CN111883860A - Method for recovering appearance of waste lead-acid battery - Google Patents
Method for recovering appearance of waste lead-acid battery Download PDFInfo
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- CN111883860A CN111883860A CN202010513417.3A CN202010513417A CN111883860A CN 111883860 A CN111883860 A CN 111883860A CN 202010513417 A CN202010513417 A CN 202010513417A CN 111883860 A CN111883860 A CN 111883860A
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- China
- Prior art keywords
- acid battery
- waste lead
- battery
- lead
- liquid medicine
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Abstract
The invention discloses a method for restoring the appearance of a waste lead-acid battery, which relates to the field of battery restoration, wherein the majority of the shell material of the lead-acid battery is ABS, the shell material of the lead-acid battery is PP material for automobiles, the top of the lead-acid battery is provided with a plastic sealing cover which can be unscrewed, and vent holes are arranged on the plastic sealing cover, the ABS and PP plastic is terpolymer of three monomers of acrylonitrile, butadiene and styrene, the relative contents of the three monomers can be randomly changed to prepare various resins, the characteristics that the ABS plastic is dissolved in cyclohexanone are utilized, according to the actual proportion, experiments show that 80 parts of cyclohexanone and 20 parts of turpentine are prepared and mixed with 1-2 parts of dichloroethane liquid medicine to be uniformly prepared, so that the ABS and PP plastic are dissolved in the prepared liquid medicine, dust on the surface is cleaned and then put into the liquid medicine, the shell of the lead-acid battery is dissolved, and only stays for 2-5 seconds in winter and 1-3 seconds in summer, and the surface of the waste lead-acid battery can be damaged after being dried, and the new surface of the waste lead-acid battery can be recovered.
Description
Technical Field
The invention relates to the field of battery repair, in particular to a method for recovering the appearance of a waste lead-acid battery.
Background
In the prior art, for a waste lead-acid storage battery, a plurality of methods and processes for repairing the anode, the cathode and the electrolyte in the waste lead-acid storage battery are provided, for example, in the invention patent with the patent number of CN107681211A named as 'valve control type sealed lead-acid storage battery repairing process', the method has a good improvement and improvement for realizing the internal repairing of the lead-acid storage battery, prolonging the power supply time and prolonging the service life of the storage battery, but the prior art does not have a good repairing method for the surface repairing of the lead-acid storage battery.
The appearance of the waste lead-acid storage battery is damaged to a certain degree, and a repair technology for repairing the appearance of the waste lead-acid storage battery is needed.
Disclosure of Invention
The invention aims to: the method for restoring the appearance of the waste lead-acid storage battery is provided, and the problem that the appearance of the waste lead-acid storage battery is damaged to a certain degree and a restoration technology is needed to restore the appearance of the waste lead-acid storage battery is solved.
The technical scheme adopted by the invention is as follows:
a method for recovering the appearance of a waste lead-acid battery comprises the following steps:
s1: cleaning dust on the outer surface of the waste lead-acid battery, and naturally drying the waste lead-acid battery in a ventilated place for later use;
s2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: placing the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2 and staying for 2-5 seconds in winter; stay for 1-3 seconds in summer
S4: and taking out the battery, and putting the battery on an airing rack for airing.
The lead-acid storage battery shell is mainly made of ABS (acrylonitrile butadiene styrene), the automobile is made of PP (polypropylene), a plastic sealing cover which can be unscrewed is arranged at the top of the lead-acid storage battery shell, a vent hole is arranged on the plastic sealing cover, the ABS and PP plastics are terpolymer of three monomers of acrylonitrile (A), butadiene (B) and styrene (S), the relative contents of the three monomers can be changed at will to prepare various resins, the characteristics that the ABS plastics are dissolved in cyclohexanone are utilized, according to the actual proportion, the cyclohexanone 80 and the turpentine 20 are prepared and mixed with the liquid medicine of 1-2-dichloroethane to be prepared uniformly, so that the ABS and PP plastics are dissolved in the prepared liquid medicine, dust on the surface is cleaned and then put into the liquid medicine to dissolve the lead-acid storage battery shell, the dust is remained for 2-5 seconds in winter, and remained for 1-3 seconds in summer to ensure that the lead-acid storage battery shell, and the surface of the waste lead-acid battery can be damaged after being dried, and the surface of the waste lead-acid battery can be recovered.
Further, in step S1, the used lead-acid battery has printed characters on its surface, and the original printed characters are washed away after the surface dust of the used lead-acid battery is cleaned.
The printing contains other ink, resin, or the like, and is washed away to prevent the reaction with the chemical solution in step S2.
Further, in the step S1, the air drying time is 6 hours in summer and 12 hours in winter.
The air drying time is about 6 hours in summer and about 12 hours in winter according to experiments because the temperature and the air volume are different between summer and winter.
Further, when the battery is dried in the step S4, the area of the battery contacting the drying rack is minimized.
In step S4, since a certain amount of liquid medicine adheres to the outer surface of the waste lead-acid battery when the battery is taken out of the liquid medicine, and the contact surface of the waste lead-acid battery may change due to reaction with the drying rack in contact with the waste lead-acid battery, we should try to ensure that the area of the lead-acid battery in contact with the drying rack is the minimum.
Further, in the step S3, when the waste lead-acid battery is placed in the liquid medicine, the plastic sealing cover and the vent hole at the top end of the waste lead-acid battery are not immersed in the liquid medicine, and the other parts are immersed in the liquid medicine.
The lead-acid accumulator of general lead-acid battery has a plastic sealing cover on its top, which can be unscrewed and has a ventilation hole. These are used for filling pure water, checking an electrolyte and discharging gas. Therefore, when the waste lead-acid battery is put into the liquid medicine, the plastic sealing cover and the vent hole at the top end of the waste lead-acid battery are ensured not to be immersed into the liquid medicine, and other parts are immersed into the liquid medicine. So that the liquid medicine does not enter the electrolyte inside.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
1. the invention provides a method for recovering the appearance of a waste lead-acid battery, which solves the problem that the waste lead-acid battery can be damaged to a certain extent on the outer surface thereof and can be recovered;
2. the invention provides a method for recovering the appearance of a waste lead-acid battery, which can only repair the damage of the appearance of the lead-acid battery without damaging the internal electrolyte of the lead-acid battery.
Drawings
The invention will now be described, by way of example, with reference to the accompanying drawings, in which:
FIG. 1 is a functional block diagram of the present invention;
Detailed Description
All of the features disclosed in this specification, or all of the steps in any method or process so disclosed, may be combined in any combination, except combinations of features and/or steps that are mutually exclusive.
It is noted that relational terms such as "first" and "second," and the like, may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The present invention will be described in detail with reference to fig. 1.
Example 1
A method for recovering the appearance of a waste lead-acid battery, as shown in fig. 1, comprises the following steps:
s1: cleaning dust on the outer surface of the waste lead-acid battery, and naturally drying the waste lead-acid battery in a ventilated place for later use;
s2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: putting the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2 for staying for 2-5 seconds in winter; summer 1-3 seconds.
S4: and taking out the battery, and putting the battery on an airing rack for airing.
The majority of the lead-acid storage battery shell material is ABS, the automobile is PP material, the top of the lead-acid storage battery is provided with a plastic sealing cover which can be unscrewed, the upper surface of the lead-acid storage battery shell material is also provided with a vent hole, the ABS and PP plastic is terpolymer of three monomers of acrylonitrile (A), butadiene (B) and styrene (S), the relative contents of the three monomers can be randomly changed to prepare various resins, the characteristics that the ABS plastic is dissolved in cyclohexanone are utilized, according to the actual proportioning, the experiment shows that cyclohexanone 80 and turpentine 20 are prepared and mixed with liquid medicine of 1-2-dichloroethane to be uniformly prepared, so that the ABS and PP plastic are dissolved in the prepared liquid medicine, dust on the surface is cleaned and then put into the liquid medicine to dissolve the lead-acid storage battery shell, the dust only stays for 2-5 seconds in winter, and 1-3 in summer ensures that the lead-acid storage battery shell, and the surface of the waste lead-acid battery can be damaged after being dried, and the surface of the waste lead-acid battery can be recovered.
Example 2
A method for recovering the appearance of a waste lead-acid battery, as shown in fig. 1, comprises the following steps:
s1: cleaning the surface dust of the waste lead-acid battery, wherein the surface of the waste lead-acid battery is printed, cleaning the surface dust of the waste lead-acid battery, cleaning the original printed characters, and naturally airing the ventilated part for later use;
s2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: putting the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2 for staying for 2-5 seconds in winter; summer 1-3 seconds.
S4: and taking out the battery, and putting the battery on an airing rack for airing.
This example is different from example 1 only in that in step S1, printing contains other ink, resin, or the like, which is washed away to prevent reaction with the liquid medicine in step S2.
Example 3
A method for recovering the appearance of a waste lead-acid battery, as shown in fig. 1, comprises the following steps:
s1: and (3) cleaning the surface dust of the waste lead-acid battery, and naturally drying the waste lead-acid battery in a ventilated place for later use, wherein the drying time is 6 hours in summer and about 12 hours in winter.
S2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: putting the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2 for staying for 2-5 seconds in winter; summer 1-3 seconds.
S4: and taking out the battery, and putting the battery on an airing rack for airing.
The present embodiment is different from embodiment 1 only in that the air-drying time is 12 hours in summer and 24 hours in winter in step S1.
The air drying time is about 6 hours in summer and about 12 hours in winter according to experiments because the temperature and the air volume are different between summer and winter.
Example 4
A method for recovering the appearance of a waste lead-acid battery, as shown in fig. 1, comprises the following steps:
s1: cleaning dust on the outer surface of the waste lead-acid battery, and naturally drying the waste lead-acid battery in a ventilated place for later use;
s2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: putting the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2 for staying for 2-5 seconds in winter; summer 1-3 seconds
S4: and taking out the battery, putting the battery on a drying rack for drying, and enabling the area of the battery contacting the drying rack to be the minimum when the battery is dried.
The present embodiment is different from embodiment 1 only in that the area of the battery contacting the drying rack is minimized when the battery is dried in the step S4.
In step S4, since a certain amount of liquid medicine adheres to the outer surface of the waste lead-acid battery when the battery is taken out of the liquid medicine, and the contact surface of the waste lead-acid battery may change due to reaction with the drying rack in contact with the waste lead-acid battery, we should try to ensure that the area of the lead-acid battery in contact with the drying rack is the minimum.
Example 5
A method for recovering the appearance of a waste lead-acid battery, as shown in fig. 1, comprises the following steps:
s1: cleaning dust on the outer surface of the waste lead-acid battery, and naturally drying the waste lead-acid battery in a ventilated place for later use;
s2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: putting the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2, wherein when the waste lead-acid battery is put into the liquid medicine, the plastic sealing cover and the vent hole at the top end of the waste lead-acid battery are not immersed into the liquid medicine, other parts of the waste lead-acid battery are immersed into the liquid medicine, and the waste lead-acid battery stays in the liquid medicine for 2 to 5 seconds in winter; summer 1-3 seconds.
S4: and taking out the battery, and putting the battery on an airing rack for airing.
The present embodiment is different from embodiment 1 only in that, in step S3, when the waste lead-acid battery is placed in the liquid medicine, the plastic sealing cover and the vent hole at the top end of the waste lead-acid battery are not immersed in the liquid medicine, and the other parts are immersed in the liquid medicine.
The lead-acid accumulator of general lead-acid battery has a plastic sealing cover on its top, which can be unscrewed and has a ventilation hole. These are used for filling pure water, checking an electrolyte and discharging gas. Therefore, when the waste lead-acid battery is put into the liquid medicine, the plastic sealing cover and the vent hole at the top end of the waste lead-acid battery are ensured not to be immersed into the liquid medicine, and other parts are immersed into the liquid medicine. So that the liquid medicine does not enter the electrolyte inside.
The above description is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be made by those skilled in the art without inventive work within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope defined by the claims.
Claims (5)
1. A method for recovering the appearance of a waste lead-acid battery is characterized by comprising the following steps:
s1: cleaning dust on the outer surface of the waste lead-acid battery, and naturally drying the waste lead-acid battery in a ventilated place for later use;
s2: preparing cyclohexanone 80 and turpentine 20, and mixing with medicinal liquid of 1-2-dichloroethane to mix uniformly;
s3: placing the waste lead-acid battery dried in the step S1 into the liquid medicine mixed in the step S2 and staying for 2-5 seconds in winter; stay for 1-3 seconds in summer
S4: and taking out the battery, and putting the battery on an airing rack for airing.
2. The method for recovering the appearance of the waste lead-acid battery as claimed in claim 1, wherein the method comprises the following steps: in the step S1, the surface of the waste lead-acid battery has printed characters, and the original printed characters are cleaned after the surface dust of the waste lead-acid battery is cleaned.
3. The method for recovering the appearance of the waste lead-acid battery as claimed in claim 1, wherein the method comprises the following steps: in the step S1, the air drying time is 6 hours in summer, 12 hours in winter or drying.
4. The method for recovering the appearance of the waste lead-acid battery as claimed in claim 1, wherein the method comprises the following steps: when the battery is dried in the step S4, the area of the battery contacting the drying rack is minimized.
5. The method for recovering the appearance of the waste lead-acid battery as claimed in claim 1, wherein the method comprises the following steps: in the step S3, when the waste lead-acid battery is placed in the liquid medicine, the plastic sealing cover and the vent hole at the top end of the waste lead-acid battery are not immersed in the liquid medicine, and other parts are immersed in the liquid medicine.
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