CN111847879A - Water-soluble black ceramic glaze and preparation method thereof - Google Patents
Water-soluble black ceramic glaze and preparation method thereof Download PDFInfo
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- CN111847879A CN111847879A CN202010791886.1A CN202010791886A CN111847879A CN 111847879 A CN111847879 A CN 111847879A CN 202010791886 A CN202010791886 A CN 202010791886A CN 111847879 A CN111847879 A CN 111847879A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention discloses a water-soluble black ceramic glaze and a preparation method thereof, wherein the water-soluble black ceramic glaze is prepared from the following raw materials in parts by mass: 40-50 parts of ammonium hexafluorozirconate, 4-10 parts of sodium tripolyphosphate, 30-60 parts of zinc hexafluorosilicate, 12-25 parts of ammonium fluosilicate, 15-25 parts of ammonium fluoroborate, 10-16 parts of ammonium fluoroaluminate, 1-4 parts of sodium hexametaphosphate, 2-4 parts of carboxymethyl cellulose, 1-4 parts of a stabilizer, 2-5 parts of a composite antibacterial agent and a colorant in a mass ratio of 1: 3-6. Has the advantages that: the porcelain glaze has good glossiness, stable chemical property and bright color, and the prepared black ceramic glaze layer has no toxicity, the black glaze layer ceramic adopts a spraying method for glazing when glazing in the processing process while eliminating the health safety hidden trouble, the tedious process that most of the traditional ceramic glazes are made into slurry is avoided, the ceramic product prepared by adopting the water-soluble black ceramic glaze is beautiful, the artistic effect is good, the preparation process is simple, and the manufacturability is high.
Description
Technical Field
The invention relates to the technical field of ceramic glaze, in particular to water-soluble black ceramic glaze and a preparation method thereof.
Background
With the increasing living standard of people, the requirements on the quality and the grade of daily ceramic products are higher and higher, the development types and the colors of the color glaze cover all fields of red, orange, yellow, green, cyan, blue and purple, and besides the requirements, a plurality of color glazes with new purposes are continuously published. For ceramic products, the ceramic glaze can improve the service performance, play a role in decoration and the like. Black is a color with many different cultural meanings. The matching of black and white is never too time-consuming and always positioned at the front of fashion. Meanwhile, black and white are extremely opposite colors, but sometimes people feel that they have an indisputable commonality between the colors. Black seems to be the master of the whole color world, black means sensitive, body-sticked, lovely, rich. Therefore, the development of black ceramic glaze with pure color and good chemical stability is a popular subject of the research in the ceramic pigment industry. In particular water-soluble black ceramic glazes.
An effective solution to the problems in the related art has not been proposed yet.
Disclosure of Invention
Aiming at the problems in the related art, the invention provides a water-soluble black ceramic glaze and a preparation method thereof, so as to overcome the technical problems in the prior related art.
The technical scheme of the invention is realized as follows:
according to one aspect of the present invention, a water-soluble black ceramic glaze is provided.
The water-soluble black ceramic glaze is prepared from the following raw materials in parts by mass:
40-50 parts of ammonium hexafluorozirconate, 4-10 parts of sodium tripolyphosphate, 30-60 parts of zinc hexafluorosilicate, 12-25 parts of ammonium fluosilicate, 15-25 parts of ammonium fluoroborate, 10-16 parts of ammonium fluoroaluminate, 1-4 parts of sodium hexametaphosphate, 2-4 parts of carboxymethyl cellulose, 1-4 parts of a stabilizer, 2-5 parts of a composite antibacterial agent and a colorant in a mass ratio of 1: 3-6.
Further, the colorant comprises the following raw material components: 10-20 parts of iron nitrate, 10-16 parts of manganese carbonate, 5-10 parts of boric acid, 2-4 parts of silver nitrate and 3-9 parts of lanthanum nitrate.
Further, the stabilizing agent comprises the following raw material components: 1-3 parts of yttrium oxide and 1-3 parts of calcium zirconate.
Further, the composite antibacterial agent comprises the following raw material components: 1-5 parts of nano graphene, 1-5 parts of graphite, 7-10 parts of phenolic resin, 7-10 parts of epoxy resin, 1-3 parts of quartz, 2-5 parts of calcite, 15-20 parts of titanium dioxide, 10-30 parts of silver molybdate and 30-50 parts of ammonium dihydrogen phosphate.
According to another aspect of the present invention, there is provided a method for preparing a water-soluble black ceramic glaze.
The preparation method of the water-soluble black ceramic glaze comprises the following steps:
taking raw materials according to the weight parts, adding ammonium hexafluorozirconate, sodium tripolyphosphate, zinc hexafluorosilicate, ammonium fluorosilicate, ammonium fluoroborate, ammonium fluoroaluminate, sodium hexametaphosphate, carboxymethyl cellulose, a stabilizer and a composite antibacterial agent into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a raw material I after screening;
preserving the prepared raw material I by adopting a sealed plastic tank, and well performing moisture-proof sealing;
taking raw materials according to the weight parts, adding the raw materials of ferric nitrate, manganese carbonate, boric acid, silver nitrate and lanthanum nitrate into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a second raw material after screening;
preserving the prepared raw material II by adopting a sealed plastic tank, and well performing moisture-proof sealing;
dissolving the raw material I and the raw material II in water according to the mass ratio of 1:3-6 to prepare a water-soluble black ceramic glaze solution;
and packaging the obtained water-soluble black ceramic glaze with a plastic product, and sealing and preventing moisture to finish the preparation of the water-soluble black ceramic glaze.
Furthermore, the mesh number of the mesh sieve is 280 meshes and 330 meshes.
Further, the water-soluble black ceramic glaze solution is 25-35% of the solution in percentage by mass.
Further, the use method of the water-soluble black ceramic glaze comprises the following steps: uniformly spraying the water-soluble black ceramic glaze solution on a ceramic blank body through a sprayer, firing the ceramic blank body in a kiln for 6-8h at the high temperature of 1100-1300 ℃ in the nitrogen atmosphere, and finally preparing the black glaze layer ceramic under the conditions of heat preservation, fire stopping and temperature reduction.
The invention has the beneficial effects that: the water-soluble black ceramic glaze is prepared from chemical components such as ammonium hexafluorozirconate containing fluoride ions, ammonium fluoroaluminate, zinc hexafluorosilicate and the like, and can be dissolved with silicate in a ceramic biscuit into a whole, so that the ceramic glaze has good glossiness, stable chemical property and bright color, a black ceramic glaze layer with pure color tone is effectively prepared, the prepared black ceramic glaze layer has no toxicity, the stability of the ceramic material is improved by matching with a stabilizing agent, under the condition of the mixture of nano graphene, graphite, phenolic resin, epoxy resin, quartz, calcite, titanium dioxide, silver molybdate and ammonium dihydrogen phosphate in a composite antibacterial agent, the antibacterial black ceramic glaze layer has strong antibacterial capacity, has certain conductivity, is lasting in time and harmless to a human body, and further improves the dispersion uniformity and functional stability in the ceramic glaze, and when the black glaze layer ceramic eliminates the potential safety hazard of health, the glaze is applied by adopting a spraying method during the process of glazing, so that the complicated process that most of the traditional ceramic glaze is prepared into slurry is avoided, the ceramic product prepared by adopting the water-soluble black ceramic glaze is beautiful, has great artistic effect, and has simple preparation process and high manufacturability.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings needed in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings without creative efforts.
Fig. 1 is a flow chart of a water-soluble black ceramic glaze and a preparation method thereof according to an embodiment of the present invention.
Detailed Description
For further explanation of the various embodiments, the drawings which form a part of the disclosure and which are incorporated in and constitute a part of this specification, illustrate embodiments and, together with the description, serve to explain the principles of operation of the embodiments, and to enable others of ordinary skill in the art to understand the various embodiments and advantages of the invention, and, by reference to these figures, reference is made to the accompanying drawings, which are not to scale and wherein like reference numerals generally refer to like elements.
According to an embodiment of the present invention, there is provided a water-soluble black ceramic glaze.
According to the water-soluble black ceramic glaze provided by the embodiment of the invention, the water-soluble black ceramic glaze is prepared from the following raw materials in parts by mass:
40-50 parts of ammonium hexafluorozirconate, 4-10 parts of sodium tripolyphosphate, 30-60 parts of zinc hexafluorosilicate, 12-25 parts of ammonium fluosilicate, 15-25 parts of ammonium fluoroborate, 10-16 parts of ammonium fluoroaluminate, 1-4 parts of sodium hexametaphosphate, 2-4 parts of carboxymethyl cellulose, 1-4 parts of a stabilizer, 2-5 parts of a composite antibacterial agent and a colorant in a mass ratio of 1: 3-6.
Wherein the colorant comprises the following raw material components: 10-20 parts of iron nitrate, 10-16 parts of manganese carbonate, 5-10 parts of boric acid, 2-4 parts of silver nitrate and 3-9 parts of lanthanum nitrate.
The stabilizer comprises the following raw material components: 1-3 parts of yttrium oxide and 1-3 parts of calcium zirconate.
The composite antibacterial agent comprises the following raw materials: 1-5 parts of nano graphene, 1-5 parts of graphite, 7-10 parts of phenolic resin, 7-10 parts of epoxy resin, 1-3 parts of quartz, 2-5 parts of calcite, 15-20 parts of titanium dioxide, 10-30 parts of silver molybdate and 30-50 parts of ammonium dihydrogen phosphate.
In order to clearly understand the technical scheme of the invention, the technical scheme of the invention is described in detail through specific examples.
Example one
The water-soluble black ceramic glaze is prepared from the following raw materials in parts by weight:
40 parts of ammonium hexafluorozirconate, 4 parts of sodium tripolyphosphate, 30 parts of zinc hexafluorosilicate, 12 parts of ammonium fluosilicate, 15 parts of ammonium fluoroborate, 10 parts of ammonium fluoroaluminate, 1 part of sodium hexametaphosphate, 2 parts of carboxymethyl cellulose, 1 part of stabilizer, 2 parts of composite antibacterial agent and a colorant in a mass ratio of 1: 3.
Wherein the colorant comprises the following raw material components: 10 parts of iron nitrate, 10 parts of manganese carbonate, 5 parts of boric acid, 2 parts of silver nitrate and 3 parts of lanthanum nitrate.
The stabilizer comprises the following raw material components: 1 part of yttrium oxide and 1 part of calcium zirconate.
The composite antibacterial agent comprises the following raw materials: 1 part of nano graphene, 1 part of graphite, 7 parts of phenolic resin, 7 parts of epoxy resin, 1 part of quartz, 2 parts of calcite, 15 parts of titanium dioxide, 10 parts of silver molybdate and 30 parts of ammonium dihydrogen phosphate.
Example two
The water-soluble black ceramic glaze is prepared from the following raw materials in parts by weight:
43 parts of ammonium hexafluorozirconate, 6 parts of sodium tripolyphosphate, 40 parts of zinc hexafluorosilicate, 17 parts of ammonium fluorosilicate, 18 parts of ammonium fluoroborate, 12 parts of ammonium fluoroaluminate, 2 parts of sodium hexametaphosphate, 2.5 parts of carboxymethyl cellulose, 2 parts of a stabilizer, 3 parts of a composite antibacterial agent and a colorant in a mass ratio of 1: 4.
Wherein the colorant comprises the following raw material components: 13 parts of iron nitrate, 12 parts of manganese carbonate, 7 parts of boric acid, 2.5 parts of silver nitrate and 5 parts of lanthanum nitrate.
The stabilizer comprises the following raw material components: 1.8 parts of yttrium oxide and 1.8 parts of calcium zirconate.
The composite antibacterial agent comprises the following raw materials: 2 parts of nano graphene, 2 parts of graphite, 8 parts of phenolic resin, 8 parts of epoxy resin, 1.8 parts of quartz, 3 parts of calcite, 16 parts of titanium dioxide, 15 parts of silver molybdate and 35 parts of ammonium dihydrogen phosphate.
EXAMPLE III
The water-soluble black ceramic glaze is prepared from the following raw materials in parts by weight:
46 parts of ammonium hexafluorozirconate, 8 parts of sodium tripolyphosphate, 50 parts of zinc hexafluorosilicate, 20 parts of ammonium fluorosilicate, 20 parts of ammonium fluoroborate, 14 parts of ammonium fluoroaluminate, 3 parts of sodium hexametaphosphate, 3 parts of carboxymethyl cellulose, 3 parts of a stabilizer, 4 parts of a composite antibacterial agent and a coloring agent in a mass ratio of 1: 5.
Wherein the colorant comprises the following raw material components: 18 parts of iron nitrate, 14 parts of manganese carbonate, 8 parts of boric acid, 3 parts of silver nitrate and 7 parts of lanthanum nitrate.
The stabilizer comprises the following raw material components: 2.5 parts of yttrium oxide and 2.5 parts of calcium zirconate.
The composite antibacterial agent comprises the following raw materials: 4 parts of nano graphene, 4 parts of graphite, 9 parts of phenolic resin, 9 parts of epoxy resin, 2.5 parts of quartz, 4 parts of calcite, 18 parts of titanium dioxide, 25 parts of silver molybdate and 40 parts of ammonium dihydrogen phosphate.
Example four
The water-soluble black ceramic glaze is prepared from the following raw materials in parts by weight:
50 parts of ammonium hexafluorozirconate, 10 parts of sodium tripolyphosphate, 60 parts of zinc hexafluorosilicate, 25 parts of ammonium fluorosilicate, 25 parts of ammonium fluoroborate, 16 parts of ammonium fluoroaluminate, 4 parts of sodium hexametaphosphate, 4 parts of carboxymethyl cellulose, 4 parts of a stabilizer, 5 parts of a composite antibacterial agent and a coloring agent in a mass ratio of 1: 6.
Wherein the colorant comprises the following raw material components: 20 parts of iron nitrate, 16 parts of manganese carbonate, 10 parts of boric acid, 4 parts of silver nitrate and 9 parts of lanthanum nitrate.
The stabilizer comprises the following raw material components: 3 parts of yttrium oxide and 3 parts of calcium zirconate.
The composite antibacterial agent comprises the following raw materials: 5 parts of nano graphene, 5 parts of graphite, 10 parts of phenolic resin, 10 parts of epoxy resin, 3 parts of quartz, 5 parts of calcite, 20 parts of titanium dioxide, 30 parts of silver molybdate and 50 parts of ammonium dihydrogen phosphate.
The preparation method of the water-soluble black ceramic glaze comprises the following steps:
taking raw materials according to the weight parts, adding ammonium hexafluorozirconate, sodium tripolyphosphate, zinc hexafluorosilicate, ammonium fluorosilicate, ammonium fluoroborate, ammonium fluoroaluminate, sodium hexametaphosphate, carboxymethyl cellulose, a stabilizer and a composite antibacterial agent into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a raw material I after screening;
preserving the prepared raw material I by adopting a sealed plastic tank, and well performing moisture-proof sealing;
taking raw materials according to the weight parts, adding the raw materials of ferric nitrate, manganese carbonate, boric acid, silver nitrate and lanthanum nitrate into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a second raw material after screening;
preserving the prepared raw material II by adopting a sealed plastic tank, and well performing moisture-proof sealing;
dissolving the raw material I and the raw material II in water according to the mass ratio of 1:3-6 to prepare a water-soluble black ceramic glaze solution;
and packaging the obtained water-soluble black ceramic glaze with a plastic product, and sealing and preventing moisture to finish the preparation of the water-soluble black ceramic glaze.
For the convenience of understanding the above technical solution of the present invention, the following detailed description is made on the flow of the above solution of the present invention with reference to the accompanying drawings, and specifically is as follows:
according to the embodiment of the invention, a preparation method of the water-soluble black ceramic glaze is also provided.
As shown in fig. 1, in the actual production process, the preparation of the water-soluble black ceramic glaze comprises the following steps:
step S101, taking raw materials according to weight parts, adding ammonium hexafluorozirconate, sodium tripolyphosphate, zinc hexafluorosilicate, ammonium fluorosilicate, ammonium fluoroborate, ammonium fluoroaluminate, sodium hexametaphosphate, carboxymethyl cellulose, a stabilizer and a composite antibacterial agent into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a raw material I after screening;
step S103, storing the prepared raw material I by adopting a sealed plastic tank, and well performing moisture-proof sealing;
step S105, taking the raw materials according to the weight parts, adding the raw materials of iron nitrate, manganese carbonate, boric acid, silver nitrate and lanthanum nitrate into a grinder, grinding and mixing uniformly, screening under a sieve to obtain a second raw material;
s107, preserving the prepared raw material II by adopting a sealed plastic tank, and well performing moisture-proof sealing;
step S109, dissolving the raw material I and the raw material II in water according to the mass ratio of 1:3-6 to prepare water-soluble black ceramic glaze solution;
and step S111, packaging the obtained water-soluble black ceramic glaze with a plastic product, and sealing and damp-proofing to finish the preparation of the water-soluble black ceramic glaze.
In one embodiment, the mesh size of the mesh screen is 280-330 mesh.
In one embodiment, the water-soluble black ceramic glaze solution is 25-35% by mass.
In one embodiment, the water-soluble black ceramic glaze is used by the method comprising the following steps: uniformly spraying the water-soluble black ceramic glaze solution on a ceramic blank body through a sprayer, firing the ceramic blank body in a kiln for 6-8h at the high temperature of 1100-1300 ℃ in the nitrogen atmosphere, and finally preparing the black glaze layer ceramic under the conditions of heat preservation, fire stopping and temperature reduction.
For the convenience of understanding the technical solutions of the present invention, the following detailed description will be made on the working principle or the operation mode of the present invention in the practical process.
In summary, according to the above technical solution of the present invention, the water-soluble black ceramic glaze material is composed of chemical components such as ammonium hexafluorozirconate containing fluoride ions, ammonium fluoroaluminate, and zinc hexafluorosilicate, and can be dissolved with silicate in a ceramic biscuit into a whole, so that the glaze material has good glossiness, stable chemical properties, bright color, and can be effectively made into a black ceramic glaze layer with pure color tone, and the prepared black ceramic glaze layer has no toxicity, the stability of the ceramic material is improved by matching with a stabilizer, the antibacterial ability is strong under the condition of the mixture of nano graphene, graphite, phenolic resin, epoxy resin, quartz, calcite, titanium dioxide, silver molybdate, and ammonium dihydrogen phosphate in the composite antibacterial agent, and the glaze material has certain conductivity, long-lasting time, no harm to human body, and the dispersion uniformity and functional stability in the ceramic glaze material are further improved, the black glaze layer ceramic is glazed by adopting a spraying method during glazing in the processing process while the potential health safety hazard of the black glaze layer ceramic is eliminated, so that the complicated process that most of the traditional ceramic glaze is made into slurry is avoided, and the ceramic product made of the water-soluble black ceramic glaze is attractive and has an artistic effect, and the preparation process is simple and high in manufacturability.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (8)
1. The water-soluble black ceramic glaze is characterized by being prepared from the following raw materials in parts by mass:
40-50 parts of ammonium hexafluorozirconate, 4-10 parts of sodium tripolyphosphate, 30-60 parts of zinc hexafluorosilicate, 12-25 parts of ammonium fluosilicate, 15-25 parts of ammonium fluoroborate, 10-16 parts of ammonium fluoroaluminate, 1-4 parts of sodium hexametaphosphate, 2-4 parts of carboxymethyl cellulose, 1-4 parts of a stabilizer, 2-5 parts of a composite antibacterial agent and a colorant in a mass ratio of 1: 3-6.
2. The water-soluble black ceramic glaze according to claim 1, wherein the colorant comprises the following raw material components: 10-20 parts of iron nitrate, 10-16 parts of manganese carbonate, 5-10 parts of boric acid, 2-4 parts of silver nitrate and 3-9 parts of lanthanum nitrate.
3. The water-soluble black ceramic glaze according to claim 1, wherein the stabilizer comprises the following raw material components: 1-3 parts of yttrium oxide and 1-3 parts of calcium zirconate.
4. The water-soluble black ceramic glaze according to claim 1, wherein the composite antibacterial agent comprises the following raw material components: 1-5 parts of nano graphene, 1-5 parts of graphite, 7-10 parts of phenolic resin, 7-10 parts of epoxy resin, 1-3 parts of quartz, 2-5 parts of calcite, 15-20 parts of titanium dioxide, 10-30 parts of silver molybdate and 30-50 parts of ammonium dihydrogen phosphate.
5. The method for preparing a water-soluble black ceramic glaze according to claim 1, wherein the method for preparing a water-soluble black ceramic glaze according to claim 1 comprises the steps of:
taking raw materials according to the weight parts, adding ammonium hexafluorozirconate, sodium tripolyphosphate, zinc hexafluorosilicate, ammonium fluorosilicate, ammonium fluoroborate, ammonium fluoroaluminate, sodium hexametaphosphate, carboxymethyl cellulose, a stabilizer and a composite antibacterial agent into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a raw material I after screening;
preserving the prepared raw material I by adopting a sealed plastic tank, and well performing moisture-proof sealing;
taking raw materials according to the weight parts, adding the raw materials of ferric nitrate, manganese carbonate, boric acid, silver nitrate and lanthanum nitrate into a grinder, grinding and mixing uniformly, screening under a mesh screen, and obtaining a second raw material after screening;
preserving the prepared raw material II by adopting a sealed plastic tank, and well performing moisture-proof sealing;
dissolving the raw material I and the raw material II in water according to the mass ratio of 1:3-6 to prepare a water-soluble black ceramic glaze solution;
and packaging the obtained water-soluble black ceramic glaze with a plastic product, and sealing and preventing moisture to finish the preparation of the water-soluble black ceramic glaze.
6. The method for preparing a water-soluble black ceramic glaze according to claim 5, wherein the mesh number of the mesh screen is 280-330 meshes.
7. The method for preparing water-soluble black ceramic glaze according to claim 5, wherein the water-soluble black ceramic glaze solution is a 25-35% solution by mass percentage.
8. The method for preparing water-soluble black ceramic glaze according to claim 5, wherein the water-soluble black ceramic glaze is used by the following method: uniformly spraying the water-soluble black ceramic glaze solution on a ceramic blank body through a sprayer, firing the ceramic blank body in a kiln for 6-8h at the high temperature of 1100-1300 ℃ in the nitrogen atmosphere, and finally preparing the black glaze layer ceramic under the conditions of heat preservation, fire stopping and temperature reduction.
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