKDAMFXBOUOVMF-UHFFFAOYSA-N 4-hydroxy-n-(3-triethoxysilylpropyl)butanamide Chemical compound CCO[Si](OCC)(OCC)CCCNC(=O)CCCO QKDAMFXBOUOVMF-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- GIPOFCXYHMWROH-UHFFFAOYSA-L 2-aminoacetate;iron(2+) Chemical compound [Fe+2].NCC([O-])=O.NCC([O-])=O GIPOFCXYHMWROH-UHFFFAOYSA-L 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 7
- BTVVNGIPFPKDHO-UHFFFAOYSA-K cerium(3+);octadecanoate Chemical compound [Ce+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O BTVVNGIPFPKDHO-UHFFFAOYSA-K 0.000 claims description 7
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 6
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 229940044172 calcium formate Drugs 0.000 claims description 6
- 239000004281 calcium formate Substances 0.000 claims description 6
- 235000019255 calcium formate Nutrition 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000010812 mixed waste Substances 0.000 claims description 6
- 239000002984 plastic foam Substances 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- 229940037003 alum Drugs 0.000 claims description 5
- 238000003892 spreading Methods 0.000 claims description 5
- 230000007480 spreading Effects 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000010424 alunite Substances 0.000 claims description 2
- 229910052934 alunite Inorganic materials 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003469 silicate cement Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- KPZTWMNLAFDTGF-UHFFFAOYSA-D trialuminum;potassium;hexahydroxide;disulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KPZTWMNLAFDTGF-UHFFFAOYSA-D 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 11
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- 230000002411 adverse Effects 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 16
- 239000002893 slag Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 12
- 239000002440 industrial waste Substances 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000012535 impurity Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000005416 organic matter Substances 0.000 description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000010446 mirabilite Substances 0.000 description 6
- 239000010802 sludge Substances 0.000 description 5
- -1 2-amino-4-methylthio butyric acid iron Chemical compound 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000011398 Portland cement Substances 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- RWDJJOUSDATHMI-UHFFFAOYSA-N benzenesulfinic acid;sodium Chemical compound [Na].OS(=O)C1=CC=CC=C1 RWDJJOUSDATHMI-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 150000004698 iron complex Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FFEARJCKVFRZRR-UHFFFAOYSA-N methionine Chemical compound CSCCC(N)C(O)=O FFEARJCKVFRZRR-UHFFFAOYSA-N 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010914 pesticide waste Substances 0.000 description 1
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- 239000011347 resin Substances 0.000 description 1
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- 238000000926 separation method Methods 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN201910530047.1A CN111889478B (en) | 2019-06-19 | 2019-06-19 | Harmless utilization method of waste residues generated by resource utilization of hazardous waste inorganic salts |
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CN201910530047.1A CN111889478B (en) | 2019-06-19 | 2019-06-19 | Harmless utilization method of waste residues generated by resource utilization of hazardous waste inorganic salts |
Publications (2)
Publication Number | Publication Date |
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CN111889478A CN111889478A (en) | 2020-11-06 |
CN111889478B true CN111889478B (en) | 2022-05-20 |
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CN201910530047.1A Active CN111889478B (en) | 2019-06-19 | 2019-06-19 | Harmless utilization method of waste residues generated by resource utilization of hazardous waste inorganic salts |
Country Status (1)
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CN (1) | CN111889478B (en) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN87100738A (en) * | 1986-02-20 | 1987-09-23 | 布拉德福斯·H·约翰斯 | The technology and the equipment of curing, sealing, stabilisation and the detoxifcation of heavy metal in the materials such as metallic residue, soil, lime-ash |
CN101551108A (en) * | 2009-05-11 | 2009-10-07 | 东南大学 | Incineration treatment method of municipal sludge and device thereof |
CN102614834A (en) * | 2011-01-28 | 2012-08-01 | 华中农业大学 | Method for adsorbing and recovering heavy metals of lead and copper by persimmon tannin-containing metal adsorbent |
KR20120119485A (en) * | 2011-04-21 | 2012-10-31 | 이주형 | Treatment method on reusing of construction waste for acquiring of high quality recycling aggregate and combustible material |
CN108658554A (en) * | 2018-05-15 | 2018-10-16 | 苗霞明 | A kind of preparation method of the porous autoclaved lime-sand brick of copper tailing |
CN108947458A (en) * | 2018-09-29 | 2018-12-07 | 福建江夏学院 | A kind of high tenacity perfusion mortar and preparation method thereof |
CN109848169A (en) * | 2018-12-21 | 2019-06-07 | 兰州何捷环保科技有限公司 | A kind of organic saliferous breeze refinement treatment process |
-
2019
- 2019-06-19 CN CN201910530047.1A patent/CN111889478B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN87100738A (en) * | 1986-02-20 | 1987-09-23 | 布拉德福斯·H·约翰斯 | The technology and the equipment of curing, sealing, stabilisation and the detoxifcation of heavy metal in the materials such as metallic residue, soil, lime-ash |
CN101551108A (en) * | 2009-05-11 | 2009-10-07 | 东南大学 | Incineration treatment method of municipal sludge and device thereof |
CN102614834A (en) * | 2011-01-28 | 2012-08-01 | 华中农业大学 | Method for adsorbing and recovering heavy metals of lead and copper by persimmon tannin-containing metal adsorbent |
KR20120119485A (en) * | 2011-04-21 | 2012-10-31 | 이주형 | Treatment method on reusing of construction waste for acquiring of high quality recycling aggregate and combustible material |
CN108658554A (en) * | 2018-05-15 | 2018-10-16 | 苗霞明 | A kind of preparation method of the porous autoclaved lime-sand brick of copper tailing |
CN108947458A (en) * | 2018-09-29 | 2018-12-07 | 福建江夏学院 | A kind of high tenacity perfusion mortar and preparation method thereof |
CN109848169A (en) * | 2018-12-21 | 2019-06-07 | 兰州何捷环保科技有限公司 | A kind of organic saliferous breeze refinement treatment process |
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CN111889478A (en) | 2020-11-06 |
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Effective date of registration: 20230506 Address after: No. 8, Group 2, Fu'an Pian, Fuli Village, Jinfeng Town, Zhangjiagang City, Suzhou City, Jiangsu Province, 215625 Patentee after: Nie Bin Address before: 015000 Xinhong West Road, economic and Technological Development Zone, Bayannur City, Inner Mongolia Autonomous Region Patentee before: Inner Mongolia Zhongtai Huijin Environmental Protection Technology Co.,Ltd. |
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Effective date of registration: 20230712 Address after: 750336 Xinhong West Road, Bayannur Economic and Technological Development Zone, Inner Mongolia Patentee after: Inner Mongolia Zhongtai Huijin Environmental Protection Technology Co.,Ltd. Address before: No. 8, Group 2, Fu'an Pian, Fuli Village, Jinfeng Town, Zhangjiagang City, Suzhou City, Jiangsu Province, 215625 Patentee before: Nie Bin |
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