CN111849089A - Super-hydrophobic self-cleaning PVC composite material and preparation method thereof - Google Patents
Super-hydrophobic self-cleaning PVC composite material and preparation method thereof Download PDFInfo
- Publication number
- CN111849089A CN111849089A CN202010795192.5A CN202010795192A CN111849089A CN 111849089 A CN111849089 A CN 111849089A CN 202010795192 A CN202010795192 A CN 202010795192A CN 111849089 A CN111849089 A CN 111849089A
- Authority
- CN
- China
- Prior art keywords
- parts
- composite material
- temperature
- super
- pvc composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 37
- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 238000004140 cleaning Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 32
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 21
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 21
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 21
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 12
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 12
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 12
- 238000001125 extrusion Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000004605 External Lubricant Substances 0.000 claims abstract description 5
- 239000004610 Internal Lubricant Substances 0.000 claims abstract description 5
- 238000005461 lubrication Methods 0.000 claims description 14
- 239000003381 stabilizer Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 10
- 238000004381 surface treatment Methods 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 238000007788 roughening Methods 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims 1
- 238000005498 polishing Methods 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides a super-hydrophobic self-cleaning PVC composite material and a preparation method thereof, relating to the technical field of new materials and processing, wherein the composite material comprises the following components in parts by weight: 100 parts of PVC, 30-100 parts of polytetrafluoroethylene, 3-6 parts of heat stabilizer, 0.1-0.5 part of internal lubricant, 0.5-2 parts of external lubricant, 1-10 parts of chlorinated polyethylene and 1-15 parts of processing aid. The method comprises the following steps: uniformly mixing at high speed according to the weight fraction; carrying out sheet extrusion molding processing on the mixed material, wherein the processing temperature range is 170-210 ℃; and (4) polishing the surface of the high-temperature sheet just exiting from the mold. The super-hydrophobic self-cleaning PVC composite material prepared by the invention is simple and convenient in method, green and environment-friendly, can be processed and formed at one time, and is suitable for industrial production.
Description
Technical Field
The invention relates to a new material and a processing method, in particular to a super-hydrophobic self-cleaning PVC composite material and a preparation method thereof.
Background
The super-hydrophobic material has a plurality of unique surface properties, such as self-cleaning, corrosion prevention, super-hydrophobicity and the like, so that the super-hydrophobic material has wide application scenes in production and life, such as antifogging and antiscaling of glass surfaces, desert water collection, self-cleaning building materials, waterproof and antifouling of textiles, waterproof and antifouling treatment and the like. In recent years, with the increasing attention of super-hydrophobic materials, artificially prepared super-hydrophobic materials are continuously appearing, such as super-hydrophobic coatings, super-hydrophobic films, super-hydrophobic gels, super-hydrophobic fabrics, super-hydrophobic metal surfaces and the like. However, research on superhydrophobicity of commonly used general-purpose plastics (e.g., PP, PE, PVC, etc.) has been rarely reported.
The PVC material has the advantages of high mechanical strength, good heat resistance, low cost, good chemical resistance, difficult corrosion, long service life and the like, and is widely applied to the aspect of building materials. For example, in a PVC drain pipe, impurities in the discharged sewage are easily adhered to the inner wall of the pipe to form dirt, which increases the fluid resistance of the pipe and reduces the sewage discharge capacity.
At present, most methods for improving the hydrophobicity of materials are to spray a super-hydrophobic coating on the surface or carry out simple surface treatment, but the coating is easy to peel off and has short service life; the surface treatment mostly adopts an etching method, and the environmental pollution is relatively large.
The present application was made based on this.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a super-hydrophobic self-cleaning PVC composite material and a preparation method thereof, and the preparation method is environment-friendly and simple.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a super-hydrophobic self-cleaning PVC composite material comprises the following components in parts by weight: 100 parts of PVC, 30-100 parts of polytetrafluoroethylene, 3-6 parts of heat stabilizer, 0.1-0.5 part of internal lubricant, 0.5-2 parts of external lubricant, 1-10 parts of chlorinated polyethylene and 1-15 parts of processing aid.
Further, the polymerization degree of the PVC powder is 700-1100.
Furthermore, the particle size of the polytetrafluoroethylene powder is 2-10 μm.
Further, the heat stabilizer is one of a lead salt stabilizer, a calcium zinc stabilizer or an organic tin stabilizer.
A preparation method of a super-hydrophobic self-cleaning PVC composite material comprises the following steps:
(1) mixing materials: respectively weighing PVC, polytetrafluoroethylene, a stabilizer, internal lubrication, external lubrication, chlorinated polyethylene and a processing aid according to the proportion, adding the materials into a high-speed mixer, mixing at high speed until the temperature reaches 110-120 ℃, then cold mixing until the temperature reaches 50-60 ℃, and discharging;
(2) extruding and molding by a double-screw extruder: during extrusion, the temperature of the first zone is 170-180 ℃, the temperature of the second zone is 185-195 ℃, the temperature of the third zone is 180-190 ℃, the temperature of the fourth zone is 180-190 ℃, the temperature of the fifth zone is 175-185 ℃, and the temperature of the head is 190-210 ℃;
(3) surface treatment: when the material is extruded out of the neck mold, the surface of the neck mold is polished to remove a melt film on the surface of an extruded sheet, and simultaneously, the roughening treatment of the surface of the PVC composite material is realized.
Further, the surface treatment process is completed when the material is just extruded out of the die and the temperature is kept above 170 ℃.
The invention has the advantages of super-hydrophobic principle and realization:
(1) the invention utilizes the low surface energy of the polytetrafluoroethylene, and the polytetrafluoroethylene can be mixed with the PVC to reduce the integral surface energy of the material.
(2) The invention controls the dispersion effect of the polytetrafluoroethylene particles on the surface of the extruded sheet by regulating and controlling the content of the polytetrafluoroethylene.
(3) According to the invention, through polishing the surface of the high-temperature PVC sheet, the molten film on the surface of the sheet can be removed, so that as many polytetrafluoroethylene particles as possible are exposed, and a micro concave-convex structure can be constructed, so that the super-hydrophobicity of PVC is realized.
(4) The super-hydrophobic PVC composite material prepared by the invention has good self-cleaning property and good mechanical property.
(5) The raw materials required by the super-hydrophobic self-cleaning PVC composite material prepared by the invention are sold in the market, are easy to obtain, have simple preparation process and are easy to realize industrial continuous production.
(6) The PVC composite material prepared by the invention has a super-hydrophobic surface which is not easy to damage and is suitable for long-term use.
In conclusion, the super-hydrophobic self-cleaning PVC composite material prepared by the invention is prepared by adopting a traditional extrusion molding mode, is simple and convenient in method, is green and environment-friendly, can be processed and molded at one time, and is suitable for industrial production.
Detailed Description
In order to make the technical means of the present invention and the technical effects achieved by the technical means more clear and more complete disclosure, 3 embodiments are provided:
example 1
The super-hydrophobic self-cleaning PVC composite material comprises the following components in parts by weight: 100 parts of PVC, 30 parts of polytetrafluoroethylene, 3.5 parts of heat stabilizer, 0.4 part of internal lubricant, 0.6 part of external lubricant, 3 parts of chlorinated polyethylene and 1.5 parts of processing aid.
The polymerization degree of the PVC powder is 1000.
The particle size of the polytetrafluoroethylene powder is 2-10 μm.
The heat stabilizer is lead salt stabilizer.
The preparation method of the oil-stain-resistant non-stick PVC composite material comprises the following steps:
(1) mixing materials: respectively weighing PVC, polytetrafluoroethylene, a stabilizer, internal lubrication, external lubrication, chlorinated polyethylene and a processing aid according to the proportion, adding the materials into a high-speed mixer, mixing at high speed until the temperature reaches 120 ℃, then cold mixing until the temperature reaches 60 ℃, and discharging;
(2) the mixture is extruded and molded by a double-screw extruder, and the temperature of a first zone is 170 ℃, the temperature of a second zone is 195 ℃, the temperature of a third zone is 185 ℃, the temperature of a fourth zone is 180 ℃, the temperature of a fifth zone is 180 ℃, and the temperature of a machine head is 200 ℃ during extrusion.
(3) And (3) surface treatment, namely polishing the surface of the material when the material is extruded out of the neck mold.
Example 2
The super-hydrophobic self-cleaning PVC composite material comprises the following components in parts by weight: 100 parts of PVC, 50 parts of polytetrafluoroethylene, 4 parts of heat stabilizer, 0.4 part of internal lubrication, 0.6 part of external lubrication, 3 parts of chlorinated polyethylene and 1.5 parts of processing aid.
The polymerization degree of the PVC powder is 1000.
The particle size of the polytetrafluoroethylene powder is 2-10 μm.
The heat stabilizer is calcium zinc stabilizer.
The preparation method of the super-hydrophobic self-cleaning PVC composite material comprises the following steps:
(1) mixing materials: respectively weighing PVC, polytetrafluoroethylene, a stabilizer, internal lubrication, external lubrication, chlorinated polyethylene and a processing aid according to the proportion, adding the materials into a high-speed mixer, mixing at high speed until the temperature reaches 110 ℃, then cold mixing until the temperature reaches 60 ℃, and discharging;
(2) the mixture is extruded and molded by a double-screw extruder, and during extrusion, the temperature of a first zone is 170 ℃, the temperature of a second zone is 190 ℃, the temperature of a third zone is 185 ℃, the temperature of a fourth zone is 180 ℃, the temperature of a fifth zone is 180 ℃, and the temperature of a machine head is 210 ℃.
(3) And (3) surface treatment, namely polishing the surface of the material when the material is extruded out of the neck mold.
Example 3
The super-hydrophobic self-cleaning PVC composite material comprises the following components in parts by weight: 100 parts of PVC, 60 parts of polytetrafluoroethylene, 3.5 parts of heat stabilizer, 0.4 part of internal lubricant, 0.6 part of external lubricant, 4 parts of chlorinated polyethylene and 2 parts of processing aid.
The polymerization degree of the PVC powder is 1000.
The particle size of the polytetrafluoroethylene powder is 2-10 μm.
The heat stabilizer is lead salt stabilizer.
The preparation method of the super-hydrophobic self-cleaning PVC composite material comprises the following steps:
(1) mixing materials: respectively weighing PVC, polytetrafluoroethylene, a stabilizer, internal lubrication, external lubrication, chlorinated polyethylene and a processing aid according to the proportion, adding the materials into a high-speed mixer, mixing at high speed until the temperature reaches 120 ℃, then cold mixing until the temperature reaches 60 ℃, and discharging;
(2) the mixture is extruded and molded by a double-screw extruder, and the temperature of a first zone is 170 ℃, the temperature of a second zone is 195 ℃, the temperature of a third zone is 185 ℃, the temperature of a fourth zone is 180 ℃, the temperature of a fifth zone is 180 ℃, and the temperature of a machine head is 210 ℃ during extrusion.
(3) And (3) surface treatment, namely polishing the surface of the material when the material is extruded out of the neck mold.
Comparative example:
the PVC composite material comprises the following components in parts by weight: 100 parts of PVC, 30 parts of calcium carbonate, 3.5 parts of heat stabilizer, 0.4 part of internal lubrication, 0.6 part of external lubrication, 2 parts of chlorinated polyethylene and 1 part of processing aid.
The preparation method comprises the steps of material mixing and extrusion molding.
TABLE 1 test results of the samples
| Testing performance | Example 1 | Example 2 | Example 3 | Comparative example | Standard of merit |
| Tensile Strength (MPa) | 35.3 | 33.3 | 30.5 | 39.0 | GB/T8804.2-2003 |
| Elongation at Break (%) | 21.9 | 52.4 | 46.1 | 43.6 | GB/T8804.2-2003 |
| Water contact Angle (°) | 149.3 | 158.7 | 160.4 | 94.4 | Instrumental self-test |
The larger the contact angle, the better the hydrophobicity, as can be seen from the test results in the above table, and the hydrophobicity is better in examples 1, 2, and 3 than in comparative examples. The water contact angles of the PVC composite materials in the embodiment 2 and the embodiment 3 are both larger than 150 degrees, and the super-hydrophobic property and the self-cleaning property of the materials are realized. And the super-hydrophobic self-cleaning PVC composite material is placed in a high-temperature environment of 70 ℃ for heat treatment for 2h, the super-hydrophobic characteristic can still be maintained, and the surface structure is not easy to damage.
The above description is provided for the purpose of further elaboration of the technical solutions provided in connection with the preferred embodiments of the present invention, and it should not be understood that the embodiments of the present invention are limited to the above description, and it should be understood that various simple deductions or substitutions can be made by those skilled in the art without departing from the spirit of the present invention, and all such alternatives are included in the scope of the present invention.
Claims (6)
1. A super-hydrophobic self-cleaning PVC composite material is characterized in that: the paint comprises the following components in parts by weight: 100 parts of PVC, 30-100 parts of polytetrafluoroethylene, 3-6 parts of heat stabilizer, 0.1-0.5 part of internal lubricant, 0.5-2 parts of external lubricant, 1-10 parts of chlorinated polyethylene and 1-15 parts of processing aid.
2. The superhydrophobic self-cleaning PVC composite material of claim 1, wherein the degree of polymerization of the PVC powder is 700-1100.
3. The superhydrophobic self-cleaning PVC composite material of claim 1, wherein the polytetrafluoroethylene powder particle size is 2-10 μ ι η.
4. The superhydrophobic self-cleaning PVC composite material of claim 1, wherein the heat stabilizer is one of a lead salt stabilizer, a calcium zinc stabilizer or an organic tin stabilizer.
5. A preparation method of a super-hydrophobic self-cleaning PVC composite material comprises the following steps:
(1) mixing materials: respectively weighing PVC, polytetrafluoroethylene, a stabilizer, internal lubrication, external lubrication, chlorinated polyethylene and a processing aid according to the proportion, adding the materials into a high-speed mixer, mixing at high speed until the temperature reaches 110-120 ℃, then cold mixing until the temperature reaches 50-60 ℃, and discharging;
(2) extruding and molding by a double-screw extruder: during extrusion, the temperature of the first zone is 170-180 ℃, the temperature of the second zone is 185-195 ℃, the temperature of the third zone is 180-190 ℃, the temperature of the fourth zone is 180-190 ℃, the temperature of the fifth zone is 175-185 ℃, and the temperature of the head is 190-210 ℃;
(3) surface treatment: when the material is extruded out of the neck mold, the surface of the neck mold is polished to remove a melt film on the surface of an extruded sheet, and simultaneously, the roughening treatment of the surface of the PVC composite material is realized.
6. The preparation method of the superhydrophobic self-cleaning PVC composite material of claim 5, wherein the preparation method comprises the following steps: and (3) finishing the surface treatment process when the material is just extruded out of the die and the temperature is kept above 170 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010795192.5A CN111849089B (en) | 2020-08-10 | 2020-08-10 | Super-hydrophobic self-cleaning PVC composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010795192.5A CN111849089B (en) | 2020-08-10 | 2020-08-10 | Super-hydrophobic self-cleaning PVC composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111849089A true CN111849089A (en) | 2020-10-30 |
| CN111849089B CN111849089B (en) | 2022-05-13 |
Family
ID=72971806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010795192.5A Active CN111849089B (en) | 2020-08-10 | 2020-08-10 | Super-hydrophobic self-cleaning PVC composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111849089B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112644096A (en) * | 2021-01-14 | 2021-04-13 | 浙江同正管道技术有限公司 | High-temperature-resistant oleophobic PVC (polyvinyl chloride) material and pipe capable of being repeatedly processed and preparation method thereof |
| CN112852039A (en) * | 2021-01-07 | 2021-05-28 | 镇江博洛加新材料科技有限公司 | Composite material with self-cleaning function |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050167877A1 (en) * | 2002-03-12 | 2005-08-04 | Creavis Gesellschaft F. Techn. U. Innovation Mbh | Injection molded body having self-cleaning properties, and method for producing injection molded bodies of this type |
| CN104163990A (en) * | 2013-05-16 | 2014-11-26 | 苏州御诚数码科技有限公司 | Preparation method of polytetrafluoroethylene modified polypropylene composite material |
| CN105385059A (en) * | 2015-11-04 | 2016-03-09 | 安徽瑞丰管业有限公司 | Polyvinyl chloride tubular product and preparation method thereof |
| CN108864612A (en) * | 2018-07-21 | 2018-11-23 | 浙江德首新型建材有限公司 | Hollow spiral hush pipe and preparation method thereof |
| CN109929224A (en) * | 2019-03-01 | 2019-06-25 | 广东京兆工程塑料有限公司 | A kind of ageing-resistant PCT composite material and preparation method |
-
2020
- 2020-08-10 CN CN202010795192.5A patent/CN111849089B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050167877A1 (en) * | 2002-03-12 | 2005-08-04 | Creavis Gesellschaft F. Techn. U. Innovation Mbh | Injection molded body having self-cleaning properties, and method for producing injection molded bodies of this type |
| CN104163990A (en) * | 2013-05-16 | 2014-11-26 | 苏州御诚数码科技有限公司 | Preparation method of polytetrafluoroethylene modified polypropylene composite material |
| CN105385059A (en) * | 2015-11-04 | 2016-03-09 | 安徽瑞丰管业有限公司 | Polyvinyl chloride tubular product and preparation method thereof |
| CN108864612A (en) * | 2018-07-21 | 2018-11-23 | 浙江德首新型建材有限公司 | Hollow spiral hush pipe and preparation method thereof |
| CN109929224A (en) * | 2019-03-01 | 2019-06-25 | 广东京兆工程塑料有限公司 | A kind of ageing-resistant PCT composite material and preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112852039A (en) * | 2021-01-07 | 2021-05-28 | 镇江博洛加新材料科技有限公司 | Composite material with self-cleaning function |
| CN112644096A (en) * | 2021-01-14 | 2021-04-13 | 浙江同正管道技术有限公司 | High-temperature-resistant oleophobic PVC (polyvinyl chloride) material and pipe capable of being repeatedly processed and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111849089B (en) | 2022-05-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111849089B (en) | Super-hydrophobic self-cleaning PVC composite material and preparation method thereof | |
| CN1276043C (en) | High temperature resistance anticorrosive polyolefin composition and its use | |
| CN109679491B (en) | Corrosion-resistant anti-blocking drainage pipeline and preparation method thereof | |
| CN102174234A (en) | Base station antenna polyvinyl chloride (PVC) profile housing with surface self-cleaning function and preparation method thereof | |
| CN105385007A (en) | Preparation method of polyethylene pipe for delivering chemical products | |
| CN113357446A (en) | Self-cleaning floor heating pipeline and preparation method thereof | |
| CN101759933A (en) | Glassfiber reinforced polypropylene material without fiber exposion and manufacturing process thereof | |
| CN111073244A (en) | Polycarbonate composition and preparation method thereof | |
| CN113121932B (en) | PVC-U drainage pipe fitting and preparation method and application thereof | |
| CN111171473B (en) | Large-diameter PVC-U water supply accessory injection molding granules and preparation method thereof | |
| CN102167874B (en) | Preparation method of fluorine plastic resin thin film | |
| CN115260724A (en) | Environment-friendly PLA spraying-free composite material and preparation method thereof | |
| CN111440398B (en) | Special material for ion-crosslinked polyvinyl chloride protection tube | |
| CN108692134B (en) | Internal and external double-corrosion-resistant plastic-coated composite pipe and one-step forming process thereof | |
| CN116135923B (en) | Polyvinyl chloride material and preparation method and application thereof | |
| CN105295253A (en) | Sound absorption and noise reduction construction pipe and preparation method thereof | |
| CN113150424B (en) | Low-sag high-finish polyethylene composition and preparation method and application thereof | |
| CN114250016A (en) | Polyethylene anticorrosive powder and preparation method and application of polyethylene anticorrosive powder and coated steel pipe | |
| CN114889227B (en) | Anti-scaling PVC pipe and preparation method thereof | |
| CN112724521B (en) | Super-hydrophobic anti-scaling pipe and preparation method thereof | |
| CN105385062A (en) | Preparation method of chemical corrosion resistant PVC pipe | |
| CN116787867B (en) | Multilayer flexible pipe lined with fluorine-containing layer and preparation method thereof | |
| CN117447807A (en) | Weather-resistant surface self-cleaning ABS material and preparation method thereof | |
| CN115975280A (en) | Manufacturing and processing technology of polyethylene plastic pipe | |
| KR100388896B1 (en) | High-lubricant·anti-finger print steel sheet superior in the formability and the blackenning of surface on pressing in low temperature and the process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A superhydrophobic self-cleaning PVC composite material and its preparation method Granted publication date: 20220513 Pledgee: Shaoxing Branch of Bank of Hangzhou Co.,Ltd. Pledgor: ZHEJIANG TONGZHENG PIPE TECHNOLOGY Co.,Ltd. Registration number: Y2024980014540 |