CN111809453A

CN111809453A - High-strength regenerated white board paper

Info

Publication number: CN111809453A
Application number: CN202010700090.0A
Authority: CN
Inventors: 苗成仁
Original assignee: Miao Guanghou
Current assignee: Miao Guanghou
Priority date: 2018-09-20
Filing date: 2018-09-20
Publication date: 2020-10-23
Also published as: CN111778775A; CN111764192A; CN111851123A; CN109024092B; CN109024092A

Abstract

The invention discloses high-strength recycled white board paper, and belongs to the field of papermaking. The floor is at least provided with a surface layer, a lining layer, a core layer and a bottom layer, wherein the bottom layer is prepared from the following raw materials in parts by weight: 90-100 parts of mixed fiber; 15-20 parts of jebei fiber; 10-13 parts of mineral fiber; wherein the mixed fiber comprises the following components in percentage by mass (3-4): 1 mango tree wood fibers and polylactic acid fibers; the fineness of the polylactic acid fiber is 0.15-0.2 dpf, and the length of the polylactic acid fiber is 10-15 mm; the mineral fiber has a diameter of 0.1 to 0.15 μm and a length of 2 to 5 mm. The invention has the following beneficial effects: 1. the polylactic acid fiber has high crystallinity and high orientation degree, thereby having high heat resistance and high strength and being beneficial to improving the tearing strength of the white board paper; 2. longer gibberella fibers can form better net-shaped lamination, shorter mango tree fibers are attached, and the overall strength is improved; 3. the mineral fiber has a high length-diameter ratio, and can achieve good economic benefit.

Description

High-strength regenerated white board paper

This application is divisional application, and the original case patent number is: 201811099378.6, having application date of 2018, 9 and 20, and having the name: a high-strength high-moisture-proof regenerated white board paper and a production process.

Technical Field

The invention relates to the field of papermaking, in particular to high-strength recycled white board paper.

Background

The white paperboard is a paperboard with white and smooth front surface and gray bottom mostly on the back surface, and the white paperboard is mainly used for making a paper box for packaging after single-side color printing or used for designing and handmade products.

The white board paper generally comprises a surface layer, a lining layer, a core layer and a bottom layer, and is manufactured by pulp of different layers on a multi-cylinder multi-dryer paper machine or a long cylinder mixed paper board machine. The fiber proportion of the paper pulp of each layer is different, and the fiber proportion of the paper pulp of each layer is different according to the quality of paper making.

The first layer is surface pulp, which is required to have high whiteness and certain strength, and usually adopts bleached sulfate wood pulp or part of bleached chemical straw pulp and white paper edge waste paper pulp; the second layer is a lining layer which plays a role of isolating the surface layer from the core layer, and also needs to have certain whiteness, and 100 percent mechanical wood pulp or light-colored waste paper pulp is usually used; the third layer is a core layer which mainly plays a role in filling so as to increase the thickness of the paperboard and improve the stiffness, the mixed waste paper pulp or straw pulp is generally adopted, and the thickest and high-quantitative paperboard is usually coated with pulp for several times by using a plurality of net troughs; the last layer is the bottom layer, which has the functions of improving the appearance of the paper board, improving the strength and preventing curling, high-yield pulp or better waste paper pulp is usually used as the raw material for papermaking, the bottom color of the paper board is more grey, and other bottom colors can be produced according to requirements.

The white board is mostly composed of pulp fibers, the strength of the white board is limited, the white board is easy to tear or break when being bent, the bottom layer is generally used for improving the strength, the requirement on raw materials is high, the pulp fibers are generally made of plant fibers, but the strength of the pulp fibers is limited due to the inherent characteristics of the plant fibers, and therefore the white board cannot form high strength.

Disclosure of Invention

The invention provides a high-strength recycled white board which can solve the problems pointed out in the background art.

The high-strength high-moisture-proof regenerated white board paper at least comprises a surface layer, a lining layer, a core layer and a bottom layer, wherein the bottom layer is prepared from the following raw materials in parts by weight:

90-100 parts of mixed fiber;

15-20 parts of jebei fiber;

10-13 parts of mineral fiber;

wherein the mixed fiber comprises the following components in percentage by mass (3-4): 1 mango tree wood fibers and polylactic acid fibers;

the fineness of the polylactic acid fiber is 0.15-0.2 dpf, and the length of the polylactic acid fiber is 10-15 mm;

the mineral fiber has a diameter of 0.1 to 0.15 μm and a length of 2 to 5 mm.

Preferably, the core layer comprises an elastic layer, the elastic layer is made of high-elasticity polyethylene fibers, the thickness ratio of the elastic layer to the core layer is (1-1.5): 3, and the elastic layer is located at 1/3, close to the lining layer, of the core layer.

The invention provides high-strength recycled white board paper, which has the following beneficial effects:

1. the polylactic acid fiber has good biodegradability, and can be completely decomposed into CO in nature after being discarded₂And H₂O, and has high heat resistance and high strength due to high crystallinity and high orientation degree, thereby being beneficial to improving the tearing strength of the white board paper;

2. the longer Jibei fiber can form better net-shaped lamination to attach the shorter-length mango tree fiber, thereby improving the overall strength;

3. the length-diameter ratio of the mineral fiber is higher, the mineral fiber can be effectively interwoven with the plant fiber, the strength of the mineral fiber is slightly lower than that of the plant fiber, but the cost of the mineral fiber is lower than that of the plant fiber, so that better economic benefit can be achieved, and the high strength of the polylactic acid fiber can make up for the strength loss caused by the mineral fiber;

drawings

Fig. 1 is a schematic structural diagram of a high-strength high-moisture-proof recycled white board provided by the invention.

FIG. 2 is a schematic structural diagram of a stirring device in the production process of a high-strength high-moisture-proof recycled white board provided by the invention;

FIG. 3 is an enlarged view of a portion A of FIG. 2;

fig. 4 is a top view of fig. 2.

Description of reference numerals:

10. surface course, 11, lining, 12, reinforcing layer, 13, core layer, 14, elastic layer, 15, bottom layer, 20, motor, 21, stirring tank, 22, stirring rod, 23, stirring blade, 231 and reflux tank.

Detailed Description

An embodiment of the present invention will be described in detail below with reference to the accompanying drawings, but it should be understood that the scope of the present invention is not limited to the embodiment.

As shown in fig. 1, the high-strength high-moisture-proof recycled white board provided by the embodiment of the present invention includes a surface layer 10, a lining layer 11, a core layer 13, and a bottom layer 15, which are sequentially disposed, wherein the bottom layer 15 is made of the following raw materials in parts by weight:

90-100 parts of mixed fiber;

15-20 parts of jebei fiber;

10-13 parts of mineral fiber;

the mineral fiber has a diameter of 0.1 to 0.15 μm and a length of 2 to 5 mm.

In a specific embodiment, the surface layer 10 comprises the following raw materials in parts by weight: 60-85% of calcium carbonate, 5-20% of kaolin, 0.1-0.3% of dispersing agent, 8-15% of adhesive, 0.1-0.6% of water repellent agent, 0.1-0.3% of lubricant, and waste paper pulp is adopted for the lining layer 11 and the core layer 13.

In a specific embodiment, in order to improve the moisture resistance of the white board, water-absorbent resin particles are embedded in the bottom layer 15, the particle size of the water-absorbent resin particles is 100-120 μm, and the water-absorbent resin particles account for 8-12% of the bottom layer 15 by mass. The water-absorbing resin is a macromolecule containing hydrophilic groups and a cross-linked structure, and can spontaneously absorb water at a certain temperature and pressure, so that the water enters the resin, and the free enthalpy of the whole system is reduced until the balance is achieved. The surface area of the granular water-absorbent resin is greatly increased, the length of polylactic acid fiber is 10-15 mm, the length of mineral fiber is 2-5 mm, the fiber is long, the content of fine fiber is low, the performance of the whole mat is good, the reticular fiber is uniform, and the water-absorbent resin with the particle size range of 100-120 mu m can be perfectly embedded in the fiber layer.

In one embodiment, the core layer 13 includes an elastic layer 14, the elastic layer 14 is made of high-elasticity polyethylene fibers, the thickness ratio of the high-elasticity polyethylene fibers to the core layer 13 is (1-1.5): 3, and the high-elasticity polyethylene fibers are located at 1/3, which is close to the lining layer 11, of the core layer 13, and the high-elasticity polyethylene fibers are fibers with the highest specific strength and specific modulus in the world at present. The elastic layer 14 is net-shaped, the fiber diameter is 200-250 mu m, the net-shaped high-elasticity polyethylene fiber can be interwoven with the paper pulp fiber of the core layer 13, the adhesive force is increased, the high-elasticity polyethylene fiber has ultrahigh strength, and the bursting resistance and the folding resistance of the white board paper can be obviously increased. The elastic layer 14 is ensured to be positioned at 1/3 of the core layer 13 close to the lining layer 11, the elastic layer 14 can be basically positioned in the middle of the white board, the white board can be ensured to have better folding endurance no matter the white board is bent from the surface layer 10 or the bottom layer 15, the elastic layer 14 can ensure that the white board absorbs most of stress when being bent, and the reset can be easily realized due to the elastic strength of the high-elasticity polyethylene fibers during the recovery, so that the paper is prevented from being broken.

In a specific embodiment, a reinforcing layer 12 is further disposed between the liner layer 11 and the core layer 13, and the reinforcing layer 12 is made of a negative poisson's ratio material of an inward-folding mechanism. The negative poisson's sRatio (r) effect, which refers to the expansion of a material in the transverse direction in the elastic range when stretched; while under compression, the material shrinks in the transverse direction instead. The material is generally broken because when the material is stretched in one direction, the material perpendicular to the direction of the applied force is contracted and deformed, so that the strength of the contracted part is reduced, and the material is broken. The negative poisson ratio material of internal rotation folding mechanism forms negative poisson ratio effect through linking each other in certain form at the summit, when certain direction of material receives the tensile, the contained angle on each rectangle or triangle-shaped limit that links up each other changes, along with the increase of contained angle, the material connects folding and produce the expansion deformation on the tensile direction of perpendicular to, this process makes the unit area density of material reduce, external force has been absorbed, but can not destroy the structural strength of material, simultaneously because material unit structure takes place to rotate, decompose external force on two not equidirectional, avoid the material to bear the ascending external force of single direction, thereby the ascending stress intensity of single direction has been offset greatly, thereby the bursting strength of paper has been promoted indirectly.

The first embodiment is as follows:

a preparation method of high-strength high-moisture-proof regenerated white board paper comprises the following specific steps:

s1, respectively adding chemical agents into the raw materials of the surface layer 10, the lining layer 11 and the core layer 13, and disintegrating to obtain corresponding slurry, wherein the raw materials can be selected according to actual needs, and waste paper pulp is adopted in the embodiment;

s2, crushing, dispersing and bleaching 25 parts by weight of mango tree wood fibers, mixing and stirring the mango tree wood fibers and polylactic acid fibers by a stirring device, gradually adding 15 parts by weight of Gilbert cell fibers in the stirring process, stirring at a speed of 600r/min, controlling the fineness of the polylactic acid fibers to be 0.15dpf and the length to be 10mm, and obtaining mixed slurry; because the length of the polylactic acid fiber is longer and the length of the mango tree fiber is shorter, the high-degree stirring is beneficial to fully mixing the mango tree fiber and the polylactic acid fiber so as to increase the interweaving degree;

s3, diluting 10 parts by weight of mineral fibers with water to 20% -30% to obtain mineral fiber slurry, stirring the mixed slurry at a speed of 150r/min, gradually adding the mineral fiber slurry, controlling the diameter of the mineral fibers to be 0.1 mu m and the length to be 2mm, introducing steam during stirring, keeping the steam temperature at 100 ℃ for 30min, and preparing bottom layer 15 slurry; because the texture of the mineral fiber is crisp, the mineral fiber can be broken by high-speed stirring, and the mineral fiber is difficult to be fully interwoven and mixed with the polylactic acid fiber and the mango tree wood fiber when the speed is low, the stirring speed when the mineral fiber is added is controlled, and the control of the interweaving quality and the interweaving length of the mineral fiber is facilitated;

s31, mixing and stirring the slurry of the bottom layer 15 and water-absorbent resin particles with the particle size of 100 microns by a stirring device, wherein the water-absorbent resin accounts for 8% by mass, and the stirring speed is 100r/min and the stirring is carried out for 10 min;

s32, spraying the slurry of the core layer 13, and controlling the thickness to be 1/3 of the total thickness of the core layer 13;

s33, laying an elastic layer 14 made of high-elasticity polyethylene fibers on the slurry of the core layer 13 in the S32;

s34, continuously spraying the slurry of the core layer 13 on the elastic layer 14 to a preset thickness;

s35, laying a negative Poisson ratio material net of the internal rotation folding mechanism on the slurry of the core layer 13 in the S34, wherein the reinforcing layer 12 is positioned between the lining layer 11 and the core layer 13;

and S4, continuously pulping and drying to obtain the white board.

Example two:

s2, crushing, dispersing and bleaching 30 parts by weight of mango tree wood fibers, mixing and stirring the mango tree wood fibers and polylactic acid fibers by a stirring device, gradually adding 20 parts by weight of Gilbert cell fibers in the stirring process, stirring at a speed of 700r/min, and controlling the fineness and the length of the polylactic acid fibers to be 0.2dpf and 15mm to obtain mixed slurry; because the length of the polylactic acid fiber is longer and the length of the mango tree fiber is shorter, the high-degree stirring is beneficial to fully mixing the mango tree fiber and the polylactic acid fiber so as to increase the interweaving degree;

s3, diluting 13 parts by weight of mineral fibers with water to 30% to obtain mineral fiber slurry, stirring the mixed slurry at the speed of 200r/min, gradually adding the mineral fiber slurry, controlling the diameter of the mineral fibers to be 0.15 mu m and the length to be 5mm, introducing steam during stirring, keeping the steam temperature at 115 ℃ for 40min, and preparing bottom layer 15 slurry; because the texture of the mineral fiber is crisp, the mineral fiber can be broken by high-speed stirring, and the mineral fiber is difficult to be fully interwoven and mixed with the polylactic acid fiber and the mango tree wood fiber when the speed is low, the stirring speed when the mineral fiber is added is controlled, and the control of the interweaving quality and the interweaving length of the mineral fiber is facilitated;

s31, mixing and stirring the slurry of the bottom layer 15 and water-absorbent resin particles with the particle size of 120 mu m by a stirring device, wherein the water-absorbent resin accounts for 12 mass percent, the stirring speed is 150r/min, and the stirring is carried out for 15 min;

and S4, continuously pulping and drying to obtain the white board.

Example three:

s2, crushing, dispersing and bleaching 27 parts by weight of mango tree wood fibers, mixing and stirring with polylactic acid fibers through a stirring device, gradually adding 17 parts by weight of Chilbert fibers in the stirring process, stirring at a speed of 650r/min, controlling the fineness of the polylactic acid fibers to be 0.17dpf and the length to be 13mm, and obtaining mixed slurry; because the length of the polylactic acid fiber is longer and the length of the mango tree fiber is shorter, the high-degree stirring is beneficial to fully mixing the mango tree fiber and the polylactic acid fiber so as to increase the interweaving degree;

s3, diluting 12 parts by weight of mineral fibers with water to 25% to obtain mineral fiber slurry, stirring the mixed slurry at a speed of 170r/min and gradually adding the mineral fiber slurry, controlling the diameter of the mineral fibers to be 0.13 mu m and the length to be 3mm, introducing steam during stirring, keeping the steam temperature at 107 ℃ for 40min, and preparing bottom layer 15 slurry; because the texture of the mineral fiber is crisp, the mineral fiber can be broken by high-speed stirring, and the mineral fiber is difficult to be fully interwoven and mixed with the polylactic acid fiber and the mango tree wood fiber when the speed is low, the stirring speed when the mineral fiber is added is controlled, and the control of the interweaving quality and the interweaving length of the mineral fiber is facilitated;

s31, mixing and stirring the slurry of the bottom layer 15 and water-absorbent resin particles with the particle size of 110 mu m by a stirring device, wherein the water-absorbent resin accounts for 10 mass percent, the stirring speed is 130r/min, and the stirring time is 13 min;

and S4, continuously pulping and drying to obtain the white board.

Comparative example one:

the other portions are the same as those of the example, except that the bamboo fiber and the mango tree fiber are mixed in step S2.

Comparative example two:

the other portions are the same as the first comparative example except that only bamboo fibers are mixed with mango tree fibers without the gibba fibers in step S2.

Comparative example three:

the other portions are the same as those of the embodiment, except that step S3 is eliminated.

Comparative example four:

the other portions are the same as those of the embodiment, except that step S31 is eliminated.

Comparative example five:

the other portions are the same as those of the embodiment except that the steps S32-S34 are eliminated.

Comparative example six:

the other portions are the same as those of the embodiment, except that step S35 is eliminated.

The results of the performance tests of the white boards of examples 1-3 and comparative examples 1-6 are shown in Table 1.

TABLE 1 white board Performance test

As shown in fig. 2 to 4, the stirring device in the above embodiment includes: the stirring device comprises a stirring tank 21, a driving motor 20, a stirring rod 22 and stirring blades 23 arranged on the stirring rod 22, wherein the driving motor 20 is positioned at the bottom of the stirring tank 21, an output shaft of the driving motor 20 extends into the stirring tank 21 and is connected to the stirring rod 22 in a driving manner, the output shaft of the driving motor 20 is in dynamic sealing connection with the stirring tank 21, the stirring blades 23 are fixedly arranged on the stirring rod 22, the stirring blades 23 are distributed in a spiral ascending manner, the pitch of the stirring blades gradually decreases, namely the stirring rod 22 is vertically arranged, and the pitch of the stirring blades 23 gradually decreases towards the direction away from the driving motor 20, namely the distance between every two adjacent stirring blades 23 gradually decreases; the stirring blades 23 are all arranged obliquely upwards, and the lower ends of the stirring blades deflect along the rotating direction, so that when the stirring blades 23 drive the fluid to flow, the fluid is driven to rotate and the trend of upward movement is generated; the stirring blades 23 are made of soft rubber, a plurality of reflux grooves 231 with one side communicated with each other are formed in the stirring blades 23, and the width of each reflux groove 231 is 5-10mm, so that the stirring blades 23 are prevented from being too rigid and breaking fibers.

Because stirring vane 23 is when rotatory stirring, liquid can form the swirl, lead to the velocity of flow uneven, the swirl center, the velocity of flow in the middle of swirl outside and the swirl increases in proper order, be unfavorable for the homogeneous mixing stirring, the stirring vane 23 that utilizes the slope to set up can reduce the formation of swirl to a certain extent, be favorable to the homogeneous stirring of material, especially to longer polylactic acid fibre and the fibrous stirring of shorter mango tree, because both length differs, want to form better interweaving needs stable and efficient stirring, can improve both degree of mixing to a certain extent through the formation that reduces the swirl. The stirring blades 23 spirally ascend and can form a fault on the liquid level depth at different heights, namely, after two adjacent layers have the same flow velocity and are prior, turbulence can be formed due to dislocation, the problem that the stirring effect is low due to unidirectional synchronous rotation of materials is avoided, and the mixing degree is forcefully improved. Since the pitch of the stirring blade 23 gradually decreases in the direction away from the driving motor 20 and the stirring blade 23 is more likely to form a vortex closer to the liquid surface, the density of the stirring blade 23 increases in the direction closer to the liquid surface, which is advantageous for further reducing the probability of vortex formation.

Because the texture of the mineral fiber is crisp and the strength of the mineral fiber is slightly lower than that of the plant fiber, the stirring blade 23 rotating at a high speed easily breaks the mineral fiber, the stirring blade 23 is made of soft rubber, and meanwhile, the mineral fiber can be effectively prevented from being broken by depending on the backflow groove 231, so that the interweaving degree of the mineral fiber and other plant fibers is improved, and the strength of the white board paper is improved. The width of the backflow groove 231 is larger than the length of the mineral fibers, so that the mineral fibers can perfectly pass through the backflow groove 231, and the probability of breaking the mineral fibers is reduced to the maximum extent.

The above disclosure is only for a few specific embodiments of the present invention, however, the present invention is not limited to the above embodiments, and any variations that can be made by those skilled in the art are intended to fall within the scope of the present invention.

Claims

1. The high-strength high-moisture-proof regenerated white board paper at least comprises a surface layer, a lining layer, a core layer and a bottom layer, and is characterized in that the bottom layer is prepared from the following raw materials in parts by weight:

90-100 parts of mixed fiber;

15-20 parts of jebei fiber;

10-13 parts of mineral fiber;

the mineral fiber has a diameter of 0.1 to 0.15 μm and a length of 2 to 5 mm.

2. The high-strength high-moisture-proof regenerated white board as claimed in claim 1, wherein the core layer comprises an elastic layer, the elastic layer is made of high-elasticity polyethylene fibers, the thickness ratio of the elastic layer to the core layer is (1-1.5): 3, and the elastic layer is located at 1/3, close to the lining layer, of the core layer.