CN111807700B - Glass composition for white spirit bottles - Google Patents
Glass composition for white spirit bottles Download PDFInfo
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- CN111807700B CN111807700B CN202010759519.3A CN202010759519A CN111807700B CN 111807700 B CN111807700 B CN 111807700B CN 202010759519 A CN202010759519 A CN 202010759519A CN 111807700 B CN111807700 B CN 111807700B
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- oxide
- glass composition
- white spirit
- content
- glass
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- 239000011521 glass Substances 0.000 title claims abstract description 39
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000292 calcium oxide Substances 0.000 claims abstract description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 13
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 12
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 10
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910001947 lithium oxide Inorganic materials 0.000 claims abstract description 8
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 22
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052810 boron oxide Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 7
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 abstract description 5
- 238000000137 annealing Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical group O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000020097 white wine Nutrition 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a glass composition for white spirit bottles, which comprises the following components in percentage by weight: silica, alumina, magnesia, diboron trioxide, sodium oxide, potassium oxide, calcium oxide, lithium oxide; and further comprises yttria. The glass composition not only helps to achieve a lower coefficient of thermal expansion, but also a greater surface tension.
Description
Technical Field
The invention belongs to the technical field of glass; relates to a glass composition for white spirit bottles.
Background
At present, glass bottles used in the white spirit industry are more in variety, and different glass wine bottles are large in chemical composition difference and uneven in quality. And many components of the white spirit bottle react with white spirit in the process of containing the white spirit in a more or less ion exchange manner and the like, and influence physical change and chemical change of the white spirit to a certain extent, so that sensory evaluation of the white spirit is different. Thus, the composition of the glass composition used in the white spirit bottles has a significant impact on the physicochemical properties of the white spirit bottles, which in turn have a potential impact on the quality of the white spirit they contain. Among the many physicochemical properties of white spirit bottles, the properties of interest are two important indicators of thermal expansion coefficient and surface tension.
Soda lime glass is generally used as glass for white spirit bottles, and the main components of the glass composition comprise silicon dioxide, aluminum oxide, calcium oxide, magnesium oxide, sodium oxide, additives and the like. The glass generally meets the requirements of relevant national standards such as GB/T24694-2009, GB/T3562-1999, GB/T19778-2005 and the like on performances such as internal pressure resistance, thermal shock resistance, impact resistance, water resistance, internal stress, heavy metal dissolution limit and the like of white spirit bottle products. However, two important indexes of the thermal expansion coefficient and the surface tension of the white spirit bottles are still not satisfactory.
Chinese patent application CN110734221a discloses a novel environment-friendly high-whiteness bottle and can glass, which comprises the following components in weight percentage: siO (SiO) 2 ：72-75％，Al 2 O 3 ：1.5-2.5％，CaO：8-12％，MgO：1-3％，(Na 2 O+K 2 O)：12-14％，B 2 O 3 ：1-3％，Li 2 O：0.2-1.0％，BaO：0.2-1.0％，CeO 2 :0.1-0.5% and proper amount of physical decolorizer. Under the condition of not increasing the manufacturing cost, the mechanical strength and the chemical stability of the high-whiteness bottle and tank glass are improved by changing the proportion of main raw materials and introducing new substancesThe glass of the traditional high-whiteness bottle and can is fragile and easy to separate sodium, thereby meeting the requirements of high-speed canning of winery, and simultaneously meeting the requirements of environmental protection and food safety by using a clarifier which does not contain fluorine, arsenic and antimony. However, the improvement of the two important indexes of the thermal expansion coefficient and the surface tension of the white spirit bottle is limited.
Accordingly, there remains a need to address the above-identified deficiencies of the prior art by providing a glass composition that provides greater improvements in both the important factors of thermal expansion and surface tension.
Disclosure of Invention
The invention aims to provide a glass composition for a white spirit bottle. Compared with the prior art, the glass composition for the white spirit bottle has lower thermal expansion coefficient and larger surface tension.
In order to solve the technical problems, the invention adopts the following technical scheme: the glass composition for the white spirit bottles comprises the following components in percentage by weight: silica, alumina, magnesia, diboron trioxide, sodium oxide, potassium oxide, calcium oxide, lithium oxide; characterized in that the glass composition further comprises yttria.
The glass composition according to the invention, wherein the content of yttrium oxide is 0.6-1 wt.%.
The glass composition according to the invention, wherein the content of alumina is 2.6-3.2 wt.%.
The glass composition according to the invention, wherein the content of silica is 71-73wt%.
The glass composition according to the present invention, wherein the glass composition further comprises strontium oxide.
The glass composition according to the invention, wherein the weight ratio of strontium oxide to calcium oxide is 1:4.
The glass composition according to the invention, wherein the sum of the contents of calcium oxide and strontium oxide is 8-10 wt.%.
The glass composition according to the invention, wherein the weight ratio of sodium oxide to potassium oxide is 3:1.
The glass composition according to the present invention, wherein the sum of the contents of sodium oxide and potassium oxide is 9 to 12wt%.
The glass composition according to the present invention contains 1.5 to 2.5wt%, 1 to 2wt% and 0.4 to 0.8wt% of magnesium oxide, diboron trioxide and lithium oxide, respectively.
The glass composition according to the invention, wherein the balance is other unavoidable impurities.
In a specific embodiment, the glass composition according to the invention comprises the following components in percentage by weight: silica: 72.2wt%, aluminum oxide: 3wt%, magnesium oxide: 2.1wt%, diboron trioxide: 1.5 percent of sodium oxide: 8.1wt% of potassium oxide: 2.7wt% of calcium oxide: 7.2wt% of strontium oxide: 1.8wt% of lithium oxide: 0.6wt% of yttrium oxide: 0.8wt%.
In the present invention, silica, alumina, magnesia and yttria are incorporated in oxide form; the diboron trioxide is introduced in the form of boric acid; sodium oxide, potassium oxide, calcium oxide, strontium oxide, and lithium oxide are introduced in the form of carbonates. The purity of the raw materials is above 99.0%.
Batching, mixing and grinding according to the designed formula; feeding the uniformly mixed materials into a glass melting furnace, wherein the furnace pressure is 2-4Pa, and melting at a high temperature of 1450-1550 ℃ to obtain glass liquid; adding molten glass into a preheated mold at 1160-1240 ℃ for molding operation; and then annealing operation is carried out, the annealing temperature is 500-600 ℃, the annealing time is 0.2-2h, and finally cooling to room temperature at the speed of 10-15 ℃/min, thus obtaining the white wine bottle.
The inventors found that the use of the glass composition according to the invention for the preparation of white spirit bottles, in combination with the use of yttria and strontium oxide in a specific ratio, with a suitable increase in the content of aluminium oxide, not only contributes to a lower coefficient of thermal expansion, but also to a greater surface tension, compared to the prior art.
Detailed Description
The invention is further described below in conjunction with the detailed description.
It should be understood that the description of the specific embodiments is merely illustrative of the principles and spirit of the invention, and not in limitation thereof. Further, it should be understood that various changes, substitutions, omissions, modifications, or adaptations to the present invention may be made by those skilled in the art after having read the present disclosure, and such equivalent embodiments are within the scope of the present invention as defined in the appended claims.
In the present invention, all parts are parts by weight unless otherwise indicated.
In the present invention, the test conditions for the thermal expansion coefficient are: the temperature rising rate is 5 ℃/min, and the temperature range is room temperature to 800 ℃. The surface tension is measured by a heating microscopy method.
Example 1
The glass composition comprises the following components in percentage by weight: silica: 72.2wt%, aluminum oxide: 3wt%, magnesium oxide: 2.1wt%, diboron trioxide: 1.5 percent of sodium oxide: 8.1wt% of potassium oxide: 2.7wt% of calcium oxide: 7.2wt% of strontium oxide: 1.8wt% of lithium oxide: 0.6wt% of yttrium oxide: 0.8wt%.
Batching, mixing and grinding according to the designed formula; feeding the uniformly mixed materials into a glass melting furnace, melting the materials at a high temperature of 1500 ℃ under the furnace pressure of 3Pa to obtain glass liquid; adding molten glass into a preheated mold at 1200 ℃ for molding operation; and then annealing operation is carried out, the annealing temperature is 560 ℃, the annealing time is 0.5h, and finally cooling to room temperature at the speed of 12 ℃/min, so that the white spirit bottle is prepared.
Comparative example 1
As in example 1, yttria was replaced with ceria.
Comparative example 2
As in example 1, the aluminum oxide content was adjusted to 2wt%; the sodium oxide content was adjusted to 9.1wt%.
Comparative example 3
As in example 1, strontium oxide was not added and the calcium oxide content was adjusted to 9wt%.
Performance testing
The white spirit bottles obtained in example 1 and comparative examples 1 to 3 were measured for their thermal expansion coefficients and surface tension. The results are shown in Table 1.
TABLE 1
As can be seen from Table 1, the white spirit bottles obtained in example 1 of the present invention obtained not only lower thermal expansion coefficients but also higher surface tension as compared with comparative examples 1 to 3.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention are included in the protection scope of the present invention.
Claims (1)
1. The glass composition for the white spirit bottles comprises the following components in percentage by weight: silica, aluminum oxide, magnesium oxide, boron oxide, sodium oxide, potassium oxide, calcium oxide, strontium oxide, lithium oxide and yttrium oxide, the balance being other unavoidable impurities;
wherein the content of the silicon dioxide is 71-73wt%;
the content of the aluminum oxide is 2.6-3.2wt%;
the contents of magnesium oxide, diboron trioxide and lithium oxide are respectively 1.5-2.5wt%, 1-2wt% and 0.4-0.8wt%;
the weight ratio of strontium oxide to calcium oxide is 1:4; the sum of the content of calcium oxide and strontium oxide is 8-10wt%;
the weight ratio of the sodium oxide to the potassium oxide is 3:1; the sum of the content of sodium oxide and potassium oxide is 9-12wt%;
the content of yttrium oxide is 0.6-1wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010759519.3A CN111807700B (en) | 2020-07-31 | 2020-07-31 | Glass composition for white spirit bottles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010759519.3A CN111807700B (en) | 2020-07-31 | 2020-07-31 | Glass composition for white spirit bottles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111807700A CN111807700A (en) | 2020-10-23 |
| CN111807700B true CN111807700B (en) | 2023-12-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010759519.3A Active CN111807700B (en) | 2020-07-31 | 2020-07-31 | Glass composition for white spirit bottles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111807700B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114436529A (en) * | 2022-01-07 | 2022-05-06 | 四川中科玻璃有限公司 | White wine bottle glass with low thermal expansion coefficient and high surface tension and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1594166A (en) * | 2003-09-08 | 2005-03-16 | 郭柏驿 | Glass for sealing with metal or alloy |
| CN104024171A (en) * | 2011-10-31 | 2014-09-03 | 旭硝子株式会社 | Glass substrate and method for producing same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6811941B2 (en) * | 2015-07-17 | 2021-01-13 | 日本電気硝子株式会社 | Borosilicate glass for pharmaceutical containers |
| WO2018121491A1 (en) * | 2016-12-29 | 2018-07-05 | 广东东阳光药业有限公司 | Borosilicate glass with high chemical resistance and application thereof |
| CN115716715B (en) * | 2017-02-07 | 2024-09-17 | Ａｇｃ株式会社 | Chemically strengthened glass |
-
2020
- 2020-07-31 CN CN202010759519.3A patent/CN111807700B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1594166A (en) * | 2003-09-08 | 2005-03-16 | 郭柏驿 | Glass for sealing with metal or alloy |
| CN104024171A (en) * | 2011-10-31 | 2014-09-03 | 旭硝子株式会社 | Glass substrate and method for producing same |
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| Publication number | Publication date |
|---|---|
| CN111807700A (en) | 2020-10-23 |
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