CN111873599A - Manufacturing method of waterproof disk and waterproof disk - Google Patents
Manufacturing method of waterproof disk and waterproof disk Download PDFInfo
- Publication number
- CN111873599A CN111873599A CN202010766228.7A CN202010766228A CN111873599A CN 111873599 A CN111873599 A CN 111873599A CN 202010766228 A CN202010766228 A CN 202010766228A CN 111873599 A CN111873599 A CN 111873599A
- Authority
- CN
- China
- Prior art keywords
- quartz stone
- smc
- waterproof
- manufacturing
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
Abstract
The application relates to a manufacturing method of a waterproof disc and the waterproof disc, wherein the manufacturing method comprises the following steps of: lay the quartzy slabstone on the mould surface, throw material to the mould with SMC sheet moulding compound in, compression molding obtains the compound product of quartzy stone and SMC, has solved the waterproof dish of pure SMC promptly and has not wear-resisting, the mar not, intensity, the not enough problem of toughness, has solved the installation of pure quartzy stone as waterproof dish again, the problem of leaking. The application not only improves various comprehensive performances of the integral bathroom waterproof plate, but also ensures the convenient and integrated performance of the integral bathroom waterproof plate, so that the integral bathroom waterproof plate is wear-resistant and the strength and toughness of the integral bathroom waterproof plate are improved; and simultaneously improves the performances of surface scratch resistance and the like.
Description
The application is a divisional application of an invention patent application with the application date of 2017, 8 and 21, and the application number of 201710716820.4, and the invention name of the invention is 'a manufacturing method of a waterproof disc and the waterproof disc'.
Technical Field
The application relates to a manufacturing method of a waterproof plate of an integral bathroom and the waterproof plate.
Background
The artificial quartz stone is a synthetic stone manufactured by a manual method, and has the advantages of strong acid resistance, corrosion resistance, abrasion resistance, high temperature resistance, impact resistance, compression resistance, fracture resistance, permeation resistance, easy cleaning, convenient construction and the like; the color of the patterns can be controlled manually, the appearance can imitate marble, granite and the like, the decorative plate not only has the elegance of natural marble and the hardness of granite, but also has the fineness and the warm feeling like wood, and also has the luster like ceramic and plasticity, and the treatment of the deformation, the adhesion, the turning and other parts has unique points, can be made into any shape, is combined with beauty and practicability, and is an ideal modern building decorative material.
SMC (Sheet molding compound) is a Sheet material composed of unsaturated polyester resin, low shrinkage additive, filler, curing agent, thickener, mold release agent, glass fiber, etc., and has the characteristics of low shrinkage, high strength, convenient molding, etc., and its mechanical properties are comparable to those of some metal materials, so that it is widely used in vehicle housings, pressure-bearing backing plates, bathtubs and purification tanks in building facilities, switch housings and partition boards in the electronic industry, etc.
In the prior art, the waterproof disk is made of pure quartz stone materials or pure SMC materials, the waterproof disk made of the pure quartz stone materials has the problems of inconvenient installation and water leakage, and the waterproof disk made of the pure SMC materials is not wear-resistant, is not cross-scratch-resistant and has insufficient strength and toughness.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a manufacturing method of a waterproof disc and the waterproof disc.
In order to solve the technical problems, the invention adopts the following technical scheme:
a manufacturing method of a waterproof disc comprises the following steps of compression molding: and paving a quartz stone plate with the thickness of 4-8mm on the surface of the mold, feeding SMC sheet molding compound into the mold, and performing compression molding to obtain a quartz stone and SMC composite product.
Wherein, the thickness of the quartz stone plate is preferably 6 mm. If the thickness of the quartz stone plate is too thick, the mould pressing combination of the quartz stone and the SMC is influenced, and the optimal quartz stone and SMC composite product can be obtained after the quartz stone plate and SMC sheet moulding compound with the thickness of 4-8mm are mould pressed.
Preferably, in the compression molding step, the temperature of the front surface of the mold is 135-155 ℃, the temperature of the back surface of the mold is 125-140 ℃, and the compression molding pressure of the mold is 20-80 kg/cm2The molding time is 120-360 seconds.
Preferably, the manufacturing method further comprises the steps of: mixing and stirring raw materials for manufacturing the quartz stone plate to be uniform, vacuumizing, pressing, forming and curing.
Preferably, the preparation steps of the quartz stone plate are as follows: mixing and stirring raw materials for manufacturing the quartz stone plate to be uniform, after vacuumizing, distributing the materials to be uniform in thickness through a distribution system, and then curing and molding the materials at the temperature of 20-90 ℃ through a mold to obtain the high-hardness quartz stone matt product.
Preferably, the step of preparing the quartz stone plate further comprises polishing the quartz stone matte product to obtain the quartz stone plate with a bright surface.
Preferably, the raw materials of the quartz stone plate comprise, by mass, 5% -20% of acrylic resin, 65% -80% of quartz sand, 0.1% -5% of a silane coupling agent, 0.1% -5% of a curing agent and 0-5% of a pigment.
Preferably, the SMC sheet molding compound comprises the following raw materials in parts by mass: 80-95 parts of unsaturated resin; 5-20 parts of a low shrinkage agent; 30-180 parts of a filler; 1-2 parts of an initiator; 2-10 parts of an internal release agent; 0.5-2 parts of thickening agent.
Preferably, the SMC sheet molding compound is prepared by uniformly stirring and mixing the raw materials according to the proportion to prepare resin paste; coating the resin paste on the upper and lower polyethylene films, uniformly scattering glass fiber sections on the resin paste, extruding and compounding to fully soak the resin paste and the glass fiber; and thickening the rolled sheet in a thickening chamber to prepare SMC sheet molding compound.
The application also provides a waterproof disc manufactured by the manufacturing method, and the waterproof disc is manufactured by a quartz stone and SMC composite product.
Due to the adoption of the technical scheme, compared with the prior art, the invention has the following advantages:
the application waterproof dish, use quartzy stone material and SMC material suppression to form, solved the waterproof dish of pure SMC promptly and not wear-resisting, not resistant mar, intensity, problem that toughness is not enough, solved the installation of pure quartzite as waterproof dish again, the problem of leaking. The application not only improves various comprehensive performances of the integral bathroom waterproof plate, but also ensures the convenient and integrated performance of the integral bathroom waterproof plate, so that the integral bathroom waterproof plate is wear-resistant and the strength and toughness of the integral bathroom waterproof plate are improved; and simultaneously improves the performances of surface scratch resistance and the like.
Detailed Description
The present invention will be described in further detail with reference to specific examples. It is to be understood that these embodiments are provided to illustrate the general principles, major features and advantages of the present invention, and the present invention is not limited in scope by the following embodiments. The implementation conditions used in the examples can be further adjusted according to specific requirements, and the implementation conditions not indicated are generally the conditions in routine experiments.
Example 1
A manufacturing method of a waterproof disc comprises the following steps:
the manufacturing method of the quartz stone plate comprises the following steps: mixing and stirring raw materials for manufacturing the quartz stone slab to be uniform, after vacuumizing, distributing the materials to be uniform in thickness through a distribution system, then curing and molding the materials at the temperature of 20 ℃ through a mold to obtain the quartz matte board, and polishing the quartz matte board to obtain the quartz stone slab with the thickness of 4mm and bright surface. In this embodiment, the raw materials for manufacturing the quartz stone slab include, by mass, 5% of acrylic resin, 80% of quartz sand, 5% of a silane coupling agent, 5% of a curing agent, and 5% of a pigment.
SMC sheet molding compound preparation: the SMC sheet molding compound comprises 95 parts of unsaturated resin according to the mass part; 5 parts of low shrinkage agent(ii) a 30 parts of a filler; 1 part of an initiator; 2 parts of an internal release agent; 0.5 part of thickening agent. Uniformly stirring and mixing all the raw materials according to the proportion to prepare resin paste; coating the resin paste on the upper and lower polyethylene films, uniformly scattering glass fiber sections on the resin paste, extruding and compounding to fully soak the resin paste and the glass fiber; and thickening the rolled sheet in a thickening chamber to prepare SMC sheet molding compound. And (3) carrying out die pressing by adopting a 1000T press during extrusion compounding, wherein the temperatures of the front and the back of the die are 145 ℃ and 136 ℃ respectively, and the die pressing pressure is as follows: 50kg/cm2And the forming time is 180 seconds, the thickness of the final product is 3 millimeters, trimming is carried out after the die pressing is finished, and flash on the periphery of the product is finished. In this example, the shrinkage of the SMC was 0.02%.
A compression molding step: paving a quartz stone plate on the surface of a mould, feeding SMC sheet molding compound into the mould, and carrying out compression molding to obtain a quartz stone and SMC composite product, wherein in the step, the front side of the mould is in contact with the quartz stone plate, the back side of the mould is in contact with the SMC sheet molding compound, the temperature of the front side of the mould is 135 ℃, the temperature of the back side of the mould is 125 ℃, and the molding pressure of the mould is 20kg/cm2The molding time was 360 seconds.
Example 2
A manufacturing method of a waterproof disc comprises the following steps:
the manufacturing method of the quartz stone plate comprises the following steps: the method comprises the steps of mixing and stirring raw materials for manufacturing the quartz stone slab to be uniform, after vacuumizing, distributing the materials to be uniform in thickness through a distribution system, then curing and molding the materials at the temperature of 29 ℃ through a mold to obtain a high-hardness quartz stone matte product, polishing the quartz stone matte product to obtain the quartz stone slab with the thickness of 6mm and a bright surface, wherein the raw materials comprise 20% of acrylic resin, 65% of quartz sand, 5% of a silane coupling agent, 5% of a curing agent and 5% of a pigment in percentage by mass.
SMC sheet molding compound preparation: uniformly stirring and mixing all the raw materials according to the proportion to prepare resin paste; coating the resin paste on the upper and lower polyethylene films, uniformly scattering glass fiber sections on the resin paste, extruding and compounding to fully soak the resin paste and the glass fiber; thickening the rolled sheetThickening indoors to prepare SMC sheet molding compound. The SMC sheet molding compound comprises 80 parts of unsaturated resin by mass; 20 parts of a low shrinkage agent; 180 parts of a filler; 2 parts of an initiator; 10 parts of an internal release agent; and 2 parts of a thickening agent. And (3) carrying out die pressing by adopting a 3000T press during extrusion compounding, wherein the temperatures of the front and the back of the die are 145 ℃ and 136 ℃ respectively, and the die pressing pressure is as follows: 50kg/cm2And the forming time is 180 seconds, the thickness of the final product is 3 millimeters, trimming is carried out after the die pressing is finished, and flash on the periphery of the product is finished. The SMC had a shrinkage of 0.1%.
A compression molding step: paving a quartz stone plate on the surface of a mould, feeding SMC sheet molding compound into the mould, and carrying out compression molding to obtain a quartz stone and SMC composite product, wherein in the step, the front side of the mould is in contact with the quartz stone plate, the back side of the mould is in contact with the SMC sheet molding compound, the temperature of the front side of the mould is 155 ℃, the temperature of the back side of the mould is 140 ℃, and the molding pressure of the mould is 80kg/cm2The molding time was 120 seconds.
Example 3
A manufacturing method of a waterproof disc comprises the following steps:
the manufacturing method of the quartz stone plate comprises the following steps: mixing and stirring raw materials for manufacturing the quartz stone slab to be uniform, after vacuumizing, distributing the materials to be uniform in thickness through a distribution system, then curing and molding the materials at the temperature of 29 ℃ through a mold to obtain a high-hardness quartz stone matte product, and polishing the quartz stone matte product to obtain the quartz stone slab with the thickness of 8mm and a bright surface, wherein the raw materials comprise 19.8% of acrylic resin, 80% of quartz sand, 0.1% of silane coupling agent and 0.1% of curing agent in percentage by mass.
SMC sheet molding compound preparation: uniformly stirring and mixing all the raw materials according to the proportion to prepare resin paste; coating the resin paste on the upper and lower polyethylene films, uniformly scattering glass fiber sections on the resin paste, extruding and compounding to fully soak the resin paste and the glass fiber; and thickening the rolled sheet in a thickening chamber to prepare SMC sheet molding compound. The SMC sheet molding compound comprises 85 parts of unsaturated resin by mass; 15 parts of a low shrinkage agent; filler 100Preparing; 1.5 parts of an initiator; 6 parts of an internal release agent; 1.5 parts of thickening agent. And (3) carrying out die pressing by adopting a 1500T press during extrusion compounding, wherein the temperatures of the front and the back of the die are 145 ℃ and 136 ℃ respectively, and the die pressing pressure is as follows: 50kg/cm2And the forming time is 180 seconds, the thickness of the final product is 3 millimeters, trimming is carried out after the die pressing is finished, and flash on the periphery of the product is finished. The SMC had a shrinkage of 0.05%.
A compression molding step: paving a quartz stone plate on the surface of a mould, feeding SMC sheet molding compound into the mould, and carrying out compression molding to obtain a quartz stone and SMC composite product, wherein in the step, the front side of the mould is in contact with the quartz stone plate, the back side of the mould is in contact with the SMC sheet molding compound, the temperature of the front side of the mould is 145 ℃, the temperature of the back side of the mould is 135 ℃, and the molding pressure of the mould is 60kg/cm2The molding time was 240 seconds.
As a preferred embodiment, acrylic resin is used in the raw material of the quartz stone plate, the acrylic resin has thermoplasticity, and after the quartz stone plate and the SMC sheet molding compound are molded, the adhesion between the quartz stone layer and the SMC layer is firm.
The SMC sheet molding compound controls the shrinkage rate of SMC between 0.02% and 0.1% by adjusting the proportion of unsaturated resin and low shrinkage additive in the formula, so as to ensure that a product is firmly bonded after a quartz plate and SMC are integrally molded.
In some comparative examples, when a quartz stone plate made of a general resin was compression-molded with SMC, the adhesion between the quartz stone layer and the SMC layer was weak and the quartz stone layer was easily detached.
Table 1 shows the results of performance tests on the waterproof disks made of the quartz stone slabs and SMC composite products of examples 1-3 of the present application compared to a pair of a pure SMC moulded waterproof disk:
TABLE 1 comparison of Performance test results
The above conclusion data show that the waterproof disk made of the composite product of the quartz stone plate and the SMC of the embodiment of the application has greatly improved acid resistance, corrosion resistance, wear resistance, breaking strength, compressive strength and bending strength compared with the molded waterproof disk made of pure SMC in the comparative example, and various comprehensive properties of the waterproof disk of the integral bathroom are improved.
Table 2 shows a comparison of the prior art SMC sheet molding compound with the components of the examples.
TABLE 2 SMC sheet Molding Compound composition
Raw material | Comparative example 1 | Comparative example 2 | Example 1 | Example 2 | Example 3 |
Unsaturated resin | 70g | 98g | 95g | 80g | 85g |
Low shrinkage agent | 30g | 2g | 5g | 20g | 15g |
Filler material | 30g | 100g | 30g | 180g | 100g |
Initiator | 1g | 1.5g | 1g | 2g | 1.5g |
Internal mold release agent | 2g | 6g | 2g | 10g | 6g |
Thickening agent | 0.5g | 1.5g | 0.5g | 2g | 1.5g |
Table 3 shows a comparison of the properties of the SMC sheet molding compounds made with the components of Table 2 under the same fabrication conditions.
TABLE 3 comparison of the Properties of SMC sheet Molding Compounds
Comparative example 1 | Comparative example 2 | Example 1 | Example 2 | Example 3 | |
Shrinkage (Normal temperature and pressure) | 0.15% | 0.01% | 0.02% | 0.1% | 0.05% |
As can be seen from tables 2 and 3, the ratio of each raw material component is different, and the shrinkage of the SMC sheet molding compound is greatly affected. In the examples of the present application, the shrinkage of the SMC sheet molding compound is significantly less compared to the prior art. The shrinkage rate of the SMC sheet molding compound seriously affects the bonding firmness of the product after the quartz plate and the SMC are integrally molded.
The present invention has been described in detail, and the embodiments are only used for understanding the method and the core idea of the present invention, and the purpose of the present invention is to enable those skilled in the art to understand the content of the present invention and to implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.
Claims (10)
1. The manufacturing method of the waterproof disc is characterized by comprising the following steps of: paving a quartz stone plate with the thickness of 4-8mm on the surface of a mould, feeding SMC sheet molding compound into the mould, and carrying out compression molding to obtain a composite product of quartz stone and SMC;
the raw and other materials of quartzy slabstone include ya keli resin, inferior gram force resin has the thermoplasticity, inferior gram force resin is used for bonding quartzy stone layer and SMC layer when quartzy slabstone and SMC sheet moulding compound compression molding.
2. The method for manufacturing the waterproof disk according to claim 1, wherein the thickness of the quartz stone plate is 6 mm.
3. The method for manufacturing the waterproof disc as claimed in claim 1, wherein in the compression molding step, the temperature of the front surface of the mold is 135-155 ℃, the temperature of the back surface of the mold is 125-140 ℃, and the molding pressure of the mold is 20-80 kg/cm2The molding time is 120-360 seconds.
4. The method of claim 1, further comprising the step of preparing the quartz stone slab by: mixing and stirring raw materials for manufacturing the quartz stone plate to be uniform, distributing after vacuumizing, and forming and curing.
5. The method for manufacturing a waterproof plate according to claim 4, wherein the quartz stone plate is prepared by the following steps: mixing and stirring raw materials for manufacturing the quartz stone slab to be uniform, after vacuumizing, distributing the materials to be uniform in thickness through a distribution system, and then curing and molding the materials at the temperature of 20-90 ℃ through a mold to obtain the quartz stone matte board.
6. The method for manufacturing a waterproof disk according to claim 5, wherein the step of preparing the quartz stone slab further comprises polishing the quartz stone matte plate to obtain a quartz stone slab with a bright surface.
7. The method of claim 6, wherein the raw materials of the quartz stone slab comprise: 5-20% of acrylic resin, 65-80% of quartz sand, 0.1-5% of silane coupling agent, 0.1-5% of curing agent and 0-5% of pigment by mass percent.
8. The method for manufacturing the waterproof plate as claimed in claim 4, wherein the SMC sheet molding compound comprises the following raw materials in parts by mass: 80-95 parts of unsaturated resin; 5-20 parts of a low shrinkage agent; 30-180 parts of a filler; 1-2 parts of an initiator; 2-10 parts of an internal release agent; 0.5-2 parts of thickening agent.
9. The method for manufacturing a waterproof disk according to claim 8, wherein: the SMC sheet molding compound is prepared by the steps of uniformly stirring and mixing the raw materials according to the proportion to prepare resin paste; coating the resin paste on the upper and lower polyethylene films, uniformly scattering small sections of glass fibers on the resin paste, extruding and compounding to fully soak the resin paste and the glass fibers to form SMC sheets, and thickening the SMC sheets to prepare the SMC sheet molding compound.
10. The waterproof plate manufactured by the manufacturing method of any one of claims 1 to 9, characterized in that: the waterproof plate is made of a composite product of the quartz stone and the SMC.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010766228.7A CN111873599B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710716820.4A CN107512064B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
CN202010766228.7A CN111873599B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710716820.4A Division CN107512064B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111873599A true CN111873599A (en) | 2020-11-03 |
CN111873599B CN111873599B (en) | 2022-12-13 |
Family
ID=60723421
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010766228.7A Active CN111873599B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
CN201710716820.4A Active CN107512064B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710716820.4A Active CN107512064B (en) | 2017-08-21 | 2017-08-21 | Manufacturing method of waterproof disk and waterproof disk |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN111873599B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113729527A (en) * | 2021-09-08 | 2021-12-03 | 广水科逸住宅设备有限公司 | Waterproof plate and preparation method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116530861A (en) * | 2018-07-02 | 2023-08-04 | 苏州科硕住宅科技有限公司 | Waterproof disc |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1103616A (en) * | 1994-10-18 | 1995-06-14 | 张茂安 | Structural product with colour stone effect and its producing method |
WO2005051648A1 (en) * | 2003-11-28 | 2005-06-09 | Inax Corporation | Temperature sensitive member, method of manufacturing the member, sheet for thermal insulating part, and method of modifying waterproof pan for bathroom |
CN102746466A (en) * | 2011-06-10 | 2012-10-24 | 泰州科逸新材料有限公司 | Resin composition for high water resistance sheet molding compound, high water resistance sheet molding compound, and high water resistance bathtub |
CN103553430A (en) * | 2013-11-06 | 2014-02-05 | 江门市德山复合材料科技有限公司 | Artificial acrylic quartz stone slab and preparation method thereof |
CN104556832A (en) * | 2015-01-06 | 2015-04-29 | 武汉石尚高新建材有限公司 | Preparation method of artificial quartzite plate |
CN204541406U (en) * | 2015-01-30 | 2015-08-12 | 陈月馀 | A kind of quartz composite platform |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101337805B (en) * | 2008-08-25 | 2012-01-11 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
JP5727462B2 (en) * | 2010-03-24 | 2015-06-03 | 電気化学工業株式会社 | Surface conductive laminated sheet and electronic component packaging container |
CN102092163B (en) * | 2010-12-09 | 2013-07-31 | 苏州科逸住宅设备股份有限公司 | Glassfibre reinforced plastics and preparation method thereof |
CN203296300U (en) * | 2013-05-31 | 2013-11-20 | 成都汇玉科技产业有限公司 | Synthetic quartz stone hollow plastic composite decorative plate |
-
2017
- 2017-08-21 CN CN202010766228.7A patent/CN111873599B/en active Active
- 2017-08-21 CN CN201710716820.4A patent/CN107512064B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1103616A (en) * | 1994-10-18 | 1995-06-14 | 张茂安 | Structural product with colour stone effect and its producing method |
WO2005051648A1 (en) * | 2003-11-28 | 2005-06-09 | Inax Corporation | Temperature sensitive member, method of manufacturing the member, sheet for thermal insulating part, and method of modifying waterproof pan for bathroom |
CN102746466A (en) * | 2011-06-10 | 2012-10-24 | 泰州科逸新材料有限公司 | Resin composition for high water resistance sheet molding compound, high water resistance sheet molding compound, and high water resistance bathtub |
CN103553430A (en) * | 2013-11-06 | 2014-02-05 | 江门市德山复合材料科技有限公司 | Artificial acrylic quartz stone slab and preparation method thereof |
CN104556832A (en) * | 2015-01-06 | 2015-04-29 | 武汉石尚高新建材有限公司 | Preparation method of artificial quartzite plate |
CN204541406U (en) * | 2015-01-30 | 2015-08-12 | 陈月馀 | A kind of quartz composite platform |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113729527A (en) * | 2021-09-08 | 2021-12-03 | 广水科逸住宅设备有限公司 | Waterproof plate and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN111873599B (en) | 2022-12-13 |
CN107512064A (en) | 2017-12-26 |
CN107512064B (en) | 2020-07-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20120283087A1 (en) | Synthetic quartz composition and production process therefor | |
CN107512064B (en) | Manufacturing method of waterproof disk and waterproof disk | |
WO2015074321A1 (en) | Thermoplastic resin composite material and application thereof | |
CN112373073B (en) | Preparation process of synthetic quartz stone imitating three-dimensional texture of natural stone | |
CN105060776A (en) | Composite artificial stone table board and preparation method thereof | |
CN103189327A (en) | Synthetic acrylic marble having pearl-containing pattern and method of producing the same | |
EP2347688B1 (en) | Resin-based composite material sanitary appliance and manufacturing method thereof | |
CN109369067A (en) | Novel artificial composite board and preparation method | |
CN203267335U (en) | Bathroom equipment | |
CN101474827B (en) | Normal temperature manufacturing process for MMA high-intensity artificial stone special-shaped pot/trough | |
CN111635181A (en) | Fiber cement board for floor and preparation method and application thereof | |
KR101299270B1 (en) | Artificial marble containing waste glass chip of plate type and method for fabricating thereof | |
CN109664395A (en) | Quartzite slate of imitation marble and preparation method thereof | |
CN109161132A (en) | Polyvinyl chloride automotive trim panel and preparation method thereof | |
CN1100365A (en) | Metallic glass fibre reinforced plastic material and its producing technology | |
US20190126570A1 (en) | Manufacturing method of color decorative plate | |
CN105694795B (en) | Wallboard for integral bathroom and preparation method thereof | |
CN111944201B (en) | Nano antibacterial agent and preparation method thereof, stain-resistant antibacterial resin composition, sheet molding compound and stain-resistant antibacterial bathtub | |
CN101019717A (en) | Composite top board and its making process | |
CN102816421A (en) | Large-particle granite imitated bulk molding compound and molding method thereof | |
CN101705036B (en) | Coating capable of replacing electroplated decorative chromium layer | |
CN113416019B (en) | Hot-press molded granite kitchen sink and preparation process thereof | |
CN219055634U (en) | Glass fiber reinforced plastic structure with artificial stone effect | |
CN102726966A (en) | Table top plate manufactured by covering acryl materials on PVC (polyvinyl chloride) wood plastic plate | |
CA2698643C (en) | A resin-based composite sanitary ware and preparation method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |